ITMI20110779A1 - SAND MATERIAL WITH EFFECT - SAND AND ITS MANUFACTURING PROCEDURE - Google Patents

SAND MATERIAL WITH EFFECT - SAND AND ITS MANUFACTURING PROCEDURE Download PDF

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Publication number
ITMI20110779A1
ITMI20110779A1 IT000779A ITMI20110779A ITMI20110779A1 IT MI20110779 A1 ITMI20110779 A1 IT MI20110779A1 IT 000779 A IT000779 A IT 000779A IT MI20110779 A ITMI20110779 A IT MI20110779A IT MI20110779 A1 ITMI20110779 A1 IT MI20110779A1
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IT
Italy
Prior art keywords
paper material
pigments
patina
kaolins
base support
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IT000779A
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Italian (it)
Inventor
Ferruccio Gilberti
Luca Monacelli
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Gruppo Cordenons Spa
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Application filed by Gruppo Cordenons Spa filed Critical Gruppo Cordenons Spa
Priority to IT000779A priority Critical patent/ITMI20110779A1/en
Priority to EP12167036.8A priority patent/EP2520709B1/en
Priority to ES12167036.8T priority patent/ES2579057T3/en
Priority to PT121670368T priority patent/PT2520709T/en
Publication of ITMI20110779A1 publication Critical patent/ITMI20110779A1/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/66Coatings characterised by a special visual effect, e.g. patterned, textured

Description

DESCRIZIONE DESCRIPTION

“MATERIALE CARTACEO AD EFFETTO-SABBIA E RELATIVO PROCEDIMENTO DI FABBRICAZIONE†⠀ œ PAPER MATERIAL WITH SAND EFFECT AND RELATED MANUFACTURING PROCESSâ €

La presente invenzione si riferisce ad un materiale cartaceo (carta/cartoncino) ad effetto-ruvido sabbia e al relativo procedimento di fabbricazione; più precisamente, il materiale cartaceo dell’invenzione, grazie ad un impasto appositamente studiato e ad uno specifico trattamento superficiale, perde al tatto le caratteristiche tipiche dei materiali cartacei e si caratterizza per un effetto al tatto simile alla sabbia. The present invention refers to a paper material (paper / cardboard) with a rough sand effect and to the relative manufacturing process; more precisely, the paper material of the invention, thanks to a specially studied mixture and a specific surface treatment, loses to the touch the typical characteristics of paper materials and is characterized by a touch effect similar to sand.

Nel settore cartario à ̈ costante la ricerca di nuovi tipi di carte aventi aspetti e/o finiture particolari, soprattutto destinate all’imballaggio, al confezionamento, alla realizzazione di materiale illustrativo, alla stampa di qualità, eccetera. In the paper sector there is a constant search for new types of paper with particular aspects and / or finishes, especially intended for packaging, wrapping, the creation of illustrative material, quality printing, and so on.

Non di rado, però, l’ottenimento di effetti particolari pregiudica altre caratteristiche della carta, ad esempio la stampabilità. Not infrequently, however, the achievement of particular effects jeopardizes other characteristics of the paper, such as printability.

È uno scopo della presente invenzione quello di fornire un materiale cartaceo che abbia un effetto al tatto differente dai tradizionali materiali cartacei e sia al contempo stampabile con elevata qualità di stampa. It is an object of the present invention to provide a paper material which has a different touch effect from traditional paper materials and is at the same time printable with high printing quality.

La presente invenzione à ̈ dunque relativa ad un materiale cartaceo e al relativo procedimento di fabbricazione come definiti nelle annesse rivendicazioni 1 e, rispettivamente, 8. The present invention therefore relates to a paper material and the related manufacturing process as defined in the attached claims 1 and 8, respectively.

Preferite forme di attuazione del materiale cartaceo e del relativo procedimento di fabbricazione sono definite nelle rivendicazioni dipendenti da 2 a 7 e, rispettivamente, da 9 a 18. Preferred embodiments of the paper material and of the relative manufacturing process are defined in the dependent claims 2 to 7 and, respectively, 9 to 18.

L’invenzione fornisce dunque un materiale cartaceo (carta/cartoncino) ad effetto sabbia il quale, grazie ad un impasto appositamente studiato e ad uno specifico trattamento superficiale, perde al tatto le caratteristiche tipiche dei materiali cartacei e si caratterizza per un effetto al tatto simile alla sabbia, avendo una finitura superficiale ruvida tipica di una superficie coperta di sabbia fine. The invention therefore provides a paper material (paper / cardboard) with a sand effect which, thanks to a specially designed mixture and a specific surface treatment, loses the typical characteristics of paper materials to the touch and is characterized by a touch effect similar to sand, having a rough surface finish typical of a surface covered with fine sand.

Il materiale cartaceo dell’invenzione risulta inoltre perfettamente stampabile con elevata qualità di stampa e consente di ottenere effetti grafici particolari, difficili da ottenere con tradizionali carte patinate. The paper material of the invention is also perfectly printable with high printing quality and allows to obtain particular graphic effects, difficult to obtain with traditional coated papers.

In dettaglio, il materiale cartaceo del trovato comprende un supporto base che à ̈ formato da una miscela di fibre cellulosiche e contiene almeno una sostanza polimerica, atta a conferire alla miscela di fibre resistenza meccanica (a secco e ad umido), e una carica inorganica, atta a conferire al materiale buone caratteristiche di macchinabilità. In detail, the paper material of the invention comprises a base support which is formed by a mixture of cellulosic fibers and contains at least one polymeric substance, capable of giving the mixture of fibers mechanical strength (dry and wet), and an inorganic filler , able to give the material good machinability characteristics.

Il supporto base ha almeno una superficie (faccia) trattata con almeno un collante superficiale ed una patina aventi particolari componenti, in modo tale che il materiale cartaceo, per effetto combinato della composizione del supporto base e del trattamento superficiale, abbia un effetto al tatto simile alla sabbia. Chiaramente, entrambe le facce del supporto base possono essere trattate allo stesso modo. The base support has at least one surface (face) treated with at least one surface glue and a patina having particular components, so that the paper material, due to the combined effect of the composition of the base support and the surface treatment, has a similar touch effect. to the sand. Clearly, both faces of the base support can be treated equally.

Preferibilmente, la sostanza polimerica inclusa nel supporto base comprende una o più resine a base di colofonia e/o di alchil chetene dimero e/o di acido acetil succinico e/o di epocloridrina, e/o amidi modificati; e la carica inorganica à ̈ una carica minerale comprendente una o più sostanze scelte nel gruppo costituito da carbonati, caolini, talco, loro miscele. Preferably, the polymeric substance included in the base support comprises one or more resins based on rosin and / or alkyl ketene dimer and / or acetyl succinic acid and / or epochlorhydrin, and / or modified starches; and the inorganic filler is a mineral filler comprising one or more substances selected from the group consisting of carbonates, kaolins, talc, their mixtures.

Il collante superficiale à ̈ per esempio un collante a base di amido e/o di alcol polivinilico e/o di polimeri acrilici, poliuretanici e/o stirolo-butadienici. The surface adhesive is, for example, an adhesive based on starch and / or polyvinyl alcohol and / or acrylic, polyurethane and / or styrene-butadiene polymers.

Inoltre, il materiale cartaceo dell’invenzione à ̈ provvisto di una patina, applicata sulla superficie trattata (chiaramente, il materiale cartaceo può avere entrambe le superfici trattate e provviste di patina). In addition, the paper material of the invention is provided with a patina, applied to the treated surface (clearly, the paper material can have both surfaces treated and coated with patina).

In particolare, la patina à ̈ formata da uno o più polimeri leganti (per esempio polimeri a base poliuretanica e/o siliconica, e/o polimeri acrilici, stirolo-butadienici, polivinil-acetati, alcol polivinilico, e similari) e/o cere, in miscela con pigmenti, per esempio pigmenti a struttura lamellare o piatta, come ad esempio carbonato di calcio precipitato (PCC), caolini per patinatura, caolini calcinati e/o lamellari, in abbinamento a pigmenti a base di silicati di calcio aventi diversa granulometria e grado di bianco superiore a circa 85 (secondo la norma DIN 5033). In particular, the patina is formed by one or more binding polymers (for example polyurethane and / or silicone based polymers, and / or acrylic, styrene-butadiene polymers, polyvinyl acetates, polyvinyl alcohol, and the like) and / or waxes , mixed with pigments, for example pigments with a lamellar or flat structure, such as precipitated calcium carbonate (PCC), kaolins for coating, calcined and / or lamellar kaolins, in combination with pigments based on calcium silicates having different granulometry and whiteness higher than about 85 (according to DIN 5033).

Proprio questi pigmenti a base di silicati di calcio, aventi preferibilente particelle di granulometria varia (cioà ̈ dimensioni diverse) e un particolare grado di bianco sono di particolare importanza per il risultato desiderato. Precisely these pigments based on calcium silicates, preferably having particles of various granulometry (ie different sizes) and a particular degree of whiteness, are of particular importance for the desired result.

In particolare, i pigmenti comprendono wallastonite (silicato di calcio di formula CaSiO3). In particular, the pigments include wallastonite (calcium silicate of the formula CaSiO3).

Preferibilmente, la quantità di polimero per faccia à ̈ preferibilmente compresa tra 5% e 100% rispetto ai pigmenti; la grammatura del materiale cartaceo à ̈ compresa tra circa 90 e circa 350 g/mq; la quantità di patina spalmata su ciascuna faccia à ̈ compresa tra circa 5 e circa 20 g/mq. Preferably, the amount of polymer per face is preferably comprised between 5% and 100% with respect to the pigments; the weight of the paper material is between about 90 and about 350 g / m2; the amount of patina spread on each face is between about 5 and about 20 g / m2.

La patina può essere colorata e/o spalmata su un supporto base colorato; preferibilmente, si usano colori in pasta e pigmenti organici o inorganici. The patina can be colored and / or spread on a colored base support; preferably, paste colors and organic or inorganic pigments are used.

Il materiale cartaceo appena descritto viene realizzato, in accordo con un ulteriore aspetto della presente invenzione, con il metodo seguente. The paper material just described is made, in accordance with a further aspect of the present invention, with the following method.

Viene realizzato dapprima il supporto base, con tecnica di formazione della carta sostanzialmente nota, per esempio su una macchina continua per la fabbricazione della carta. The basic support is first made, with a substantially known paper forming technique, for example on a paper making machine.

In sostanza, si predispone un impasto acquoso di fibre di cellulosa e contenente la sostanza polimerica (resine a base di colofonia e/o di alchil chetene dimero e/o di acido acetil succinico e/o di epocloridrina, e/o amidi modificati) e la carica inorganica (carbonati, caolini, talco, eccetera). Basically, an aqueous slurry of cellulose fibers is prepared and contains the polymeric substance (resins based on rosin and / or alkyl ketene dimer and / or acetyl succinic acid and / or epochlorhydrin, and / or modified starches) and the inorganic charge (carbonates, kaolins, talc, etc.).

Successivamente, si rimuove acqua dall’impasto per formare il supporto base del materiale cartaceo. Subsequently, water is removed from the mixture to form the basic support of the paper material.

Segue una fase di trattamento superficiale di una o entrambe le facce del supporto base con una soluzione acquosa di collante superficiale, per esempio composto da una soluzione acquosa di amido al 10% in peso, e/o collante acrilico al 5% in peso, o collanti similari come descritto in precedenza (collanti a base di alcol polivinilico e/o di polimeri acrilici, poliuretanici e/o stirolo-butadienici). Il trattamento con il collante superficiale serve anche a conferire al materiale cartaceo una corretta penetrazione all’acqua, indispensabile per la successiva fase di patinatura. This is followed by a step of surface treatment of one or both faces of the base support with an aqueous solution of surface glue, for example composed of an aqueous solution of starch at 10% by weight, and / or acrylic glue at 5% by weight, or similar adhesives as described above (adhesives based on polyvinyl alcohol and / or acrylic, polyurethane and / or styrene-butadiene polymers). The treatment with the surface glue also serves to give the paper material correct water penetration, which is essential for the subsequent coating phase.

Il metodo comprende poi, dopo il trattamento superficiale con collante, una fase di lisciatura del supporto base, in cui il supporto base à ̈ lisciato fino a valori di liscio Bendsten ISO 2494 inferiore a circa 50 ml/min e preferibilmente inferiore a circa 30 ml/min e indicativamente intorno a 20 ml/min. The method then includes, after the surface treatment with glue, a smoothing phase of the base support, in which the base support is smoothed up to Bendsten ISO 2494 smooth values of less than about 50 ml / min and preferably less than about 30 ml. / min and roughly around 20 ml / min.

Successivamente, si applica la patina precedentemente descritta. Subsequently, the previously described patina is applied.

Preferibilmente, l’applicazione della patina avviene tramite spalmatura eseguita con macchina a lama d’aria o con lama lisciante ed à ̈ seguita da una fase di asciugatura della patina, condotta in forno ad infrarossi e/o ad aria calda a temperatura compresa tra circa 100°C e circa 180°C e con tempo di permanenza in forno compreso fra 0,5 e 4 minuti. Preferably, the application of the patina takes place by spreading performed with an air knife or with a smoothing blade and is followed by a drying phase of the patina, carried out in an infrared and / or hot air oven at a temperature included between about 100 ° C and about 180 ° C and with a residence time in the oven between 0.5 and 4 minutes.

Infine, il metodo comprende una fase di trattamento meccanico della superficie provvista della patina, in particolare una fase di lisciatura e/o una fase di goffratura. Finally, the method comprises a step of mechanical treatment of the surface provided with the patina, in particular a smoothing step and / or an embossing step.

Resta poi inteso che al materiale cartaceo e al relativo metodo di fabbricazione qui descritti ed illustrati possono essere apportate modifiche e varianti che non escono dall’ambito dell’invenzione come definito nelle annesse rivendicazioni. It is then understood that modifications and variations may be made to the paper material and the relative manufacturing method described and illustrated herein which do not depart from the scope of the invention as defined in the attached claims.

Claims (18)

RIVENDICAZIONI 1. Materiale cartaceo ad effetto-ruvido sabbia, comprendente un supporto base, formato da una miscela di fibre di cellulosa contenente almeno una sostanza polimerica, atta a conferire alla miscela di fibre resistenza meccanica, e una carica inorganica; e avente almeno una superficie trattata con almeno un collante superficiale e provvista di una patina formata da uno o più polimeri leganti e/o cere, in miscela con pigmenti; e in cui i pigmenti comprendono pigmenti a base di silicati di calcio, in modo tale che il materiale cartaceo abbia un effetto al tatto ruvido simile alla sabbia. CLAIMS 1. Paper material with rough sand effect, comprising a base support, formed by a mixture of cellulose fibers containing at least one polymeric substance, capable of giving the mixture of fibers mechanical strength, and an inorganic filler; and having at least one surface treated with at least one surface glue and provided with a patina formed by one or more binding polymers and / or waxes, mixed with pigments; and wherein the pigments comprise calcium silicate based pigments such that the paper material has a rough, sand-like touch effect. 2. Materiale cartaceo secondo la rivendicazione 1, in cui la sostanza polimerica inclusa nel supporto base comprende una o più resine a base di colofonia e/o di alchil chetene dimero e/o di acido acetil succinico e/o di epocloridrina, e/o amidi modificati. 2. A paper material according to claim 1, wherein the polymeric substance included in the base carrier comprises one or more resins based on rosin and / or alkyl ketene dimer and / or acetyl succinic acid and / or epochlorhydrin, and / or modified starches. 3. Materiale cartaceo secondo la rivendicazione 1 o 2, in cui la carica inorganica à ̈ una carica minerale e comprende una o più sostanze scelte nel gruppo costituito da carbonati, caolini, talco, loro miscele. 3. Paper material according to claim 1 or 2, wherein the inorganic filler is a mineral filler and comprises one or more substances selected from the group consisting of carbonates, kaolins, talc, their mixtures. 4. Materiale cartaceo secondo una delle rivendicazioni precedenti, in cui il collante superficiale à ̈ un collante a base di amido e/o alcol polivinilico e/o polimeri acrilici, poliuretanici e/o stirolo-butadienici. Paper material according to one of the preceding claims, wherein the surface glue is a starch and / or polyvinyl alcohol-based glue and / or acrylic, polyurethane and / or styrene-butadiene polymers. 5. Materiale cartaceo secondo una delle rivendicazioni precedenti, in cui i pigmenti a base di silicati di calcio hanno granulometria varia e grado di bianco superiore a circa 85 secondo la norma DIN 5033. Paper material according to one of the preceding claims, in which the pigments based on calcium silicates have various granulometry and a degree of whiteness higher than about 85 according to DIN 5033. 6. Materiale cartaceo secondo una delle rivendicazioni precedenti, in cui la patina comprende pigmenti a struttura lamellare o piatta, come ad esempio carbonato di calcio precipitato (PCC), caolini per patinatura, caolini calcinati e/o lamellari, in abbinamento ai pigmenti a base di silicati di calcio. Paper material according to one of the preceding claims, in which the patina comprises pigments with a lamellar or flat structure, such as for example precipitated calcium carbonate (PCC), kaolins for coating, calcined and / or lamellar kaolins, in combination with the pigments based of calcium silicates. 7. Materiale cartaceo secondo una delle rivendicazioni precedenti, in cui i polimeri leganti comprendono polimeri a base poliuretanica, acrilica, di alcol polivinilico, stirolo-butadienica e/o siliconica. Paper material according to one of the preceding claims, wherein the binding polymers comprise polymers based on polyurethane, acrylic, polyvinyl alcohol, styrene-butadiene and / or silicone. 8. Metodo di fabbricazione del materiale cartaceo secondo una delle rivendicazioni precedenti, comprendente le fasi di: (a) predisporre un impasto acquoso di fibre di cellulosa contenente almeno una sostanza polimerica, atta a conferire alla miscela di fibre resistenza meccanica, e una carica inorganica; (b) rimuovere acqua dall’impasto per formare un supporto base del materiale cartaceo; (c) trattare almeno una superficie del supporto base con almeno un collante superficiale, in modo tale da conferire al supporto base caratteristiche di penetrazione all’acqua idonee per una successiva fase di patinatura; (d) applicare alla superficie trattata una patina formata da uno o più polimeri leganti e/o cere, in miscela con pigmenti comprendenti pigmenti a base di silicati di calcio, in modo tale che il materiale cartaceo abbia un effetto al tatto simile alla sabbia. 8. Method for manufacturing the paper material according to one of the preceding claims, comprising the steps of: (a) preparing an aqueous slurry of cellulose fibers containing at least one polymeric substance, capable of giving the fiber mixture mechanical strength, and an inorganic filler; (b) removing water from the dough to form a base support for the paper material; (c) treating at least one surface of the base support with at least one surface glue, in such a way as to give the base support water penetration characteristics suitable for a subsequent coating phase; (d) apply to the treated surface a patina formed by one or more binding polymers and / or waxes, mixed with pigments including pigments based on calcium silicates, so that the paper material has a touch effect similar to sand. 9. Metodo secondo la rivendicazione 8, in cui la sostanza polimerica inclusa nel supporto base comprende una o più resine a base di colofonia e/o alchil chetene dimero e/o di acido acetil succinico e/o di epocloridrina, e/o amidi modificati. Method according to claim 8, wherein the polymeric substance included in the base carrier comprises one or more resins based on rosin and / or alkyl ketene dimer and / or acetyl succinic acid and / or epochlorhydrin, and / or modified starches . 10. Metodo secondo la rivendicazione 8 o 9, in cui la carica inorganica à ̈ una carica minerale e comprende una o più sostanze scelte nel gruppo costituito da carbonati, caolini, talco, loro miscele. 10. Method according to claim 8 or 9, wherein the inorganic filler is a mineral filler and comprises one or more substances selected from the group consisting of carbonates, kaolins, talc, their mixtures. 11. Metodo secondo una delle rivendicazioni da 8 a 10, in cui il collante superficiale à ̈ un collante a base di amido e/o alcol polivinilico e/o polimeri acrilici, poliuretanici e/o stirolo-butadienici. Method according to one of claims 8 to 10, wherein the surface adhesive is an adhesive based on starch and / or polyvinyl alcohol and / or acrylic, polyurethane and / or styrene-butadiene polymers. 12. Metodo secondo una delle rivendicazioni da 8 a 11, in cui i pigmenti a base di silicati di calcio hanno granulometria varia e grado di bianco superiore a 85 secondo la norma DIN 5033. Method according to one of claims 8 to 11, wherein the pigments based on calcium silicates have various granulometry and whiteness higher than 85 according to DIN 5033. 13. Metodo secondo una delle rivendicazioni da 8 a 12, in cui la patina comprende pigmenti a struttura lamellare o piatta, come ad esempio carbonato di calcio, carbonato di calcio precipitato (PCC), caolini calcinati e/o lamellari, caolini per patinatura in abbinamento ai pigmenti a base di silicati di calcio. Method according to one of claims 8 to 12, wherein the patina comprises pigments with a lamellar or flat structure, such as for example calcium carbonate, precipitated calcium carbonate (PCC), calcined and / or lamellar kaolins, kaolins for coating in combination with pigments based on calcium silicates. 14. Metodo secondo una delle rivendicazioni da 8 a 13, in cui i polimeri leganti comprendono polimeri a base poliuretanica, acrilica, di alcool polivinilico, stirolobutadienica e/o siliconica. Method according to one of claims 8 to 13, wherein the binding polymers comprise polyurethane, acrylic, polyvinyl alcohol, styrene butadiene and / or silicone based polymers. 15. Metodo secondo una delle rivendicazioni da 8 a 14, comprendente, dopo il trattamento superficiale con collante, una fase di lisciatura del supporto base, in cui il supporto base à ̈ lisciato fino a valori di liscio Bendsten ISO 2494 inferiore a circa 50 ml/min, preferibilmente inferiore a circa 30 ml/min e indicativamente intorno a 20 ml/min. Method according to one of claims 8 to 14, comprising, after the surface treatment with glue, a step of smoothing the base support, in which the base support is smoothed down to Bendsten ISO 2494 smooth values of less than about 50 ml / min, preferably less than about 30 ml / min and indicatively around 20 ml / min. 16. Metodo secondo una delle rivendicazioni da 8 a 15, in cui la fase di applicazione della patina avviene tramite spalmatrice a lama d’aria o a lama lisciante. Method according to one of claims 8 to 15, in which the patina application step takes place by means of an air knife or smoothing knife spreader. 17. Metodo secondo una delle rivendicazioni da 8 a 16, comprendente una fase di asciugatura della patina, condotta in forno ad infrarossi e/o ad aria calda a temperatura compresa tra circa 100°C e circa 180°C e con tempo di permanenza in forno compreso fra 0,5 e 4 minuti. Method according to one of claims 8 to 16, comprising a patina drying step, carried out in an infrared and / or hot air oven at a temperature between about 100 ° C and about 180 ° C and with a residence time in oven between 0.5 and 4 minutes. 18. Metodo secondo una delle rivendicazioni da 8 a 17, comprendente una fase di trattamento meccanico della superficie provvista della patina, in particolare una fase di lisciatura e/o una fase di goffratura.Method according to one of claims 8 to 17, comprising a step of mechanical treatment of the surface provided with the patina, in particular a smoothing step and / or an embossing step.
IT000779A 2011-05-06 2011-05-06 SAND MATERIAL WITH EFFECT - SAND AND ITS MANUFACTURING PROCEDURE ITMI20110779A1 (en)

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Application Number Priority Date Filing Date Title
IT000779A ITMI20110779A1 (en) 2011-05-06 2011-05-06 SAND MATERIAL WITH EFFECT - SAND AND ITS MANUFACTURING PROCEDURE
EP12167036.8A EP2520709B1 (en) 2011-05-06 2012-05-07 Sand-effect paper material and corresponding manufacturing method
ES12167036.8T ES2579057T3 (en) 2011-05-06 2012-05-07 Paper material with sand effect and corresponding manufacturing method
PT121670368T PT2520709T (en) 2011-05-06 2012-05-07 Sand-effect paper material and corresponding manufacturing method

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ITMI20130979A1 (en) * 2013-06-13 2014-12-14 Gruppo Cordenons Spa PAPER MATERIAL WITH HOLOGRAPHIC AND METAL PERLESCENT EFFECT AND RELATIVE PROCESS OF MANUFACTURE
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US9777143B2 (en) 2014-04-11 2017-10-03 Georgia-Pacific Consumer Products Lp Polyvinyl alcohol fibers and films with mineral fillers and small cellulose particles
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