CN106221620A - A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof - Google Patents

A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof Download PDF

Info

Publication number
CN106221620A
CN106221620A CN201610604628.1A CN201610604628A CN106221620A CN 106221620 A CN106221620 A CN 106221620A CN 201610604628 A CN201610604628 A CN 201610604628A CN 106221620 A CN106221620 A CN 106221620A
Authority
CN
China
Prior art keywords
parts
polyvinyl chloride
cold
modified polyvinyl
coupling agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610604628.1A
Other languages
Chinese (zh)
Other versions
CN106221620B (en
Inventor
王进
刘玉星
冉文生
李树刚
张世宁
雷振凯
孙志鹏
王爱冬
邓卫萍
黄河
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinjiang Uygur Autonomous Region Product Quality Supervision and Inspection Research Institute
Original Assignee
Xinjiang Uygur Autonomous Region Product Quality Supervision and Inspection Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinjiang Uygur Autonomous Region Product Quality Supervision and Inspection Research Institute filed Critical Xinjiang Uygur Autonomous Region Product Quality Supervision and Inspection Research Institute
Priority to CN201610604628.1A priority Critical patent/CN106221620B/en
Publication of CN106221620A publication Critical patent/CN106221620A/en
Application granted granted Critical
Publication of CN106221620B publication Critical patent/CN106221620B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/22—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C09J127/24—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers modified by chemical after-treatment halogenated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
    • C09J111/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof, this adhesive is prepared from by the raw material of following weight portion: superchlorinated polyvinyl chloride resin 13 17 parts, 1,2 dichloroethanes 59 66 parts, nano-calcium carbonate 35 parts, triethyl citrate 11 17 parts, dehydroabietic acid 20 ester 6 14 parts, neoprene latex 7 17 parts, alkylphenol polyoxyethylene 25 parts, nano silicon 10 15 parts, heat filling 10 20 parts, infrared external reflection titanium dioxide 0.7 5.3 parts, light stabilizer 0.2 1 parts, coupling agent 0.1 0.2 parts.Gained adhesive of the present invention has excellent weatherability, tolerance to cold and toughness, and comprehensive strength is higher.

Description

A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof
Technical field
The present invention relates to field of material preparation, be specifically related to a kind of cold-resistant modified polyvinyl chloride adhesive and preparation side thereof Method.
Background technology
Polyvinyl chloride film adhesive is applicable to bonding and the repairing of polyvinyl chloride product, and following PVC water channel, handrail are viscous Connect, pre-fixing of electroplating bath, but existing polyvinyl chloride film adhesive has that weatherability is poor, tolerance to cold is low, toughness is low, comprehensive The shortcomings such as intensity is low, greatly limit its range of application.
Summary of the invention
For solving the problems referred to above, the invention provides a kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof, institute Obtaining adhesive and have excellent weatherability, tolerance to cold and toughness, comprehensive strength is higher.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of cold-resistant modified polyvinyl chloride adhesive, is prepared from by the raw material of following weight portion:
Superchlorinated polyvinyl chloride resin 13-17 part, 1,2-dichloroethanes 59-66 part, nano-calcium carbonate 3-5 part, triethyl citrate 11-17 part, dehydroabietic acid 20 ester 6-14 part, neoprene latex 7-17 part, alkylphenol polyoxyethylene 2-5 part, nanometer titanium dioxide Silicon 10-15 part, heat filling 10-20 part, infrared external reflection titanium dioxide 0.7-5.3 part, light stabilizer 0.2-1 part, coupling agent 0.1-0.2 part.
Preferably, the raw material of following weight portion it is prepared from:
Superchlorinated polyvinyl chloride resin 15 parts, 1,2-dichloroethanes 62.5 parts, nano-calcium carbonate 4 parts, triethyl citrate 14 parts, de- Hydrogen abietic acid 20 ester 10 parts, neoprene latex 12 parts, alkylphenol polyoxyethylene 3.5 parts, nano silicon 12.5 parts, heat conduction are filled out Expect 15 parts, infrared external reflection titanium dioxide 3 parts, light stabilizer 0.6 part, coupling agent 0.15 part.
Wherein, described heat filling is that magnesium oxide, aluminium hydroxide, boron nitride, aluminium nitride in mass ratio 1: 2: 3: 1 mixes institute , the particle diameter of described heat filling is more than 98% in 0.5um-2.0um, purity.
Wherein, described light stabilizer be salicylate, benzophenone, triazines, benzotriazole UV absorbent with And one or more mixture in hindered amines free radical scavenger.
Wherein, described infrared external reflection titanium dioxide particle diameter is 1100nm-1600nm, TiO2Content is 80%-90%, table Roll cover SiO2With Al2O3Content be 10-20%.
Wherein, described coupling agent is that silane coupler, titanate coupling agent in mass ratio 1: 1 mixes gained.
The preparation method of above-mentioned a kind of cold-resistant modified polyvinyl chloride adhesive, comprises the steps:
S1, formula as described in claim 1-6 weigh each component；
S2, by the nano silicon weighed by supersonic oscillations equipment be scattered in pure water formation nanometer titanium dioxide Silicon particle dispersion；
S3, step S2 gained dispersion liquid is injected double screw extruder by liquid feeding pump, with superchlorinated polyvinyl chloride resin altogether Mixed, it is heated to water and all evaporates, obtain mixture；
S4, mixture is placed in homogenizer, adds 1 weighed, 2-dichloroethanes, nano-calcium carbonate, citric acid Triethyl, dehydroabietic acid 20 ester, neoprene latex, alkylphenol polyoxyethylene, heat filling, infrared external reflection titanium dioxide, light Stabilizer, coupling agent, stir 10-30min, discharging, is heated to 80 DEG C～during 95 DEG C of temperature, is kept stirring for 25～45min, then Stop heating, naturally cool to room temperature, to obtain final product.
The method have the advantages that
By triethyl citrate, the synergism of dehydroabietic acid 20 ester, greatly strengthen the tolerance to cold of binding agent；Logical Cross the interpolation of alkylphenol polyoxyethylene so that the binding agent corrosion resistance of gained improves；The interpolation of nano silicon so that The binding agent of gained can keep excellent toughness during life-time service all the time；Use infrared external reflection titanium dioxide, Ke Yi great The visible ray of amplitude reflection sunlight and infrared part energy, the collaborative contribution of the heat release of heat filling, can make relatively in addition The surface temperature of binding agent is greatly reduced, is greatly improved its weatherability.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out further Describe in detail.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit this Bright.
Heat filling used in following example is magnesium oxide, aluminium hydroxide, boron nitride, aluminium nitride in mass ratio 1: 2: 3: 1 mixing gained, the particle diameter of described heat filling is more than 98% in 0.5um-2.0um, purity；Described light stabilizer is water One in poplar acid esters, benzophenone, triazines, the UV absorbent of benzotriazole and hindered amines free radical scavenger or Multiple mixture；Described infrared external reflection titanium dioxide particle diameter is 1100nm-1600nm, TiO2Content is 80%-90%, surface Clad SiO2With Al2O3Content be 10-20%；Described coupling agent is silane coupler, titanate coupling agent in mass ratio 1: 1 mixing gained.
Embodiment 1
A kind of cold-resistant modified polyvinyl chloride adhesive, is prepared from by the raw material of following weight portion:
Superchlorinated polyvinyl chloride resin 13 parts, 1,2-dichloroethanes 59 parts, nano-calcium carbonate 3 parts, triethyl citrate 11 parts, dehydrogenation Abietic acid 20 ester 6 parts, neoprene latex 7 parts, alkylphenol polyoxyethylene 2 parts, nano silicon 10 parts, heat filling 10 parts, Infrared external reflection titanium dioxide 0.7 part, light stabilizer 0.2 part, coupling agent 0.1 part.
Embodiment 2
A kind of cold-resistant modified polyvinyl chloride adhesive, is prepared from by the raw material of following weight portion:
Superchlorinated polyvinyl chloride resin 15 parts, 1,2-dichloroethanes 62.5 parts, nano-calcium carbonate 4 parts, triethyl citrate 14 parts, de- Hydrogen abietic acid 20 ester 10 parts, neoprene latex 12 parts, alkylphenol polyoxyethylene 3.5 parts, nano silicon 12.5 parts, heat conduction are filled out Expect 15 parts, infrared external reflection titanium dioxide 3 parts, light stabilizer 0.6 part, coupling agent 0.15 part.
Embodiment 3
A kind of cold-resistant modified polyvinyl chloride adhesive, is prepared from by the raw material of following weight portion:
Superchlorinated polyvinyl chloride resin 17 parts, 1,2-dichloroethanes 66 parts, nano-calcium carbonate 5 parts, triethyl citrate 17 parts, dehydrogenation Abietic acid 20 ester 14 parts, neoprene latex 17 parts, alkylphenol polyoxyethylene 5 parts, nano silicon 15 parts, heat filling 20 Part, infrared external reflection titanium dioxide 5.3 parts, light stabilizer 1 part, coupling agent 0.2 part.
The embodiment of the present invention additionally provides the preparation method of a kind of cold-resistant modified polyvinyl chloride adhesive, including walking as follows Rapid:
S1, formula as described in claim 1-6 weigh each component；
S2, by the nano silicon weighed by supersonic oscillations equipment be scattered in pure water formation nanometer titanium dioxide Silicon particle dispersion；
S3, step S2 gained dispersion liquid is injected double screw extruder by liquid feeding pump, with superchlorinated polyvinyl chloride resin altogether Mixed, it is heated to water and all evaporates, obtain mixture；
S4, mixture is placed in homogenizer, adds 1 weighed, 2-dichloroethanes, nano-calcium carbonate, citric acid Triethyl, dehydroabietic acid 20 ester, neoprene latex, alkylphenol polyoxyethylene, heat filling, infrared external reflection titanium dioxide, light Stabilizer, coupling agent, stir 10-30min, discharging, is heated to 80 DEG C～during 95 DEG C of temperature, is kept stirring for 25～45min, then Stop heating, naturally cool to room temperature, to obtain final product.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (7)

1. a cold-resistant modified polyvinyl chloride adhesive, it is characterised in that be prepared from by the raw material of following weight portion:
Superchlorinated polyvinyl chloride resin 13-17 part, 1,2-dichloroethanes 59-66 part, nano-calcium carbonate 3-5 part, triethyl citrate 11-17 Part, dehydroabietic acid 20 ester 6-14 part, neoprene latex 7-17 part, alkylphenol polyoxyethylene 2-5 part, nano silicon 10- 15 parts, heat filling 10-20 part, infrared external reflection titanium dioxide 0.7-5.3 part, light stabilizer 0.2-1 part, coupling agent 0.1-0.2 Part.
2. modified polyvinyl chloride adhesive as claimed in claim 1 a kind of cold-resistant, it is characterised in that former by following weight portion Material is prepared from:
Superchlorinated polyvinyl chloride resin 15 parts, 1,2-dichloroethanes 62.5 parts, nano-calcium carbonate 4 parts, triethyl citrate 14 parts, dehydrogenation fir Acid 20 ester 10 parts, neoprene latex 12 parts, alkylphenol polyoxyethylene 3.5 parts, nano silicon 12.5 parts, heat filling 15 Part, infrared external reflection titanium dioxide 3 parts, light stabilizer 0.6 part, coupling agent 0.15 part.
3. a kind of cold-resistant modified polyvinyl chloride adhesive as claimed in claim 1, it is characterised in that described heat filling is oxygen Changing magnesium, aluminium hydroxide, boron nitride, aluminium nitride in mass ratio 1: 2: 3: 1 and mix gained, the particle diameter of described heat filling is at 0.5um- 2.0um, purity is more than 98%.
4. a kind of cold-resistant modified polyvinyl chloride adhesive as claimed in claim 1, it is characterised in that described light stabilizer is One in salicylate, benzophenone, triazines, the UV absorbent of benzotriazole and hindered amines free radical scavenger Or multiple mixture.
5. a kind of cold-resistant modified polyvinyl chloride adhesive as claimed in claim 1, it is characterised in that described infrared external reflection two Titanium oxide particle diameter is 1100nm-1600nm, TiO2Content is 80%-90%, surface coating layer SiO2With Al2O3Content be 10- 20%.
6. a kind of cold-resistant modified polyvinyl chloride adhesive as claimed in claim 1, it is characterised in that described coupling agent is silane Coupling agent, titanate coupling agent in mass ratio 1: 1 mixes gained.
7. the preparation method of a kind of cold-resistant modified polyvinyl chloride adhesive as described in any one of claim 1-6, its feature exists In, comprise the steps:
S1, formula as described in claim 1-6 weigh each component；
S2, by the nano silicon weighed by supersonic oscillations equipment be scattered in pure water formation nano silicon grain Sub-dispersion liquid；
S3, by step S2 gained dispersion liquid by liquid feeding pump inject double screw extruder, with superchlorinated polyvinyl chloride resin be blended, add Heat is all evaporated to water, obtains mixture；
S4, mixture is placed in homogenizer, adds 1 weighed, 2-dichloroethanes, nano-calcium carbonate, Fructus Citri Limoniae triethylenetetraminehexaacetic acid Ester, dehydroabietic acid 20 ester, fluorine fourth latex, alkylphenol polyoxyethylene, heat filling, infrared external reflection titanium dioxide, light are stable Agent, coupling agent, stir 10-30min, discharging, is heated to 80 DEG C～during 95 DEG C of temperature, is kept stirring for 25～45min, then stops Heating, naturally cools to room temperature, to obtain final product.
CN201610604628.1A 2016-07-22 2016-07-22 A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof Expired - Fee Related CN106221620B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610604628.1A CN106221620B (en) 2016-07-22 2016-07-22 A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610604628.1A CN106221620B (en) 2016-07-22 2016-07-22 A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106221620A true CN106221620A (en) 2016-12-14
CN106221620B CN106221620B (en) 2018-09-21

Family

ID=57533837

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610604628.1A Expired - Fee Related CN106221620B (en) 2016-07-22 2016-07-22 A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106221620B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3369794A1 (en) * 2017-03-02 2018-09-05 Anglian Windows Limited Laminated structure
US20210371639A1 (en) * 2018-09-28 2021-12-02 Sekisui Chemical Co., Ltd. Chlorinated vinyl chloride resin composition for window frame, and window frame member

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85102366A (en) * 1985-04-01 1986-04-10 河北省邯郸市塑料研究所 The waterproof concrete adhesive constituent
CN102277106A (en) * 2011-09-09 2011-12-14 湖北孚龙管业科技有限公司 Super polyvinyl chloride (PVC) adhesive and production method thereof
CN102898880A (en) * 2012-08-14 2013-01-30 成钢 Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint
CN104403228A (en) * 2014-11-20 2015-03-11 安徽渡江电缆集团有限公司 Modified polyvinyl chloride cable material with high cold resistance
CN104845557A (en) * 2015-05-28 2015-08-19 青岛千帆高新技术有限公司 Special adhesive for safe leather

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85102366A (en) * 1985-04-01 1986-04-10 河北省邯郸市塑料研究所 The waterproof concrete adhesive constituent
CN102277106A (en) * 2011-09-09 2011-12-14 湖北孚龙管业科技有限公司 Super polyvinyl chloride (PVC) adhesive and production method thereof
CN102898880A (en) * 2012-08-14 2013-01-30 成钢 Green environment-friendly multifunctional energy-night-storage nano-grade luminescent paint
CN104403228A (en) * 2014-11-20 2015-03-11 安徽渡江电缆集团有限公司 Modified polyvinyl chloride cable material with high cold resistance
CN104845557A (en) * 2015-05-28 2015-08-19 青岛千帆高新技术有限公司 Special adhesive for safe leather

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3369794A1 (en) * 2017-03-02 2018-09-05 Anglian Windows Limited Laminated structure
GB2560307A (en) * 2017-03-02 2018-09-12 Anglian Windows Ltd Laminated structure
GB2560307B (en) * 2017-03-02 2022-02-16 Anglian Windows Ltd Laminated structure
US20210371639A1 (en) * 2018-09-28 2021-12-02 Sekisui Chemical Co., Ltd. Chlorinated vinyl chloride resin composition for window frame, and window frame member

Also Published As

Publication number Publication date
CN106221620B (en) 2018-09-21

Similar Documents

Publication Publication Date Title
CN104151970B (en) Hydrate colour transparent heat insulating dope and preparation method and using method
CN106221620B (en) A kind of cold-resistant modified polyvinyl chloride adhesive and preparation method thereof
CN105838297A (en) Method for preparing environment-friendly thermoplastic resin aqueous adhesive
CN104004422B (en) A kind of priming paint
CN106189722A (en) A kind of water nano heat insulation color steel baking vanish formula and preparation method
CN106566328B (en) High damping properties damping paint
CN104140722B (en) The emulsion coatings formula that a kind of acicular wollastonite is filling-modified
CN107189640A (en) A kind of composite fireproof anti-corrosion material for cable testing bridge
CN110437776A (en) A kind of double-component aqueous redwood splicing adhesive and its application
CN105419546A (en) Ultraviolet-resistant anti-radiation double-side coated polyester aluminized film and production method thereof
CN107245312A (en) A kind of enhanced stone material gum
CN108285508A (en) Protective film high viscous development of Acrylate Emulsion Pressure-Sensitive Adhesive and preparation method and application in using
CN102807789A (en) High-temperature-resistant ink for packaging of medical aluminum foil
CN107815150A (en) A kind of graphene heat-insulation light coating and its preparation method and application
CN106433351B (en) Non-ignitable grade damping paint
CN109354969A (en) A kind of imitative anode powder coating and preparation method thereof
CN108503976A (en) Modified polyvinyl chloride material and preparation method thereof
CN106046575A (en) Novel stone wood-plastic composite material
CN106753148A (en) A kind of special unsaturated polyester resin adhesive of quartzite slate
CN102634304B (en) Low-temperature high-performance 3 PE (Poly Ethylene) photopolymer adhesive and preparation method thereof
CN107867022B (en) A kind of high steam remote heat supply three-decker formula composite steel tube
CN107974200A (en) The preparation process of anticorrosion timber
CN107699090A (en) A kind of coating of temperature control bar seam air outlet
CN104530850A (en) Inner wall latex paint with room temperature regulating function and preparation method thereof
CN105860529A (en) Nanometer thermal-insulation high-transparency anti-dazzle glass coating

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180921

Termination date: 20190722