CN109072562A - Pearly-lustre metal effect paper wood material and relative manufacturing process with high-light-fastness - Google Patents

Pearly-lustre metal effect paper wood material and relative manufacturing process with high-light-fastness Download PDF

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Publication number
CN109072562A
CN109072562A CN201780009267.9A CN201780009267A CN109072562A CN 109072562 A CN109072562 A CN 109072562A CN 201780009267 A CN201780009267 A CN 201780009267A CN 109072562 A CN109072562 A CN 109072562A
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CN
China
Prior art keywords
carrier
paper wood
wood material
coating
pearlescent pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201780009267.9A
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Chinese (zh)
Other versions
CN109072562B (en
Inventor
卢卡·蒙纳塞莉
费鲁乔·贝尼亚米诺·吉尔伯蒂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gruppo Cordenons S P A
Gruppo Cordenons SpA
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Gruppo Cordenons S P A
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Publication of CN109072562A publication Critical patent/CN109072562A/en
Application granted granted Critical
Publication of CN109072562B publication Critical patent/CN109072562B/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/005—Mechanical treatment

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

A kind of paper wood material, the paper wood material includes carrier is carrier, the carrier is carrier is made of the mixture of cellulose fibre, the cellulose fibre includes at least one polymer material for being suitable for generating the mixture with fiber mechanical strength and inorganic filler, the surface that there is the carrier is carrier at least one to be handled at least one surface cement is applied to the coating on the processed surface at least one, and the coating includes at least the pearlescent pigment of high-light-fastness.

Description

Pearly-lustre metal effect paper wood material and relative manufacturing process with high-light-fastness
Specification
The present invention relates to paper wood material (paper wood/card) and relative manufacturing process.
In paper industry, the novel paper wood with specific feature and covering with paint is constantly looked for, packaging is especially designed to, beats The paper wood of packet, realization expository material, good printing etc..
However, the realization of special-effect be to other characteristics such as impressionability of paper wood it is unfavorable, this is much.
Technical assignment of the invention is to provide a kind of paper wood material, imitates with the optics different from conventional paper wood material Fruit, while can be printed with high printing quality.
The technical assignment is solved by a kind of paper wood material, which includes carrier is carrier, the carrier is carrier by The mixture of cellulose fibre is made, which includes at least one mixing for being suitable for generation and having fiber mechanical strength The polymer material of object and inorganic filler, the table that there is the carrier is carrier at least one to be handled at least one surface cement Face is applied to the coating on the processed surface at least one, it is characterised in that the coating includes at least high-light-fastness Pearlescent pigment.
The invention also discloses a kind of methods for manufacturing paper wood material, method includes the following steps:
The water-containing pulp of cellulose fibre is prepared, which includes at least one suitable for generating with fibre machine The polymer material of the mixture of tool intensity and inorganic filler；
Water is removed, from paper pulp to form the carrier is carrier of paper wood material；
With at least one surface of at least one surface cement processing carrier is carrier；
It is smoothed on the processed surface of carrier is carrier；
The coating for including at least the pearlescent pigment of high-light-fastness is applied to the surface of the smoothing processing.
In a preferred embodiment, pearlescent pigment is borosilicate or aluminosilicate, and specifically mica.
In a preferred embodiment, pearlescent pigment be coated with metal oxide such as iron oxide, titanium oxide or The transparent borosilicate or aluminosilicate of tin oxide.
In a preferred embodiment, pearlescent pigment has various colors, granularity and shape.
In a preferred embodiment, coating include in one kind of the form of mixtures of the pearlescent pigment or more Kind binder polymer and/or wax.
In a preferred embodiment, coating include in the pearlescent pigment and with magnetic or diamagnetism metal face The one or more binder polymers and/or wax of the form of mixtures of material.
In a preferred embodiment, metallic pigments have various colors, granularity and shape.
In a preferred embodiment, the metal effect pigments of coating are commonly used in those of outdoor stages paint.
Therefore, coating includes pearlescent pigment, and optionally including metallic pigments and pearlescent pigment.
In addition, coating also may include organic and inorganic pigment other than pearlescent pigment and metallic pigments.
Also may be present includes organic or inorganic pigment in carrier is carrier, can be coloured.
Therefore, because the paper pulp and particular surface coating treatment that specially design, the present invention provides the pearly-lustres of high-light-fastness Paper wood material (paper wood/card).
Paper wood material of the invention may also prove to high printing quality perfect printing, and can realize utilization The specific graphical effect that the paper wood routinely coated is difficult to realize.
In particular, paper wood material of the invention includes the carrier is carrier made of the mixture of cellulose fibre, and It includes at least one polymer materials for being suitable for generating the mixture with fiber mechanical strength (when drying or wetting), and Suitable for assigning the inorganic filler of the well processable characteristic of material.
Carrier is carrier has at least one surface handled at least one surface cement that coating is applied thereto (face), so that paper wood material has the pearl with various colors due to the composition of carrier is carrier and the combined effect of surface treatment Light effect.Obviously, two faces of carrier is carrier can be handled in an identical manner.
Preferably, include the polymer material in carrier is carrier include it is one or more based on rosin and/or Resin and/or modified starch based on alkyl ketone group dimer and/or based on acetyl succinic acid and/or based on epoxychloropropane； And inorganic filler be mineral filler, the mineral filler include it is one or more selected from carbonate, kaolin, talcum and they Mixture substance.
Surface cement is for example based on starch and/or based on polyvinyl alcohol and/or acrylic acid, polyurethane and/or benzene second The adhesive of alkene-butadiene polymer.
As described above, paper wood material according to the present invention is equipped with coating, it is applied on treated surface, and obviously, Paper wood material can have processed surface and set both cated surfaces.
In particular, coating by one or more binder polymers (such as based on polyurethane and/or siloxanes, and/or Acrylic acid, styrene-butadiene, polyvinyl acetate, polymer of polyvinyl alcohol etc.) and/or wax formed, in dyestuff and The form of the mixture of pigment for example, having various colors, granularity and shape, and has the ultraviolet light component exposure to sunlight The pearlescent pigment of stable characteristic.
The amount of polymers in every face accounts between 5 weight % and 100 weight % preferably with respect to pigment；The paper wood base of paper wood material About 90g/m is accounted for again2About 450g/m2Between；The amount for sprawling coating on each face accounts for about 5g/m2About 20g/m2Between.
It coating pigmentable and/or spreads on the carrier is carrier through colouring；It is preferable to use coloring paste and organic or inorganics Pigment.
According to another aspect of the present invention, paper wood material described above is realized using following methods.
First technology is formed using substantially known paper wood, such as realize on the sequential machine for manufacturing paper wood Carrier is carrier.
Substantially, water-containing pulp is prepared, the water-containing pulp includes the mixture of cellulose fibre and includes polymer Substance (it is based on rosin and/or based on alkyl ketone group and/or based on acetyl group succinic acid and/or based on the resin of chloropropane, And/or modified starch) and inorganic filler (carbonate, kaolin, talcum etc.).
Then, water is removed from the paper pulp, to form the carrier is carrier of paper wood material.
Later, the step of carrying out one or two face with the aqueous solution surface treatment carrier is carrier of surface cement, The aqueous solution of the surface cement is for example by the aqueous solution of 10 weight % starch and/or 5 weight % acrylic adhesives Agent or similar adhesive agent composition.
After being surface-treated with adhesive, then this method includes the smoothing step of carrier is carrier, wherein by base Plinth carrier is smoothly until 2494 roughness value of Bendtsen ISO is less than about 450ml/min., preferably less than about 400ml/ Min, and about 350ml/min or so carry out the application step of aforementioned coatings later.
Preferably, it is applied by being sprawled with air knife or smooth blade, rotation offset, rotation engraving and flexible platemaking technology The application of layer.
Then, the step of coating is dried, the step is in infrared and/or air oven at about 100 DEG C to about 180 At a temperature in the range of DEG C, and carried out in the baking oven time between 0.5 minute and 4 minutes in range.
Finally, the step of setting cated surface the method includes mechanical treatment, specifically smooth and/or embossing step Suddenly.
Still it should be understood that, it may be considered that it is disclosed herein and explanation paper wood material and relative manufacturing process, to carry out Without departing from the modifications and variations of the scope of the invention as defined by the appended claims.

Claims (16)

1. a kind of paper wood material, the paper wood material includes carrier is carrier, the carrier is carrier by cellulose fibre mixture Composition, the cellulose fibre include it is at least one be suitable for generate have fiber mechanical strength mixture polymer material and Inorganic filler, the surface that there is the carrier is carrier at least one to be handled at least one surface cement are applied at least one Coating on the processed surface, it is characterised in that the coating includes at least the pearlescent pigment of high-light-fastness.
2. paper wood material according to claim 1, it is characterised in that the pearlescent pigment has various colors, granularity and shape Shape.
3. paper wood material according to claim 1, it is characterised in that the coating includes in mixed with the pearlescent pigment The one or more binder polymers and/or wax of solvate form.
4. paper wood material according to claim 1, it is characterised in that the coating include in the pearlescent pigment and with The one or more binder polymers and/or wax of magnetic or diamagnetism metallic pigments form of mixtures.
5. paper wood material according to any one of the preceding claims, it is characterised in that the pearlescent pigment is borosilicate Or aluminosilicate.
6. the paper wood material according to preceding claims, it is characterised in that the pearlescent pigment is coated with metal oxide Transparent borosilicate or aluminosilicate.
7. paper wood material according to any one of the preceding claims, it is characterised in that include in the carrier is carrier The polymer material includes one or more based on rosin and/or based on alkyl ketone group dimer and/or is based on acetyl amber Amber acid and/or resin and/or modified starch based on epoxychloropropane.
8. paper wood material according to any one of the preceding claims, it is characterised in that the inorganic filler is filled out for mineral Material, and it includes one or more substances selected from carbonate, kaolin, talcum and their mixture.
9. paper wood material according to any one of the preceding claims, it is characterised in that the surface cement is based on shallow lake The adhesive of powder and/or polyvinyl alcohol and/or acrylic acid, polyurethane and/or styrene-butadiene.
10. the paper wood material according to any one of claim 3 to 8, it is characterised in that the binder polymer includes Polymer based on polyurethane, acrylic acid, polyvinyl alcohol, styrene-butadiene and/or siloxanes.
11. a kind of method for manufacturing paper wood material, the described method comprises the following steps:
The water-containing pulp of cellulose fibre is prepared, the cellulose fibre includes at least one mechanical with fiber suitable for generating The polymer material of the mixture of intensity and inorganic filler；
Water is removed from the paper pulp, to form the carrier is carrier of the paper wood material；
At least one surface of the carrier is carrier is handled at least one surface cement；
It is smoothed on the processed surface of the carrier is carrier；
The coating for including at least the pearlescent pigment of high-light-fastness is applied to the surface of the smoothed processing.
12. the method according to preceding claims, it is characterised in that by the processed smooth surface until It is left that 2494 roughness value of Bendtsen ISO is less than about 450ml/min, preferably less than about 400ml/min and about 350ml/min It is right.
13. method described in 0 or 11 according to claim 1, it is characterised in that be applied to the painting on the processed surface Layer is comprising in form of mixtures, the pearlescent pigment, magnetism or diamagnetism metallic pigments and one or more binders are poly- Close object and/or wax.
14. method according to any one of claims 10 to 12, it is characterised in that the step of applying the coating passes through It is sprawled with air knife or smooth blade to carry out.
15. method described in any one of 0 to 13 according to claim 1, it is characterised in that the method includes the drying paintings Layer the step of, the step in infrared and/or air oven at a temperature in the range of about 100 DEG C to about 180 DEG C, and It is carried out in the baking oven time between 0.5 minute and 4 minutes in range.
16. according to the method for claim 14, it is characterised in that after the drying coating, carry out mechanical treatment and be equipped with The step of surface of the coating, specifically smoothing step and/or embossing step.
CN201780009267.9A 2016-02-01 2017-02-01 Pearlescent metallic effect paper material with high light resistance and related manufacturing method Active CN109072562B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITUB2016A000512A ITUB20160512A1 (en) 2016-02-01 2016-02-01 PAPER MATERIAL WITH A HIGH SOLID METAL PERLESCENT EFFECT IN LIGHT AND ITS MANUFACTURING PROCEDURE
IT102016000010127 2016-02-01
PCT/EP2017/052094 WO2017134071A1 (en) 2016-02-01 2017-02-01 Pearlescent metallic effect paper material with high lightfastness and related manufacturing method

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CN109072562A true CN109072562A (en) 2018-12-21
CN109072562B CN109072562B (en) 2021-10-29

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CN201780009267.9A Active CN109072562B (en) 2016-02-01 2017-02-01 Pearlescent metallic effect paper material with high light resistance and related manufacturing method

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US (1) US20190040583A1 (en)
EP (1) EP3405613B1 (en)
CN (1) CN109072562B (en)
ES (1) ES2786574T3 (en)
IT (1) ITUB20160512A1 (en)
WO (1) WO2017134071A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3081365A1 (en) * 2017-11-17 2019-05-23 Imerys Usa, Inc. Heat-seal coatings
WO2023126114A1 (en) * 2021-12-28 2023-07-06 Gruppo Cordenons S.P.A. Paper material with virucidal, biocidal and barrier properties to water, fats and oils
IT202100032753A1 (en) * 2021-12-28 2023-06-28 Gruppo Cordenons Spa TOTALLY CLOSURE PAPER MATERIAL PARTICULARLY FOR USE IN THE FOOD INDUSTRY

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CN1246902A (en) * 1997-02-06 2000-03-08 默克专利股份有限公司 Papers and cardboard products suitable for laser marking, method for producing same and their use for packaging materials, bank notes and securities, security paper and graphic products
EP2520709A1 (en) * 2011-05-06 2012-11-07 GRUPPO CORDENONS S.p.A. Sand-effect paper material and corresponding manufacturing method
US20130216597A1 (en) * 2010-10-26 2013-08-22 Merck Patent Gmbh Pigments
CN103498386A (en) * 2013-10-16 2014-01-08 湖北工业大学 Pearlescent pigment anti-fake cigarette paper and manufacturing method thereof
WO2014198780A1 (en) * 2013-06-13 2014-12-18 Gruppo Cordenons S.P.A. Paper material having holographic and pearlescent metallic effects and the manufacturing process thereof

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ATE366844T1 (en) * 1997-09-30 2007-08-15 Nalco Chemical Co PRODUCTION OF PAPER WITH COLLOIDAL BOROSILICATES
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CN1246902A (en) * 1997-02-06 2000-03-08 默克专利股份有限公司 Papers and cardboard products suitable for laser marking, method for producing same and their use for packaging materials, bank notes and securities, security paper and graphic products
US20130216597A1 (en) * 2010-10-26 2013-08-22 Merck Patent Gmbh Pigments
EP2520709A1 (en) * 2011-05-06 2012-11-07 GRUPPO CORDENONS S.p.A. Sand-effect paper material and corresponding manufacturing method
WO2014198780A1 (en) * 2013-06-13 2014-12-18 Gruppo Cordenons S.P.A. Paper material having holographic and pearlescent metallic effects and the manufacturing process thereof
CN103498386A (en) * 2013-10-16 2014-01-08 湖北工业大学 Pearlescent pigment anti-fake cigarette paper and manufacturing method thereof

Also Published As

Publication number Publication date
EP3405613B1 (en) 2020-01-22
ITUB20160512A1 (en) 2017-08-01
ES2786574T3 (en) 2020-10-13
WO2017134071A1 (en) 2017-08-10
US20190040583A1 (en) 2019-02-07
EP3405613A1 (en) 2018-11-28
CN109072562B (en) 2021-10-29

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