CN104629574A - High-water-resistance antibacterial waterborne woodware coating - Google Patents
High-water-resistance antibacterial waterborne woodware coating Download PDFInfo
- Publication number
- CN104629574A CN104629574A CN201510025422.9A CN201510025422A CN104629574A CN 104629574 A CN104629574 A CN 104629574A CN 201510025422 A CN201510025422 A CN 201510025422A CN 104629574 A CN104629574 A CN 104629574A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- solution
- stirring
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a high-water-resistance antibacterial waterborne woodware coating. The high-water-resistance antibacterial waterborne woodware coating comprises the following raw materials: a waterborne silica sol/acrylic polyurethane composite emulsion, nanometer silicon nitride, nanometer zinc oxide, bamboo charcoal powder, kaolin, doped nanometer titanium dioxide, benzyl alcohol, ethylene glycol butyl ether, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, dipropylene glycol, diglycol, 2-amino-2-methyl-1-propanol, a silane coupling agent, hydroxypropyl methyl cellulose, chitosan, a defoaming agent, a dispersant, a flatting agent and water. The high-water-resistance antibacterial waterborne woodware coating has the advantages of high strength, good abrasion resistance and scratch resistance, excellent water resistance and antibacterial property, good comprehensive property and long service life as the woodware coating.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high water-fast germ resistance water-borne wood coating.
Background technology
Woodwork coating refers to that timber-work comprises coating used on the goods of solid wood and wood-based plate, comprise the coating that furniture, door and window, wall dunnage, floor, daily living article, wooden musical instrument, sports goods, stationery, toy for children etc. are selected, in general woodwork coating is based on coatings for furniture.Woodwork coating gives the required aesthetic features such as timber and wood based material color, gloss, and woodenware can also be made to resist destruction because humidity, bacteria breed, biological degradation, chemical damage etc. cause simultaneously.
Water-borne wood coating is due to nontoxic, environmental protection, volatilizable thing are few, security high has become people's research focus.Relative to solvent wood coatings, the aspect also Shortcomings such as the water tolerance of water-borne wood coating, wear resistance and anti-microbial property, can not meet the requirement of society.
Summary of the invention
The present invention proposes a kind of high water-fast germ resistance water-borne wood coating, its intensity is high, wear resistance and adhesion strength good, water tolerance and anti-microbial property excellent, as woodwork coating good combination property, long service life.
The present invention proposes a kind of high water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 65-80 part, nano-silicon nitride 2-6 part, nano zine oxide 3-8 part, bamboo charcoal powder 3-6 part, kaolin 2-10 part, doped nano titanium dioxide 3-5 part, phenylcarbinol 0.3-0.9 part, butyl glycol ether 0.5-2 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.2-0.6 part, dipropylene glycol 0.1-0.6 part, glycol ether 0.2-0.8 part, 2-amino-2-methyl-1-propanol 0.15-0.5 part, silane coupling agent 0.5-1 part, Vltra tears 1-2.5 part, chitosan 2-6 part, defoamer 0.3-1.5 part, dispersion agent 0.5-2 part, flow agent 0.3-1.2 part, water 8-20 part,
Wherein, described doped nano titanium dioxide is prepared according to following technique: added by tetrabutyl titanate in dehydrated alcohol, then add Glacial acetic acid, obtain solution A after stirring; Silver nitrate aqueous solution, copper nitrate aqueous solution and aqueous solution of urea are added in dehydrated alcohol, after stirring, obtains solution B; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 3-5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1-1.5h of 480-600 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Preferably, in its raw material, the weight ratio of nano zine oxide, bamboo charcoal powder, doped nano titanium dioxide, chitosan is 4-6:4-5:3.5-4:3-4.
Preferably, in its raw material, the weight part of phenylcarbinol is 0.5-0.7 part, the weight part of butyl glycol ether is 0.9-1.3 part, 2,2, the weight part of 4-trimethylammonium-1,3-pentanediol mono isobutyrate is 0.35-0.46 part, the weight part of dipropylene glycol is 0.35-0.45 part, the weight part of glycol ether is 0.4-0.6 part, the weight part of 2-amino-2-methyl-1-propanol is 0.25-0.4 part.
Preferably, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 70-73 part, nano-silicon nitride 3.5-4.6 part, nano zine oxide 4.3-5.2 part, bamboo charcoal powder 4.2-4.6 part, kaolin 6-9 part, doped nano titanium dioxide 3.8-4 part, phenylcarbinol 0.6-0.65 part, butyl glycol ether 1-1.2 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.38-0.42 part, dipropylene glycol 0.38-0.42 part, glycol ether 0.45-0.52 part, 2-amino-2-methyl-1-propanol 0.28-0.32 part, silane coupling agent 0.7-0.9 part, Vltra tears 1.8-2.2 part, chitosan 3.4-3.7 part, defoamer 0.8-1.3 part, dispersion agent 1.1-1.6 part, flow agent 0.8-1.2 part, water 12-15 part.
Preferably, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 72 parts, nano-silicon nitride 4.3 parts, nano zine oxide 5 parts, bamboo charcoal powder 4.4 parts, kaolin 8 parts, doped nano titanium dioxide 3.8 parts, phenylcarbinol 0.63 part, butyl glycol ether 1.1 parts, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.4 part, dipropylene glycol 0.38 part, glycol ether 0.46 part, 2-amino-2-methyl-1-propanol 0.29 part, silane coupling agent 0.75 part, Vltra tears 1.9 parts, chitosan 3.6 parts, defoamer 1.2 parts, dispersion agent 1.5 parts, flow agent 1.1 parts, 14 parts, water.
Preferably, described doped nano titanium dioxide is prepared according to following technique: by volume 30-50 part tetrabutyl titanate adds in 60-80 part dehydrated alcohol by part, then adds 10-25 part Glacial acetic acid, obtains solution A after stirring; 30-50 part silver nitrate aqueous solution, 10-30 part copper nitrate aqueous solution and 15-35 part aqueous solution of urea are added in 40-80 part dehydrated alcohol, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 5-8%, and in copper nitrate aqueous solution, the massfraction of cupric nitrate is 5-10%, in aqueous solution of urea, the massfraction of urea is 3-8%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4-5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.2-1.4h of 500-550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Preferably, described doped nano titanium dioxide is prepared according to following technique: by volume 40 parts of tetrabutyl titanates add in 65 parts of dehydrated alcohols by part, then adds 18 parts of Glacial acetic acid, obtains solution A after stirring; 35 parts of silver nitrate aqueous solutions, 18 parts of copper nitrate aqueous solutions and 20 parts of aqueous solution of urea are added in 50 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 7%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 8%, in aqueous solution of urea, the massfraction of urea is 7%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4.5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.4h of 550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Preferably, described water silica sol-acroleic acid polyurethane composite emulsion is prepared according to following technique: by weight by after 10-25 part isoflurane chalcone diisocyanate and the mixing of 5-15 part PCDL, pass into nitrogen, then 75-85 DEG C is warming up to, stir insulation 3-5h, be cooled to 65-70 DEG C, add 15-35 part acetone successively, 3-8 part dimethylol propionic acid, 2-10 part 1, 4-butyleneglycol and 0.8-2 part N-Methyl pyrrolidone, 8-12h is incubated after being warming up to 75-85 DEG C, stop logical nitrogen and be cooled to 60-65 DEG C, 50-55 DEG C is cooled to after adding 8-20 part hydroxyethyl methylacrylate insulation 4-6h, add 3-10 part triethylamine and 3-15 part Isooctyl methacrylate successively and obtain solution A after stirring, 5-15 part silicon sol is added in 30-50 part deionized water, add solution A after stirring and stir, then add 3-10 part quadrol and stir, logical nitrogen is also heated to 75-80 DEG C, then 1-1.5 part Diisopropyl azodicarboxylate and 0.3-0.8 part benzoyl peroxide is added, stirring reaction 3-6h, after cooling, discharging obtains described water silica sol-acroleic acid polyurethane composite emulsion.
In a particular embodiment, height of the present invention is water-fast germ resistance water-borne wood coating, in its raw material, the weight part of water silica sol/acroleic acid polyurethane composite emulsion can be 65, 67, 68.3, 70, 72, 74, 75.6, 78, 79, 79.3 parts, the weight part of nano-silicon nitride can be 2.3, 2.5, 2.8, 3, 3.4, 3.6, 3.8, 4, 4.3, 4.7, 5, 5.6 parts, the weight part of nano zine oxide can be 3.2, 3.6, 3.78, 4, 4.2, 4.6, 4.9, 5.3, 5.7, 6, 6.4, 6.8, 7, 7.3, 7.8 parts, the weight part of bamboo charcoal powder can be 3.6, 4, 4.5, 4.7, 5, 5.3, 5.86 parts, kaolinic weight part can be 2.6, 2.8, 3, 3.4, 3.8, 4, 4.5, 4.8, 5, 5.3, 5.7, 6, 6.4, 6.8, 7, 7.3, 7.8, 8, 8.6, 8.9, 9, 9.4 parts, the weight part of doped nano titanium dioxide can be 3.2, 3.5, 3.78, 3.9, 4, 4.2, 4.5, 4.67, 4.8, 4.93 parts, the weight part of phenylcarbinol can be 0.36, 0.42, 0.53, 0.6, 0.7, 0.8, 0.9 part, the weight part of butyl glycol ether can be 0.5, 0.56, 0.6, 0.68, 0.8, 0.93, 1, 1.2, 1.35, 1.4, 1.16, 1.5, 1.56, 1.8, 1.9, 1.93, 2 parts, the weight part of 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate can be 0.2, 0.26, 0.3, 0.35, 0.4, 0.46, 0.5, 0.53, 0.6 part, the weight part of dipropylene glycol can be 0.1, 0.17, 0.2, 0.23, 0.3, 0.35, 0.4, 0.46, 0.5, 0.53, 0.6 part, the weight part of glycol ether can be 0.2, 0.3, 0.34, 0.5, 0.56, 0.7, 0.74, 0.78, 0.8 part, the weight part of 2-amino-2-methyl-1-propanol can be 0.18, 0.23, 0.3, 0.34, 0.4, 0.45, 0.5 part, the weight part of silane coupling agent can be 0.5, 0.6, 0.67, 0.8, 0.94, 1 part, the weight part of Vltra tears can be 1, 1.2, 1.35, 1.46, 1.5, 1.6, 1.7, 1.8, 1.94, 2, 2.1, 2.3, 2.45, 2.5 parts, the weight part of chitosan can be 2, 2.3, 2.5, 2.8, 3, 3.4, 3.7, 4, 4.3, 4.6, 4.86, 5, 5.3, 5.7, 5.9, 6 parts, the weight part of defoamer can be 0.3, 0.45, 0.6, 0.67, 0.8, 0.89, 0.93, 1, 1.1, 1.15, 1.2, 1.26, 1.3, 1.34, 1.45, 1.5 parts, the weight part of dispersion agent can be 0.5, 0.56, 0.63, 0.7, 0.8, 0.86, 0.9, 1, 1.1, 1.15, 1.23, 1.34, 1.4, 1.5, 1.6, 1.67, 1.7, 1.78, 1.8, 1.83, 1.9, 2 parts, the weight part of flow agent can be 0.35, 0.4, 0.46, 0.5, 0.53, 0.6, 0.67, 0.8, 0.83, 0.9, 0.94, 1, 1.1, 1.2 parts, the weight part of water can be 8.5, 9, 10, 10.3, 11, 12, 13, 14, 15.6, 16, 17, 18, 18.3, 19, 19.4 parts.
Height of the present invention is water-fast, and germ resistance water-borne wood coating is prepared according to following technique: stirred after mixing with water by water silica sol/acroleic acid polyurethane composite emulsion, then nano-silicon nitride is added, nano zine oxide, bamboo charcoal powder, kaolin, doped nano titanium dioxide, phenylcarbinol is added after stirring 10-25min with the rotating speed of 300r/min, butyl glycol ether, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate, dipropylene glycol, glycol ether, 2-amino-2-methyl-1-propanol, silane coupling agent, the defoamer of 1/2 weight in units of defoamer is added after the rotating speed of 200r/min stirs 5-10min, chitosan is added after stirring 5-15min with 250r/min, dispersion agent, flow agent, remaining defoamer is added after stirring 3-8min with the speed of 400r/min, Vltra tears is added after stirring 3-9min, the water-fast germ resistance water-borne wood coating of described height is obtained after stirring 5-15min with the rotating speed of 600r/min.
In the present invention, with water silica sol/acroleic acid polyurethane composite emulsion for filmogen, at phenylcarbinol, butyl glycol ether, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, dipropylene glycol, glycol ether, 2-amino-2-methyl-1-propanol auxiliary under, good film-forming property, and there is certain cryoprotective effects, prevent the generation of the not film forming phenomenon of low temperature in the winter time, and silicon sol is incorporated in acroleic acid polyurethane emulsion, be equivalent to large hard section, enhance rigidity and the hardness of coating, again due to silicon sol surface cover by many silanols, polarity is strong, it well can be combined with the polar group of matrix surface, improve the sticking power of film, in the film process of coating, between silica sol granule, dehydrating condensation becomes cross-linked network voluntarily, acroleic acid polyurethane molecular chain is distributed in inorganic crosslinking network, define organic and inorganic inierpeneirating network structure, the existence of cross-linked network improves the density of film, hinder the diffusion in film of water molecules and organic solvent and absorption, improve water tolerance and the solvent resistance of film, doped nano titanium dioxide is silver, copper, the nano titanium oxide of N codoped, there is synergy in codoped, the doped nano titanium dioxide obtained is made to have absorption region widely, effectively can stop the compound of electron-hole, impurity level can be formed, narrow the energy level width of titanium dioxide, improve the catalytic activity of doped nano titanium dioxide, and control silver, the doping of copper and N, while raising coating degradation property, prevent the check surface of coating, nano zine oxide transparency is high, there is excellent normal temperature luminescent properties, to ultraviolet, there is good protection effect, coordinating with bamboo charcoal powder adds in coating, consolidate the degradation effect of doped nano titanium dioxide, improve germ resistance and the ageing resistance of coating, reach the object of cleaning ambient, nano aluminium oxide has scratch resistance, wear-resisting performance, adds in coating, coordinates with nano zine oxide, kaolin, doped nano titanium dioxide, improves the intensity of coating while improving coating scratch resistance, wear resistance, chitosan joins in coating, coordinates as thickening material with Vltra tears, have adjusted the viscosity of coating, and chitosan has the effect of Antibacterial activity simultaneously, further increases the anti-microbial property of coating.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
Embodiment 1
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 80 parts, nano-silicon nitride 2 parts, nano zine oxide 8 parts, bamboo charcoal powder 3 parts, kaolin 10 parts, doped nano titanium dioxide 3 parts, phenylcarbinol 0.9 part, butyl glycol ether 0.5 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.6 part, dipropylene glycol 0.1 part, glycol ether 0.8 part, 2-amino-2-methyl-1-propanol 0.15 part, silane coupling agent 1 part, Vltra tears 1 part, chitosan 6 parts, defoamer 0.3 part, dispersion agent 2 parts, flow agent 0.3 part, 20 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: added by tetrabutyl titanate in dehydrated alcohol, then add Glacial acetic acid, obtain solution A after stirring; Silver nitrate aqueous solution, copper nitrate aqueous solution and aqueous solution of urea are added in dehydrated alcohol, after stirring, obtains solution B; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 3h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1h of 600 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Embodiment 2
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 65 parts, nano-silicon nitride 6 parts, nano zine oxide 3 parts, bamboo charcoal powder 6 parts, kaolin 2 parts, doped nano titanium dioxide 5 parts, phenylcarbinol 0.3 part, butyl glycol ether 2 parts, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.2 part, dipropylene glycol 0.6 part, glycol ether 0.2 part, 2-amino-2-methyl-1-propanol 0.5 part, silane coupling agent 0.5 part, Vltra tears 2.5 parts, chitosan 2 parts, defoamer 1.5 parts, dispersion agent 0.5 part, flow agent 1.2 parts, 8 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: added by tetrabutyl titanate in dehydrated alcohol, then add Glacial acetic acid, obtain solution A after stirring; Silver nitrate aqueous solution, copper nitrate aqueous solution and aqueous solution of urea are added in dehydrated alcohol, after stirring, obtains solution B; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.5h of 480 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Embodiment 3
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 70 parts, nano-silicon nitride 4.6 parts, nano zine oxide 4.3 parts, bamboo charcoal powder 4.6 parts, kaolin 6 parts, doped nano titanium dioxide 4 parts, phenylcarbinol 0.6 part, butyl glycol ether 1.2 parts, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.38 part, dipropylene glycol 0.42 part, glycol ether 0.45 part, 2-amino-2-methyl-1-propanol 0.32 part, silane coupling agent 0.7 part, Vltra tears 2.2 parts, chitosan 3.4 parts, defoamer 1.3 parts, dispersion agent 1.1 parts, flow agent 1.2 parts, 12 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: by volume 30 parts of tetrabutyl titanates add in 80 parts of dehydrated alcohols by part, then adds 10 parts of Glacial acetic acid, obtains solution A after stirring; 50 parts of silver nitrate aqueous solutions, 10 parts of copper nitrate aqueous solutions and 35 parts of aqueous solution of urea are added in 40 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 8%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 5%, in aqueous solution of urea, the massfraction of urea is 8%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.2h of 550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
Embodiment 4
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 73 parts, nano-silicon nitride 3.5 parts, nano zine oxide 5.2 parts, bamboo charcoal powder 4.2 parts, kaolin 9 parts, doped nano titanium dioxide 3.8 parts, phenylcarbinol 0.65 part, butyl glycol ether 1 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.42 part, dipropylene glycol 0.38 part, glycol ether 0.52 part, 2-amino-2-methyl-1-propanol 0.28 part, silane coupling agent 0.9 part, Vltra tears 1.8 parts, chitosan 3.7 parts, defoamer 0.8 part, dispersion agent 1.6 parts, flow agent 0.8 part, 15 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: by volume 50 parts of tetrabutyl titanates add in 60 parts of dehydrated alcohols by part, then adds 25 parts of Glacial acetic acid, obtains solution A after stirring; 30 parts of silver nitrate aqueous solutions, 30 parts of copper nitrate aqueous solutions and 15 parts of aqueous solution of urea are added in 80 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 5%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 10%, in aqueous solution of urea, the massfraction of urea is 3%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.4h of 500 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling;
Described water silica sol-acroleic acid polyurethane composite emulsion is prepared according to following technique: by weight by after 10 parts of isoflurane chalcone diisocyanates and 15 parts of PCDL mixing, pass into nitrogen, then 75 DEG C are warming up to, stir insulation 5h, be cooled to 65 DEG C, add 35 parts of acetone successively, 3 parts of dimethylol propionic acids, 10 part 1, 4-butyleneglycol and 0.8 part of N-Methyl pyrrolidone, 8h is incubated after being warming up to 85 DEG C, stop logical nitrogen and be cooled to 65 DEG C, 50 DEG C are cooled to after adding 8 parts of hydroxyethyl methylacrylate insulation 6h, add 10 parts of triethylamines and 3 parts of Isooctyl methacrylates successively and obtain solution A after stirring, 15 parts of silicon sol are added in 30 parts of deionized waters, add solution A after stirring and stir, then add 10 parts of quadrols and stir, logical nitrogen is also heated to 75 DEG C, then 1.5 parts of Diisopropyl azodicarboxylates and 0.3 part of benzoyl peroxide is added, stirring reaction 6h, after cooling, discharging obtains described water silica sol-acroleic acid polyurethane composite emulsion.
Embodiment 5
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 78 parts, nano-silicon nitride 3.8 parts, nano zine oxide 5.3 parts, bamboo charcoal powder 4.7 parts, kaolin 3.8 parts, doped nano titanium dioxide 4.8 parts, phenylcarbinol 0.53 part, butyl glycol ether 0.8 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.46 part, dipropylene glycol 0.53 part, glycol ether 0.78 part, 2-amino-2-methyl-1-propanol 0.45 part, silane coupling agent 0.94 part, Vltra tears 1.94 parts, chitosan 4.3 parts, defoamer 1.1 parts, dispersion agent 1.34 parts, flow agent 0.83 part, 18 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: by volume 40 parts of tetrabutyl titanates add in 75 parts of dehydrated alcohols by part, then adds 18 parts of Glacial acetic acid, obtains solution A after stirring; 37 parts of silver nitrate aqueous solutions, 23 parts of copper nitrate aqueous solutions and 19 parts of aqueous solution of urea are added in 60 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 7%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 8%, in aqueous solution of urea, the massfraction of urea is 6.5%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4.6h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.27h of 540 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling;
Described water silica sol-acroleic acid polyurethane composite emulsion is prepared according to following technique: by weight by after 25 parts of isoflurane chalcone diisocyanates and 5 parts of PCDL mixing, pass into nitrogen, then 85 DEG C are warming up to, stir insulation 3h, be cooled to 70 DEG C, add 15 parts of acetone successively, 8 parts of dimethylol propionic acids, 2 part 1, 4-butyleneglycol and 2 parts of N-Methyl pyrrolidone, 12h is incubated after being warming up to 75 DEG C, stop logical nitrogen and be cooled to 60 DEG C, 55 DEG C are cooled to after adding 20 parts of hydroxyethyl methylacrylate insulation 4h, add 3 parts of triethylamines and 15 parts of Isooctyl methacrylates successively and obtain solution A after stirring, 5 parts of silicon sol are added in 50 parts of deionized waters, add solution A after stirring and stir, then add 3 parts of quadrols and stir, logical nitrogen is also heated to 80 DEG C, then 1 part of Diisopropyl azodicarboxylate and 0.8 part of benzoyl peroxide is added, stirring reaction 3h, after cooling, discharging obtains described water silica sol-acroleic acid polyurethane composite emulsion.
Embodiment 6
Height of the present invention is water-fast germ resistance water-borne wood coating, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 72 parts, nano-silicon nitride 4.3 parts, nano zine oxide 5 parts, bamboo charcoal powder 4.4 parts, kaolin 8 parts, doped nano titanium dioxide 3.8 parts, phenylcarbinol 0.63 part, butyl glycol ether 1.1 parts, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.4 part, dipropylene glycol 0.38 part, glycol ether 0.46 part, 2-amino-2-methyl-1-propanol 0.29 part, silane coupling agent 0.75 part, Vltra tears 1.9 parts, chitosan 3.6 parts, defoamer 1.2 parts, dispersion agent 1.5 parts, flow agent 1.1 parts, 14 parts, water,
Wherein, described doped nano titanium dioxide is prepared according to following technique: by volume 40 parts of tetrabutyl titanates add in 65 parts of dehydrated alcohols by part, and then 18 parts add Glacial acetic acid, obtain solution A after stirring; 35 parts of silver nitrate aqueous solutions, 18 parts of copper nitrate aqueous solutions and 20 parts of aqueous solution of urea are added in 50 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 7%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 8%, in aqueous solution of urea, the massfraction of urea is 7%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4.5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.4h of 550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling;
Described water silica sol-acroleic acid polyurethane composite emulsion is prepared according to following technique: by weight by after 20 parts of isoflurane chalcone diisocyanates and 10 parts of PCDL mixing, pass into nitrogen, then 80 DEG C are warming up to, stir insulation 4h, be cooled to 68 DEG C, add 30 parts of acetone successively, 6 parts of dimethylol propionic acids, 8 part 1, 4-butyleneglycol and 1.3 parts of N-Methyl pyrrolidone, 10h is incubated after being warming up to 80 DEG C, stop logical nitrogen and be cooled to 62 DEG C, 53 DEG C are cooled to after adding 15 parts of hydroxyethyl methylacrylate insulation 5.2h, add 8 parts of triethylamines and 10 parts of Isooctyl methacrylates successively and obtain solution A after stirring, 10 parts of silicon sol are added in 45 parts of deionized waters, add solution A after stirring and stir, then add 8 parts of quadrols and stir, logical nitrogen is also heated to 78 DEG C, then 1.3 parts of Diisopropyl azodicarboxylates and 0.5 part of benzoyl peroxide is added, stirring reaction 5h, after cooling, discharging obtains described water silica sol-acroleic acid polyurethane composite emulsion.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. one kind high water-fast germ resistance water-borne wood coating, it is characterized in that, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 65-80 part, nano-silicon nitride 2-6 part, nano zine oxide 3-8 part, bamboo charcoal powder 3-6 part, kaolin 2-10 part, doped nano titanium dioxide 3-5 part, phenylcarbinol 0.3-0.9 part, butyl glycol ether 0.5-2 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.2-0.6 part, dipropylene glycol 0.1-0.6 part, glycol ether 0.2-0.8 part, 2-amino-2-methyl-1-propanol 0.15-0.5 part, silane coupling agent 0.5-1 part, Vltra tears 1-2.5 part, chitosan 2-6 part, defoamer 0.3-1.5 part, dispersion agent 0.5-2 part, flow agent 0.3-1.2 part, water 8-20 part,
Wherein, described doped nano titanium dioxide is prepared according to following technique: added by tetrabutyl titanate in dehydrated alcohol, then add Glacial acetic acid, obtain solution A after stirring; Silver nitrate aqueous solution, copper nitrate aqueous solution and aqueous solution of urea are added in dehydrated alcohol, after stirring, obtains solution B; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 3-5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1-1.5h of 480-600 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
2. high water-fast germ resistance water-borne wood coating according to claim 1, it is characterized in that, in its raw material, the weight ratio of nano zine oxide, bamboo charcoal powder, doped nano titanium dioxide, chitosan is 4-6:4-5:3.5-4:3-4.
3. high water-fast germ resistance water-borne wood coating according to claim 1 or 2, it is characterized in that, in its raw material, the weight part of phenylcarbinol is 0.5-0.7 part, the weight part of butyl glycol ether is 0.9-1.3 part, 2,2, the weight part of 4-trimethylammonium-1,3-pentanediol mono isobutyrate is 0.35-0.46 part, the weight part of dipropylene glycol is 0.35-0.45 part, the weight part of glycol ether is 0.4-0.6 part, the weight part of 2-amino-2-methyl-1-propanol is 0.25-0.4 part.
4. high water-fast germ resistance water-borne wood coating according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 70-73 part, nano-silicon nitride 3.5-4.6 part, nano zine oxide 4.3-5.2 part, bamboo charcoal powder 4.2-4.6 part, kaolin 6-9 part, doped nano titanium dioxide 3.8-4 part, phenylcarbinol 0.6-0.65 part, butyl glycol ether 1-1.2 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.38-0.42 part, dipropylene glycol 0.38-0.42 part, glycol ether 0.45-0.52 part, 2-amino-2-methyl-1-propanol 0.28-0.32 part, silane coupling agent 0.7-0.9 part, Vltra tears 1.8-2.2 part, chitosan 3.4-3.7 part, defoamer 0.8-1.3 part, dispersion agent 1.1-1.6 part, flow agent 0.8-1.2 part, water 12-15 part.
5. high water-fast germ resistance water-borne wood coating according to any one of claim 1-4, it is characterized in that, its raw material comprises following component by weight: water silica sol/acroleic acid polyurethane composite emulsion 72 parts, nano-silicon nitride 4.3 parts, nano zine oxide 5 parts, bamboo charcoal powder 4.4 parts, kaolin 8 parts, doped nano titanium dioxide 3.8 parts, phenylcarbinol 0.63 part, butyl glycol ether 1.1 parts, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.4 part, dipropylene glycol 0.38 part, glycol ether 0.46 part, 2-amino-2-methyl-1-propanol 0.29 part, silane coupling agent 0.75 part, Vltra tears 1.9 parts, chitosan 3.6 parts, defoamer 1.2 parts, dispersion agent 1.5 parts, flow agent 1.1 parts, 14 parts, water.
6. high water-fast germ resistance water-borne wood coating according to any one of claim 1-5, it is characterized in that, described doped nano titanium dioxide is prepared according to following technique: by volume 30-50 part tetrabutyl titanate adds in 60-80 part dehydrated alcohol by part, then add 10-25 part Glacial acetic acid, after stirring, obtain solution A; 30-50 part silver nitrate aqueous solution, 10-30 part copper nitrate aqueous solution and 15-35 part aqueous solution of urea are added in 40-80 part dehydrated alcohol, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 5-8%, and in copper nitrate aqueous solution, the massfraction of cupric nitrate is 5-10%, in aqueous solution of urea, the massfraction of urea is 3-8%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4-5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.2-1.4h of 500-550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
7. high water-fast germ resistance water-borne wood coating according to any one of claim 1-6, it is characterized in that, described doped nano titanium dioxide is prepared according to following technique: by volume 40 parts of tetrabutyl titanates add in 65 parts of dehydrated alcohols by part, then add 18 parts of Glacial acetic acid, after stirring, obtain solution A; 35 parts of silver nitrate aqueous solutions, 18 parts of copper nitrate aqueous solutions and 20 parts of aqueous solution of urea are added in 50 parts of dehydrated alcohols, solution B is obtained after stirring, wherein, in silver nitrate aqueous solution, the massfraction of Silver Nitrate is 7%, in copper nitrate aqueous solution, and the massfraction of cupric nitrate is 8%, in aqueous solution of urea, the massfraction of urea is 7%; Be added drop-wise in solution A by solution B under whipped state, stop after stirring 4.5h, then at room temperature ageing, oven dry, put into retort furnace afterwards, at the temperature lower calcination 1.4h of 550 DEG C, pulverizes and obtain described doped nano titanium dioxide after cooling.
8. high water-fast germ resistance water-borne wood coating according to any one of claim 1-7, it is characterized in that, described water silica sol-acroleic acid polyurethane composite emulsion is prepared according to following technique: by weight by after 10-25 part isoflurane chalcone diisocyanate and the mixing of 5-15 part PCDL, pass into nitrogen, then 75-85 DEG C is warming up to, stir insulation 3-5h, be cooled to 65-70 DEG C, add 15-35 part acetone successively, 3-8 part dimethylol propionic acid, 2-10 part 1, 4-butyleneglycol and 0.8-2 part N-Methyl pyrrolidone, 8-12h is incubated after being warming up to 75-85 DEG C, stop logical nitrogen and be cooled to 60-65 DEG C, 50-55 DEG C is cooled to after adding 8-20 part hydroxyethyl methylacrylate insulation 4-6h, add 3-10 part triethylamine and 3-15 part Isooctyl methacrylate successively and obtain solution A after stirring, 5-15 part silicon sol is added in 30-50 part deionized water, add solution A after stirring and stir, then add 3-10 part quadrol and stir, logical nitrogen is also heated to 75-80 DEG C, then 1-1.5 part Diisopropyl azodicarboxylate and 0.3-0.8 part benzoyl peroxide is added, stirring reaction 3-6h, after cooling, discharging obtains described water silica sol-acroleic acid polyurethane composite emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510025422.9A CN104629574A (en) | 2015-01-19 | 2015-01-19 | High-water-resistance antibacterial waterborne woodware coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510025422.9A CN104629574A (en) | 2015-01-19 | 2015-01-19 | High-water-resistance antibacterial waterborne woodware coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104629574A true CN104629574A (en) | 2015-05-20 |
Family
ID=53208834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510025422.9A Pending CN104629574A (en) | 2015-01-19 | 2015-01-19 | High-water-resistance antibacterial waterborne woodware coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104629574A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105951511A (en) * | 2016-06-16 | 2016-09-21 | 铜陵锋帆彩色印务有限公司 | Bactericidal paperboard and preparation method thereof |
| CN106497382A (en) * | 2016-09-20 | 2017-03-15 | 西安建筑科技大学 | A kind of antibacterial coating for drinking water field, antibacterial water tank and preparation method |
| CN108715712A (en) * | 2018-06-15 | 2018-10-30 | 青岛诺德知识产权有限公司 | A kind of machinery fungicidal paint and preparation method thereof |
| CN109169706A (en) * | 2018-07-19 | 2019-01-11 | 大美泰康（天津）生态科技有限公司 | Complex antimicrobials and antibacterial bacteriostatic type multifunctional inorganic ecologic coating obtained |
| CN111995915A (en) * | 2020-08-11 | 2020-11-27 | 深圳市鼎元恒泰科技有限公司 | Water-soluble composite antibacterial coating and preparation method thereof |
| CN118325355A (en) * | 2024-06-11 | 2024-07-12 | 湖南鲁丽木业有限公司 | High-strength bamboo-wood composite material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1840595A (en) * | 2005-04-01 | 2006-10-04 | 深圳市海川实业股份有限公司 | Aqueous wood paint and method for preparing same |
| CN101974285A (en) * | 2010-09-30 | 2011-02-16 | 江苏大象东亚制漆有限公司 | Long-acting antibacterial polyurethane water-based wood paint composition |
| CN102504694A (en) * | 2011-12-19 | 2012-06-20 | 大连理工大学 | Water-based naon-sized pre-coated coil top coating and preparation method thereof |
| CN103805054A (en) * | 2014-03-04 | 2014-05-21 | 北京市市政工程研究院 | Concrete outer wall protective agent and preparation method thereof |
-
2015
- 2015-01-19 CN CN201510025422.9A patent/CN104629574A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1840595A (en) * | 2005-04-01 | 2006-10-04 | 深圳市海川实业股份有限公司 | Aqueous wood paint and method for preparing same |
| CN101974285A (en) * | 2010-09-30 | 2011-02-16 | 江苏大象东亚制漆有限公司 | Long-acting antibacterial polyurethane water-based wood paint composition |
| CN102504694A (en) * | 2011-12-19 | 2012-06-20 | 大连理工大学 | Water-based naon-sized pre-coated coil top coating and preparation method thereof |
| CN103805054A (en) * | 2014-03-04 | 2014-05-21 | 北京市市政工程研究院 | Concrete outer wall protective agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄湘桦等: "水溶性硅溶胶/丙烯酸聚氨酯纳米复合乳液的制备", 《电镀与涂饰》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105951511A (en) * | 2016-06-16 | 2016-09-21 | 铜陵锋帆彩色印务有限公司 | Bactericidal paperboard and preparation method thereof |
| CN106497382A (en) * | 2016-09-20 | 2017-03-15 | 西安建筑科技大学 | A kind of antibacterial coating for drinking water field, antibacterial water tank and preparation method |
| CN108715712A (en) * | 2018-06-15 | 2018-10-30 | 青岛诺德知识产权有限公司 | A kind of machinery fungicidal paint and preparation method thereof |
| CN109169706A (en) * | 2018-07-19 | 2019-01-11 | 大美泰康（天津）生态科技有限公司 | Complex antimicrobials and antibacterial bacteriostatic type multifunctional inorganic ecologic coating obtained |
| CN111995915A (en) * | 2020-08-11 | 2020-11-27 | 深圳市鼎元恒泰科技有限公司 | Water-soluble composite antibacterial coating and preparation method thereof |
| CN118325355A (en) * | 2024-06-11 | 2024-07-12 | 湖南鲁丽木业有限公司 | High-strength bamboo-wood composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104629574A (en) | High-water-resistance antibacterial waterborne woodware coating | |
| CN104629576A (en) | High-performance water-based wood coating | |
| CN111592803B (en) | Bio-based water-based paint and preparation method and application thereof | |
| CN101671509B (en) | Emulsion paint for preventing mosquitoes and flies and preparation method thereof | |
| CN104263198A (en) | Nanocomposite road marking coating material | |
| CN102061125B (en) | UV (Ultra-Violet)-high elastic putty | |
| CN103881500A (en) | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN102676035A (en) | High-glossiness, scratch-resistant, wear-resistant and environment-friendly waterborne wood varnish and preparation method thereof | |
| CN105440925A (en) | Waterborne woodware surface color modifier | |
| CN105086685A (en) | Weather-resistance water-resistance acrylate paint for scaffold | |
| CN102746561B (en) | A kind of Wood-plastic material and preparation method thereof | |
| CN104877549A (en) | Ultraviolet curable water-based antibacterial paint used for wooden products | |
| CN102267150A (en) | Water-based wood protective agent and preparation method thereof | |
| CN105778692B (en) | Dumb light Lacquer finish clear finish and preparation method thereof | |
| CN104877551A (en) | Ultraviolet curable water-based composite antibacterial paint used for wooden products | |
| KR101570670B1 (en) | Synthetic wood composition and preparing method of Synthetic wood using thereof | |
| CN104761993B (en) | Polyurethane anticorrosion insulating mold coating and preparation method thereof | |
| CN104845471B (en) | A kind of mildew resistant paint based on Nanometer Copper | |
| CN101993654A (en) | Ultraviolet (UV) high elasticity primer | |
| CN108165146B (en) | Durable antibacterial water-based wood coating and preparation method thereof | |
| CN104877548A (en) | Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products | |
| CN107418330A (en) | A kind of novel heat insulation insulating moulding coating and preparation method thereof | |
| CN107805447A (en) | The preparation method that a kind of wood furniture is painted with flame-proof antibiotic | |
| CN106543893A (en) | A kind of organic-silicon-modified silicate paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150520 |