CN101423677A - Method for preparing transparent and heat insulating water ultraviolet curing coating - Google Patents
Method for preparing transparent and heat insulating water ultraviolet curing coating Download PDFInfo
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Abstract
The invention relates to a method for preparing an aqueous ultraviolet photo-cured coating with transparence and heat insulation and belongs to the technical field of environment-friendly energy-saving coating. The coating consists of a modified heat insulating nanometer serous fluid for emulsifying and compounding an aqueous UV prepolymer, a light evocating agent, a coating additive and the like. The modified heat insulating nanometer serous fluid carries out emulsification and compounding on the aqueous UV prepolymer so as to obviously improve the dispersion and stability of the coating, wherein a heat insulation nanometer powder body is an oxide consisting of tin, stibium, zinc, copper and aluminum so that the coating has high transparency and heat insulation and low radiation; the coating uses water as a solvent, fully meets the requirement of environmental protection, adopts a spraying or knifing mode, utilizes ultraviolet radiation for curing and film forming, can realize the automatic coating of production lines and has convenient construction; and a coating film has the characteristics of good weather resistance, high rigidity, strong adhesive force and the like.
Description
Technical field
The present invention relates to a kind of transparent heat-insulated coating material solidified preparation method of aquosity ultraviolet light (UV), belong to the environmental protection and energy saving technical field of coatings.
Background technology
Now, the situation that face world energy sources, is becoming tight resource day, China advocates energetically and makes up Sustainable development, conservation-minded society, and the promotion and application of energy-saving coatings have significance.In all kinds of energy consumptions, constructure heating and air-conditioning power consumption occupy quite great proportion, and account for about 60% of whole building and heating and air-conditioning power consumption by the door and window dispersed heat.People have taked variety of way to carry out the heat-insulating and energy-saving processing in recent years, as pad pasting glass, sunlight controlling coated glass and low emissivity glass etc., the above two visible light transmissivity is lower, though the latter has light thermal property preferably, but production prices are higher, are difficult to enter common people house.Therefore, developing a kind of heat insulation Clear paint is to carry out the energy-conservation optimal selection of glass heat-proof, but to satisfy aspects such as its function, use properties and environment protection simultaneously, also need solve a lot of problems, for example: solvent type heat insulation coating, though dispersion stability is better, water-fast, solvent resistance good, the volatile organic solvent environmental pollution is very big; The aqueous dispersion type thermal insulating coating, though realized environmental protection, it is water-fast in use, weathering resistance is relatively poor, film forming properties is bad; Traditional preparation method carries out physical blending with function powder and matrix resin, and the problem that coating exists bad dispersibility, poor stability, very easily reunites causes the effect of heat insulation of nano paint poor.
The coating material solidified technology of aquosity ultraviolet light (UV) is because of it meets environmental protection, energy-conservation, cleaner production theory is paid close attention to by people day by day.Its advantage mainly contains: needn't regulate viscosity by reactive thinner, can solve volatile solvent and toxicity, irritating problem; Can reduce the shrinking percentage of cured film, improve the tack of cured film ground; Be easy to obtain the preceding inviscid dry film of photocuring; Can obtain the film-type cured film; Spraying is convenient in the controlling flow sex change easily of used water or thickening material; Equipment, container etc. are easy to clean; Reduced the inflammableness of coating.Therefore, the present invention prepares a kind of waterborne UV coating, adopts modification heat insulation nano slurry that water-based UV prepolymer is carried out the compound transparent heat insulating dope that makes of emulsification, and it is environmental protection and every excellent performance not only, dispersiveness and stability in storage are also fine, have solved the problems referred to above effectively.
Summary of the invention
The objective of the invention is to overcome the prior art shortcoming, a kind of transparent heat-insulated coating material solidified preparation method of aquosity ultraviolet light (UV) is provided.This coating is solvent, UV film-forming with water, is a kind of environmental protection and energy saving coating of good weatherability; It is compound that its macromolecule matrix resin uses the heat insulation nano slurry of modification that water-based UV prepolymer is carried out emulsification, obviously improved the dispersed and stable of coating.
Technical scheme of the present invention: a kind of preparation method of transparent heat-insulated UV-curable waterborne coatings comprises the steps:
(1) preparation of modification heat insulation nano slurry:
Get heat insulation nano powder and surface-modifying agent mixed grinding by proportioning, add deionized water again and dispersant is even, regulating the pH value is 8-9, Ball milling again after the first ultrasonic dispersing; Each raw material and shared massfraction (%) proportioning thereof are as follows:
Heat insulation nano powder 5-20
Surface-modifying agent 5-20
Dispersion agent 0-2
Deionized water 58-90
The pH regulator agent is an amount of
Described heat insulation nano powder is a kind of composite nano oxide, its preparation method is: tin chloride, antimony chloride, zinc chloride, cupric chloride and aluminum chloride are configured to solution, repetitive scrubbing filters, ℃ calcines with the dehydration of propyl carbinol component distillation, suction filtration desolventizing, 80-100 ℃ drying, 400-900 behind the precipitation agent ammonia precipitation process, and its mol ratio is Sn: Sb: Zn: Cu: Al=20: 1-2: 0.2-0.5: 0.1: 0.1.
Described surface-modifying agent is a kind of among silane coupling agent KH560, the KH570 (being 2% 95% ethanolic soln), and dispersion agent is polyurethane acrylic ester water coating dispersant such as EFKA4550 or EFKA4560; The pH regulator agent is an ammoniacal liquor.The particle diameter that makes nano pulp is 20-80nm.
(2) preparation of water-based UV transparent heat insulating dope
In prepared water-based UV prepolymer, add the modification heat insulation nano slurry that step (1) makes by proportioning, emulsification 3-4h under 3000-4000rpm stirs, remove solvent, add light trigger, thinner, defoamer and flow agent etc. again and stir, leave standstill froth breaking and promptly get water-based UV transparent heat insulating dope.Coating adopts the mode of spraying or blade coating to be applied to glass, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.Each raw material and shared massfraction (%) proportioning thereof are as follows:
Water-based UV prepolymer 20-40
Modification heat insulation nano slurry 40-60
Light trigger 3-10
Thinner 0-20
Defoamer 0.2-1
Flow agent 0.2-1
The preparation method of described water-based UV prepolymer is: with the polyester polyol of processed, isophorone diisocyanate (IPDI), catalyzer dibutyl tin laurate (DBT), hydrophilic chain extender dimethylol propionic acid (DMPA) and glycol ether (DEG) react 4-5h down at 70-80 ℃, in reaction, drip the hydroxy acrylate that is dissolved with hydroquinone of polymerization retarder then and carry out end capping 2-3h, the viscosity that can add a small amount of solvent (acetone or butanone) conditioned reaction system in the reaction process, reaction cooled to add triethylamine (TEA) neutralization below 50 ℃, make water-based UV polyurethane acrylate prepolymer; The mol ratio of each raw material is polyester polyol: IPDI: DMPA: DEG: hydroxy acrylate=0.75: 2.2-2.7: 0.5-0.8: 0.4: 1.4-1.8, and catalyzer DBT and hydroquinone of polymerization retarder are respectively 0.5% and 0.2% of system total mass; Wherein the hydroxyl value of polyester polyol is 57.3mgKOH/g, and molecular weight is 1941, the new prosperous urethane of Wuxi City company limited, and hydroxy acrylate is one or more among HEA, HMEA, HPA, the HMPA.Described water-based UV prepolymer also can be other without emulsive water-based UV prepolymer such as esters of acrylic acid, epoxy acrylate, polyester acrylate, modification acrylate etc.
Described light trigger is Darocur1173, and thinner is a deionized water, and defoamer is water-borne coatings defoamer such as THIX278 or THIX318, and flow agent is water-borne coatings organo-siloxane type slip(ping)agent and flow agent such as EFKA3580 or EFKA3030.
Described waterborne UV coating adopts the mode of spraying or blade coating, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
Beneficial effect of the present invention:
(1) waterborne UV coating of the present invention's preparation is solvent with water, meets the requirement of national environmental protection fully; Adopt the mode of spraying or blade coating, use the UV-irradiation film forming, can realize the automatic assembly line application, easy construction, curing speed is fast, production efficiency is high, and film have good weather, performances such as hardness, sticking power.
(2) waterborne UV coating of the present invention preparation has high transparent, thermal insulation and low radiance, tests after it is applied to common white film-forming on glass, and this coated glass visible light transmissivity reaches more than 85%; Midsummer, room temp was than using simple glass to reduce 5-8 ℃.
(3) the present invention adopts modification heat insulation nano slurry compound to the emulsification of water-based UV prepolymer, a kind of chemical bonding is arranged between its modified powder and the resin, thereby the dispersiveness of coating and stability are significantly improved.
Embodiment
Embodiment 1
A kind of composition and weight percent (%) of transparent heat-insulated waterborne UV coating are as follows:
Water-based UV prepolymer 25
Heat insulation nano slurry 50
Light trigger Darocur1173 4
Deionized water 20
Defoamer THIX278 0.5
Flow agent EFKA3580 0.5
Wherein the solids content of heat insulation nano slurry is 20%, and it consists of heat insulation nano powder 20g, KH560 (2%) 20g, and EFKA4550 dispersion agent 2g, deionized water 58g, the preparation method is with above-mentioned step (1).The preparation method of coating is with above-mentioned step (2), and the coating that makes adopts the mode of spraying to be applied to glass surface, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
Embodiment 2
A kind of composition and weight percent (%) of transparent heat-insulated waterborne UV coating are as follows:
Water-based UV prepolymer 25
Heat insulation nano slurry 55
Light trigger Darocur1173 6
Deionized water 12.8
Defoamer THIX278 0.6
Flow agent EFKA3030 0.6
Wherein the solids content of heat insulation nano slurry is 15%, and it consists of heat insulation nano powder 15g, KH570 (2%) 15g, and EFKA4550 dispersion agent 1.5g, deionized water 68.5g, the preparation method is with above-mentioned step (1).The preparation method of coating is with above-mentioned step (2), and the coating that makes adopts the mode of spraying to be applied to glass surface, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
Embodiment 3
A kind of composition and weight percent (%) of transparent heat-insulated waterborne UV coating are as follows:
Water-based UV prepolymer 30
Heat insulation nano slurry 55
Light trigger Darocur1173 8
Deionized water 5.4
Defoamer THIX318 0.8
Flow agent EFKA3580 0.8
Wherein the solids content of heat insulation nano slurry is 10%, and it consists of heat insulation nano powder 10g, KH560 (2%) 8g, and KH570 (2%) 2g, EFKA4560 dispersion agent 1g, deionized water 79g, the preparation method is with above-mentioned step (1).The preparation method of coating is with above-mentioned step (2), and the coating that makes adopts the mode of blade coating to be applied to glass surface, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
Embodiment 4
A kind of composition and weight percent (%) of transparent heat-insulated waterborne UV coating are as follows:
Water-based UV prepolymer 35
Heat insulation nano slurry 50
Light trigger Darocur1173 10
Deionized water 3
Defoamer THIX318 1
Flow agent EFKA3030 1
Wherein the solids content of heat insulation nano slurry is 5%, and it consists of heat insulation nano powder 5g, KH560 (2%) 2g, and KH570 (2%) 3g, EFKA4560 dispersion agent 0.5g, deionized water 89.5g, the preparation method is with above-mentioned step (1).The preparation method of coating is with above-mentioned step (2), and the coating that makes adopts the mode of blade coating to be applied to glass surface, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
Claims (10)
1, a kind of preparation method of transparent heat-insulated UV-curable waterborne coatings is characterized in that, comprises the steps:
(1) preparation of modification heat insulation nano slurry
Get heat insulation nano powder and surface-modifying agent mixed grinding by proportioning, add deionized water again and dispersant is even, regulating the pH value is 8-9, Ball milling again after the first ultrasonic dispersing; Each raw material and shared quality % mark proportioning thereof are as follows:
Heat insulation nano powder 5-20
Surface-modifying agent 5-20
Dispersion agent 0-2
Deionized water 58-90
The pH regulator agent is an amount of
(2) preparation of water-based UV transparent heat insulating dope
In the water-based UV prepolymer for preparing, add the modification heat insulation nano slurry that step (1) makes by proportioning, under 3000-4000rpm stirs emulsification 3-4 hour, remove solvent, add light trigger, thinner, defoamer and flow agent again and stir, leave standstill froth breaking and promptly get water-based UV transparent heat insulating dope; Coating adopts the mode of spraying or blade coating to be applied to glass, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again; Each raw material and shared quality % mark proportioning thereof are as follows:
Water-based UV prepolymer 20-40
Modification heat insulation nano slurry 40-60
Light trigger 3-10
Thinner 0-20
Defoamer 0.2-1
Flow agent 0.2-1.
2, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1, it is characterized in that described heat insulation nano powder is a kind of composite nano oxide, its preparation method is: tin chloride, antimony chloride, zinc chloride, cupric chloride and aluminum chloride are configured to solution, repetitive scrubbing filters, ℃ calcines with the dehydration of propyl carbinol component distillation, suction filtration desolventizing, 80-100 ℃ drying, 400-900 behind the precipitation agent ammonia precipitation process, and its mol ratio is Sn: Sb: Zn: Cu: Al=20: 1-2: 0.2-0.5: 0.1: 0.1.
3, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1, the particle diameter that it is characterized in that described modification heat insulation nano slurry is 20-80nm.
4, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1, it is characterized in that described surface-modifying agent is a kind of among silane coupling agent KH560, the KH570, KH560, KH570 are 95% ethanolic soln of mass concentration 2%.
5, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1 is characterized in that described dispersion agent is the polyurethane acrylic ester water coating dispersant, selects EFKA4550 or EFKA4560 for use.
6, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1 is characterized in that described pH regulator agent is an ammoniacal liquor.
7, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1, it is characterized in that: the preparation method of described water-based UV prepolymer is: with the polyester polyol of processed, isophorone diisocyanate IPDI, catalyzer dibutyl tin laurate DBT, hydrophilic chain extender dimethylol propionic acid DMPA and glycol ether DEG reacted 4-5 hour down at 70-80 ℃, dripping the hydroxy acrylate that is dissolved with hydroquinone of polymerization retarder then in reaction carried out end capping 2-3 hour, allow to add a small amount of solvent acetone or butanone in the reaction process, the viscosity of conditioned reaction system, reaction is cooled to the triethylamine of adding below 50 ℃ TEA neutralization, make water-based UV polyurethane acrylate prepolymer; The mol ratio of each raw material is polyester polyol: IPDI: DMPA: DEG: hydroxy acrylate=0.75: 2.2-2.7: 0.5-0.8: 0.4: 1.4-1.8, and catalyzer DBT and hydroquinone of polymerization retarder are respectively 0.5% and 0.2% of system total mass; Hydroxy acrylate is one or more among Hydroxyethyl acrylate HEA, hydroxyethyl methylacrylate HMEA, Propylene glycol monoacrylate HPA, the Rocryl 410 HMPA.
8, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1 is characterized in that: described water-based UV prepolymer or for other without emulsive water-based UV prepolymer: esters of acrylic acid, epoxy acrylate, polyester acrylate or modification acrylate.
9, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1, it is characterized in that: described light trigger is Darocur1173, thinner is a deionized water, defoamer is the water-borne coatings defoamer, select THIX278 or THIX318 for use, flow agent is a water-borne coatings organo-siloxane type flow agent: EFKA3580 or EFKA3030.
10, the preparation method of a kind of transparent heat-insulated UV-curable waterborne coatings according to claim 1 is characterized in that: described waterborne UV coating adopts the mode of spraying or blade coating, and the ultraviolet light irradiation film-forming is used in Infrared Heating levelling, oven dry again.
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Address after: No.8, Hongxing Road, Liangxi District, Wuxi City, Jiangsu Province Patentee after: Jiangnan University Address before: College of chemistry and material engineering Jiangnan University No. 1800 214122 Jiangsu city of Wuxi Province Li Lake Avenue Patentee before: Jiangnan University |