CN104263198A - Nanocomposite road marking coating material - Google Patents

Nanocomposite road marking coating material Download PDF

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Publication number
CN104263198A
CN104263198A CN201410484463.XA CN201410484463A CN104263198A CN 104263198 A CN104263198 A CN 104263198A CN 201410484463 A CN201410484463 A CN 201410484463A CN 104263198 A CN104263198 A CN 104263198A
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China
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parts
nano
titanium dioxide
coating material
road mark
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CN201410484463.XA
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Chinese (zh)
Inventor
潘峥嵘
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JURONG YIGE NANO MATERIAL FACTORY
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JURONG YIGE NANO MATERIAL FACTORY
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Priority to CN201410484463.XA priority Critical patent/CN104263198A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a nanocomposite road marking coating material. The nanocomposite road marking coating material comprises the following ingredients in parts by weight: 20-30 parts of glass powder, 6-10 parts of aluminum oxide powder, 50-80 parts of filler, 30-40 parts of epoxy resin, 15-20 parts of aqueous epoxy modified acrylate, 15-20 parts of glass micro-beads, 10-20 parts of chitin, 15-20 parts of chitosan, 20-40 parts of nano titanium white, 15-20 parts of nano zinc oxide, 10-15 parts of nano-silica, 2-4 parts of 25wt% ammonia water, 30-40 parts of acrylic emulsion and 15-20 parts of nano rare-earth self-luminous material. The invention further discloses a preparation method of the nano coating material. The nanocomposite road marking coating material disclosed by the invention is high in drying speed and long in service life, is wear-resistant and anti-fouling and has a bacterium resisting effect, and nano-materials or nano-structured ingredients are introduced into an organic coating material, so that organic and inorganic matched compositing or hybridization is realized. The advantages of organic polymers and inorganic-structured ingredients are integrated, so that the properties of the coating material are obviously improved.

Description

A kind of nano combined road mark paint
Technical field
The invention belongs to technical field of coatings, relate to a kind of nano combined road mark paint particularly.
Background technology
Water-based road guide line coating is environmental protection comparatively, fast drying, is coated with thickness, and China is about manufacturer's Introduced From Abroad waterborne road line paint but all do not obtain satisfied effect in application process, and therefore, water-borne coatings is also in exploitation and applicable stage at home.The wear resistance of coating, quick-drying become the emphasis of research.In addition, the development of new energy and save energy have become the joint demand of world today people, and along with reaching its maturity of photoelectric technology, many countries all turn to the emphasis of research the light-light conversion how realizing material, namely store light, then luminous.Existing nano combined road mark paint function is simple, and work-ing life has much room for improvement.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the invention provides a kind of nano combined road mark paint, has the advantage that drying is quick, wear resistance is good, antibacterial ability is strong.
Technical scheme: in order to solve the problems of the technologies described above, the present invention proposes a kind of nano combined road mark paint, it comprises the component of following parts by weight: 20 ~ 30 parts, glass powder, titanium dioxide two aluminium powder 6 ~ 10 parts, filler 50 ~ 80 parts, epoxy resin 30 ~ 40 parts, waterborne epoxy modified acrylic ester 15 ~ 20 parts, glass microballon 15 ~ 20 parts, chitin 10 ~ 20 parts, chitosan 15 ~ 20 parts, nanometer titanium dioxide 20 ~ 40 parts, nano zine oxide 15 ~ 20 parts, nano silicon 10 ~ 15 parts, 25wt% ammoniacal liquor 2 ~ 4 parts, ACRYLIC EMULSION 30 ~ 40 parts and Nano Rare soil nature self-luminescent material 15 ~ 20 parts.
Preferably, described nano combined road mark paint comprises the component of following parts by weight: 25 parts, glass powder, titanium dioxide two aluminium powder 8 parts, filler 70 parts, epoxy resin 35 parts, waterborne epoxy modified acrylic ester 18 parts, glass microballon 17 parts, chitin 15 parts, chitosan 18 parts, nanometer titanium dioxide 30 parts, nano zine oxide 18 parts, nano silicon 13 parts, 25wt% ammoniacal liquor 3 parts, ACRYLIC EMULSION 35 parts and Nano Rare soil nature self-luminescent material 18 parts.
Wherein, described filler is any one in calcium titanate, talcum powder and ground silica.Preferably, be talcum powder.
Described ACRYLIC EMULSION is any one or a few in benzene emulsion, acrylate and vinyl acetate emulsion, vac-veova emulsion, pure-acrylic emulsion.Preferably, be benzene emulsion.
Further, as preferably, the particle diameter of described ACRYLIC EMULSION is 0.15 ~ 0.5 μm.
The present invention proposes the preparation method of above-mentioned nano combined road mark paint simultaneously, the glass powder of formula ratio, filler, epoxy resin, 25wt% ammoniacal liquor, chitin and chitosan is comprised the steps: to be mixed to join in stirrer, at 30 ~ 40 DEG C, stir 0.5 ~ 1h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, ACRYLIC EMULSION and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 0.5 ~ 1h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 0.5h, obtain nano combined road mark paint.
Waterborne epoxy modified acrylic ester has concentrated the characteristic of acrylate and epoxy resin, by the combination with nano silicon, can improve the degree of crosslinking of coating, greatly strengthen the over-all properties of coating.Nanometer silicon dioxide particle size is little, specific surface area is large, surface also exists the hydroxyl of a large amount of unsaturated link(age) and different bond styles, there is bonding reaction in the hydroxyl, carboxyl, nitrogen-atoms etc. of activity hydroxy easily and in coating polymer on its surface, form nano intercalation compounding material structure, greatly can increase cross-linking density and the Intermolecular Forces of coating, improve coating property.
Chitin and chitosan all has good binding property, biocompatibility, biological degradability and special adsorptivity, be a kind of nontoxic, have no side effect, free of contamination nitrogenous superpolymer, for traffic marker luminous paint can pollutent in a large number in absorbed air and virus, bacterium, especially have high germ resistance to the intestinal bacteria in bacterium, streptococcus aureus, botrytis cinerea, least bit germ.
Nanometer titanium dioxide can not affect the reproductivity of bacterium, and the skin of energy attack bacteria cell, and permeates cell membranes, destroys the membrane structure of bacterium, reaches the object of the secondary pollution that thorough bacterium for degrading disease prevents intracellular toxin from causing further.
Nano zine oxide has sterilization, wear-resisting, absorption UV-lamp effect, more eager to excel in whatever one does than traditional nano-titanium to ultraviolet protection function.
Beneficial effect: compared with prior art, composite by between invention raw material, nano combined road mark paint of the present invention has fast drying, wear-resisting, anti-soil, long service life and have the effect resisting bacterium simultaneously, nano material or nanostructure component is introduced in organic coating and realize compound that organic and inorganic phase coordinates or hydridization.The advantage of comprehensive organic polymer and inorganic structure component, makes coating property significantly be improved.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvement, these improvement also should be considered as protection scope of the present invention.The Nano Rare soil nature self-luminescent material used in the present invention is bought from Guangdong Na Ming novel material scientific & technical corporation.
Embodiment 1:
A kind of nano combined road mark paint, comprises the component of following parts by weight: 25 parts, glass powder, titanium dioxide two aluminium powder 8 parts, calcium titanate 70 parts, epoxy resin 35 parts, waterborne epoxy modified acrylic ester 18 parts, glass microballon 17 parts, chitin 15 parts, chitosan 18 parts, nanometer titanium dioxide 30 parts, nano zine oxide 18 parts, nano silicon 13 parts, 25wt% ammoniacal liquor 3 parts, benzene emulsion (particle diameter is 0.4 μm) 35 parts and Nano Rare soil nature self-luminescent material 18 parts.
Its preparation method is as follows: be mixed to join in stirrer by the glass powder of formula ratio, calcium titanate, chitin and chitosan, at 35 DEG C, stir 1h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, benzene emulsion and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 1h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 0.5h, obtain nano combined road mark paint.
Embodiment 2:
A kind of nano combined road mark paint, comprises the component of following parts by weight: 20 parts, glass powder, titanium dioxide two aluminium powder 10 parts, talcum powder 50 parts, epoxy resin 40 parts, waterborne epoxy modified acrylic ester 15 parts, glass microballon 20 parts, chitin 10 parts, chitosan 20 parts, nanometer titanium dioxide 20 parts, nano zine oxide 15 parts, nano silicon 15 parts, 25wt% ammoniacal liquor 2 parts, pure-acrylic emulsion 40 parts (particle diameter is 0.35 μm) and Nano Rare soil nature self-luminescent material 15 parts.
Its preparation method is as follows: be mixed to join in stirrer by the glass powder of formula ratio, talcum powder, chitin and chitosan, at 30 DEG C, stir 0.8h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, pure-acrylic emulsion and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 0.8h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 0.5h, obtain nano combined road mark paint.
Embodiment 3
A kind of nano combined road mark paint, comprises the component of following parts by weight: 30 parts, glass powder, titanium dioxide two aluminium powder 6 parts, ground silica 80 parts, epoxy resin 30 parts, waterborne epoxy modified acrylic ester 20 parts, glass microballon 15 parts, chitin 20 parts, chitosan 15 parts, nanometer titanium dioxide 40 parts, nano zine oxide 15 parts, nano silicon 15 parts, 25wt% ammoniacal liquor 2 parts, vac-veova emulsion (particle diameter is 0.35 μm) 40 parts and Nano Rare soil nature self-luminescent material 15 parts.
Its preparation method is as follows: be mixed to join in stirrer by the glass powder of formula ratio, ground silica, chitin and chitosan, at 40 DEG C, stir 1h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, vac-veova emulsion and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 1h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 1h, obtain nano combined road mark paint.
Embodiment 4
A kind of nano combined road mark paint, comprises the component of following parts by weight: 26 parts, glass powder, titanium dioxide two aluminium powder 7 parts, talcum powder 75 parts, epoxy resin 36 parts, waterborne epoxy modified acrylic ester 18 parts, glass microballon 18 parts, chitin 17 parts, chitosan 17 parts, nanometer titanium dioxide 23 parts, nano zine oxide 19 parts, nano silicon 13 parts, 25wt% ammoniacal liquor 3 parts, benzene emulsion (particle diameter is 0.25 μm) 32 parts and Nano Rare soil nature self-luminescent material 18 parts.
Its preparation method is as follows: be mixed to join in stirrer by the glass powder of formula ratio, talcum powder, chitin and chitosan, at 35 DEG C, stir 1h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, benzene emulsion and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 1h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 1h, obtain nano combined road mark paint.

Claims (6)

1. a nano combined road mark paint, is characterized in that, it comprises the component of following parts by weight:
20 ~ 30 parts, glass powder, titanium dioxide two aluminium powder 6 ~ 10 parts, filler 50 ~ 80 parts, epoxy resin 30 ~ 40 parts, waterborne epoxy modified acrylic ester 15 ~ 20 parts, glass microballon 15 ~ 20 parts, chitin 10 ~ 20 parts, chitosan 15 ~ 20 parts, nanometer titanium dioxide 20 ~ 40 parts, nano zine oxide 15 ~ 20 parts, nano silicon 10 ~ 15 parts, 25wt% ammoniacal liquor 2 ~ 4 parts, ACRYLIC EMULSION 30 ~ 40 parts and Nano Rare soil nature self-luminescent material 15 ~ 20 parts.
2. nano combined road mark paint according to claim 1, is characterized in that, it comprises the component of following parts by weight:
25 parts, glass powder, titanium dioxide two aluminium powder 8 parts, filler 70 parts, epoxy resin 35 parts, waterborne epoxy modified acrylic ester 18 parts, glass microballon 17 parts, chitin 15 parts, chitosan 18 parts, nanometer titanium dioxide 30 parts, nano zine oxide 18 parts, nano silicon 13 parts, 25wt% ammoniacal liquor 3 parts, ACRYLIC EMULSION 35 parts and Nano Rare soil nature self-luminescent material 18 parts.
3. nano combined road mark paint according to claim 1, is characterized in that, described filler is any one in calcium titanate, talcum powder and ground silica.
4. nano combined road mark paint according to claim 1, is characterized in that, described ACRYLIC EMULSION is any one or a few in benzene emulsion, acrylate and vinyl acetate emulsion, vac-veova emulsion, pure-acrylic emulsion.
5. accumulating type luminous nano material according to claim 4, is characterized in that, the particle diameter of described ACRYLIC EMULSION is 0.15 ~ 0.5 μm.
6. the preparation method of nano combined road mark paint according to claim 1, it is characterized in that, the glass powder of formula ratio, filler, epoxy resin, 25wt% ammoniacal liquor, chitin and chitosan is comprised the steps: to be mixed to join in stirrer, at 30 ~ 40 DEG C, stir 0.5 ~ 1h, obtain A mixed solution; The glass microballon of formula ratio, titanium dioxide aluminium powder, nanometer titanium dioxide, nano zine oxide, nano silicon, waterborne epoxy modified acrylic resin, ACRYLIC EMULSION and Nano Rare soil nature self-luminescent material are mixed to join in stirrer, 0.5 ~ 1h is stirred under normal temperature, obtain B liquid, the A liquid obtained is joined in B liquid, stir 0.5h, obtain nano combined road mark paint.
CN201410484463.XA 2014-09-19 2014-09-19 Nanocomposite road marking coating material Pending CN104263198A (en)

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CN106634310A (en) * 2016-12-29 2017-05-10 沈阳化工研究院有限公司 Environment-friendly water-based road marking coating and preparation method thereof
CN108276899A (en) * 2018-01-25 2018-07-13 天途路业集团有限公司 A kind of multicomponent spraying gage mark coating and its preparation method and application
CN110528419A (en) * 2019-07-25 2019-12-03 安徽子午线标识标牌工程有限公司 A kind of two-sided traffic signboard and preparation method thereof
CN112662261A (en) * 2020-12-31 2021-04-16 山西中涂交通科技股份有限公司 Self-cleaning road marking paint and preparation method thereof

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Application publication date: 20150107