CN105860529A - Nanometer thermal-insulation high-transparency anti-dazzle glass coating - Google Patents

Nanometer thermal-insulation high-transparency anti-dazzle glass coating Download PDF

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CN105860529A
CN105860529A CN201610304447.7A CN201610304447A CN105860529A CN 105860529 A CN105860529 A CN 105860529A CN 201610304447 A CN201610304447 A CN 201610304447A CN 105860529 A CN105860529 A CN 105860529A
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parts
high anti
insulating
nano heat
dazzle glas
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凌卫平
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Anhui Herun Special Glass Co Ltd
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Anhui Herun Special Glass Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a nanometer thermal-insulation high-transparency anti-dazzle glass coating. The nanometer thermal-insulation high-transparency anti-dazzle glass coating is prepared from organic silicon resin, nanometer composite filler, epoxy resin, alkyd resin, acrylic resin, styrene elastomer, polyvinylpyrrolidone, 1-hexadecanesulfonic acid, silane coupling agents, calcium phosphate, hollow glass microspheres, methylcellulose, kaolin, mica powder, titanium dioxide, zinc oxide, antimonous oxide, alumina, dioctyl phthalate, absolute ethyl alcohol, trinitrotoluene and adhesives. The nanometer thermal-insulation high-transparency anti-dazzle glass coating is high in light transparency and good in thermal insulation effect.

Description

The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating
Technical field
The present invention relates to glass-film technical field, particularly relate to the high anti-dazzle glas film thoroughly of a kind of nano heat-insulating.
Background technology
At present, anti-dazzle glas is also known as anti reflection glass or non-reflecting glass.Anti-dazzle glas reduces glass surface Reflectivity so that reflectivity≤2%, light transmittance >=80%, glossiness >=60%.Anti-dazzle glas is a kind of by glass Glass carries out the glass of specially treated, and its principle is high-quality glass single-sided or two-sided to carry out PROCESS FOR TREATMENT so that it is There is compared with simple glass relatively low reflectivity, make the reflectance reduction of light to less than 1%, thus reduce ring The interference of border light, improves the definition of picture, reduces screen reflecting, makes image apparent, true to nature, allows sight Reward person enjoys more preferably visual effect.
Anti-dazzle glas film of the prior art is while carrying out the light transmission of raising glass, for heat insulation property Cannot can improve simultaneously, therefore need a kind of translucidus that can improve of exploitation badly and can improve again the anti-of heat-proof quality Dizzy glass-film.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes the high saturating anti-dazzle glass of a kind of nano heat-insulating Glass film, light transmission is strong, good heat-insulation effect.
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 30-60 part, nanocomposite filler 10-30 part, epoxy resin 5-15 part, alkyd resin 2-8 part, Acrylic resin 1-6 part, styrenic elastomer 2-4 part, polyvinylpyrrolidone 3-5 part, cetyl Benzene sulfonic acid sodium salt 1-4 part, silane coupler 2-5 part, calcium phosphate 1-5 part, hollow glass micro-2-6 part, first Base fiber 1-4 part, kaolin 2-6 part, mica powder 1-4 part, titanium dioxide 2-6 part, zinc oxide 1-4 part, Antimony oxide 3-5 part, aluminum oxide 1-4 part, dioctyl phthalate 2-5 part, absolute ethyl alcohol 1-5 Part, trinitrotoluene 2-6 part, adhesive 1-8 part.
Preferably, the raw material of nanocomposite filler includes by weight: indiumchloride solution 2-5 part, stannic chloride Solution 1-3 part, polyethylene glycol 2-6 part, ammoniacal liquor 3-8 part.
Preferably, nanocomposite filler is prepared by following technique: by indiumchloride solution and tin chloride solution Mix and obtain material a, then material a is warming up to 60-80 DEG C, be incubated 10-30min, be subsequently adding Polyethylene glycol mixes, and adds ammoniacal liquor and be hydrolyzed, and regulation pH value, to 6.8-7.2, stirs 1-3h, The most still aging 1-3h, sediment distilled water and ethanol carry out filtering and washing, then do in 70-90 DEG C Dry 8-12h, calcines 1-3h in 600-800 DEG C after grinding, naturally obtains nanocomposite filler after cooling.
Preferably, the substance withdrawl syndrome of indiumchloride solution is 0.15-0.35mol/L, the thing of tin chloride solution The amount concentration of matter is 0.01-0.03mol/L.
Preferably, organic siliconresin, nanocomposite filler, epoxy resin, alkyd resin, acrylic resin It is 35-55:15-25:8-12:3-7:2-5:2.5-3.5 with the weight ratio of styrenic elastomer.
Preferably, organic siliconresin, polyvinylpyrrolidone, cetyl benzenesulfonic acid sodium, silane coupler, Calcium phosphate, hollow glass are micro-, Methyl cellulose, kaolin, mica powder, titanium dioxide, zinc oxide, three oxidation The weight ratio of two antimony and aluminum oxide is 35-55:3.5-4.5:2-3:2.5-4.5:2-4:3-5:2-3:3-5: 2-3:3-5:2-3:3.5-4.5:2-3.
Preferably, its raw material includes by weight: organic siliconresin 35-55 part, nanocomposite filler 15-25 Part, epoxy resin 8-12 part, alkyd resin 3-7 part, acrylic resin 2-5 part, styrenic elastomer 2.5-3.5 Part, polyvinylpyrrolidone 3.5-4.5 part, cetyl benzenesulfonic acid sodium 2-3 part, silane coupler 3-4 Part, calcium phosphate 2-4 part, hollow glass micro-3-5 part, Methyl cellulose 2-3 part, kaolin 3-5 part, cloud Female powder 2-3 part, titanium dioxide 3-5 part, zinc oxide 2-3 part, antimony oxide 3.5-4.5 part, aluminum oxide 2-3 part, dioctyl phthalate 3-4 part, absolute ethyl alcohol 2-4 part, trinitrotoluene 3-5 part, gluing Agent 2-7 part.
Preferably, its raw material includes by weight: organic siliconresin 45 parts, nanocomposite filler 20 parts, Epoxy resin 10 parts, alkyd resin 5 parts, acrylic resin 3.5 parts, styrenic elastomer 3 parts, poly-second Alkene pyrrolidone 4 parts, 2.5 parts of cetyl benzenesulfonic acid sodium, silane coupler 3.5 parts, 3 parts of calcium phosphate, Micro-4 parts of hollow glass, Methyl cellulose 2.5 parts, kaolin 4 parts, mica powder 2.5 parts, titanium dioxide 4 parts, 2.5 parts of zinc oxide, antimony oxide 4 parts, 2.5 parts of aluminum oxide, dioctyl phthalate 3.5 parts, Absolute ethyl alcohol 3 parts, trinitrotoluene 4 parts, adhesive 4.5 parts.
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating of the present invention, its raw material includes that organic siliconresin, nanometer are multiple Close filler, epoxy resin, alkyd resin, acrylic resin, styrenic elastomer, polyvinylpyrrolidone, Cetyl benzenesulfonic acid sodium, silane coupler, calcium phosphate, hollow glass are micro-, Methyl cellulose, kaolin, Mica powder, titanium dioxide, zinc oxide, antimony oxide, aluminum oxide, dioctyl phthalate, anhydrous second Alcohol, trinitrotoluene and adhesive.Wherein with organic siliconresin as major ingredient, auxiliary adds epoxy resin, alcohol Acid resin, acrylic resin and styrenic elastomer, as major ingredient supporting material, are effectively increased epoxy resin Hardness and heat resistance, the nanocomposite filler of interpolation with indiumchloride solution and tin chloride solution as raw material, It is prepared for the nano composite material containing indium and tin, owing to making the present invention's containing the nano composite material of indium and tin Anti-dazzle glas film rough surface, nano composite material is nanometer materials, surface is the most smooth do not occur micro- See defect, therefore the overlay film effect of anti-dazzle glas film is not affected；Nano composite material containing indium and tin exists During preparation due to aggregated particle size not quite, therefore little on light transmission impact；Nanocomposite filler is to red Outer light has the strongest albedo, when thermal-radiating infrared light is reflected layer by layer by function nano particle, thus rises Arrive heat insulation effect.Therefore while improve light transmission, also improve heat insulation effect；That adds is poly- Vinylpyrrolidone, cetyl benzenesulfonic acid sodium, silane coupler, calcium phosphate, hollow glass are micro-, methyl Fiber, kaolin, mica powder, titanium dioxide, zinc oxide, antimony oxide, aluminum oxide, phthalic acid Dioctyl ester, absolute ethyl alcohol, trinitrotoluene and adhesive, as auxiliary agent and filler, are effectively improved the present invention and prevent The combination property of dizzy glass-film, is effectively increased hardness, wear-resisting and heat resistance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment, Equivalents etc. are the most within the scope of the present invention.
Embodiment 1
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 45 parts, nanocomposite filler 20 parts, epoxy resin 10 parts, alkyd resin 5 parts, acrylic acid tree 3.5 parts of fat, styrenic elastomer 3 parts, polyvinylpyrrolidone 4 parts, cetyl benzenesulfonic acid sodium 2.5 Part, silane coupler 3.5 parts, 3 parts of calcium phosphate, micro-4 parts of hollow glass, Methyl cellulose 2.5 parts, height 4 parts of ridge soil, mica powder 2.5 parts, titanium dioxide 4 parts, 2.5 parts of zinc oxide, antimony oxide 4 parts, oxygen Change 2.5 parts of aluminium, dioctyl phthalate 3.5 parts, absolute ethyl alcohol 3 parts, trinitrotoluene 4 parts, glue Glutinous agent 4.5 parts.
Nanocomposite filler is prepared by following technique: by 3.5 parts of substance withdrawl syndrome be by weight The indiumchloride solution of 0.25mol/L and 2 parts of substance withdrawl syndrome be the tin chloride solution mixing of 0.02mol/L all The even material a that obtains, is then warming up to 70 DEG C by material a, is incubated 20min, is subsequently adding 4 parts of polyethylene glycol Mixing, and add 5.5 parts of ammoniacal liquor and be hydrolyzed, regulation pH value, to 7.0, stirs 2h, then stands Ageing 2h, sediment distilled water and ethanol carry out filtering and washing, then in 80 DEG C of dry 10h, after grinding Calcine 2h in 700 DEG C, naturally obtain nanocomposite filler after cooling.
Embodiment 2
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 30 parts, nanocomposite filler 30 parts, epoxy resin 5 parts, alkyd resin 8 parts, acrylic acid tree 1 part of fat, styrenic elastomer 4 parts, polyvinylpyrrolidone 3 parts, 4 parts of cetyl benzenesulfonic acid sodium, Silane coupler 2 parts, 5 parts of calcium phosphate, micro-2 parts of hollow glass, Methyl cellulose 4 parts, kaolin 2 parts, Mica powder 4 parts, titanium dioxide 2 parts, 4 parts of zinc oxide, antimony oxide 3 parts, 4 parts of aluminum oxide, adjacent benzene Dioctyl phthalate dioctyl ester 2 parts, absolute ethyl alcohol 5 parts, trinitrotoluene 2 parts, adhesive 8 parts.
Nanocomposite filler is prepared by following technique: by 2 parts of substance withdrawl syndrome be by weight The indiumchloride solution of 0.35mol/L and 1 part of substance withdrawl syndrome be the tin chloride solution mixing of 0.03mol/L all The even material a that obtains, is then warming up to 60 DEG C by material a, is incubated 30min, is subsequently adding 2 parts of polyethylene glycol Mixing, and add 8 parts of ammoniacal liquor and be hydrolyzed, regulation pH value, to 6.8, stirs 3h, then stands old Change 1h, sediment distilled water and ethanol carry out filtering and washing, then in 90 DEG C of dry 8h, after grinding in 800 DEG C of calcining 1h, obtain nanocomposite filler after cooling naturally.
Embodiment 3
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 60 parts, nanocomposite filler 10 parts, epoxy resin 15 parts, alkyd resin 2 parts, acrylic acid tree 6 parts of fat, styrenic elastomer 2 parts, polyvinylpyrrolidone 5 parts, 1 part of cetyl benzenesulfonic acid sodium, Silane coupler 5 parts, 1 part of calcium phosphate, micro-6 parts of hollow glass, Methyl cellulose 1 part, kaolin 6 parts, Mica powder 1 part, titanium dioxide 6 parts, 1 part of zinc oxide, antimony oxide 5 parts, 1 part of aluminum oxide, adjacent benzene Dioctyl phthalate dioctyl ester 5 parts, absolute ethyl alcohol 1 part, trinitrotoluene 6 parts, adhesive 1 part.
Nanocomposite filler is prepared by following technique: by 5 parts of substance withdrawl syndrome be by weight The indiumchloride solution of 0.15mol/L and 3 parts of substance withdrawl syndrome be the tin chloride solution mixing of 0.01mol/L all The even material a that obtains, is then warming up to 80 DEG C by material a, is incubated 10min, is subsequently adding 6 parts of polyethylene glycol Mixing, and add 3 parts of ammoniacal liquor and be hydrolyzed, regulation pH value, to 7.2, stirs 1h, then stands old Change 3h, sediment distilled water and ethanol carry out filtering and washing, then in 70 DEG C of dry 12h, after grinding in 600 DEG C of calcining 3h, obtain nanocomposite filler after cooling naturally.
Embodiment 4
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 35 parts, nanocomposite filler 25 parts, epoxy resin 8 parts, alkyd resin 7 parts, acrylic acid tree 2 parts of fat, styrenic elastomer 3.5 parts, polyvinylpyrrolidone 3.5 parts, cetyl benzenesulfonic acid sodium 3 Part, silane coupler 3 parts, 4 parts of calcium phosphate, micro-3 parts of hollow glass, Methyl cellulose 3 parts, kaolin 3 Part, mica powder 3 parts, titanium dioxide 3 parts, 3 parts of zinc oxide, antimony oxide 3.5 parts, 3 parts of aluminum oxide, Dioctyl phthalate 3 parts, absolute ethyl alcohol 4 parts, trinitrotoluene 3 parts, adhesive 7 parts.
Nanocomposite filler is prepared by following technique: by 2.5 parts of substance withdrawl syndrome be by weight The indiumchloride solution of 0.32mol/L and 1.5 parts of substance withdrawl syndrome are that the tin chloride solution of 0.025mol/L mixes Close and uniformly obtain material a, then material a is warming up to 65 DEG C, be incubated 25min, be subsequently adding 3 parts of poly-second Glycol mixes, and adds 7 parts of ammoniacal liquor and be hydrolyzed, and regulation pH value, to 6.9, stirs 2.5h, then Still aging 1.5h, sediment distilled water and ethanol carry out filtering and washing, then in 85 DEG C of dry 9h, grind Calcine 1.5h in 750 DEG C after mill, naturally obtain nanocomposite filler after cooling.
Embodiment 5
The high anti-dazzle glas film thoroughly of a kind of nano heat-insulating that the present invention proposes, its raw material includes by weight: organic Silicones 55 parts, nanocomposite filler 15 parts, epoxy resin 12 parts, alkyd resin 3 parts, acrylic acid tree 5 parts of fat, styrenic elastomer 2.5 parts, polyvinylpyrrolidone 4.5 parts, cetyl benzenesulfonic acid sodium 2 Part, silane coupler 4 parts, 2 parts of calcium phosphate, micro-5 parts of hollow glass, Methyl cellulose 2 parts, kaolin 5 Part, mica powder 2 parts, titanium dioxide 5 parts, 2 parts of zinc oxide, antimony oxide 4.5 parts, 2 parts of aluminum oxide, Dioctyl phthalate 4 parts, absolute ethyl alcohol 2 parts, trinitrotoluene 5 parts, adhesive 2 parts.
Nanocomposite filler is prepared by following technique: by 4.5 parts of substance withdrawl syndrome be by weight The indiumchloride solution of 0.18mol/L and 2.5 parts of substance withdrawl syndrome are that the tin chloride solution of 0.015mol/L mixes Close and uniformly obtain material a, then material a is warming up to 75 DEG C, be incubated 15min, be subsequently adding 5 parts of poly-second Glycol mixes, and adds 4 parts of ammoniacal liquor and be hydrolyzed, and regulation pH value, to 7.1, stirs 1.5h, then Still aging 2.5h, sediment distilled water and ethanol carry out filtering and washing, then in 75 DEG C of dry 11h, Calcine 2.5h in 650 DEG C after grinding, naturally obtain nanocomposite filler after cooling.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (8)

1. the high anti-dazzle glas film thoroughly of nano heat-insulating, it is characterised in that its raw material includes by weight: have Machine silicones 30-60 part, nanocomposite filler 10-30 part, epoxy resin 5-15 part, alkyd resin 2-8 Part, acrylic resin 1-6 part, styrenic elastomer 2-4 part, polyvinylpyrrolidone 3-5 part, 16 Sodium alkyl benzene sulfonate 1-4 part, silane coupler 2-5 part, calcium phosphate 1-5 part, hollow glass micro-2-6 part, Methyl cellulose 1-4 part, kaolin 2-6 part, mica powder 1-4 part, titanium dioxide 2-6 part, zinc oxide 1-4 Part, antimony oxide 3-5 part, aluminum oxide 1-4 part, dioctyl phthalate 2-5 part, absolute ethyl alcohol 1-5 part, trinitrotoluene 2-6 part, adhesive 1-8 part.
The high anti-dazzle glas film thoroughly of nano heat-insulating the most according to claim 1, it is characterised in that nanometer is multiple The raw material closing filler includes by weight: indiumchloride solution 2-5 part, tin chloride solution 1-3 part, poly-second two Alcohol 2-6 part, ammoniacal liquor 3-8 part.
The high anti-dazzle glas film thoroughly of nano heat-insulating the most according to claim 1 and 2, it is characterised in that receive Rice compounded mix is prepared by following technique: is mixed with tin chloride solution by indiumchloride solution and obtains thing Material a, is then warming up to 60-80 DEG C by material a, is incubated 10-30min, is subsequently adding polyethylene glycol mixing Uniformly, and adding ammoniacal liquor and be hydrolyzed, regulation pH value, to 6.8-7.2, stirs 1-3h, the most still aging 1-3h, sediment distilled water and ethanol carry out filtering and washing, then in 70-90 DEG C of dry 8-12h, grind After in 600-800 DEG C calcine 1-3h, naturally cool down after obtain nanocomposite filler.
4. according to the high anti-dazzle glas film thoroughly of the nano heat-insulating described in any one of claim 1-3, it is characterised in that The substance withdrawl syndrome of indiumchloride solution is 0.15-0.35mol/L, and the substance withdrawl syndrome of tin chloride solution is 0.01-0.03mol/L。
5. according to the high anti-dazzle glas film thoroughly of the nano heat-insulating described in any one of claim 1-4, it is characterised in that Organic siliconresin, nanocomposite filler, epoxy resin, alkyd resin, acrylic resin and styrene elastomer The weight ratio of body is 35-55:15-25:8-12:3-7:2-5:2.5-3.5.
6. according to the high anti-dazzle glas film thoroughly of the nano heat-insulating described in any one of claim 1-5, it is characterised in that Organic siliconresin, polyvinylpyrrolidone, cetyl benzenesulfonic acid sodium, silane coupler, calcium phosphate, sky Heart glass is micro-, Methyl cellulose, kaolin, mica powder, titanium dioxide, zinc oxide, antimony oxide and oxidation The weight ratio of aluminium is 35-55:3.5-4.5:2-3:2.5-4.5:2-4:3-5:2-3:3-5:2-3: 3-5:2-3:3.5-4.5:2-3.
7. according to the high anti-dazzle glas film thoroughly of the nano heat-insulating described in any one of claim 1-6, it is characterised in that Its raw material includes by weight: organic siliconresin 35-55 part, nanocomposite filler 15-25 part, asphalt mixtures modified by epoxy resin Fat 8-12 part, alkyd resin 3-7 part, acrylic resin 2-5 part, styrenic elastomer 2.5-3.5 part, Polyvinylpyrrolidone 3.5-4.5 part, cetyl benzenesulfonic acid sodium 2-3 part, silane coupler 3-4 part, Calcium phosphate 2-4 part, hollow glass micro-3-5 part, Methyl cellulose 2-3 part, kaolin 3-5 part, mica powder 2-3 part, titanium dioxide 3-5 part, zinc oxide 2-3 part, antimony oxide 3.5-4.5 part, aluminum oxide 2-3 Part, dioctyl phthalate 3-4 part, absolute ethyl alcohol 2-4 part, trinitrotoluene 3-5 part, adhesive 2-7 part.
8. according to the high anti-dazzle glas film thoroughly of the nano heat-insulating described in any one of claim 1-7, it is characterised in that Its raw material includes by weight: organic siliconresin 45 parts, nanocomposite filler 20 parts, epoxy resin 10 parts, Alkyd resin 5 parts, acrylic resin 3.5 parts, styrenic elastomer 3 parts, polyvinylpyrrolidone 4 parts, 2.5 parts of cetyl benzenesulfonic acid sodium, silane coupler 3.5 parts, 3 parts of calcium phosphate, micro-4 parts of hollow glass, Methyl cellulose 2.5 parts, kaolin 4 parts, mica powder 2.5 parts, titanium dioxide 4 parts, 2.5 parts of zinc oxide, Antimony oxide 4 parts, 2.5 parts of aluminum oxide, dioctyl phthalate 3.5 parts, absolute ethyl alcohol 3 parts, Trinitrotoluene 4 parts, adhesive 4.5 parts.
CN201610304447.7A 2016-05-06 2016-05-06 Nanometer thermal-insulation high-transparency anti-dazzle glass coating Withdrawn CN105860529A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951985A (en) * 2006-10-20 2007-04-25 南京工业大学 Transparent heat-insulating film and its preparing process
CN101423677A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing transparent and heat insulating water ultraviolet curing coating
CN105062328A (en) * 2015-07-31 2015-11-18 安徽和润特种玻璃有限公司 High performance antiglare film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951985A (en) * 2006-10-20 2007-04-25 南京工业大学 Transparent heat-insulating film and its preparing process
CN101423677A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing transparent and heat insulating water ultraviolet curing coating
CN105062328A (en) * 2015-07-31 2015-11-18 安徽和润特种玻璃有限公司 High performance antiglare film

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Application publication date: 20160817