CN102898880A - Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint - Google Patents
Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint Download PDFInfo
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- CN102898880A CN102898880A CN2012102986016A CN201210298601A CN102898880A CN 102898880 A CN102898880 A CN 102898880A CN 2012102986016 A CN2012102986016 A CN 2012102986016A CN 201210298601 A CN201210298601 A CN 201210298601A CN 102898880 A CN102898880 A CN 102898880A
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Abstract
The invention belongs to a nano-grade composite material technology used in a paint field for modifying paint, and provides a green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint. The invention belongs to the technical field of multifunctional energy-night-storage luminescent paint preparation and production. According to the nano-grade composite material, particle sizes of nano-grade materials CaCO3, ZnO, SiO2, TiO2 and Al2O3, and tourmaline maifanite, chitin and chitosan viscose fiber bentonite, kaolin, silicon lime soil, and the like are reduced to a nano grade; and the nano-particles are uniformly dispersed in a paint through methods of ball milling and dispersing agent adding. Therefore, the paint is a green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint provided with multiple functions such as trace element releasing, far-infrared irradiating, electromagnetic pollution preventing, continuous anion generating, air purifying, toxic or harmful gas absorbing, and heavy metal absorbing.
Description
Technical field:
Environmental protection multifunctional nano energy-accumulating luminous paint at night of the present invention is to belong to the nano composite material technology, is applied to paint field to change the preparation production technical field of coating energy-accumulating luminous paint at multi-functional night.
Background technology:
Though China use nano material with many performances of improving coating than external late starting more than 10 year, although the time lacks, also obtained gratifying achievement.Nano material or nanostructure component introduced realize organic cooperate with inorganic phase compound in the organic coating or be hydridization.The two advantage of comprehensive organic polymer and inorganic structure component is significantly improved coating property.For example use nano titanium oxide TiO
2, compound ferrotianium replaces good but the red lead Pb that toxicity is very large of rustless property
3O
4Pigment is widely applied in protective system.Meet the asepsis environment-protecting requirement, and price is better than again red lead.TiO
2Be again the representative that light is urged the formula sterilization, have the antibiotic and sterilizing effect, again can shield ultraviolet radiation, the multi-functional range of application of the antibiotic paint such as anti-electromagnetic wave pollution.The biological special performance of nano material will be far-reaching on the impact of coating.As mentioned above, be prepared into the main direction that nano composite dope is paint development with nano material in conjunction with traditional coating.Described nano composite dope is exactly with nano material CaCO
3, SiO
2, TiO
2, Al
2O
3Reach the size of particles such as medical stone, tourmalinite, crust rope and chitosan viscose fiber, wilkinite, kaolin, silicon dirt and be reduced to gradually nano-particles size, those are reduced to nano level, with ball milling method with add dispersion agent and solve that nanoparticle disperses and agglomeration traits.Newly-generated nano material also can evenly, stably be distributed in the polymeric matrix with atom level particle state stable existence, and the phase of generation nanoscale is the mixture of bonding perhaps.In order to overcome the reunion between nanoparticle, in the system of the nano material of being everlasting, add organic surface active agent and inorganic defloculating agent.They borrow respectively sticking power and electrostatic attraction, and absorption is deposited on nanoparticle surface, realize the surface modification of nanoparticle, have overcome the reunion of nanoparticle.For example: SiO
2, Al
2O
3, TiO
2PH value in solution is different and with positive electricity or negative electricity, therefore can select Na
+, NH
4 +, Cl
-, NO
3 -Conductive ion is made defloculating agent, makes microparticle surfaces form electrostatic double layer, thereby reaches the purpose of dispersion: nano-TiO
2The surface forms TiO
2/ Al
2O
3, TiO
2/ SiO
2Nano composite material.This is the known knowledge of the art personnel.
Silicon-dioxide SiO in the medical stone composition
2Degree accounts for 59.60%, aluminium dioxide Al
2O
3Account for 16.50%, ferric oxide Fe
2O
3Account for 2.58%, titanium dioxide TiO
2Account for 0.78%, these materials are ferrite, magnetic iron powder ions of the modal oxide compound of radiation far infrared and the anti-electromagnetic wave shielding of polluting, are again continuously simultaneously the main components in the tourmalinite of spontaneous generation negative ion.So making coating have the pollution of release of trace elements radiation far infrared anti electromagnetic wave, the application of these materials can spontaneously constantly produce the anion fine-purification air again, the nanometer environmental protection energy-accumulating luminous paint at multi-functional night of toxic and harmful and heavy metal ion in absorption, the antagonism road air.
Summary of the invention:
For the road mark paint that promotes traditional architecture coating and special purpose, reflecting roads sign coating, energy-accumulating luminous paint, luminescent coating, multi-function luminous paint, reflective composite painting, neon luminescent paint etc., be usually used in that nano material in the coating mainly contains nanometer metallic silver Ag, nanometer silver is that broad spectrum high-effect antiseptic-germicide and anti-microbial effect are lasting, to the harmful germ of the kind more than 650 that comprises bacterium, fungi, trichomonad, mycoplasma, good inhibition or killing action are arranged all.Bacterial strain flora to resistance has equal killing power.The silver of minimum number just can kill a large amount of pathogenic organisms bodies.Still do not find up to now that under lab any microorganism is not killed by silver in 6min, and nano-metal-oxide TiO
2, SiO
2, CaCO
3, ZnO, nano titanium oxide TiO
2, the photochemical catalysis ultraviolet radiation absorption stablizes germicidal action, and is low with its active height, thermally-stabilised good, antibiotic longer duration, price, humans is become a kind of photocatalyst-type anti-biotic agent of greatest concern.TiO
2After rayed, original bound state electron-hole pair becomes the excited state electronics, spread to grain surface in the hole, and the quantity that electronics, hole arrive the surface is many, and then photocatalysis efficiency is high, and reactive behavior is large, good anti-bacterial effect.Therefore the particle of nano material is less, and electronics, the hole probability of recombination in particle is less, and it is faster to arrive the surface time, and photocatalysis efficiency is higher.Nano silicon SiO
2Having hydrophobicity, anti-soil enhancement, be amorphous white powder, is a kind of nontoxic, tasteless, free of contamination ceramic, is cotton-shaped and netted accurate grain pattern, for spherical.Nano-calcium carbonate CaCO
3Has the anti-usefulness of pretending, mean particle diameter inorganic powder product in the 1-100nm scope of chemosynthesis calcium carbonate, it is a kind of Novel super-thin solid material, its crystalline structure and Electronic Structure change, produce quantum size effect, small-size effect, surface effects and macro quanta tunnel effect are compared with conventional material at aspects such as magnetic, catalytic, photo-thermal resistances and to be demonstrated the performance that is unsurpassed in excellence.Nano zine oxide ZnO has sterilization, wear-resisting, ultraviolet radiation absorption effect etc., even it is more eager to excel in whatever one does than traditional nano-titanium to ultraviolet protection function.
The nanometer titanium dioxide product must have ultraviolet light irradiation to produce electron-hole pair by excitation electron, play effect antibiotic, decomposing organic pollutant, developed at present organic and inorganic multiple-level surface coating technology, developed that antibiotic spectrum width antimicrbial power is strong, anti-microbial effect is lasting, nondiscoloration, Nanometer Titanium Dioxide powder product series that cost is low.As long as the characteristics of this product are to have lamp to exist, and no matter are long wave light source or shortwave light source, can as the excitation light source of nanometer titanium dioxide photocatalyst, make material play antibiotic and effect degradable organic pollutant.When the nanometer titanium dioxide with high security carries out sterilization, to the activated surface adsorbent, produce strong oxidizer and strong reductant by separate electronic-hole, the attack bacteria organism plays germicidal action.Nanometer titanium dioxide can not only affect the reproductivity of bacterium, and the skin of energy attack bacteria cell, and permeates cell membranes is destroyed the membrane structure of bacterium, reaches thorough bacterium for degrading, and further prevents the purpose of the secondary pollution that intracellular toxin causes.
Chitin claims again chitin two fourth matter.Chitin fiber and chitin fiber all belong to viscose fiber.Chitin belongs to polysaccharide, processes through concentrated base, can dewater, and the N-ethanoyl in the chitin structural formula reaches 55% then becomes the most important derivative chitosan of chitin when above, claims again chitosan or chitosan.It is a kind of natural antiseptic-germicide, and is main from adamantine parts of animal housing such as natural shell, crab shell, shrimp shell, fish-bone and insects.A kind of colourless, tasteless, nontoxic, sun-resistant, heat-resisting, the corrosion resistant crystallization and the amorphous substance that obtain through sloughing the N-ethanoyl.Chitin and chitosan all has good binding property, biocompatibility, biological degradability and special adsorptivity are a kind of nontoxic, have no side effect, free of contamination natural a kind of positively charged nitrogenous superpolymer, be used for traffic marker luminous paint in a large number pollutent and the virus of absorbed air, bacterium, its anti-microbial effect principle is: chitin and chitosan with positively charged ion with consist of microorganism wall sialic acid SIALIC or phospholipid negatively charged ion generation ionic bond, fettered the degree of freedom of microorganism, hinder its growth, chitin and chitosan, also be broken down into low molecule infiltration in the microbial cell wall, hinder the transfer of gene from DNA to RNA, thereby the development and fecundity that has stoped microorganism is especially to the intestinal bacteria in the bacterium, the streptococcus aureus botrytis cinerea, A. mali has high germ resistance.According to electron microscope observation, obvious morphological change has occured in bacterium after the chitin and chitosan effect: gram-positive microorganism, as streptococcus aureus, bacteria wall attenuation and to damaged, copy and be suppressed; Gram-negative bacteria: concentrated such as colibacillary bacterial cytoplasm, the space obviously enlarges, and this shows that the effect of chitin and chitosan can affect growing of bacterial cell.Chitin and chitosan just can dissolve in suitable solvent, if be mixed with the solution of finite concentration, certain viscosity, can be made into long filament or staple fibre by wet spinning or dry-spinning method, it is chitin viscose or chitosan viscose fiber that chitin fiber and chitin fiber all belong to viscose fiber.They all have very strong bacteriostasis to Gram-negative bacteria or positive bacteria, mould virus.Survey proof through bolt, to gram-positive microorganism such as the modal streptococcus aureus of people, bacteriostasis reaches 100%, and Gram-negative bacteria such as intestinal bacteria bacteriostasis are reached 70.43%, can reach 50.11% to the mould bacteriostasis of Candida albicans.
So coating of the present invention can be killed various bacteria, virus, release various trace elements in the road air dust effectively, heavy metal contamination in absorption, the antagonism air, purify the air in the traffic route, the negative aeroion that spontaneous continuous generation is useful to HUMAN HEALTH.
The present invention is further described below in conjunction with examples of implementation:
Embodiment one: nano-material modified latex gluing forms % by following quality proportioning:
(1) wetting agent 0.2%; (11) CaCO
3Nano assistant 2%;
(2) ethylene glycol 1.8%; (12) 50% phenylpropyl alcohol lactic acid 18.6%;
(3) dispersion agent 1.0%; (13) defoamer 0.2%;
(4) sanitas 0.2%; (14) 2% pre-solution glue second hydroxylated celluloses 5%;
(5) suds suppressor 0.2%; (15) the chitin viscose fiber 5%;
(6) film coalescence aid 1.2%; (16) thickening material I 0.8%;
(7) Rutile type Titanium Dioxide 10%; (17) thickening material II 0.4%;
(8) the medical stone nano powder 5%; (18) the tourmalinite nano powder 5%;
(9) the kaolin nano powder 6%; (19) silicon dirt nano powder 8%;
(10) heavy carbon nano powder 8.4%; (20) water is added to 100%.
Embodiment two: the preparation of luminescent coating forms % by following quality proportioning:
1, traffic line coating:
(1) the noctilucence nano powder 17; (7) the chitosan viscose fiber 10;
(2) titanium dioxide 9; (8) calcium carbonate 3;
(3) the medical stone nano powder 6; (9) Cobalt Manganese catalyzer 2;
(4) the tourmalinite nano powder 6; (10) granulated glass sphere 10;
(5) talcum powder 5; (11) aluminium pigment 4;
(6) the stand oil paint vehicle 27; (12) toluene 1.
2, be used for sign manufacturing coating:
(1) noctilucent material 38; (4) the quadrol solidifying agent 2;
(2) granulated glass sphere 16; (5) Resins, epoxy 34.
(3) chitin viscose 10;
Embodiment three: night, the nano luminescent coating preparation divided two steps of following A, B to form
A, the first step is at first will prepare the nano-luminescent powder at night, B, second step is multiple with luminous paint again with luminescent powder
Being mixed with the Noctilucent nanometer luminous paint sees lower:
A, noctilucence powder form % by following proportion by weight
(1)TiO
2 10； (8)B
2O
3 2；
(2)Al
2O
3 23； (9)MgO 1.5；
(3)BaCO
3 6； (10)NaCl 0.5；
(4)SrCL
2 41； (11)BsCl 2；
(5)HBO
3 3； (12)MgCO
3 2；
(6)SrCl
2 4； (13)SiO
2 1；
(7)CaCO
3 2； (14)Eu
2O
3 2。
The preparation method:
The preparation method of noctilucence powder: take by weighing various raw materials input mechanical ball grinding machines by proportioning and carry out the mechanical ball milling reason, the mixing raw material inserted in 900-1400 ℃ the High Temperature Furnaces Heating Apparatus, carry out solid state reaction 1-5h, then 800-1300 ℃ of F with inert gas replacement anti-stove Air: when air displacement passes into hydrogen or carbon 1-3h after fully again, come out of the stove the cooling after, material is screened under ultraviolet ray, carry out ball milling again and make material reach nano level, its particle diameter reaches 50 μ m and gets final product.
The nanometer luminescent coating of B, traffic line usefulness forms % by following proportion by weight
(1) the noctilucence nano powder 15; (9) UV light absorber 2;
(2) the medical stone nano powder 6; (10) titanium dioxide 4;
(3) the tourmalinite nano powder 6; (11) talcum powder 3;
(4) chitin viscose 7; (12) metallic pigment 2;
(5) lithopone 4; (13) granulated glass sphere 6;
(6) stibium trioxide 3; (14) calcium carbonate 2;
(7) silicon-dioxide 4; (15) nanometer metallic silver Ag 1;
(8) the Cobalt manganic drier 2; (16) the stand oil paint vehicle 33.
The preparation method:
The preparation method who is fit to the luminescent coating of traffic road line, at first in polymerization paint, add successively the medical stone nano powder, the tourmalinite nano powder, chitin viscose, titanium dioxide, stibium trioxide, lithopone, talcum powder, silicon-dioxide, nanometer metallic silver Ag, UV light absorber, calcium carbonate, metallic pigment etc., the high-speed stirring while adding, ground 1000 mesh sieves, its particle diameter is reached below the nano level 50 μ m, and adjust viscosity with thinner, adding the noctilucence nano powder, granulated glass sphere, the Cobalt manganic drier, continue to stir, grinding makes the particle diameter of coating below 50 μ m, adjusts the viscosity 50-150s of coating with thinner.
Embodiment four: night, nano luminescent coating formed % by following proportion by weight
(1) the propylene glycol phenylate 3; (9) nanometer silver 0.4;
(2) night nano-luminescent powder 10; (10) aerosil 0.4;
(3) the medical stone nano powder 7; (11) tributyl phosphate 0.4;
(4) the tourmalinite nano powder 6; (12) pentachlorophenol 0.2;
(5) the chitosan viscose fiber 6; (13) granulated glass sphere 6;
(6) the poly-hydroxy acid salt 0.4 of dispersion agent; (14) acrylate and vinyl acetate emulsion 30.4;
(7) the calcium carbonate nano powder 1.2; (15) water 33;
(8) talcum powder 1; Amount to 100%.
The preparation method:
The water that takes by weighing 33kg is poured in the material-compound tank, take by weighing respectively PPH 3kg, dispersion agent gathers hydroxy acid salt 0.4kg, medical stone nano powder 7kg, tourmalinite nano powder 6kg, chitosan viscose fiber 6kg, acrylate and vinyl acetate emulsion 30.4kg, calcium carbonate nano powder 1.2kg, superfine talcum powder 1kg, aerosil 0.4kg, night nano-luminescent powder 10kg, join in the material-compound tank successively and stir, after stirring, be transferred to ball milling 50min in the ball mill, after take by weighing defoamer tributyl phosphate 0.4kg, mould inhibitor pentachlorophenol 0.2kg, thickening material caustic solubility vinylformic acid 0.6kg joins in the ball mill, ball milling 15min again, the pulp finished product packing.
This, nano luminescent coating sent blue-greenish colour noctilucence at the dark place at night, covered to be applied to plastics, plank surface 0.3mm, closely arrived 3420mcd/m according to German DIN67510 standard test luminous intensity
2H twilight sunset 7.6mcd/m
2
Product application: this product can be used for the fields such as road, boats and ships, building, fire symbol, label.
Embodiment five: applicable each field luminous paint forms % by following proportion by weight
(1) the fluorescence radiation nano powder 10; (7) zinc oxide nano 1;
(2) chloroprene rubber 15; (8) sulphur 0.5;
(3) chitin viscose 5; (9) light magnesium oxide 1;
(4) the medical stone nano powder 6; (10) toluene 1;
(5) the tourmalinite nano powder 5; (11) ethyl acetate 1;
(6) white carbon black 1; (12) 2402 resins 53.5.
The preparation method:
Above-mentioned raw materials by its proportion by weight in retort blend in 40-50 ℃, insulated and stirred 13h and get final product.
Product application:
This coating is a kind of luminous paint, is a kind of inactive luminous paint, can with various material broad incorporation, be applied to the wide spectrums such as national defence troops' usefulness, traffic safety, instrument, family room's interior trim, clothes and hidden trade mark.Environmental protection safe release trace element, purifies air, adsorbs antagonism toxic and harmful and aluminium, mercury, arsenic, cadmium heavy metal objectionable impurities at spontaneous generation negative ion.
Embodiment six: reflecting roads sign coating forms % by following proportion by weight
(1) chitin viscose 8; (8) white carbon black 1;
(2) the medical stone nano powder 6; (9) wilkinite 1;
(3) the tourmalinite nano powder 6; (10) defoamer 0.2;
(4) titanium dioxide 2; (11) thickening material 0.2;
(5) talcum powder 0.6; (12) granulated glass sphere 16;
(6) water-ground limestone 2; (13) toluene 27;
(7) light calcium carbonate 7; (14) the methylene acid resin 24.
The preparation method:
At first take by weighing reaction raw materials by the top proportion by weight, thinner toluene is put into high speed dispersor, then add the methylene acid resin, disperse 4-7min in the high speed dispersor.After the shutdown, add titanium dioxide, then the high speed dispersion of starting shooting again 2-4min shuts down, and more remaining whole raw materials is dropped in the dispersion machine, and homodisperse 15-30min is carried out in start again; To disperse reacted material to change in the sand mill, the control feeding speed, then sand milling 2-3 time filters, and filtrate is product of the present invention.The scene was mixed and enters coating when granulated glass sphere was constructed again, added the granulated glass sphere total amount by the above granulated glass sphere of 20% 100 orders.The methylene acid resin is produced by Changzhou coating institute, thinner nail benzene of the present invention, and white black wood charcoal is used pigment, titanium dioxide is rutile-type preferably.
Product application:
Coating of the present invention can be sprayed on the base materials such as fabric, road, plank, plastic cord, plays channel traffic, indication road conditions, helps driver and the pedestrian rule that observe traffic laws, and guarantee people and Che a piece of wood serving as a brake to halt a carriage safety, environmental protection are without the three wastes and radiocontamination.
Embodiment seven: be fit to make the luminescent coating of label, lighting source by following proportion by weight scope %
Noctilucent material 20-70%; Compound resin 20-70%;
Softening agent 0-20%; Solidifying agent 0-20%;
Batching 0-15%; Thinner 0-5%.
Wherein compound resin refers to the collocation of the transparent resins such as Resins, epoxy, Synolac, peroxide ethenoid resin, melamine resin.
Embodiment eight: accumulation of energy at night nano luminescent coating follows these steps to two steps compositions of a minute A, B and sees lower:
A, making coating Illuminant nanometer powder form by following proportion by weight
Polyethylene wax 0.35;
Dehydrated alcohol 60;
Bluish-green luminescent powder 100.
The preparation method:
Take by weighing solution phase that polyethylene wax 0.35g is dissolved in dehydrated alcohol 60g in the solution of dehydrated alcohol 60ml, add again bluish-green luminescent powder 100g, carry out ball milling 1.5h, pulp, vacuum-drying namely obtains yellow-green colour coating nano-luminescent powder.
B, luminous paint form % by following proportion by weight
Alcohol ester-12 2.8%; Tributyl phosphate 0.6%;
Coating Illuminant nanometer powder 13%; Pentachlorophenol 0.4%;
Dispersant polycarboxylate 0.4%; Alkali swelling property vinylformic acid 0.8%;
Wilkinite 3%; Chitin viscose 6%;
Medical stone nano powder 4%; Pure-acrylic emulsion 32%;
Tourmalinite nano powder 4%; Water 33%.
The preparation method:
The water that takes by weighing 33kg is poured in the material-compound tank, takes by weighing respectively film coalescence aid alcohol ester-12,2.8kg, dispersant polycarboxylate, molecular weight 4500,0.4kg, pure-acrylic emulsion 32kg, wilkinite 3.0kg, coating Illuminant nanometer powder 13kg, the medical stone nano powder, each 4kg of tourmalinite nano powder, chitin viscose 6kg, join successively in the material-compound tank, after stirring, then turn to join and carry out ball milling 50min in the ball mill, take by weighing again defoamer tributyl phosphate 0.6kg, mould inhibitor pentachlorophenol 0.4kg, thickening material alkali swelling property vinylformic acid 0.8kg joins in the ball mill, carries out ball milling 15min, pulp, finished product packing.
This luminous paint is coated on plastic wood board or metallic surface 0.3mn, in the dark sends yellow-green light, and luminous intensity can reach 3740mcd/m
2, 10h twilight sunset 9.6mcd/m
2
Embodiment nine: fast setting noctilucence traffic marking coating forms % by following proportion by weight
(1) bisphenol-a epoxy acrylate 12;
(2) aliphatic urethane acrylate 8;
(3) polyester acrylate 5;
(4) the 16-hexanediyl ester 3;
(5) tri (propylene glycol) diacrylate 12;
(6) Viscoat 295 8;
(7) Hydroxyethyl acrylate 5;
(8) the medical stone nano powder 6;
(9) the tourmalinite nano powder 5;
(10) superfine titanium white 0.8;
(11) chitin viscose 3;
(12) ultra-fine ground silica 4;
(13) superfine light calcium carbonate 9;
(14) superfine talcum powder 10;
(15) the benzoin ether photoinitiator 5;
(16) benzoyl group phosphorus oxide compound photosensitizers 3;
(17) flow agent 0.7;
(18) antisettling agent 0.5;
Amount to 100%.
The preparation method:
(1) makes homogeneous solution A
At first the compound of benzoin ether photoinitiator 5% and the material of benzoyl group phosphorus oxide compound photosensitizers 2% are formed uniform solution A with the dissolving of 16-hexanediyl ester under 60-80 ℃ temperature by proportioning;
(2) make homogeneous solution B
By proportioning titanium dioxide 0.8%, medical stone nano powder 6%, tourmalinite nano powder 5% are added in the Viscoat 295 8%, sand milling 2h on sand mill makes it make homogeneous solution B;
(3) make homogeneous solution C
By proportioning crust rope viscose fiber 3%, superfine light calcium carbonate 9%, superfine talcum powder 10%, ultra-fine ground silica 4% are added in the material of tri (propylene glycol) diacrylate 12.8%, in sand mill sand milling 2-3h, make homogeneous solution C;
(4) make the coating finished product
After above-mentioned homogeneous solution A, B, C mixing, after fully stirring 2h, add again bisphenol-a epoxy acrylate 12.8%, add aliphatic urethane acrylate 8% after stirring 1h, add again polyester acrylate 5% behind the restir 1h, continue to stir behind the 1h intensification 50-60 ℃, continue again to stir 3h after adding flow agent 0.4% and antisettling agent 0.2%, can discharging make traffic marker fast setting noctilucence traffic marker coating of the present invention.
Claims (8)
1. its feature of the multi-functional accumulation of energy at night of environmental protection nano luminescent coating:
Nano-material modified latex coating forms % by following proportion by weight
(1) wetting agent 0.1-0.3%; (11) CaCO
3Nano assistant 1-3%;
(2) ethylene glycol 0.9-2.7%; (12) 50% phenylpropyl alcohol lactic acid 9.3-27.9%;
(3) dispersion agent 0.5-1.5%; (13) defoamer 0.1-0.3%;
(4) sanitas 0.1-0.3%; (14) 2% pre-solution glue second hydroxylated cellulose 2.5-7.5%;
(5) suds suppressor 0.1-0.3%; (15) chitin viscose fiber 2.5-7.5%;
(6) film coalescence aid 0.6-1.8%; (16) thickening material I 0.4-1.2%;
(7) Rutile type Titanium Dioxide 5-15%; (17) thickening material II 0.2-0.6%;
(8) medical stone nano powder 2.5-7.5%; (18) tourmalinite nano powder 2.5-7.5%;
(9) kaolin nano powder 3-9%; (19) silicon dirt nano powder 4-12%;
(10) heavy carbon nano powder 4.2-12.6%; (20) water is added to 100%.
2. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating is characterized in that minute two portions form A and make the noctilucence nano powder, and B nanometer luminescent coating is seen lower:
A noctilucence nano powder forms % by following proportion by weight
(1)TiO
2 5-15％； (8)B
2O
3 1-3％；
(2)Al
2O
3 20-30％； (9)MgO 1-2％；
(3)BaCO
3 1-11％； (10)NaCl 0.2-0.8％；
(4)SrCO
3 36-46％； (11)BaCl
2 1-3％；
(5)HBO
3 2-4％； (12)MgCO
3 1-3％；
(6)SrCl
2 3-5％； (13)SiO
2 0.5-1.5％；
(7)CaCO
3 1-3％； (14)Eu
2O
3 1-3％。
The nanometer luminescent coating of B traffic line usefulness forms % by following proportion by weight
(1) noctilucence nano powder 1-2%; (9) UV light absorber 1-3%;
(2) medical stone nano powder 1-11%; (10) titanium dioxide 3-5%;
(3) tourmalinite nano powder 1-11%; (11) talcum powder 2-4%;
(4) chitin viscose 2-12%; (12) metallic pigment 1-3%;
(5) lithopone 3-5%; (13) granulated glass sphere 1-11%;
(6) stibium trioxide 2-4%; (14) calcium carbonate 1-3%;
(7) silicon-dioxide 3-5%; (15) nanometer metallic silver Ag 0.5-1.5%;
(8) Cobalt Manganese catalyzer 1-3%; (16) stand oil paint vehicle 28-38%.
3. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: form % by following proportion by weight
(1) propylene glycol phenylate 2-4%; (9) nanometer silver Ag 0.2-0.6%;
(2) night nano-luminescent powder 5-15%; (10) aerosil 0.2-0.6%;
(3) medical stone nano powder 2-12%; (11) tributyl phosphate 0.2-0.6%;
(4) tourmalinite nano powder 1-11%; (12) pentachlorophenol 0.1-0.3%;
(5) chitosan viscose fiber 1-11%; (13) alkali swelling property vinylformic acid 0.4-0.8%;
(6) dispersant polycarboxylate 0.2-0.6%; (14) ester acrylic emulsion 25.4-35.4%;
(7) calcium carbonate nano powder 0.7-1.7%; (15) water 28-38%.
(8) talcum powder 0.5-1.5%;
4. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: form % by following proportion by weight
(1) fluorescence radiation nano powder 6-14%; (7) zinc oxide nano 0.5-15%;
(2) chloroprene rubber 11-19%; (8) sulphur 0.1-0.9%;
(3) chitin viscose 1-9%; (9) light magnesium oxide 0.6-1.4%;
(4) medical stone nano powder 2-10%; (10) toluene 0.6-1.4%;
(5) tourmalinite nano powder 1-9%; (11) ethyl acetate 0.6-1.4%;
(6) white carbon black 0.6-1.4%; (12) 2402 resin 49.5-57.5%.
5. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: form % by following proportion by weight
(1) chitin viscose 4-12%; (8) white carbon black 0.5-1.5%;
(2) medical stone nano powder 2-10%; (9) wilkinite 0.5-1.5%;
(3) tourmalinite nano powder 1-9%; (10) defoamer 0.1-0.3%;
(4) titanium dioxide 1-3%; (11) thickening material 0.1-0.3%;
(5) talcum powder 0.5-0.7%; (12) granulated glass sphere 12-20%;
(6) water-ground limestone 1-3%; (13) toluene 23-31%;
(7) light calcium carbonate 3-11%; (14) methylene acid resin 20-28%.
6. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: form % by following proportion by weight
(1) noctilucent material 20-70%; (4) compound resin 20-70%;
(2) softening agent 0-20%; (5) solidifying agent 0-20%;
(3) batching 0-15%; (6) thinner 0-5%.
7. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: divide A to make coating Illuminant nanometer powder by the following step, B nano luminescent coating two steps are carried out:
A makes coating Illuminant nanometer powder and forms by following proportion by weight scope
1. polyethylene wax 0.1-0.6;
2. dehydrated alcohol 40-80;
3. bluish-green luminescent powder 80-120;
B nano luminescent coating forms % by following proportion by weight
1. alcohol ester-12 2.5-3.3%; 7. tributyl phosphate 0.3-0.9%;
2. coating Illuminant nanometer powder 11-15%; 8. pentachlorophenol 0.1-0.7%;
3. dispersion agent gathers hydroxy acid salt 0.1-0.7%; 9. alkali swelling property vinylformic acid 0.5-1.1%;
4. wilkinite 1-5%; 10. chitin viscose 4-8%;
5. medical stone nano powder 2-6%;
Alcohol acrylic emulsion 30-34%;
6. tourmalinite nano powder 2-6%;
Water 31-35%.
8. the multi-functional accumulation of energy at night of environmental protection nano luminescent coating, its feature: form % by following proportion by weight
(1) bisphenol-a epoxy acrylate 10-14%; (10) superfine titanium white 0.5-1.1%;
(2) aliphatic urethane acrylate 6-10%; (11) chitin viscose 1-5%;
(3) polyester acrylate 3-7%; (12) ultra-fine ground silica 2-6%;
(4) 1.6-hexanediyl ester 1-5%; (13) superfine light calcium carbonate 7-11%;
(5) tri (propylene glycol) diacrylate 10-14%; (14) superfine talcum powder 8-12%;
(6) Viscoat 295 6-10%; (15) benzoin ether photoinitiator 3-7%;
(7) Hydroxyethyl acrylate 3-7%; (16) benzoyl group phosphorus oxide compound photosensitizers 1-5%;
(8) medical stone nano powder 4-8%; (17) flow agent 0.3-1.0%
(9) tourmalinite nano powder 3-7%; (18) antisettling agent 0.2-0.8%.
Claim 1-8 is described, it is 100% that each assembly side's composite formula forms the % sum; The lower value of the higher limit of a certain component+other components≤100; The higher limit of the lower value of a certain component+other components 〉=100.Hereby explanation.
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