CN105968776A - High-hardness thermal-resistant ultraviolet-proof radiation-protecting anti-dazzle glass film - Google Patents

High-hardness thermal-resistant ultraviolet-proof radiation-protecting anti-dazzle glass film Download PDF

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Publication number
CN105968776A
CN105968776A CN201610304440.5A CN201610304440A CN105968776A CN 105968776 A CN105968776 A CN 105968776A CN 201610304440 A CN201610304440 A CN 201610304440A CN 105968776 A CN105968776 A CN 105968776A
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parts
acrylic emulsion
ultraviolet
film
high rigidity
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凌卫平
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Anhui Herun Special Glass Co Ltd
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Anhui Herun Special Glass Co Ltd
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Priority to CN201610304440.5A priority Critical patent/CN105968776A/en
Publication of CN105968776A publication Critical patent/CN105968776A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a high-hardness thermal-resistant ultraviolet-proof radiating-protecting anti-dazzle glass film. The glass film is prepared from the raw materials of waterborne polyurethane resin, epoxy resin, urea resin, polycarbonate, styrene, methyl methacrylate, polyethylene glycol, 1,3-bis(trifluoromethyl)-benzene, silicon-acrylic emulsion, acrylic emulsion, silicon carbide, nanometer titania, nanometer composite filler, a photoinitiator, a curing agent, a defoaming agent, a dispersing agent and a thickening agent. The anti-dazzle glass film is high in hardness and has thermal-resistant, ultraviolet-proof and radiation-protecting performance.

Description

A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film
Technical field
The present invention relates to glass-film Material Field, particularly relate to a kind of high rigidity heat-resisting anti-ultraviolet radioprotective and prevent Dizzy glass-film.
Background technology
At present, anti-dazzle glas is also known as anti reflection glass or non-reflecting glass.Anti-dazzle glas reduces glass surface Reflectance so that reflectance≤2%, light transmittance >=80%, glossiness >=60%.Anti-dazzle glas is a kind of by glass Glass carries out the glass of special handling, and its principle is high-quality glass single-sided or two-sided to carry out PROCESS FOR TREATMENT so that it is There is compared with simple glass relatively low reflectivity, make the reflectance reduction of light to less than 1%, thus reduce ring The interference of border light, improves the definition of picture, reduces screen reflecting, makes image apparent, true to nature, allows sight Reward person enjoys more preferably visual effect.
The hardness of anti-dazzle glas film of the prior art, heat-resisting, anti-ultraviolet and the anti-performance of radioprotective all cannot Demand when meeting actually used, therefore needs a kind of high rigidity heat-resisting anti-ultraviolet anti-dazzle glass of radioprotective of exploitation badly Glass film meets the demand in actual production.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of heat-resisting anti-ultraviolet of high rigidity Radioprotective anti-dazzle glas film, hardness is high, and has heat-resisting, anti-ultraviolet, the performance of radioprotective.
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part includes: waterborne polyurethane resin 30-60 part, epoxy resin 5-15 part, Lauxite 2-8 part, poly-carbon Acid esters 3-9 part, styrene 2-8 part, methyl methacrylate 3-6 part, Polyethylene Glycol 1-4 part, two Benzotrifluoride 2-5 part, silicone acrylic emulsion 3-9 part, acrylic emulsion 1-4 part, carborundum 2-5 part, nanometer Titanium dioxide 1-4 part, nanocomposite filler 20-30 part, light trigger 1-5 part, firming agent 2-4 part, Defoamer 3-6 part, dispersant 1-4 part, thickening agent 2-5 part.
Preferably, the raw material of nanocomposite filler includes by weight: nano silicon 3-9 part, anhydrous Ethanol 1-5 part, stannic chloride 2-6 part, Butter of antimony. 3-9 part, hydrochloric acid solution 2-5 part, detergent alkylate Sodium sulfonate 1-4 part, sodium borohydride 2-6 part.
Preferably, nanocomposite filler is prepared by following technique: by nano silicon ultrasonic disperse in Dehydrated alcohol obtains material a, then in material a, adds stannic chloride and Butter of antimony. mix homogeneously obtains thing Material b, then adds hydrochloric acid solution and dodecylbenzene sodium sulfonate mix homogeneously in material b, then uses ammonia Regulation pH to 8.8-9.2 obtains material c；Sodium borohydride ultrasonic disperse 5-10min is added in material c, Then being warming up to 170-190 DEG C, insulation 1-3h obtains material d；Material d is washed 1-3 time, in 50-70 DEG C Dry 20-28h obtains nanocomposite filler.
Preferably, waterborne polyurethane resin, epoxy resin, Lauxite, Merlon, styrene, first The weight ratio of base acrylic acid methyl ester., Polyethylene Glycol, two benzotrifluoride, silicone acrylic emulsion and acrylic emulsion is 35-55:8-12:3-7:4-8:3-7:4-5:2-3:3-4:4-8:2-3.
Preferably, waterborne polyurethane resin, silicone acrylic emulsion, acrylic emulsion, carborundum, nanometer titanium dioxide The weight ratio of titanium and nanocomposite filler is 35-55:4-8:2-3:3-4:2-3:22-28.
Preferably, its raw material includes by weight: waterborne polyurethane resin 35-55 part, epoxy resin 8-12 Part, Lauxite 3-7 part, Merlon 4-8 part, styrene 3-7 part, methyl methacrylate 4-5 Part, Polyethylene Glycol 2-3 part, two benzotrifluoride 3-4 parts, silicone acrylic emulsion 4-8 part, acrylic emulsion 2-3 Part, carborundum 3-4 part, nano titanium oxide 2-3 part, nanocomposite filler 22-28 part, light trigger 2-4 part, firming agent 2.5-3.5 part, defoamer 4-5 part, dispersant 2-3 part, thickening agent 3-4 part.
Preferably, its raw material includes by weight: waterborne polyurethane resin 45 parts, epoxy resin 10 parts, Lauxite 5 parts, Merlon 6 parts, styrene 5 parts, methyl methacrylate 4.5 parts, poly-second two Alcohol 2.5 part, two benzotrifluoride 3.5 parts, silicone acrylic emulsion 6 parts, acrylic emulsion 2.5 parts, carborundum 3.5 parts, nano titanium oxide 2.5 parts, nanocomposite filler 25 parts, light trigger 3 parts, firming agent 3 Part, defoamer 4.5 parts, dispersant 2.5 parts, thickening agent 3.5 parts.
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film of the present invention, its raw material includes that aqueous is gathered Urethane resin, epoxy resin, Lauxite, Merlon, styrene, methyl methacrylate, poly-second Glycol, two benzotrifluorides, silicone acrylic emulsion, acrylic emulsion, carborundum, nano titanium oxide, nanometer Compounded mix, light trigger, firming agent, defoamer, dispersant and thickening agent.The aqueous wherein added is gathered Urethane resin is major ingredient, the epoxy resin of interpolation, Lauxite, Merlon, styrene, metering system Acid methyl ester, Polyethylene Glycol, two benzotrifluoride, silicone acrylic emulsion and acrylic emulsion are as aqueous polyurethane tree The supporting material of fat, is effectively increased the heat resistance of waterborne polyurethane resin；The carborundum of interpolation, nanometer Titanium dioxide and nanocomposite filler are as filler, it is possible to be effectively improved anti-dazzle glas film of the present invention hardness and Heat resistance；The nanocomposite filler added uses nano silicon to be precursor, then will with reducing agent Its reduction is the most compound with nano antimony-doped tin dioxide thus be prepared for nanocomposite filler, and nano antimony-doped two The nanoparticle of stannum oxide adsorbs on the surface of nano silicon, adds on the surface of nano silicon Conductive nodes, defines conductive network, effectively avoids the stacking of nano silicon, improves simultaneously The chemical property of nano silicon, and then it is effectively increased the anti-wear performance of anti-dazzle glas film of the present invention, Anti-dazzle glas film of the present invention is made to have heat-resisting, anti-ultraviolet, antistatic and the shielding property of excellence.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment, Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of waterborne polyurethane resin can be 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts, 60 parts；The weight portion of epoxy resin can be 5 parts, 6 Part, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；Lauxite Weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of Merlon can Think 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；Cinnamic weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of methyl methacrylate can be 3 parts, 3.5 Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of Polyethylene Glycol can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Between the weight portion of two benzotrifluorides can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of silicone acrylic emulsion can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of acrylic emulsion can be 1 part, 1.5 parts, 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts；The weight portion of carborundum can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of nano titanium oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of nanocomposite filler can be 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts；The weight portion of light trigger can be 1 Part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of firming agent can be 2 parts, 2.5 parts, 3 parts, 3.5 Part, 4 parts；The weight portion of defoamer can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of dispersant can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts； The weight portion of thickening agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts.
Embodiment 1
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part includes: waterborne polyurethane resin 45 parts, epoxy resin 10 parts, Lauxite 5 parts, Merlon 6 Part, styrene 5 parts, methyl methacrylate 4.5 parts, Polyethylene Glycol 2.5 part, two benzotrifluoride 3.5 Part, silicone acrylic emulsion 6 parts, acrylic emulsion 2.5 parts, carborundum 3.5 parts, nano titanium oxide 2.5 parts, Nanocomposite filler 25 parts, light trigger 3 parts, 3 parts of firming agent, defoamer 4.5 parts, dispersant 2.5 Part, thickening agent 3.5 parts.
Nanocomposite filler is prepared by following technique: by weight by ultrasonic point of 6 parts of nano silicons Dissipate in 3 parts of dehydrated alcohol, obtain material a, in material a, then add 4 parts of stannic chlorides and 6 parts of tri-chlorination Antimony mix homogeneously obtains material b, then adds 3.5 parts of hydrochloric acid solutions and 2.5 parts of dodecyls in material b Benzene sulfonic acid sodium salt mix homogeneously, then obtains material c with ammonia regulation pH to 9.0；4 are added in material c Part sodium borohydride ultrasonic disperse 7.5min, is then warming up to 180 DEG C, and insulation 2h obtains material d；By material D washes 2 times, obtains nanocomposite filler in 60 DEG C of dry 24h.
Embodiment 2
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part includes: waterborne polyurethane resin 30 parts, epoxy resin 15 parts, Lauxite 2 parts, Merlon 9 Part, styrene 2 parts, methyl methacrylate 6 parts, Polyethylene Glycol 1 part, two benzotrifluoride 5 parts, Silicone acrylic emulsion 3 parts, acrylic emulsion 4 parts, carborundum 2 parts, nano titanium oxide 4 parts, nano combined Filler 20 parts, light trigger 5 parts, 2 parts of firming agent, defoamer 6 parts, dispersant 1 part, thickening agent 5 Part.
Nanocomposite filler is prepared by following technique: by weight by ultrasonic point of 3 parts of nano silicons Dissipate in 5 parts of dehydrated alcohol, obtain material a, in material a, then add 2 parts of stannic chlorides and 9 parts of tri-chlorination Antimony mix homogeneously obtains material b, then adds 2 parts of hydrochloric acid solutions and 4 parts of detergent alkylate sulphurs in material b Acid sodium mix homogeneously, then obtains material c with ammonia regulation pH to 8.8；6 parts of boron are added in material c Sodium hydride ultrasonic disperse 5min, is then warming up to 190 DEG C, and insulation 1h obtains material d；Material d is washed 3 times, obtain nanocomposite filler in 50 DEG C of dry 28h.
Embodiment 3
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part include: waterborne polyurethane resin 60 parts, epoxy resin 5 parts, Lauxite 8 parts, Merlon 3 parts, Styrene 8 parts, methyl methacrylate 3 parts, Polyethylene Glycol 4 part, two benzotrifluoride 2 parts, silicon third Emulsion 9 parts, acrylic emulsion 1 part, carborundum 5 parts, nano titanium oxide 1 part, nanocomposite filler 30 parts, light trigger 1 part, 4 parts of firming agent, defoamer 3 parts, dispersant 4 parts, thickening agent 2 parts.
Nanocomposite filler is prepared by following technique: by weight by ultrasonic point of 9 parts of nano silicons Dissipate in 1 part of dehydrated alcohol, obtain material a, in material a, then add 6 parts of stannic chlorides and 3 parts of tri-chlorination Antimony mix homogeneously obtains material b, then adds 5 parts of hydrochloric acid solutions and 1 part of detergent alkylate sulphur in material b Acid sodium mix homogeneously, then obtains material c with ammonia regulation pH to 9.2；2 parts of boron are added in material c Sodium hydride ultrasonic disperse 10min, is then warming up to 170 DEG C, and insulation 3h obtains material d；Material d is washed 1 time, obtain nanocomposite filler in 70 DEG C of dry 20h.
Embodiment 4
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part includes: waterborne polyurethane resin 35 parts, epoxy resin 12 parts, Lauxite 3 parts, Merlon 8 Part, styrene 3 parts, methyl methacrylate 5 parts, Polyethylene Glycol 2 part, two benzotrifluoride 4 parts, Silicone acrylic emulsion 4 parts, acrylic emulsion 3 parts, carborundum 3 parts, nano titanium oxide 3 parts, nano combined Filler 22 parts, light trigger 4 parts, 2.5 parts of firming agent, defoamer 5 parts, dispersant 2 parts, thickening agent 4 parts.
Nanocomposite filler is prepared by following technique: by weight by ultrasonic point of 4 parts of nano silicons Dissipate in 4 parts of dehydrated alcohol, obtain material a, in material a, then add 3 parts of stannic chlorides and 8 parts of tri-chlorination Antimony mix homogeneously obtains material b, then adds 3 parts of hydrochloric acid solutions and 3 parts of detergent alkylate sulphurs in material b Acid sodium mix homogeneously, then obtains material c with ammonia regulation pH to 8.9；5 parts of boron are added in material c Sodium hydride ultrasonic disperse 6min, is then warming up to 185 DEG C, and insulation 1.5h obtains material d；By material d water Wash 3 times, obtain nanocomposite filler in 55 DEG C of dry 26h.
Embodiment 5
A kind of high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film that the present invention proposes, its raw material is by weight Part include: waterborne polyurethane resin 55 parts, epoxy resin 8 parts, Lauxite 7 parts, Merlon 4 parts, Styrene 7 parts, methyl methacrylate 4 parts, Polyethylene Glycol 3 part, two benzotrifluoride 3 parts, silicon third Emulsion 8 parts, acrylic emulsion 2 parts, carborundum 4 parts, nano titanium oxide 2 parts, nanocomposite filler 28 parts, light trigger 2 parts, 3.5 parts of firming agent, defoamer 4 parts, dispersant 3 parts, thickening agent 3 parts.
Nanocomposite filler is prepared by following technique: by weight by ultrasonic point of 8 parts of nano silicons Dissipate in 2 parts of dehydrated alcohol, obtain material a, in material a, then add 5 parts of stannic chlorides and 4 parts of tri-chlorination Antimony mix homogeneously obtains material b, then adds 4 parts of hydrochloric acid solutions and 2 parts of detergent alkylate sulphurs in material b Acid sodium mix homogeneously, then obtains material c with ammonia regulation pH to 9.1；3 parts of boron are added in material c Sodium hydride ultrasonic disperse 9min, is then warming up to 175 DEG C, and insulation 2.5h obtains material d；By material d water Wash 1 time, obtain nanocomposite filler in 65 DEG C of dry 22h.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (7)

1. a high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film, it is characterised in that its raw material is by weight Amount part includes: waterborne polyurethane resin 30-60 part, epoxy resin 5-15 part, Lauxite 2-8 part, poly- Carbonic ester 3-9 part, styrene 2-8 part, methyl methacrylate 3-6 part, Polyethylene Glycol 1-4 part, Two benzotrifluoride 2-5 parts, silicone acrylic emulsion 3-9 part, acrylic emulsion 1-4 part, carborundum 2-5 part, receive Rice titanium dioxide 1-4 part, nanocomposite filler 20-30 part, light trigger 1-5 part, firming agent 2-4 part, Defoamer 3-6 part, dispersant 1-4 part, thickening agent 2-5 part.
High rigidity the most according to claim 1 heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film, its feature Being, the raw material of nanocomposite filler includes by weight: nano silicon 3-9 part, dehydrated alcohol 1-5 Part, stannic chloride 2-6 part, Butter of antimony. 3-9 part, hydrochloric acid solution 2-5 part, dodecylbenzene sodium sulfonate 1-4 Part, sodium borohydride 2-6 part.
High rigidity the most according to claim 1 and 2 heat-resisting anti-ultraviolet radioprotective anti-dazzle glas film, its Being characterised by, nanocomposite filler is prepared by following technique: by nano silicon ultrasonic disperse in nothing Water-ethanol obtains material a, then in material a, adds stannic chloride and Butter of antimony. mix homogeneously obtains thing Material b, then adds hydrochloric acid solution and dodecylbenzene sodium sulfonate mix homogeneously in material b, then uses ammonia Water regulation pH to 8.8-9.2 obtains material c；Sodium borohydride ultrasonic disperse 5-10min is added in material c, Then being warming up to 170-190 DEG C, insulation 1-3h obtains material d；Material d is washed 1-3 time, in 50-70 DEG C Dry 20-28h obtains nanocomposite filler.
4. according to the high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas described in any one of claim 1-3 Film, it is characterised in that waterborne polyurethane resin, epoxy resin, Lauxite, Merlon, styrene, Methyl methacrylate, Polyethylene Glycol, two benzotrifluoride, silicone acrylic emulsion and the weight ratio of acrylic emulsion For 35-55:8-12:3-7:4-8:3-7:4-5:2-3:3-4:4-8:2-3.
5. according to the high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas described in any one of claim 1-4 Film, it is characterised in that waterborne polyurethane resin, silicone acrylic emulsion, acrylic emulsion, carborundum, nanometer two The weight ratio of titanium oxide and nanocomposite filler is 35-55:4-8:2-3:3-4:2-3:22-28.
6. according to the high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas described in any one of claim 1-5 Film, it is characterised in that its raw material includes by weight: waterborne polyurethane resin 35-55 part, epoxy resin 8-12 part, Lauxite 3-7 part, Merlon 4-8 part, styrene 3-7 part, methyl methacrylate 4-5 part, Polyethylene Glycol 2-3 part, two benzotrifluoride 3-4 parts, silicone acrylic emulsion 4-8 part, propylene yogurt Liquid 2-3 part, carborundum 3-4 part, nano titanium oxide 2-3 part, nanocomposite filler 22-28 part, light Initiator 2-4 part, firming agent 2.5-3.5 part, defoamer 4-5 part, dispersant 2-3 part, thickening agent 3-4 Part.
7. according to the high rigidity heat-resisting anti-ultraviolet radioprotective anti-dazzle glas described in any one of claim 1-6 Film, it is characterised in that its raw material includes by weight: waterborne polyurethane resin 45 parts, epoxy resin 10 Part, Lauxite 5 parts, Merlon 6 parts, styrene 5 parts, methyl methacrylate 4.5 parts, poly- Ethylene glycol 2.5 part, two benzotrifluoride 3.5 parts, silicone acrylic emulsion 6 parts, acrylic emulsion 2.5 parts, carbon SiClx 3.5 parts, nano titanium oxide 2.5 parts, nanocomposite filler 25 parts, light trigger 3 parts, solidification Agent 3 parts, defoamer 4.5 parts, dispersant 2.5 parts, thickening agent 3.5 parts.
CN201610304440.5A 2016-05-06 2016-05-06 High-hardness thermal-resistant ultraviolet-proof radiation-protecting anti-dazzle glass film Withdrawn CN105968776A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107722598A (en) * 2017-10-12 2018-02-23 广东华粘新材料研究有限公司 The preparation method of high-strength polyurethane
CN108084354A (en) * 2017-12-27 2018-05-29 安徽省二邦化工有限公司 A kind of UV resistant synthetic resin and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103360854A (en) * 2012-03-28 2013-10-23 厦门纳诺泰克科技有限公司 High-transparency low-radiation energy-saving combined material for glass and preparation method thereof
CN104177802A (en) * 2014-08-15 2014-12-03 无锡三帝特种高分子材料有限公司 Radiation-resistant sticking film for computer screen
CN104503009A (en) * 2014-12-09 2015-04-08 成都摩卡科技有限责任公司 Anti-dazzle solar film and preparation method thereof
CN105038553A (en) * 2015-07-31 2015-11-11 安徽和润特种玻璃有限公司 Anti-fouling and abrasion-resistant film used for anti-dazzle glass
CN105060729A (en) * 2015-07-31 2015-11-18 安徽和润特种玻璃有限公司 Stain-resistant, wear-resistant and antistatic coating film for anti-glare glasses

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360854A (en) * 2012-03-28 2013-10-23 厦门纳诺泰克科技有限公司 High-transparency low-radiation energy-saving combined material for glass and preparation method thereof
CN104177802A (en) * 2014-08-15 2014-12-03 无锡三帝特种高分子材料有限公司 Radiation-resistant sticking film for computer screen
CN104503009A (en) * 2014-12-09 2015-04-08 成都摩卡科技有限责任公司 Anti-dazzle solar film and preparation method thereof
CN105038553A (en) * 2015-07-31 2015-11-11 安徽和润特种玻璃有限公司 Anti-fouling and abrasion-resistant film used for anti-dazzle glass
CN105060729A (en) * 2015-07-31 2015-11-18 安徽和润特种玻璃有限公司 Stain-resistant, wear-resistant and antistatic coating film for anti-glare glasses

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107722598A (en) * 2017-10-12 2018-02-23 广东华粘新材料研究有限公司 The preparation method of high-strength polyurethane
CN108084354A (en) * 2017-12-27 2018-05-29 安徽省二邦化工有限公司 A kind of UV resistant synthetic resin and preparation method thereof

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