CN113004783A - Ultraviolet-curing polyurethane acrylate coating and preparation method thereof - Google Patents
Ultraviolet-curing polyurethane acrylate coating and preparation method thereof Download PDFInfo
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- CN113004783A CN113004783A CN202110279144.5A CN202110279144A CN113004783A CN 113004783 A CN113004783 A CN 113004783A CN 202110279144 A CN202110279144 A CN 202110279144A CN 113004783 A CN113004783 A CN 113004783A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to an ultraviolet light curing urethane acrylate coating and a preparation method thereof. The ultraviolet light curing polyurethane acrylate coating provided by the invention comprises the following raw material components in parts by weight: the adhesive comprises, by weight, 15-30 parts of a polyurethane acrylate prepolymer A20-35 parts, a polyurethane acrylate prepolymer B15-30 parts, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 5-10 parts of trimethylolpropane triacrylate, 5-10 parts of poly dipentaerythritol hexaacrylate, 10-15 parts of isobornyl acrylate, 2-5 parts of a photoinitiator and 0.1-1 part of a leveling assistant. The ultraviolet light curing polyurethane acrylate coating provided by the invention has the advantages of high hardness, good wear resistance, high scratch resistance, lasting oil stain resistance, oil resistance, water resistance, good acid and alkali resistance, high transparency and burning resistance.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to an ultraviolet-curing urethane acrylate coating and a preparation method thereof.
Background
The light-cured coating is a liquid formula added with a photoinitiator by irradiating a light source with certain intensity, and the photoinitiator absorbs light quanta to generate active groups to initiate polymerization reaction, so that liquid resin is instantly converted into a solid film. Photocured coatings have gained rapid development due to the properties of the photocuring technique itself, as compared to conventional naturally dried or thermally cured coatings. First, the photocuring is performed only at normal temperature, and the construction unsuitable for the product of the heat drying method can be satisfied. Second, the photo-curing technique enables coating quality, such as mechanical properties and gloss, to be brought to a higher level, in addition to improving productivity and saving energy consumption. Third, because a "solventless" system is used, expensive waste disposal facilities do not have to be installed during the manufacturing application.
The photocureable coating mainly comprises four parts: photoinitiator, resin prepolymer, reactive diluent and auxiliary agent. Prepolymers, also known as photosensitive resins, are film-forming substances which are present in considerable proportions in the overall system and have a decisive influence on the properties of the coating film. There are two main types: radical polymerization type resins and cationic polymerization type resins.
Among all UV photocureable coatings, the polyurethane acrylate coating has the advantages of high hardness, good luster, strong toughness and yellowing resistance, and is the most widely applied UV photocureable coating. Although the polyurethane acrylate coating has the advantages of good adhesion, high surface hardness, good gloss and strong toughness, the oil stain resistance is generally poor.
The principle of stain resistance: the stain resistance of organic coatings is mainly related to the surface energy and surface characteristics of the coating, neglecting the influence of external factors. The smaller the surface energy, the better the stain resistance because the contaminants are generally oil stains caused by water, which accumulate to a large extent, and the stains are relatively less likely to form as long as water droplets do not readily adhere thereto. Therefore, the micro-rough structure is formed on the surface of the coating, and the oil stain is not easy to adhere to the surface of the coating by increasing the contact angle between the pollution source and the coating.
The traditional solution for improving the stain resistance of a paint film is to use a fluorine-containing auxiliary agent or add inorganic nano particles in the preparation process of the paint to improve the stain resistance effect after film formation, but the method only has a transient effect and poor stain resistance durability, and mainly shows the following two points: on one hand, under the condition of high temperature and high humidity, the surface of the pattern layer is easy to damage, and the fluorine-containing auxiliary agent is easy to migrate, so that the stain resistance and stain resistance are not durable; on the other hand, if the coating is applied to floor paint, the fluorine-containing auxiliary agent is easy to fall off under the environment of long-term friction, so that the stain resistance and stain resistance of a paint film are greatly reduced, and the performances of hydrophobicity and oil resistance are also poor. Therefore, there is an urgent need to develop a urethane acrylate coating having excellent durability and oil stain resistance.
Disclosure of Invention
The invention aims to provide an ultraviolet light curing polyurethane acrylate coating and a preparation method thereof, which at least partially solve the problems in the prior art.
The invention provides an ultraviolet light curing polyurethane acrylate coating, which comprises the following raw material components in parts by weight: the adhesive comprises, by weight, 15-30 parts of a polyurethane acrylate prepolymer A20-35 parts, a polyurethane acrylate prepolymer B15-30 parts, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 5-10 parts of trimethylolpropane triacrylate, 5-10 parts of poly dipentaerythritol hexaacrylate, 10-15 parts of isobornyl acrylate, 2-5 parts of a photoinitiator and 0.1-1 part of a leveling assistant.
As a further improvement of the above scheme:
preferably, the urethane acrylate prepolymer A is a 2-functional resin with a molecular weight of 500-3000. The polyurethane acrylate prepolymer A adopted by the invention is aliphatic polyurethane acrylate, resin with good wear resistance is selected, resin with high hardness is selected, the selected resin is not easy to yellow, 100% of solid content does not contain solvent volatile matters, and resin with good adhesive force is selected and has good compatibility; one or more of the following types can be selected: NeoRad U-25-20D, NeoRad U-24-25Z, NeoRad U-6282 from Dismann.
Preferably, the urethane acrylate prepolymer B is a resin with the functionality of 8-10 and the molecular weight is 500-3000. The polyurethane acrylate prepolymer B adopted by the invention is aliphatic polyurethane acrylate, resin with good wear resistance is selected, resin with high hardness is selected, the selected resin is not easy to yellow, 100% of solid content does not contain solvent volatile matters, and resin with good adhesive force is selected and has good compatibility; one or more of the following types can be selected: AgiSyn 242, AgiSyn 2421, AgiSyn 230A from Imperial corporation; b-912, B919B from Boxing, Guangdong.
Preferably, the silicon-fluorine modified ultraviolet curing polyurethane prepolymer is 4-6 functional resin with molecular weight of 1000-3000.
Preferably, the silicon-fluorine modified ultraviolet-curing polyurethane prepolymer is hyperbranched organic silicon modified acrylate and has a highly branched structure and a large number of terminal groups. The silicon-fluorine modified ultraviolet curing polyurethane prepolymer adopted by the invention has high hardness, high wear resistance and good oil resistance, the resin is hyperbranched organic silicon modified acrylate, and the resin has a highly branched structure, a large number of terminal groups and lower viscosity, so that the resin has good leveling property, and the functional groups are highly concentrated to ensure that the resin has high reactivity. The silicon-fluorine modified ultraviolet curing polyurethane prepolymer can be one or more of the following types: L6905A, L6905B, L6905C, L6905E of Kalru, Guangdong, B-868, B-828, B-846 of Boxing, Guangdong.
Preferably, the photoinitiator is a free radical type photoinitiator. The photoinitiator adopted by the invention is a non-yellowing photoinitiator; 184 from Tianjin Jieshi Xin Shuang Co.
Preferably, the leveling assistant adopted by the invention is an organic silicon surface assistant, and is suitable for solvent-free paint systems and ink paint systems; one or more of the following types can be selected: BYK-333 from Bick, Pasteur FL-3777.
The invention provides a preparation method of the ultraviolet light curing polyurethane acrylate coating, which comprises the following steps: the method comprises the following steps: sequentially adding a polyurethane acrylate prepolymer A, a polyurethane acrylate prepolymer B, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, trimethylolpropane triacrylate, poly dipentaerythritol hexaacrylate and isobornyl acrylate, and then stirring and dispersing; step two: adding the photoinitiator into the mixture obtained in the step one in batches, and stirring and dispersing the mixture after the addition is finished until the photoinitiator is completely dissolved; step three: dripping the leveling aid into the mixture obtained in the step two, stirring and dispersing after the addition is finished until the leveling aid is uniformly dispersed in the coating system; step four: and C, sealing and storing the mixture obtained in the step three, standing for defoaming, and then storing at normal temperature.
Preferably, in the preparation method of the ultraviolet light curing polyurethane acrylate coating, in the step one, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-1000r/min, and the stirring time is 30-60 min; in the second step, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-; in the third step, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-.
Preferably, in the preparation method of the ultraviolet light curing urethane acrylate coating, the standing and defoaming temperature is 40-60 ℃, and the standing time is 1-2 hours.
The technical scheme provided by the invention has the following beneficial effects: (1) in order to enable the coating to have excellent lasting stain resistance, the stain-resistant coating is prepared by selecting the silicon modified stain-resistant polyurethane acrylic resin so as to achieve the lasting stain-resistant effect; the preparation of the stain-resistant coating by selecting the silicon modified stain-resistant polyurethane acrylic resin is characterized in that the resin is hyperbranched organic silicon modified acrylate, has a highly branched structure and a large number of terminal groups; after the resin is selected, the silicone modified chain segment is arranged at the tail end of the chain after the UV coating is formed into a film, the chain segment is incompatible with the main chain resin and can migrate to the surface to form a nano micro coarse structure, and simultaneously, the chain segment participates in network crosslinking in the curing process of the coating, and the stain resistance performance is not easy to attenuate under the conditions of high temperature and high humidity, so that the stain resistance durability of the surface of the coating is improved. (2) The ultraviolet light curing polyurethane acrylate coating provided by the invention has the advantages of high hardness, good wear resistance, high scratch resistance, lasting oil stain resistance, oil resistance, water resistance, good acid and alkali resistance, high transparency and burning resistance.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. The following examples are only for illustrating the technical solutions of the present invention more clearly, and therefore are only examples, and the protection scope of the present invention is not limited thereby. The experimental procedures in the following examples are conventional unless otherwise specified. The test materials used in the following examples were purchased from a conventional reagent store unless otherwise specified. In the quantitative tests in the following examples, three replicates were set, and the data are the mean or the mean ± standard deviation of the three replicates.
Example 1
The embodiment provides an ultraviolet curing urethane acrylate coating, which comprises the following raw material components in parts by weight: the coating comprises, by weight, 30 parts of a polyurethane acrylate prepolymer A, 15 parts of a polyurethane acrylate prepolymer B, 20 parts of a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 10 parts of trimethylolpropane triacrylate, 5 parts of poly dipentaerythritol hexaacrylate, 15 parts of isobornyl acrylate, 4 parts of a photoinitiator and 1 part of a leveling assistant.
The urethane acrylate prepolymer A used in this example was a 2-functionality resin, NeoRad U-25-20D, available from Impermann corporation; the urethane acrylate prepolymer B is 8-functionality resin, and is AgiSyn 242 purchased from Imperial corporation; the silicofluoride modified ultraviolet curing polyurethane prepolymer is L6905A which is purchased from Kohler corporation of Guangdong blue; photoinitiator was 184 purchased from tianjin jiuxian nova corporation; the leveling aid was BYK-333, available from Bick.
According to the preparation method provided by the invention, the ultraviolet curing urethane acrylate coating is prepared, and the preparation method comprises the following steps:
the method comprises the following steps: sequentially adding a polyurethane acrylate prepolymer A, a polyurethane acrylate prepolymer B, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, trimethylolpropane triacrylate, poly dipentaerythritol hexaacrylate and isobornyl acrylate into a black dispersion tank, and stirring for reaction at 25 ℃ at a dispersion speed of 600r/min for 60 min.
Step two: adding the photoinitiator in batches, keeping the temperature at 25 ℃, stirring for 60min after the addition is finished, and dispersing at the speed of 600r/min until the photoinitiator is completely dissolved.
Step three: slowly dropwise adding the leveling aid, maintaining the temperature at 25 ℃, stirring for 30min after the addition, wherein the dispersion speed is 700r/min, and uniformly dispersing the leveling aid in the coating system.
Step four: and after stirring, sealing and storing, and standing in a 50 ℃ oven for defoaming for 2 hours.
Step five: and (5) after the defoaming process is finished, storing at normal temperature, and waiting for coating.
Example 2
The embodiment provides an ultraviolet curing urethane acrylate coating, which comprises the following raw material components in parts by weight: the coating comprises, by weight, 26 parts of a polyurethane acrylate prepolymer A, 19 parts of a polyurethane acrylate prepolymer B, 25 parts of a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 10 parts of trimethylolpropane triacrylate, 5 parts of poly dipentaerythritol hexaacrylate, 10 parts of isobornyl acrylate, 4 parts of a photoinitiator and 1 part of a leveling assistant.
The urethane acrylate prepolymer A used in this example was a 2-functionality resin, NeoRad U-25-20D, available from Impermann corporation; the urethane acrylate prepolymer B is 8-functionality resin which is B-912 purchased from Boxing New Material company of Guangdong; the silicofluoride modified ultraviolet curing polyurethane prepolymer is L6905C which is purchased from Kohler corporation of Guangdong blue; photoinitiator was 184 purchased from tianjin jiuxian nova corporation; the leveling aid was BYK-333, available from Bick.
According to the preparation method provided by the invention, the ultraviolet curing urethane acrylate coating is prepared, and the preparation method comprises the following steps:
the method comprises the following steps: sequentially adding a polyurethane acrylate prepolymer A, a polyurethane acrylate prepolymer B, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, trimethylolpropane triacrylate, poly dipentaerythritol hexaacrylate and isobornyl acrylate into a black dispersion tank, and stirring for reaction at 25 ℃ at a dispersion speed of 600r/min for 60 min.
Step two: adding the photoinitiator in batches, keeping the temperature at 25 ℃, stirring for 30min after the addition is finished, and dispersing at the speed of 700r/min until the photoinitiator is completely dissolved.
Step three: slowly dropwise adding the leveling aid, maintaining the temperature at 25 ℃, stirring for 30min after the addition, wherein the dispersion speed is 500r/min, and uniformly dispersing the leveling aid in the coating system.
Step four: and after stirring, sealing and storing, and standing in a 50 ℃ oven for defoaming for 2 hours.
Step five: and (5) after the defoaming process is finished, storing at normal temperature, and waiting for coating.
Example 3
The embodiment provides an ultraviolet curing urethane acrylate coating, which comprises the following raw material components in parts by weight: the adhesive comprises, by weight, 35 parts of a polyurethane acrylate prepolymer A, 15 parts of a polyurethane acrylate prepolymer B, 15 parts of a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 10 parts of trimethylolpropane triacrylate, 5 parts of poly dipentaerythritol hexaacrylate, 15 parts of isobornyl acrylate, 4 parts of a photoinitiator and 1 part of a leveling assistant.
The urethane acrylate prepolymer A used in this example was a 2-functionality resin, which was obtained from NeoRad U6282 available from Impermann corporation; the urethane acrylate prepolymer B is 8-functionality resin and is AgiSyn 2421 purchased from Imperial corporation; the silicofluoride modified ultraviolet curing polyurethane prepolymer is L6905E which is purchased from Kohler corporation of Guangdong blue; photoinitiator was 184 purchased from tianjin jiuxian nova corporation; the leveling aid was BYK-333, available from Bick.
According to the preparation method provided by the invention, the ultraviolet curing urethane acrylate coating is prepared, and the preparation method comprises the following steps:
the method comprises the following steps: sequentially adding a polyurethane acrylate prepolymer A, a polyurethane acrylate prepolymer B, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, trimethylolpropane triacrylate, poly dipentaerythritol hexaacrylate and isobornyl acrylate into a black dispersion tank, and stirring for reaction at 25 ℃ at a dispersion speed of 600r/min for 60 min.
Step two: adding the photoinitiator in batches, keeping the temperature at 25 ℃, stirring for 60min after the addition is finished, and dispersing at the speed of 700r/min until the photoinitiator is completely dissolved.
Step three: slowly dropwise adding the leveling aid, maintaining the temperature at 25 ℃, stirring for 30min after the addition, wherein the dispersion speed is 600r/min, and uniformly dispersing the leveling aid in the coating system.
Step four: and after stirring, sealing and storing, and standing in an oven at 40 ℃ for defoaming for 2 hours.
Step five: and (5) after the defoaming process is finished, storing at normal temperature, and waiting for coating.
The ultraviolet curing urethane acrylate coating prepared in the embodiments 1 to 3 of the invention is coated on a plate, and the coating amount is as follows: 40 g/m2And the smearing mode is as follows: roller coating of the rubber roller and the laser roller, and coating thickness: 30 μm, illumination intensity: 200mj/cm2Leveling time: 1min, leveling temperature: at 50 ℃. The coated panels were tested and the results of the panel testing are shown in table 1 below.
TABLE 1 sample test results
From the results, the ultraviolet-curable polyurethane acrylate coating provided by the invention has the advantages of high hardness, good wear resistance, high scratch resistance, lasting oil stain resistance, oil resistance, water resistance, good acid and alkali resistance, high transparency and burning resistance.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the invention, and these modifications and decorations should also be regarded as the inventive content of the present invention.
Claims (10)
1. The ultraviolet-curing polyurethane acrylate coating is characterized by comprising the following raw material components in parts by weight: the adhesive comprises, by weight, 15-30 parts of a polyurethane acrylate prepolymer A20-35 parts, a polyurethane acrylate prepolymer B15-30 parts, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, 5-10 parts of trimethylolpropane triacrylate, 5-10 parts of poly dipentaerythritol hexaacrylate, 10-15 parts of isobornyl acrylate, 2-5 parts of a photoinitiator and 0.1-1 part of a leveling assistant.
2. The uv curable urethane acrylate coating according to claim 1, wherein: the polyurethane acrylate prepolymer A is 2-functionality resin with the molecular weight of 500-3000.
3. The uv curable urethane acrylate coating according to claim 1, wherein: the polyurethane acrylate prepolymer B is resin with the functionality of 8-10 and the molecular weight of 500-3000.
4. The uv curable urethane acrylate coating according to claim 1, wherein: the silicon-fluorine modified ultraviolet curing polyurethane prepolymer is 4-6 functionality resin, and the molecular weight is 1000-3000.
5. The uv curable urethane acrylate coating according to claim 1, wherein: the silicon-fluorine modified ultraviolet curing polyurethane prepolymer is hyperbranched organic silicon modified acrylate and has a highly branched structure and a large number of terminal groups.
6. The uv curable urethane acrylate coating according to claim 1, wherein: the photoinitiator is a free radical photoinitiator.
7. A method for preparing the ultraviolet-curable polyurethane acrylate coating of any one of claims 1 to 6, comprising the steps of: the method comprises the following steps: sequentially adding a polyurethane acrylate prepolymer A, a polyurethane acrylate prepolymer B, a silicon-fluorine modified ultraviolet curing polyurethane prepolymer, trimethylolpropane triacrylate, poly dipentaerythritol hexaacrylate and isobornyl acrylate, and then stirring and dispersing; step two: adding the photoinitiator into the mixture obtained in the step one in batches, and stirring and dispersing the mixture after the addition is finished until the photoinitiator is completely dissolved; step three: dripping the leveling aid into the mixture obtained in the step two, stirring and dispersing after the addition is finished until the leveling aid is uniformly dispersed in the coating system; step four: and C, sealing and storing the mixture obtained in the step three, standing for defoaming, and then storing at normal temperature.
8. The method for preparing the ultraviolet-curable polyurethane acrylate coating according to claim 7, wherein the method comprises the following steps: in the first step, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-; in the second step, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-; in the third step, the temperature is maintained at 25-40 ℃, the dispersion speed is 500-.
9. The method for preparing the ultraviolet-curable polyurethane acrylate coating according to claim 7, wherein the method comprises the following steps: in the fourth step, the temperature for standing and defoaming is 40-60 ℃.
10. The method for preparing the ultraviolet-curable polyurethane acrylate coating according to claim 7, wherein the method comprises the following steps: in the fourth step, the standing time is 1-2 h.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116102969A (en) * | 2022-09-07 | 2023-05-12 | 江苏斯迪克新材料科技股份有限公司 | Fingerprint-resistant UV (ultraviolet) curing coating for film, preparation method of fingerprint-resistant UV curing coating and preparation method of film |
| CN116694200A (en) * | 2023-05-24 | 2023-09-05 | 无锡博加电子新材料有限公司 | High-hardness wear-resistant UV (ultraviolet) curing coating |
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| CN101157808A (en) * | 2007-11-01 | 2008-04-09 | 凌云剑 | Highly wearable vacuum coating ultraviolet curing coatings |
| CN107974151A (en) * | 2017-11-15 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of UV coating of resistance to highly basic, strong acid |
| CN108084862A (en) * | 2017-11-27 | 2018-05-29 | 张家港康得新光电材料有限公司 | Cured coating and preparation method thereof, hardened layer and the protective film containing hardened layer |
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- 2021-03-16 CN CN202110279144.5A patent/CN113004783A/en active Pending
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| CN101157808A (en) * | 2007-11-01 | 2008-04-09 | 凌云剑 | Highly wearable vacuum coating ultraviolet curing coatings |
| CN107974151A (en) * | 2017-11-15 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of UV coating of resistance to highly basic, strong acid |
| CN108084862A (en) * | 2017-11-27 | 2018-05-29 | 张家港康得新光电材料有限公司 | Cured coating and preparation method thereof, hardened layer and the protective film containing hardened layer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116102969A (en) * | 2022-09-07 | 2023-05-12 | 江苏斯迪克新材料科技股份有限公司 | Fingerprint-resistant UV (ultraviolet) curing coating for film, preparation method of fingerprint-resistant UV curing coating and preparation method of film |
| CN116694200A (en) * | 2023-05-24 | 2023-09-05 | 无锡博加电子新材料有限公司 | High-hardness wear-resistant UV (ultraviolet) curing coating |
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Application publication date: 20210622 |