CN104263175B - A kind of nano modification anticorrosive coating - Google Patents
A kind of nano modification anticorrosive coating Download PDFInfo
- Publication number
- CN104263175B CN104263175B CN201410481667.8A CN201410481667A CN104263175B CN 104263175 B CN104263175 B CN 104263175B CN 201410481667 A CN201410481667 A CN 201410481667A CN 104263175 B CN104263175 B CN 104263175B
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- anticorrosive coating
- nano modification
- coalescents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 238000000576 coating method Methods 0.000 title claims abstract description 31
- 230000004048 modification Effects 0.000 title claims abstract description 24
- 238000006011 modification reaction Methods 0.000 title claims abstract description 24
- 239000000839 emulsion Substances 0.000 claims abstract description 27
- -1 titanium-iron Chemical compound 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 18
- DJHJJVWPFGHIPH-OODMECLYSA-N Chitin Chemical compound O[C@@H]1C(NC(=O)C)[C@H](O)OC(CO)[C@H]1COC[C@H]1C(NC(C)=O)[C@@H](O)[C@H](COC[C@H]2C([C@@H](O)[C@H](O)C(CO)O2)NC(C)=O)C(CO)O1 DJHJJVWPFGHIPH-OODMECLYSA-N 0.000 claims abstract description 15
- 229920002101 Chitin Polymers 0.000 claims abstract description 15
- 239000004359 castor oil Substances 0.000 claims abstract description 15
- 235000019438 castor oil Nutrition 0.000 claims abstract description 15
- 150000004760 silicates Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004593 Epoxy Substances 0.000 claims abstract description 14
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims abstract description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003429 antifungal agent Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 3
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- LYYSMBDYBWUXFG-UHFFFAOYSA-N piperazine;triazine Chemical compound C1CNCCN1.C1=CN=NN=C1 LYYSMBDYBWUXFG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000005543 nano-size silicon particle Substances 0.000 abstract description 12
- 230000000844 anti-bacterial Effects 0.000 abstract description 6
- 239000003973 paint Substances 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 230000003115 biocidal Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KANAPVJGZDNSCZ-UHFFFAOYSA-N 1,2-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)N=CC2=C1 KANAPVJGZDNSCZ-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K Aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 210000000481 Breast Anatomy 0.000 description 1
- 210000000170 Cell Membrane Anatomy 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 229940076185 Staphylococcus aureus Drugs 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229940001007 aluminium phosphate Drugs 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 210000004027 cells Anatomy 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000000593 degrading Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002158 endotoxin Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001717 pathogenic Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 230000001850 reproductive Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Abstract
The invention discloses a kind of nano modification anticorrosive coating, it includes the component of following parts by weight: aqueous epoxy emulsion 20～30 parts, composite Nano titanium-iron powder 5～8 parts, tripolycyanamide 10～15 parts, 15～20 parts of fluorinated silicate pottery, chitin 10～20 parts, aluminium triphosphate 5～8 parts, castor oil hydrogenated 0.5～0.8 part, nano silicon oxide 10～15 parts, nanometer Mg (OH)21～3 part, coalescents 1～3 parts, antifungus agent 0.3～0.5 part, silicone acrylic emulsion 30～40 parts, defoamer 0.5～0.8 part, dispersant 0.5～1 part and water 30～40 parts.Present invention further proposes the preparation method of above-mentioned nano paint.By compounding and cooperating between invention raw material, the nano modification anticorrosive coating of the present invention has anticorrosion, wear-resisting, anti-flammability and scrub resistance, length in service life and has the effect resisting antibacterial simultaneously, has the flame-retarding characteristic of excellence simultaneously.
Description
Technical field
The invention belongs to technical field of coatings, more particularly to a kind of nano modification anticorrosive coating.
Background technology
Anticorrosive paint is apply individual for conventional coating in relatively harsh etching condition, and has and can reach
A class anticorrosive paint to protector more longer than conventional anticorrosive paint.Existing anticorrosive paint is functional single, and lays particular emphasis on
Very anticorrosive paint, and anti-flammability, the antibiotic property of coating is considered less.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the present invention provides a kind of nano modification anticorrosive coating, has
Environmental protection is antibacterial, fire-retardant, scrubbing resistance and the characteristic of anti-contamination.
Technical scheme: in order to solve above-mentioned technical problem, the present invention proposes a kind of nano modification anticorrosive coating, and it includes
The component of following parts by weight:
Aqueous epoxy emulsion 20～30 parts, composite Nano titanium-iron powder 5～8 parts, tripolycyanamide 10～15 parts, fluorinated silicate
15～20 parts of pottery, chitin 10～20 parts, aluminium triphosphate 5～8 parts, castor oil hydrogenated 0.5～0.8 part, nanometer
Silicon oxide 10～15 parts, nanometer Mg (OH)21～3 part, coalescents 1～3 parts, antifungus agent 0.3～0.5 part, silicon the third breast
Liquid 30～40 parts, defoamer 0.5～0.8 part, dispersant 0.5～1 part and water 30～40 parts.
Preferably, described nano modification anticorrosive coating includes the component of following parts by weight: aqueous epoxy emulsion 25
Part, composite Nano titanium-iron powder 7 parts, tripolycyanamide 6 parts, fluorinated silicate pottery 18 parts, chitin 15 parts, three
Poly aluminium phosphate 13 parts, castor oil hydrogenated 0.7 part, nano silicon oxide 12 parts, nanometer Mg (OH)22 parts, coalescents
2 parts, antifungus agent 0.4 part, silicone acrylic emulsion 35 parts, defoamer 0.6 part, dispersant 0.8 part and 35 parts of water.
Wherein, in described composite Nano titanium-iron powder, the ratio of titanium elements and ferrum element is 5: 2.
Described coalescents is Texanol.
Described antifungus agent includes any one of isothiazolone, BIT or piperazine triazine.
Described defoamer is non-silicone mineral oil antifoam agent SP-202.
Present invention further proposes the preparation method of above-mentioned nano modification anticorrosive coating, comprise the steps: formula
The aqueous epoxy emulsion of amount, silicone acrylic emulsion, composite Nano titanium-iron powder, tripolycyanamide, fluorinated silicate pottery, chitin
It is mixed to join in blender, at 30～40 DEG C, stirs 0.5～1h, obtain A mixed liquor；By the tripolyphosphate of formula ratio
Aluminum, castor oil hydrogenated, nano silicon oxide, nanometer Mg (OH)2It is mixed to join in blender with water, stirs under room temperature
0.5～1h, obtain B liquid, the A liquid obtained is joined in B liquid, is simultaneously introduced the coalescents of formula ratio, dispersion
Agent, antifungus agent and defoamer stirring 0.5～1h, obtain nano modification anticorrosive coating.
In the formula of the present invention, chitin has good cohesive, biocompatibility, biological degradability and special suction
Attached property, be a kind of nontoxic, have no side effect, free of contamination nitrogenous high polymer, can adsorb in a large number the pollutant in air and
Virus, antibacterial, especially have high to the escherichia coli in antibacterial, staphylococcus aureus, botrytis cinerea, least bit pathogenic bacteria
Antibiotic property.
Aluminium triphosphate can not affect the reproductive capacity of antibacterial, and can the outer layer of attack bacteria cell, permeates cell membranes, broken
The membrane structure of bad antibacterial, reaches the purpose of the secondary pollution that thorough bacterium for degrading disease prevents endotoxin from causing further.
Nano silicon has hydrophobicity, anti-soil potentiation, for unformed white powder, is a kind of Inorganic Non-metallic Materials.
Tripolycyanamide is the organic fire-retardant that nitrogen content is higher, meanwhile, by adding Mg (OH) further2More strengthen
The flame resistance of coating, because Mg (OH)2There is preferable flame retardancy.
By adding fluorinated silicate ceramic component, ceramic component is utilized to migrate to film coated surface and occur hydrolysis generation hydrophilic
The silanol base of property invests film hydrophilic, thus reduces pollution.The addition of castor oil hydrogenated can improve spray coated effectively
The sagging phenomenon produced in journey, can avoid coating when storage due to sinking that the density variation of filler Yu base material causes simultaneously
The bad phenomenon such as the end, compounding by with other components, this ceramic material composition migrates and hydrophiling is all very fast, and has
There is good cleaning stability, after cleaning, remain in that long-acting hydrophilic.
Beneficial effect: compared with prior art, by compounding and cooperating between invention raw material, the nanometer of the present invention
Modified anticorrosive coating has anticorrosion, wear-resisting, anti-flammability and scrub resistance, length in service life and simultaneously having and resists thin
The effect of bacterium, has the flame-retarding characteristic of excellence simultaneously.Nano material or nanostructured component are introduced in organic coating and realizes
Compound or the hydridization that organic and inorganic phase coordinates.Comprehensive organic polymer and the advantage of inorganic structure component, make coating
Performance is significantly improved.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.It should be pointed out that, for the art is common
For technical staff, under the premise without departing from the principles of the invention, it is also possible to make some improvement, these improvement also should regard
For protection scope of the present invention.Water used in the present invention is bought from Guangdong Na Ming new material scientific & technical corporation.In the present invention
The particle size range of the nano material used is all at 240～300 mesh, and coalescents is Texanol, and defoamer is non-poly-silica
Alkane mineral oil antifoam agent SP-202, in composite Nano titanium-iron powder, the ratio of titanium elements and ferrum element is 5: 2.
Embodiment 1
A kind of nano modification anticorrosive coating, including the component of following parts by weight: aqueous epoxy emulsion 25 parts, compound
Nano-titanium iron powder 7 parts, tripolycyanamide 6 parts, fluorinated silicate pottery 18 parts, chitin 15 parts, aluminium triphosphate
13 parts, castor oil hydrogenated 0.7 part, nano silicon oxide 12 parts, nanometer Mg (OH)22 parts, coalescents 2 parts, different
Thiazolinone 0.4 part, silicone acrylic emulsion 35 parts, defoamer 0.6 part, dispersant 0.8 part and 35 parts of water.
Its preparation method is as follows: by the aqueous epoxy emulsion of formula ratio, silicone acrylic emulsion, composite Nano titanium-iron powder, melamine
Amine, fluorinated silicate pottery, chitin are mixed to join in blender, stir 0.5h at 40 DEG C, obtain A mixing
Liquid；By the aluminium triphosphate of formula ratio, castor oil hydrogenated, nano silicon oxide, nanometer Mg (OH)2It is mixed to join with water
In blender, stir 1h under room temperature, obtain B liquid, the A liquid obtained is joined in B liquid, is simultaneously introduced formula ratio
Coalescents, dispersant, isothiazolone and defoamer stirring 1h, obtain nano modification anticorrosive coating.
Embodiment 2
A kind of nano modification anticorrosive coating, including the component of following parts by weight: aqueous epoxy emulsion 20 parts, compound
20 parts of nano-titanium iron powder 8 parts, tripolycyanamide 10 parts, fluorinated silicate pottery, chitin 10 parts, aluminium triphosphate 8
Part, castor oil hydrogenated 0.5 part, nano silicon oxide 15 parts, nanometer Mg (OH)21 part, coalescents 3 parts, mildew-resistant
Agent 0.3 part, silicone acrylic emulsion 40 parts, defoamer 0.5 part, dispersant 1 part and 30 parts of water.
Its preparation method is as follows: by the aqueous epoxy emulsion of formula ratio, silicone acrylic emulsion, composite Nano titanium-iron powder, melamine
Amine, fluorinated silicate pottery, chitin are mixed to join in blender, stir 1h, obtain A mixed liquor at 30 DEG C；
By the aluminium triphosphate of formula ratio, castor oil hydrogenated, nano silicon oxide, nanometer Mg (OH)2It is mixed to join stirring with water
In machine, stir 0.5h under room temperature, obtain B liquid, the A liquid obtained is joined in B liquid, is simultaneously introduced formula ratio
Coalescents, dispersant, antifungus agent and defoamer stirring 0.5h, obtain nano modification anticorrosive coating.
Embodiment 3
A kind of nano modification anticorrosive coating, including the component of following parts by weight: aqueous epoxy emulsion 30 parts, compound
15 parts of nano-titanium iron powder 5 parts, tripolycyanamide 15 parts, fluorinated silicate pottery, chitin 20 parts, aluminium triphosphate 5
Part, castor oil hydrogenated 0.8 part, nano silicon oxide 10 parts, nanometer Mg (OH)23 parts, coalescents 1 part, benzo
Isothiazolone 0.5 part, silicone acrylic emulsion 30 parts, defoamer 0.8 part, dispersant 0.5 part and 40 parts of water.
Its preparation method is as follows: by the aqueous epoxy emulsion of formula ratio, silicone acrylic emulsion, composite Nano titanium-iron powder, melamine
Amine, fluorinated silicate pottery, chitin are mixed to join in blender, stir 1h, obtain A mixed liquor at 30 DEG C；
By the aluminium triphosphate of formula ratio, castor oil hydrogenated, nano silicon oxide, nanometer Mg (OH)2It is mixed to join stirring with water
In machine, stir 1h under room temperature, obtain B liquid, the A liquid obtained is joined in B liquid, is simultaneously introduced the one-tenth of formula ratio
Film auxiliary agent, dispersant, BIT and defoamer stirring 1h, obtain nano modification anticorrosive coating.
Embodiment 4
A kind of nano modification anticorrosive coating, including the component of following parts by weight: aqueous epoxy emulsion 28 parts, compound
17 parts of nano-titanium iron powder 6 parts, tripolycyanamide 13 parts, fluorinated silicate pottery, chitin 18 parts, aluminium triphosphate 7
Part, castor oil hydrogenated 0.7 part, nano silicon oxide 13 parts, nanometer Mg (OH)22.5 parts, coalescents 2.5 parts, anti-
Mould dose 0.4 part, silicone acrylic emulsion 37 parts, defoamer 0.7 part, dispersant 0.8 part and 36 parts of water.
Its preparation method is as follows: by the aqueous epoxy emulsion of formula ratio, silicone acrylic emulsion, composite Nano titanium-iron powder, melamine
Amine, fluorinated silicate pottery, chitin are mixed to join in blender, stir 0.8h at 35 DEG C, obtain A mixing
Liquid；By the aluminium triphosphate of formula ratio, castor oil hydrogenated, nano silicon oxide, nanometer Mg (OH)2It is mixed to join with water
In blender, stir 0.8h under room temperature, obtain B liquid, the A liquid obtained is joined in B liquid, is simultaneously introduced formula
The coalescents of amount, dispersant, antifungus agent and defoamer stirring 0.8h, obtain nano modification anticorrosive coating.
Claims (4)
1. a nano modification anticorrosive coating, it is characterised in that it includes the component of following parts by weight:
Aqueous epoxy emulsion 20～30 parts, composite Nano titanium-iron powder 5～8 parts, tripolycyanamide 10～15 parts, fluorinated silicate
15～20 parts of pottery, chitin 10～20 parts, aluminium triphosphate 5～8 parts, castor oil hydrogenated 0.5～0.8 part, nano oxygen
SiClx 10～15 parts, nanometer Mg (OH)21～3 part, coalescents 1～3 parts, antifungus agent 0.3～0.5 part, silicone acrylic emulsion
30～40 parts, defoamer 0.5～0.8 part, dispersant 0.5～1 part and water 30～40 parts, in described composite Nano titanium-iron powder
The ratio of titanium elements and ferrum element is 5: 2；
Described nano modification anticorrosive coating is prepared via a method which to obtain: by the aqueous epoxy emulsion of formula ratio, silicon
Acrylic emulsion, composite Nano titanium-iron powder, tripolycyanamide, fluorinated silicate pottery, chitin are mixed to join in blender,
At 30～40 DEG C, stir 0.5～1h, obtain A mixed liquor；By the aluminium triphosphate of formula ratio, castor oil hydrogenated, nanometer
Silicon oxide, nanometer Mg (OH)2It is mixed to join in blender with water, stirs 0.5～1h under room temperature, obtain B liquid, will
The A liquid obtained joins in B liquid, is simultaneously introduced the coalescents of formula ratio, dispersant, antifungus agent and defoamer and stirs
Mix 0.5～1h, obtain nano modification anticorrosive coating.
Nano modification anticorrosive coating the most according to claim 1, it is characterised in that described coalescents is
Texanol。
Nano modification anticorrosive coating the most according to claim 1, it is characterised in that described antifungus agent includes
Any one of isothiazolone, BIT or piperazine triazine.
Nano modification anticorrosive coating the most according to claim 1, it is characterised in that described defoamer is non-
Polysiloxanes mineral oil antifoam agent SP-202.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410481667.8A CN104263175B (en) | 2014-09-19 | A kind of nano modification anticorrosive coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410481667.8A CN104263175B (en) | 2014-09-19 | A kind of nano modification anticorrosive coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104263175A CN104263175A (en) | 2015-01-07 |
| CN104263175B true CN104263175B (en) | 2017-01-04 |
Family
ID=
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101429402A (en) * | 2008-12-12 | 2009-05-13 | 重庆斯耐博涂料有限公司 | Watersoluble metal self-drying antirusting paint |
| CN102002301A (en) * | 2010-11-10 | 2011-04-06 | 同济大学 | Fire-proof and corrosion-proof dual-function paint for water-based ultrathin expansion steel structure and preparation method thereof |
| CN102898880A (en) * | 2012-08-14 | 2013-01-30 | 成钢 | Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint |
| CN103045047A (en) * | 2012-12-21 | 2013-04-17 | 厦门大学 | Water-based ultrathin expansion type formed steel construction fire retardant coating based on expansible graphite and crystal whisker system |
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101429402A (en) * | 2008-12-12 | 2009-05-13 | 重庆斯耐博涂料有限公司 | Watersoluble metal self-drying antirusting paint |
| CN102002301A (en) * | 2010-11-10 | 2011-04-06 | 同济大学 | Fire-proof and corrosion-proof dual-function paint for water-based ultrathin expansion steel structure and preparation method thereof |
| CN102898880A (en) * | 2012-08-14 | 2013-01-30 | 成钢 | Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint |
| CN103045047A (en) * | 2012-12-21 | 2013-04-17 | 厦门大学 | Water-based ultrathin expansion type formed steel construction fire retardant coating based on expansible graphite and crystal whisker system |
Non-Patent Citations (2)
| Title |
|---|
| 环境友好型防锈颜料的研究进展及发展展望;方健君 等;《涂料技术与文摘》;20111130(第11期);第18-23页 * |
| 自清洁涂料的技术发展;何庆迪 等;《涂料技术与文摘》;20120731(第07期);第31-32页"2 亲水型自清洁"的内容 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102408220B (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN110218504A (en) | A kind of steel structure anti-corrosion paint | |
| AU2014237704B2 (en) | Superhydrophilic coating composition | |
| CN111607260A (en) | Organic-inorganic composite interior wall coating and preparation method thereof | |
| CN102229771A (en) | Diatomaceous earth active paint and preparation method thereof | |
| KR102283891B1 (en) | High thermal insulation coating composition for high-temperature surface parts | |
| CN104263114A (en) | Nano-material modified heat-insulation interior wall coating material | |
| KR20120050052A (en) | Using anion release antimicrobial polymer nano composite water-born coatings of inorganic liquid silicate and its manufacturing method | |
| CN110054917B (en) | Inorganic heat-insulating coating composition and inorganic heat-insulating coating | |
| CN106752726A (en) | Water-base epoxy coal tar pitch anticorrosive paint | |
| CN104212265A (en) | Nano modified flame-retardant interior wall coating | |
| CN110669388B (en) | Green-selected VAE formaldehyde-resistant emulsion paint composition with low VOC and capability of reducing indoor formaldehyde content | |
| CN104725969A (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| KR102393955B1 (en) | Eco-friendly Coating Composition for Radon Blocking Based on Aminoclay and Manufacturing Method Thereof | |
| CN104263175B (en) | A kind of nano modification anticorrosive coating | |
| CN114436616B (en) | Inorganic exterior wall mildew-proof stone-like paint | |
| KR101219687B1 (en) | Insulation coating composition for preventing dew condensation | |
| WO2020056628A1 (en) | Aqueous nano porcelain imitating coating and preparation method therefor | |
| CN104194545A (en) | Nanometer modified anti-contamination external wall coating | |
| KR100585189B1 (en) | Water-based Ceramic Photocatalyst Paint And Manufacturing Method Thereof | |
| CN110776797A (en) | Two-dimensional boron nitride modified emulsion paint and preparation method thereof | |
| CN105713456A (en) | Anti-aging and environment-friendly paint with excellent anticorrosion mechanical property | |
| CN104497760A (en) | Extra-weather-resistant fireproof coating | |
| CN104250493A (en) | Aqueous coating for decorating inner wall of antifouling building and preparation method of aqueous coating | |
| CN115260810A (en) | Environment-friendly flame-retardant anti-pollution coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181030 Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 212400 No. 888, Hou Zhuang village, White Rabbit Town, Jurong City, Zhenjiang, Jiangsu Patentee before: Jurong Yige Nano Material Factory |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20170104 |
|
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20170104 |