CN110510876A - A kind of matting glaze and preparation method thereof - Google Patents
A kind of matting glaze and preparation method thereof Download PDFInfo
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- CN110510876A CN110510876A CN201910871070.7A CN201910871070A CN110510876A CN 110510876 A CN110510876 A CN 110510876A CN 201910871070 A CN201910871070 A CN 201910871070A CN 110510876 A CN110510876 A CN 110510876A
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- parts
- frit
- glaze
- powder
- matting
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of matting glazes and preparation method thereof.The matting glaze, by weight, comprising: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, 0-15 parts of zirconium silicate, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of burning talcum powder, 20-35 parts of Matt frit, 0.5-1 parts of additive；Wherein, by weight, the Matt frit includes: SiO230-50 parts, Al2O315-20 parts, Fe2O30.01-0.5 parts, 3-10 parts of CaO, 0.5-5 parts of MgO, K21-5 parts of O, Na23-10 parts of O, 3-10 parts of ZnO, B2O30.1-1 parts, 10-25 parts of BaO.Inventive formulation reduces formula melting temperature, has widened formula firing range, glaze texture is made to reach fine and smooth matte effect by introducing Matt frit.
Description
Technical field
The present invention relates to ceramic decoration material fields more particularly to a kind of matting glaze and preparation method thereof.
Background technique
Shi porcelain glazed tile (water absorption rate 0.9%-2.5%) modelled after an antique is a kind of ceramic decoration material of modern times pseudo-classic decorated style
Material.In recent years, it is biased to favor of the category glazed tile of dumb light, fine and smooth texture more by the majority of consumers.It is rapidly fired to now
Under (firing time about 45 minutes) process conditions, traditional raw material glaze formula generally passes through introducing infusible compound, is burning glaze
Cheng Shiwei semi-molten state, glaze are muter but relatively rough.
In the prior art, in current Production of Ceramics, the preparation of glaze is usually that raw material weighing and burden is added water for ball milling
To fineness is required, required Ball-milling Time is long (reaching 10-20 hours), and (when summer blowing, glaze slip temperature is high for ball milling glaze slip temperature height
Up to 80 DEG C).It is big that matting glaze glaze slip prepared simultaneously is easy to appear thixotroping, pit problem occurs after leading to glazing.
Therefore, the existing technology needs to be improved and developed.
Summary of the invention
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide matting glazes and preparation method thereof, it is intended to solve
The relatively rough problem of certainly existing dumb light glaze.
A kind of matting glaze, wherein by weight, comprising: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, zirconium silicate 0-15
Part, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of burning talcum powder, add by 20-35 parts of Matt frit
Add 0.5-1 parts of agent；
Wherein, by weight, the Matt frit includes: SiO230-50 parts, Al2O315-20 parts, Fe2O3 0.01-
0.5 part, 3-10 parts of CaO, 0.5-5 parts of MgO, K21-5 parts of O, Na23-10 parts of O, 3-10 parts of ZnO, B2O30.1-1 parts, BaO
10-25 parts.
The matting glaze, wherein the additive is one of carboxymethyl cellulose, sodium tripolyphosphate, water or more
Kind.
A kind of preparation method of matting glaze as described above, wherein include:
The Matt frit is ground into frit powder；
By the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, addition
Agent is mixed to get matting glaze.
The preparation method of the matting glaze, wherein the described the step of Matt frit is ground into frit powder includes:
The raw material for preparing the Matt frit is fired into glass molten slurry, frit granules are made by water quenching；
Frit powder is processed into frit granules ball mill dry grinding.
The preparation method of the matting glaze, wherein described the raw material for preparing the Matt frit is fired into glass to melt
The temperature of slurry is 1380 DEG C -1450 DEG C.
The preparation method of the matting glaze, wherein described by the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium
The step of feldspar, kaolin, calcite, burning talcum powder, additive are mixed to get matting glaze include:
The frit powder is sieved；
By after sieving frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder,
Additive ball milling mixing obtains matting glaze.
The preparation method of the matting glaze, wherein sieve with 100 mesh sieve the frit powder.
The preparation method of the matting glaze, wherein during the ball milling mixing, glaze temperature is 45 in ball mill
℃-50℃。
The preparation method of the matting glaze, wherein further include being carried out to outside ball mill during the ball milling mixing
Shower water.
The utility model has the advantages that inventive formulation reduces formula melting temperature, has widened formula firing by introducing Matt frit
Range makes glaze texture reach fine and smooth matte effect.
Specific embodiment
The present invention provides a kind of matting glaze and preparation method thereof, to make the purpose of the present invention, technical solution and effect more
Clear, clear, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used to
It explains the present invention, is not intended to limit the present invention.
The present invention provides a kind of matting glaze, wherein by weight, comprising: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, silicon
Sour zirconium 0-15 parts, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of burning talcum powder, Matt frit
20-35 parts, 0.5-1 parts of additive；
Wherein, by weight, the Matt frit includes: SiO230-50 parts, Al2O315-20 parts, Fe2O3 0.01-
0.5 part, 3-10 parts of CaO, 0.5-5 parts of MgO, K21-5 parts of O, Na23-10 parts of O, 3-10 parts of ZnO, B2O30.1-1 parts, BaO
10-25 parts.
Compared with traditional glaze formula is by introducing infusible compound production matting glaze, inventive formulation is molten by introducing dumb light
Block (compared with traditional infusible compound, the melting temperature of Matt frit of the present invention is lower), so that it is molten to reduce formula
Melt temperature, widened formula firing range, glaze texture is made to reach fine and smooth matte effect.
It should be noted that zirconium silicate can be added in matting glaze of the present invention, zirconium silicate can not also be added.When not
When adding zirconium silicate, by weight, in matting glaze, the zirconium silicate is 0 part.
The matting glaze, wherein the additive is one of carboxymethyl cellulose, sodium tripolyphosphate, water or more
Kind.The additive can guarantee that prepared slurry reaches certain viscosity requirement.
Further, by weight, Matt frit includes: SiO240 parts, Al2O320 parts, Fe2O30.5 part, CaO 5
Part, 1 part of MgO, K21 part of O, Na25 parts of O, 7 parts of ZnO, B2O30.5 part, 15 parts of BaO.It is melted by the dumb light that said components form
Block can make the dumb light matte effect of glaze texture more fine and smooth.In addition, can also be containing certain in Matt frit in the present invention
The TiO of amount2, i.e., by weight, the Matt frit further includes TiO20-1 parts.
The Matt frit specifically can by by the following raw material be melted form frit after obtain: silica flour, potassium feldspar, life
Zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, barium carbonate.That is, the present invention is by by silica flour, potassium feldspar, life
Zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, barium carbonate can be obtained specific composition after being melted according to certain proportion
Frit.
In a kind of wherein embodiment, the matting glaze, wherein by weight, comprising: 3-5 parts of zinc oxide, carbon
Sour barium 10-15 parts, 5-15 parts of zirconium silicate, 15-20 parts of potassium feldspar, 15-20 parts of kaolin, 10-15 parts of calcite, burning talcum powder 8-
15 parts, 20-30 parts of Matt frit, 0.5-1 parts of additive.
In a kind of wherein embodiment, the matting glaze, wherein by weight, comprising: 4 parts of zinc oxide, carbonic acid
10 parts of barium, 5 parts of zirconium silicate, 15 parts of potassium feldspar, 20 parts of kaolin, 10 parts of calcite, 10 parts of burning talcum powder, 28 parts of Matt frit,
1 part of additive.
The present invention is that product is made to reach super flat, fine and smooth glaze texture, uses leaching glaze glazing process in production process.However it drenches
Glaze handicraft is very high to glaze slip performance requirement, and half fritted glaze glaze slip glaze slip thixotroping of half-feeding is big, glazing pit problem easily occurs.This
Outside, the influence in addition to glaze formula and technological parameter to glaze slip performance, ball milling processing, the conveying, aging process control side of glaze slip
Method also has a great impact to glaze slip performance.
The present invention provides a kind of preparation method of matting glaze as described above, wherein comprising steps of
The Matt frit is ground into frit powder；
By the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, addition
Agent is mixed to get matting glaze.
In the preparation method of matting glaze of the present invention, the Matt frit is ground into frit powder in advance, then with its
His raw material ball milling mixing, avoids because frit granules degree is big, and other raw material particle size (zinc oxide, barium carbonate, zirconium silicate, potassium
Feldspar, kaolin, calcite, burning talcum powder) it is smaller, cause to make in glaze slip there are the raw material that granularity is meticulous glaze slip thixotroping compared with
Greatly.Meanwhile the Matt frit is ground into frit powder in advance by the present invention, moreover it is possible to which reduction is milled to required when requiring fineness
Time.
The present invention by will silica flour, potassium feldspar, raw zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, in barium carbonate
Plurality of raw materials mix according to a certain percentage, the Matt frit of above-mentioned chemical component composition can be obtained after being melted.
In the preparation method of the matting glaze, the granularity of the raw material of the Matt frit is -350 mesh of 180 mesh.This hair
The granularity of the bright raw material for defining Matt frit should not have big difference, and avoid during being melting into Matt frit in frit
Each component mixing is uneven.
The preparation method of the matting glaze, wherein the described the step of Matt frit is ground into frit powder includes:
The Matt frit is burnt into glass molten slurry, frit granules are made by water quenching；
Frit powder is processed into frit granules ball mill dry grinding.
The present invention carries out ball to the frit granules by preparing frit with particle shape, then using ball mill first
Mill, can directly obtain even-grained frit powder.It is certainly, of the present invention that the frit granules are processed into frit powder is unlimited
In above-mentioned grinding mode.
When preparing frit granules, the raw material of the Matt frit specifically directly can be burnt into glass molten slurry by the present invention,
After be directly over water quenching frit granules be made.
It is described that the raw material for preparing the Matt frit is fired into glass molten slurry in the preparation method of the matting glaze
Temperature is 1380 DEG C -1450 DEG C.At described 1380 DEG C -1450 DEG C, the raw material for preparing frit can melt completely to be melted as glass
Slurry.
It is described that the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium is long in the preparation method of the matting glaze
The step of stone, kaolin, calcite, burning talcum powder, additive are mixed to get matting glaze include:
The frit powder is sieved；
By after sieving frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder,
Additive ball milling mixing obtains matting glaze.
Further, in the preparation method of the matting glaze, by the frit powder and zinc oxide, barium carbonate, zirconium silicate,
Potassium feldspar, kaolin, calcite, burning talcum powder sieving；By frit powder, zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolinite
Ball milling obtains matting glaze together for soil, calcite, burning talcum and additive.It that is to say, the present invention is by the raw material in dumb light glaze formula
Sieving processing is all carried out, the uniformity of the granular size of each raw material in formula is improved.
The granularity that the present invention controls when all materials enter ball mill by way of sieving approaches, and it is thin to be milled to requirement
Spend (D50=8.86um) when, it is possible to reduce the generation of the meticulous material material in glaze slip, make glaze slip fineness distribution in it is comparatively ideal just
State distribution, reduces thixotropy, improves glaze slip performance.
It is described that the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium is long in the preparation method of the matting glaze
Stone, kaolin, calcite, burning talcum powder sieving be specially by the frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar,
Kaolin, calcite, burning talcum sieve with 100 mesh sieve respectively.Under normal circumstances, using 100 meshes can allow frit powder and zinc oxide,
Barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder have similar granularity.
By the way that frit powder is processed into the frit granules elder generation ball mill dry grinding in formula, sieving obtains molten under 100 meshes
Block powder to get the frit powder for arriving about 0.1-0.3mm, then by after sieving frit powder and other raw materials weigh ball milling together, can be with
Ball-milling Time is reduced, glaze slip ball milling temperature is reduced, extends additive effective time, reduces in glaze slip and crosses fines, keep glaze slip thin
Degree distribution is in comparatively ideal normal distribution, reduces thixotropy, improves glaze slip performance.
Further, the present invention by frit powder sieve with 100 mesh sieve with 150 meshes, obtain granularity in 100 meshes down toward 150 mesh
Frit powder on sieve；Zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder are equally crossed into 100 mesh
Sieve and 250 meshes, so that the granularity of said components is in 150 meshes in 250 meshes.
In the preparation method of the matting glaze, during the ball milling mixing, glaze temperature is no more than 50 in ball mill
DEG C, glaze slip temperature is 45 DEG C -50 DEG C in the specific whole process such as glaze slip.Further, glaze slip ball milling and conveying,
Cooling measure is used during aging, and glaze slip temperature in the whole process of glaze slip is made to be no more than 50 DEG C, glaze slip performance is stablized,
Produce glazing defect sharp fall.
It further include to progress shower water outside ball mill, specifically, the present invention exists during ball milling mixing of the present invention
Water pipe is installed, in glaze slip ball milling, dress is cooled down using shower water outside ball mill, is further ensured that glaze slip exists above ball mill
Glaze slip temperature is no more than 50 DEG C when ball milling, improves the stability of technique, and the control of glaze slip temperature, which is no more than 50 DEG C, makes additive carboxylic
Methylcellulose CMC rotten problem will not occur because glaze slip temperature is too high.
In addition, glaze slip blowing out of ball mill is sent to stock tank and requires to use compressed air, it is dry that air specifically can be used
Filtering is dried to compressed air in dry machine (workshop uses De Gang Industrial Co., Ltd DK-100AA model), monthly regularly replaces
Drying machine filter core.The present invention is dried filtering by air and avoids bringing oil, water or other impurity into because of compressed air, pollutes glaze
Slurry.
Below by specific embodiment, further description of the technical solution of the present invention.
Comparative example 1
Dumb light glaze formula:
By weight, comprising: 4 parts of zinc oxide, 10 parts of barium carbonate, 5 parts of zirconium silicate, 15 parts of potassium feldspar, 20 parts of kaolin,
10 parts of calcite, 10 parts of burning talcum powder, 28 parts of Matt frit, 1 part of additive；
By weight, Matt frit includes: SiO240 parts, Al2O320 parts, Fe2O30.5 part, 5 parts of CaO, MgO 1
Part, K21 part of O, Na25 parts of O, 7 parts of ZnO, B2O30.5 part, 15 parts of BaO；
The additive is hydroxymethyl cellulose.
The preparation method of matting glaze:
Prepare Matt frit: by silica flour, potassium feldspar, raw zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, carbonic acid
Frit uniformly is melted using tank furnace after mixing said components particle in barium, and glass molten slurry, warp are burnt at 1400 DEG C of firing temperature
It crosses water quenching and frit granules is made.
Prepare matting glaze: according to 1.5 tons of glaze formula ingredient, by other raw material (zinc oxide, carbonic acid in frit powder and formula
Barium, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, additive), it is milled to and requires fineness D50=8.86um, it will
The slurry obtained after ball milling send to stock tank carry out it is aging, matting glaze is prepared.In glaze slip ball milling, fills and adopt outside ball mill
Cooled down with shower water, controls glaze slip glaze slip temperature in ball milling and be no more than 50 DEG C.
This comparative example is not processed into frit powder to the dry grinding of frit granules ball mill in advance, and sieving is not handled yet, but
Frit granules and other raw materials are directly weighed into ball milling together.The matting glaze thixotroping that comparative example 1 is prepared is larger.By dividing
Analysis, compared with other raw material particle sizes, frit granules degree is big, other raw material particle sizes are smaller, causes to exist after glaze slip ball milling
The meticulous raw material of granularity, the Non-Gaussian Distribution of glaze slip 1-0.5mm, glaze slip thixotroping are larger (measurement glaze slip thickness degree).
Meanwhile the raising of additive carboxymethyl cellulose (CMC) viscosity with temperature and decline, but when temperature rise to one timing
(temperature extremes be 50 DEG C), viscosity will be reduced permanently, i.e., during ball milling temperature is greater than 50 DEG C, and glaze slip adds plus agent carboxymethyl cellulose
(CMC) it is easy to appear denaturalization phenomenon.
Embodiment 1
Dumb light glaze formula:
By weight, comprising: 4 parts of zinc oxide, 10 parts of barium carbonate, 5 parts of zirconium silicate, 15 parts of potassium feldspar, 20 parts of kaolin,
10 parts of calcite, 10 parts of burning talcum powder, 28 parts of Matt frit, 1 part of additive；
By weight, Matt frit includes: SiO240 parts, Al2O320 parts, Fe2O30.5 part, 5 parts of CaO, MgO 1
Part, K21 part of O, Na25 parts of O, 7 parts of ZnO, B2O30.5 part, 15 parts of BaO；
The additive is hydroxymethyl cellulose.
The preparation method of matting glaze:
Prepare Matt frit: by silica flour, potassium feldspar, raw zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, carbonic acid
Said components particle is used tank furnace that frit is melted by barium after mixing, and glass molten slurry, warp are burnt at 1400 DEG C of firing temperature
It crosses water quenching and frit granules is made.
Pretreatment: frit powder is processed into the dry grinding of frit granules ball mill, by obtained frit powder, zinc oxide, carbonic acid
Barium, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder sieving, obtain frit powder of 100 meshes in 150 meshes
With zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder of 150 meshes in 250 meshes.
Prepare matting glaze: according to 1.5 tons of glaze formula ingredient, by other raw material (oxygen in the frit powder and formula after sieving
Change zinc, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, additive) it is added to ball in ball mill together
Mill, be milled to and require fineness D50=8.86um, by the slurry obtained after ball milling send to stock tank carry out it is aging, dumb light is prepared
Glaze.
Obtained glaze slip fineness is 325 mesh after the present embodiment ball milling, and tailing over 0.3-0.5%, (laser particle analyzes D50=
8.86um).The processing of the present embodiment frit powder ball milling needs Ball-milling Time about 4 hours, and comparative example 1 is direct using frit granules
Ball milling processing needs ball milling about 6 hours.This example goes out about 45 DEG C of ball temperature using the glaze slip that frit powder ball milling is processed, and comparative example
1 with frit granules ball milling process glaze slip goes out about 55-60 DEG C of ball temperature.The glaze slip of the present embodiment frit powder processing can be reduced
The generation of meticulous material material in glaze slip makes the distribution of glaze slip fineness in comparatively ideal normal distribution, reduces thixotropy, improve
Glaze slip performance.
As it can be seen that by the way that frit granules are shifted to an earlier date pre- levigate ball milling again, than directly being processed originally with frit granules, Ball-milling Time
It can reduce about 2 hours, glaze slip, which goes out ball temperature, reduces about 10 DEG C, while also can be reduced the generation of the meticulous material material in glaze slip,
Make the distribution of glaze slip fineness in comparatively ideal normal distribution, reduces thixotropy, improve glaze slip performance.In advance will in the present embodiment
Frit granules ball milling can reduce Ball-milling Time at frit powder, reduce glaze slip power consumption of polymer processing.
Embodiment 2
Dumb light glaze formula:
By weight, comprising: 4 parts of zinc oxide, 10 parts of barium carbonate, 5 parts of zirconium silicate, 15 parts of potassium feldspar, 20 parts of kaolin,
10 parts of calcite, 10 parts of burning talcum powder, 28 parts of Matt frit, 1 part of additive；
By weight, Matt frit includes: SiO240 parts, Al2O320 parts, Fe2O30.5 part, 5 parts of CaO, MgO 1
Part, K21 part of O, Na25 parts of O, 7 parts of ZnO, B2O30.5 part, 15 parts of BaO；
The additive is hydroxymethyl cellulose.
The preparation method of matting glaze:
Prepare Matt frit: by silica flour, potassium feldspar, raw zinc oxide, boric acid, lime stone, dolomite, aluminium oxide, carbonic acid
Said components particle is used tank furnace that frit is melted by barium after mixing, and glass molten slurry, warp are burnt at 1400 DEG C of firing temperature
It crosses water quenching and frit granules is made.
Pretreatment: frit powder is processed into the dry grinding of frit granules ball mill, by obtained frit powder, zinc oxide, carbonic acid
Barium, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder sieving, obtain frit powder of 100 meshes in 150 meshes
With zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder of 150 meshes in 250 meshes.
Prepare matting glaze: according to 1.5 tons of glaze formula ingredient, by other raw material (oxygen in the frit powder and formula after sieving
Change zinc, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, additive) it is added to ball in ball mill together
Mill, be milled to and require fineness D50=8.86um, by the slurry obtained after ball milling send to stock tank carry out it is aging, dumb light is prepared
Glaze.In glaze slip ball milling, dress is cooled down using shower water outside ball mill, control glaze slip glaze in ball milling and during aging
Slurry temperature degree.The workshop temperature for processing glaze slip requires control within 30 DEG C, and fan is installed above glaze slip delivery chute, passes through delivery chute
Cooling.
In glaze slip ball milling, dress is cooled down the present embodiment using shower water outside ball mill, glaze slip go out ball temperature can be with
Control is within 40 DEG C, by installing fan above glaze slip delivery chute, passes through the cooling of delivery chute, when being sent to storage glaze pond, glaze slip
Temperature can be reduced to 30 DEG C or so, can further avoid additive carboxymethyl cellulose (CMC) in glaze slip and be easy to appear change
Matter phenomenon.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can
With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention
Protect range.
Claims (10)
1. a kind of matting glaze, which is characterized in that by weight, comprising: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, zirconium silicate 0-
15 parts, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of burning talcum powder, 20-35 parts of Matt frit,
0.5-1 parts of additive；
Wherein, by weight, the Matt frit includes: SiO230-50 parts, Al2O315-20 parts, Fe2O3 0.01-0.5
Part, 3-10 parts of CaO, 0.5-5 parts of MgO, K21-5 parts of O, Na23-10 parts of O, 3-10 parts of ZnO, B2O30.1-1 parts, BaO
10-25 parts.
2. matting glaze according to claim 1, which is characterized in that by weight, the Matt frit includes: SiO2 40
Part, Al2O320 parts, Fe2O30.5 part, 5 parts of CaO, 1 part of MgO, K21 part of O, Na25 parts of O, 7 parts of ZnO, B2O30.5 part,
15 parts of BaO.
3. matting glaze according to claim 1, which is characterized in that the additive is carboxymethyl cellulose, tripolyphosphate
One of sodium, water are a variety of.
4. a kind of preparation method of matting glaze as described in claim 1 characterized by comprising
The Matt frit is ground into frit powder；
The frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, additive are mixed
Conjunction obtains matting glaze.
5. the preparation method of matting glaze according to claim 4, which is characterized in that described to be ground into the Matt frit
The step of frit powder includes:
The raw material for preparing the Matt frit is fired into glass molten slurry, frit granules are made by water quenching；
Frit powder is processed into frit granules ball mill dry grinding.
6. the preparation method of matting glaze according to claim 5, which is characterized in that described to prepare the Matt frit
The temperature that raw material is fired into glass molten slurry is 1380 DEG C -1450 DEG C.
7. the preparation method of matting glaze according to claim 4, which is characterized in that described by the frit powder and oxidation
The step of zinc, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, additive are mixed to get matting glaze packet
It includes:
The frit powder is sieved；
By after sieving frit powder and zinc oxide, barium carbonate, zirconium silicate, potassium feldspar, kaolin, calcite, burning talcum powder, addition
Agent ball milling mixing obtains matting glaze.
8. the preparation method of matting glaze according to claim 7, which is characterized in that sieve with 100 mesh sieve the frit powder.
9. the preparation method of matting glaze according to claim 7, which is characterized in that during the ball milling mixing, ball milling
Glaze temperature is 45 DEG C -50 DEG C in machine.
10. the preparation method of matting glaze according to claim 7, which is characterized in that during the ball milling mixing, also wrap
It includes to progress shower water outside ball mill.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111362576A (en) * | 2020-04-28 | 2020-07-03 | 松阳县旭日黑陶工艺厂 | Matte glaze prepared from gold mine tailing powder and processing equipment thereof |
| CN111517647A (en) * | 2020-05-08 | 2020-08-11 | 广西南山瓷器有限公司 | Glaze material for moistening glaze and preparation method thereof |
| CN112919807A (en) * | 2021-01-25 | 2021-06-08 | 青岛硕远硅胶科技有限公司 | Glaze making method for improving smoothness of glaze surface |
| CN114716146A (en) * | 2022-04-15 | 2022-07-08 | 东莞市唯美陶瓷工业园有限公司 | High-white matte fine wear-resistant glaze, ceramic tile and preparation method thereof |
| CN115806389A (en) * | 2023-01-28 | 2023-03-17 | 吴绍昌 | Lithium-free heat-resistant earthenware pot enamel and preparation process thereof |
| CN115819115A (en) * | 2022-10-28 | 2023-03-21 | 康姆罗拉有限公司 | Preparation method of ceramic glaze |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348915A (en) * | 1992-03-31 | 1994-09-20 | Ferro Corporation | High-gloss ceramic frits |
| CN101177353A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Matt glaze and method for manufacturing same |
| CN102557743A (en) * | 2011-12-14 | 2012-07-11 | 陈理敬 | Matt frit and preparation method thereof |
| CN107892589A (en) * | 2018-01-05 | 2018-04-10 | 高安市陶瓷工程中心 | A kind of sheen glaze being used in ceramic thin plate |
| CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
| CN109279919A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of water mill essence stone brick and preparation method thereof |
| CN109320202A (en) * | 2018-10-15 | 2019-02-12 | 广东宏陶陶瓷有限公司 | A kind of Gu stone texture ceramic tile and preparation method thereof |
| CN109455936A (en) * | 2019-01-07 | 2019-03-12 | 佛山市东鹏陶瓷有限公司 | Silk texture and anti-skidding unglazed glaze, preparation method and the ceramic tile using it |
| CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
-
2019
- 2019-09-16 CN CN201910871070.7A patent/CN110510876A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348915A (en) * | 1992-03-31 | 1994-09-20 | Ferro Corporation | High-gloss ceramic frits |
| CN101177353A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Matt glaze and method for manufacturing same |
| CN102557743A (en) * | 2011-12-14 | 2012-07-11 | 陈理敬 | Matt frit and preparation method thereof |
| CN107892589A (en) * | 2018-01-05 | 2018-04-10 | 高安市陶瓷工程中心 | A kind of sheen glaze being used in ceramic thin plate |
| CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
| CN109279919A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of water mill essence stone brick and preparation method thereof |
| CN109320202A (en) * | 2018-10-15 | 2019-02-12 | 广东宏陶陶瓷有限公司 | A kind of Gu stone texture ceramic tile and preparation method thereof |
| CN109455936A (en) * | 2019-01-07 | 2019-03-12 | 佛山市东鹏陶瓷有限公司 | Silk texture and anti-skidding unglazed glaze, preparation method and the ceramic tile using it |
| CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 刘连顺: "改善釉浆触变性的措施", 《陶瓷工程》 * |
| 周晓燕: "《陶瓷坯釉料制备技术》", 31 August 2017, 江西高校出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111362576A (en) * | 2020-04-28 | 2020-07-03 | 松阳县旭日黑陶工艺厂 | Matte glaze prepared from gold mine tailing powder and processing equipment thereof |
| CN111517647A (en) * | 2020-05-08 | 2020-08-11 | 广西南山瓷器有限公司 | Glaze material for moistening glaze and preparation method thereof |
| CN112919807A (en) * | 2021-01-25 | 2021-06-08 | 青岛硕远硅胶科技有限公司 | Glaze making method for improving smoothness of glaze surface |
| CN114716146A (en) * | 2022-04-15 | 2022-07-08 | 东莞市唯美陶瓷工业园有限公司 | High-white matte fine wear-resistant glaze, ceramic tile and preparation method thereof |
| CN114716146B (en) * | 2022-04-15 | 2022-11-29 | 东莞市唯美陶瓷工业园有限公司 | High-white matte fine wear-resistant glaze, ceramic tile and preparation method thereof |
| CN115819115A (en) * | 2022-10-28 | 2023-03-21 | 康姆罗拉有限公司 | Preparation method of ceramic glaze |
| CN115806389A (en) * | 2023-01-28 | 2023-03-17 | 吴绍昌 | Lithium-free heat-resistant earthenware pot enamel and preparation process thereof |
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