CN107474603A - One kind lifting metallized film decay resistance method - Google Patents
One kind lifting metallized film decay resistance method Download PDFInfo
- Publication number
- CN107474603A CN107474603A CN201710753827.3A CN201710753827A CN107474603A CN 107474603 A CN107474603 A CN 107474603A CN 201710753827 A CN201710753827 A CN 201710753827A CN 107474603 A CN107474603 A CN 107474603A
- Authority
- CN
- China
- Prior art keywords
- parts
- metallized film
- coating
- decay resistance
- lifting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/55—Boron-containing compounds
Abstract
The present invention discloses a kind of lifting metallized film decay resistance method, including following operating procedure：（1）After metallized film is cleaned, after surface sprinkling fixer, the 150min of ventilation ventilation process 120 is placed on；（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 12 15 μm；（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.Lifting metallized film decay resistance method provided by the invention, simple to operate, cost is cheap, obtained metallized film, not only good barrier property, elegant in appearance, and its surface has excellent decay resistance, greatly improves the quality of metallized film.
Description
Technical field
The invention belongs to the preparing technical field of metallized film, and in particular to a kind of lifting metallized film decay resistance
Method.
Background technology
Package compound film is generally formed by the Film laminated of several layers of unlike material, from the 1950s come out with
Come, due to its excellent combination property, be widely used in food, medicine, cosmetics, commodity, chemicals, weapon bullet
The industries such as medicine, precision instrument, instrument, complete set of equipments and electronic apparatus.It is aluminum coated composite film its good barrier property, elegant in appearance,
Occupy very big ratio in flexible package.Metallized film has excellent wearability, folding resistance and the barrier to gas, light etc.
Can, and surface has very high metallic luster, and the colour film formed after dyed is quite gorgeous, and cost and price is relatively low, but
Be due to aluminium chemical property it is more active, therefore the surface of aluminizer is easily corroded, and then have impact on its quality.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of method for lifting metallized film decay resistance.
The present invention is achieved by the following technical solutions.
One kind lifting metallized film decay resistance method, including following operating procedure：
（1）After metallized film is cleaned, after surface sprinkling fixer, ventilation ventilation process 120-150min is placed on, wherein
Fixer is made up of the component of following parts by weight：Methylpropene sodium sulfonate 2-5 parts, two molybdic acid hydrate sodium 6-10 parts, ethylenediamine base
Propanesulfonate 14-17 parts, water 240-280 parts；
（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 12-15 μm；Wherein
Coating is made up of the component of following parts by weight：Acrylic acid ester emulsion 80-88 parts, castor oil 4-8 parts, 3- propantheline bromide hydrobromides 5-
7 parts, didecylamine 2-5 parts, butyl borate 11-14 parts；
（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.
Specifically, above-mentioned steps（1）In fixer dosage be 250-300g/m2。
Specifically, above-mentioned steps（2）Middle coating is made of following methods：Successively by castor oil, 3- bromine propylamine hydrobromic acids
Salt, didecylamine, butyl borate are added into acrylic emulsion, after then persistently stirring 30min using 400r/min rotating speed,
Coating is made.
Specifically, above-mentioned steps（3）The temperature of middle drying is 70-80 DEG C.
Technical scheme more than, the beneficial effects of the invention are as follows：
Lifting metallized film decay resistance method provided by the invention, simple to operate, cost is cheap, obtained metallized film,
Not only good barrier property, elegant in appearance, and its surface has excellent decay resistance, greatly improves the product of metallized film
Matter.Fixer provided by the invention, it can effectively strengthen the surface energy of metallized film, enhancing coating is in the viscous of metallized film surface
Attached power；Coating provided by the invention, the film layer formed after drying, has extremely excellent decay resistance；Wherein didecylamine, boron
Sour tributyl can effectively lift uniformity of the coating in metallized film surface distributed, improve the simplification of blade coating.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following examples are carried out to the present invention
It is further described.It should be appreciated that specific embodiment party example described herein is not used to limit only to explain the present invention
The fixed present invention.
Embodiment 1
One kind lifting metallized film decay resistance method, including following operating procedure：
（1）After metallized film is cleaned, after surface sprinkling fixer, ventilation ventilation process 120min is placed on, wherein fixed
Liquid is made up of the component of following parts by weight：2 parts of methylpropene sodium sulfonate, 6 parts of two molybdic acid hydrate sodium, ethylenediamine base propanesulfonate 14
Part, 240 parts of water；
（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 12 μm；Wherein apply
Material is made up of the component of following parts by weight：80 parts of acrylic acid ester emulsion, 4 parts of castor oil, 5 parts of 3- propantheline bromide hydrobromides, didecyl
2 parts of amine, 11 parts of butyl borate；
（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.
Specifically, above-mentioned steps（1）In fixer dosage be 250g/m2。
Specifically, above-mentioned steps（2）Middle coating is made of following methods：Successively by castor oil, 3- bromine propylamine hydrobromic acids
Salt, didecylamine, butyl borate are added into acrylic emulsion, after then persistently stirring 30min using 400r/min rotating speed,
Coating is made.
Specifically, above-mentioned steps（3）The temperature of middle drying is 70 DEG C.
Embodiment 2
One kind lifting metallized film decay resistance method, including following operating procedure：
（1）After metallized film is cleaned, after surface sprinkling fixer, ventilation ventilation process 130min is placed on, wherein fixed
Liquid is made up of the component of following parts by weight：3 parts of methylpropene sodium sulfonate, 8 parts of two molybdic acid hydrate sodium, ethylenediamine base propanesulfonate 16
Part, 260 parts of water；
（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 14 μm；Wherein apply
Material is made up of the component of following parts by weight：86 parts of acrylic acid ester emulsion, 6 parts of castor oil, 6 parts of 3- propantheline bromide hydrobromides, didecyl
3 parts of amine, 12 parts of butyl borate；
（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.
Specifically, above-mentioned steps（1）In fixer dosage be 280g/m2。
Specifically, above-mentioned steps（2）Middle coating is made of following methods：Successively by castor oil, 3- bromine propylamine hydrobromic acids
Salt, didecylamine, butyl borate are added into acrylic emulsion, after then persistently stirring 30min using 400r/min rotating speed,
Coating is made.
Specifically, above-mentioned steps（3）The temperature of middle drying is 75 DEG C.
Embodiment 3
One kind lifting metallized film decay resistance method, including following operating procedure：
（1）After metallized film is cleaned, after surface sprinkling fixer, ventilation ventilation process 150min is placed on, wherein fixed
Liquid is made up of the component of following parts by weight：5 parts of methylpropene sodium sulfonate, 10 parts of two molybdic acid hydrate sodium, ethylenediamine base propanesulfonate
17 parts, 280 parts of water；
（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 15 μm；Wherein apply
Material is made up of the component of following parts by weight：88 parts of acrylic acid ester emulsion, 8 parts of castor oil, 7 parts of 3- propantheline bromide hydrobromides, didecyl
5 parts of amine, 14 parts of butyl borate；
（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.
Specifically, above-mentioned steps（1）In fixer dosage be 300g/m2。
Specifically, above-mentioned steps（2）Middle coating is made of following methods：Successively by castor oil, 3- bromine propylamine hydrobromic acids
Salt, didecylamine, butyl borate are added into acrylic emulsion, after then persistently stirring 30min using 400r/min rotating speed,
Coating is made.
Specifically, above-mentioned steps（3）The temperature of middle drying is 80 DEG C.
Metallized film is made with the method for each embodiment respectively, then according to GB/T 1771-2007《Paint and varnish is resistance to
The measure of neutral salt spray performance》The salt fog resistance of film is determined, according to GB/T 5210-1985《The measure farad of coating adhesion
Open method》Adhesive force of the film on vacuum aluminized film is determined, test result is as shown in table 1：
The performance test results of the metallized film face coat of table 1
| Project | Salt fog resistance/level | Adhesive force/(N/mm2) |
| Embodiment 1 | 1 | 0.96 |
| Embodiment 2 | 1 | 0.98 |
| Embodiment 3 | 1 | 0.99 |
As shown in Table 1, metallized film produced by the present invention, there is extremely excellent decay resistance, and the surface of paint film is attached
Put forth effort height, it is difficult for drop-off.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (4)
1. one kind lifting metallized film decay resistance method, it is characterised in that including following operating procedure：
（1）After metallized film is cleaned, after surface sprinkling fixer, ventilation ventilation process 120-150min is placed on, wherein
Fixer is made up of the component of following parts by weight：Methylpropene sodium sulfonate 2-5 parts, two molybdic acid hydrate sodium 6-10 parts, ethylenediamine base
Propanesulfonate 14-17 parts, water 240-280 parts；
（2）Then by step（1）Spreed coated paint on the metallized film of processing so that the thickness of coating is 12-15 μm；Wherein
Coating is made up of the component of following parts by weight：Acrylic acid ester emulsion 80-88 parts, castor oil 4-8 parts, 3- propantheline bromide hydrobromides 5-
7 parts, didecylamine 2-5 parts, butyl borate 11-14 parts；
（3）The metallized film that blade coating is coated is placed and dried in an oven, finished product.
2. according to a kind of lifting metallized film decay resistance method described in claim 1, it is characterised in that above-mentioned steps
（1）In fixer dosage be 250-300g/m2。
3. according to a kind of lifting metallized film decay resistance method described in claim 1, it is characterised in that above-mentioned steps
（2）Middle coating is made of following methods：Castor oil, 3- propantheline bromide hydrobromides, didecylamine, butyl borate are added successively
Into acrylic emulsion, after then persistently stirring 30min using 400r/min rotating speed, coating is made.
4. according to a kind of lifting metallized film decay resistance method described in claim 1, it is characterised in that above-mentioned steps
（3）The temperature of middle drying is 70-80 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710753827.3A CN107474603A (en) | 2017-08-29 | 2017-08-29 | One kind lifting metallized film decay resistance method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710753827.3A CN107474603A (en) | 2017-08-29 | 2017-08-29 | One kind lifting metallized film decay resistance method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107474603A true CN107474603A (en) | 2017-12-15 |
Family
ID=60603833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710753827.3A Pending CN107474603A (en) | 2017-08-29 | 2017-08-29 | One kind lifting metallized film decay resistance method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107474603A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987652A (en) * | 2017-12-23 | 2018-05-04 | 阜阳市阜寿缘生态农业科技有限责任公司 | A kind of preparation method of harvester resistant casing |
| CN108558211A (en) * | 2018-04-23 | 2018-09-21 | 卢皆彬 | A kind of low fever at temperature metal bright glaze preparation method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050245651A1 (en) * | 2004-05-03 | 2005-11-03 | Robin Cooper | Primer coating for enhancing adhesion of liquid toner to polymeric substrates |
| CN102127277A (en) * | 2010-01-19 | 2011-07-20 | 苗小胜 | Water soluble polymer mixed emulsion, coating and preparation method thereof |
-
2017
- 2017-08-29 CN CN201710753827.3A patent/CN107474603A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050245651A1 (en) * | 2004-05-03 | 2005-11-03 | Robin Cooper | Primer coating for enhancing adhesion of liquid toner to polymeric substrates |
| CN102127277A (en) * | 2010-01-19 | 2011-07-20 | 苗小胜 | Water soluble polymer mixed emulsion, coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987652A (en) * | 2017-12-23 | 2018-05-04 | 阜阳市阜寿缘生态农业科技有限责任公司 | A kind of preparation method of harvester resistant casing |
| CN108558211A (en) * | 2018-04-23 | 2018-09-21 | 卢皆彬 | A kind of low fever at temperature metal bright glaze preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103129047B (en) | Crystal color plate and preparation method thereof | |
| CN103129302B (en) | Cold pad pasting Coil Coating Products and preparation method thereof | |
| US11660636B2 (en) | Aluminum alloy coating, aluminum alloy wheel hub and spraying method of aluminum alloy wheel hub | |
| CN105365233B (en) | The preparation method of the compound high light film of imitative metal wire-drawing | |
| CN107474603A (en) | One kind lifting metallized film decay resistance method | |
| CN106313785A (en) | Three-colored metal imitate steel brushed printed colored steel plate | |
| CN105599388A (en) | Wire drawing type printed color steel plate for household electrical appliances and production method thereof | |
| CN104928620A (en) | Preparation method of vacuum aluminum plating film for reinforcing aluminum layer adhesion strength | |
| CN107670941A (en) | A kind of method for lifting stamping parts resistance to chemical corrosion | |
| US2875919A (en) | Method for applying and metal coating composition of a butadiene resin and organic derivative of titanium | |
| CN107962835A (en) | A kind of colored pre-coated steel plate and its preparation process with antibacterial effect | |
| CN109072562A (en) | Pearly-lustre metal effect paper wood material and relative manufacturing process with high-light-fastness | |
| CN111534188A (en) | Quick-drying environment-friendly coating for surface treatment of mechanical equipment and preparation method thereof | |
| CN102529554A (en) | Color printed steel plate continuous production process | |
| AU634652B2 (en) | Process of aftertreating conversion layers | |
| CN204036970U (en) | A kind of high-performance metal thin plate | |
| CN108864896A (en) | anti-corrosion steel plate and preparation method thereof | |
| CN211647063U (en) | Graphene powder coated aluminum veneer for architectural decoration | |
| CN108359371A (en) | A kind of high clarity printing colored steel and preparation method thereof | |
| CN106543900A (en) | A kind of environment friendly corrosion protection paint | |
| CN105442387A (en) | Coating for aluminium plated paper and spraying technology for aluminium plated paper | |
| JP2011208036A (en) | Undercoat agent for plastic with inorganic thin film, plastic film with inorganic thin film, decoration film for in-mold forming and decoration film for insert molding | |
| US3462319A (en) | Process for coating metal surfaces | |
| CN203267346U (en) | Crystal color plate | |
| CN111455364A (en) | Environment-friendly chromium-free passivation solution based on silicate and passivation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |