CN105273632A - Water-based UV vacuum coating paint and preparation method thereof - Google Patents
Water-based UV vacuum coating paint and preparation method thereof Download PDFInfo
- Publication number
- CN105273632A CN105273632A CN201510648147.6A CN201510648147A CN105273632A CN 105273632 A CN105273632 A CN 105273632A CN 201510648147 A CN201510648147 A CN 201510648147A CN 105273632 A CN105273632 A CN 105273632A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- emulsion
- poured
- ethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a water-based UV vacuum coating paint and a preparation method thereof. The water-based UV vacuum coating paint comprises the following raw materials by weight: 30-33 parts of liquid photosensitive resin, 13-15 parts of urea formaldehyde resin, 12-14 parts of water-based polishing oil, 7-9 parts of a water-based polyethylene emulsion, 6-11 parts of silicone grease, 11-13 parts of an acrylic emulsion, 3-6 parts of emulsified silicone oil, 3-8 parts of ethylene glycol monobutyl ether, 11-13 parts of ethanol, 5-10 parts of a 184 photoinitiator, 2-4 parts of petroleum coke, 10-25 parts of a methacrylic acid-2-hydroxyethyl ester monomer, and 2-4 parts of diethylamine. The water-based UV vacuum coating paint has excellent comprehensive performance.
Description
Technical field
The present invention relates to a kind of water-based UV vacuum plating paint and preparation method thereof.
Background technology
Vacuum metallizing coating was developed so far from the eighties, modal vacuum film-coated finish paint is oil-soluble UV photo-cured coating on the market at present, and its formula is: two functional group's aliphatic urethane acrylates 15%, hexafunctional aliphatic urethane acrylates 8%, trifunctional group acrylate's monomer 8%, six functional groups acrylate monomer 4%, monofunctional acrylates's ester monomer 10%, acid adhesion promoter 1%, mixed light initiator 4%, auxiliary agent 1%, solvent 49%.
But current water-based UV vacuum plating paint curing speed is easily restricted, and performance is general, is difficult to satisfy the demands of consumers.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of water-based UV vacuum plating paint with excellent over-all properties and preparation method thereof.
For solving the problem, the present invention adopts following technical scheme:
A kind of water-based UV vacuum plating paint and preparation method thereof, comprises the raw material of following parts by weight proportioning: liquid photosensitive resin 30-33 part, urea-formaldehyde resin 13-15 part, water-based gloss oil 12-14 part, aqueous polyethylene emulsion 7-9 part, silicone grease 6-11 part, ACRYLIC EMULSION 11-13 part, silicone emulsion 3-6 part, ethylene glycol monobutyl ether 3-8 part, ethanol 11-13 part, 184 light trigger 5-10 parts, refinery coke 2-4 part, methacrylic acid-2-hydroxy methacrylate monomer 10-25 part and diethylamine 2-4 part.
Further, the raw material of following parts by weight proportioning is comprised: liquid photosensitive resin 30 parts, urea-formaldehyde resin 13 parts, water-based gloss oil 12 parts, aqueous polyethylene emulsion 7 parts, silicone grease 6 parts, ACRYLIC EMULSION 11 parts, silicone emulsion 3 parts, ethylene glycol monobutyl ether 3 parts, ethanol 11 parts, 184 light trigger 5 parts, refinery coke 2 parts, methacrylic acid-2-hydroxy methacrylate monomer 10 parts and diethylamine 2 parts.
Further, the raw material of following parts by weight proportioning is comprised: liquid photosensitive resin 33 parts, urea-formaldehyde resin 15 parts, water-based gloss oil 14 parts, aqueous polyethylene emulsion 9 parts, silicone grease 11 parts, ACRYLIC EMULSION 13 parts, silicone emulsion 6 parts, ethylene glycol monobutyl ether 8 parts, ethanol 3 parts, 184 light trigger 10 parts, refinery coke 4 parts, methacrylic acid-2-hydroxy methacrylate monomer 25 parts and diethylamine 4 parts.
Further, the raw material of following parts by weight proportioning is comprised: liquid photosensitive resin 32 parts, urea-formaldehyde resin 14 parts, water-based gloss oil 13 parts, aqueous polyethylene emulsion 8 parts, silicone grease 9 parts, ACRYLIC EMULSION 12 parts, silicone emulsion 5 parts, ethylene glycol monobutyl ether 6 parts, ethanol 12 parts, 184 light trigger 7 parts, refinery coke 3 parts, methacrylic acid-2-hydroxy methacrylate monomer 15 parts and diethylamine 3 parts.
Another technical problem that the present invention will solve is to provide a kind of preparation method of water-based UV vacuum plating paint, comprises the following steps:
1) 184 light trigger 5-10 parts, refinery coke 2-4 part, methacrylic acid-2-hydroxy methacrylate monomer 10-25 part and diethylamine 2-4 part are carried out mix and blend, for subsequent use;
2) be poured in resistance furnace by mixture obtained for step 1) and carry out pyrotic smelting 120 minutes, the black object of obtained caking, is then again poured into obtained caking black object in pulverizer and carries out pulverization process, obtained dark tan powder, for subsequent use;
3) silicone grease 6-11 part is poured in vessel together with silicon silicone emulsion 3-6 part stirs rear obtained brown paste, for subsequent use;
4) liquid photosensitive resin 30-33 part, water-based gloss oil 12-14 part are poured in container together with aqueous polyethylene emulsion 7-9 part, are heated to 60 DEG C, and constantly stir, until temperature is down to normal temperature, obtained mixing liquid, for subsequent use;
5) ethanol 11-13 part is poured in reaction vessel, then slowly pours ethylene glycol monobutyl ether 3-8 part into, pour in process and constantly stir, until dissolve completely to ethylene glycol monobutyl ether 3-8 part, obtained ethylene glycol monobutyl ether solution, for subsequent use;
6) urea-formaldehyde resin 13-15 part is placed in pulverizer and is ground into powder, be then poured in boiler together with ACRYLIC EMULSION 11-13 part and be heated to 95 DEG C, be then poured in agitator kettle and urea-formaldehyde resin 13-15 part is fully dissolved, obtained mixed emulsion, for subsequent use;
7) by brown paste obtained for step 3) and step 2) obtained dark brown mixed powder is poured into after fully stirring in the obtained mixing liquid of step 4) and stirs, and obtains suspension liquid, for subsequent use;
8) be poured in mulser together with the mixed emulsion that ethylene glycol monobutyl ether solution step 5) obtained is obtained with step 6) and carry out emulsification 60 minutes, then the suspension liquid that step 7) is obtained is added, again carry out emulsification 30 minutes, obtain water-based UV vacuum plating paint of the present invention.
The invention has the beneficial effects as follows: make water-based UV vacuum plating paint have excellent gloss and antiblocking performance by being added with water-based gloss oil and being combined with ACRYLIC EMULSION, chemical stability, heat-resisting winter hardiness, weather resisteant, hydrophobic nature that silicone emulsion can make the acquisition of water-based UV vacuum plating paint excellent, be combined with 184 light triggers and urea-formaldehyde resin then can improve overall wear resistance and scratch resistance performance.
Embodiment
Embodiment 1:
A preparation method for water-based UV vacuum plating paint, comprises the raw material of following parts by weight proportioning: liquid photosensitive resin 30 parts, urea-formaldehyde resin 13 parts, water-based gloss oil 12 parts, aqueous polyethylene emulsion 7 parts, silicone grease 6 parts, ACRYLIC EMULSION 11 parts, silicone emulsion 3 parts, ethylene glycol monobutyl ether 3 parts, ethanol 11 parts, 184 light trigger 5 parts, refinery coke 2 parts, methacrylic acid-2-hydroxy methacrylate monomer 10 parts and diethylamine 2 parts.
A preparation method for water-based UV vacuum plating paint, comprises the following steps:
1) 184 light trigger 5 parts, refinery coke 2 parts, methacrylic acid-2-hydroxy methacrylate monomer 10 parts and diethylamine 2 parts are carried out mix and blend, for subsequent use;
2) be poured in resistance furnace by mixture obtained for step 1) and carry out pyrotic smelting 120 minutes, the black object of obtained caking, is then again poured into obtained caking black object in pulverizer and carries out pulverization process, obtained dark tan powder, for subsequent use;
3) rear obtained brown paste is stirred by being poured in vessel together with silicone grease 6 parts and silicon silicone emulsion 3 parts, for subsequent use;
4) liquid photosensitive resin 30 parts, water-based gloss oil 12 parts are poured in container together with aqueous polyethylene emulsion 7 parts, are heated to 60 DEG C, and constantly stir, until temperature is down to normal temperature, obtained mixing liquid, for subsequent use;
5) ethanol 11 parts is poured in reaction vessel, then slowly pours ethylene glycol monobutyl ether 3 parts into, pour in process and constantly stir, until dissolve completely to ethylene glycol monobutyl ether 3 parts, obtained ethylene glycol monobutyl ether solution, for subsequent use;
6) urea-formaldehyde resin 13 parts is placed in pulverizer and is ground into powder, be then poured in boiler together with ACRYLIC EMULSION 11 parts and be heated to 95 DEG C, be then poured in agitator kettle and urea-formaldehyde resin 13 parts is fully dissolved, obtained mixed emulsion, for subsequent use;
7) by brown paste obtained for step 3) and step 2) obtained dark brown mixed powder is poured into after fully stirring in the obtained mixing liquid of step 4) and stirs, and obtains suspension liquid, for subsequent use;
8) be poured in mulser together with the mixed emulsion that ethylene glycol monobutyl ether solution step 5) obtained is obtained with step 6) and carry out emulsification 60 minutes, then the suspension liquid that step 7) is obtained is added, again carry out emulsification 30 minutes, obtain water-based UV vacuum plating paint of the present invention.
Embodiment 2:
A kind of water-based UV vacuum plating paint and preparation method thereof, comprises the raw material of following parts by weight proportioning: liquid photosensitive resin 33 parts, urea-formaldehyde resin 15 parts, water-based gloss oil 14 parts, aqueous polyethylene emulsion 9 parts, silicone grease 11 parts, ACRYLIC EMULSION 13 parts, silicone emulsion 6 parts, ethylene glycol monobutyl ether 8 parts, ethanol 3 parts, 184 light trigger 10 parts, refinery coke 4 parts, methacrylic acid-2-hydroxy methacrylate monomer 25 parts and diethylamine 4 parts.
A preparation method for water-based UV vacuum plating paint, comprises the following steps:
1) 184 light trigger 10 parts, refinery coke 4 parts, methacrylic acid-2-hydroxy methacrylate monomer 25 parts and diethylamine 4 parts are carried out mix and blend, for subsequent use;
2) be poured in resistance furnace by mixture obtained for step 1) and carry out pyrotic smelting 120 minutes, the black object of obtained caking, is then again poured into obtained caking black object in pulverizer and carries out pulverization process, obtained dark tan powder, for subsequent use;
3) rear obtained brown paste is stirred by being poured in vessel together with silicone grease 11 parts and silicon silicone emulsion 6 parts, for subsequent use;
4) liquid photosensitive resin 33 parts, water-based gloss oil 14 parts are poured in container together with aqueous polyethylene emulsion 9 parts, are heated to 60 DEG C, and constantly stir, until temperature is down to normal temperature, obtained mixing liquid, for subsequent use;
5) ethanol 13 parts is poured in reaction vessel, then slowly pours ethylene glycol monobutyl ether 8 parts into, pour in process and constantly stir, until dissolve completely to ethylene glycol monobutyl ether 8 parts, obtained ethylene glycol monobutyl ether solution, for subsequent use;
6) urea-formaldehyde resin 15 parts is placed in pulverizer and is ground into powder, be then poured in boiler together with ACRYLIC EMULSION 13 parts and be heated to 95 DEG C, be then poured in agitator kettle and urea-formaldehyde resin 15 parts is fully dissolved, obtained mixed emulsion, for subsequent use;
7) by brown paste obtained for step 3) and step 2) obtained dark brown mixed powder is poured into after fully stirring in the obtained mixing liquid of step 4) and stirs, and obtains suspension liquid, for subsequent use;
8) be poured in mulser together with the mixed emulsion that ethylene glycol monobutyl ether solution step 5) obtained is obtained with step 6) and carry out emulsification 60 minutes, then the suspension liquid that step 7) is obtained is added, again carry out emulsification 30 minutes, obtain water-based UV vacuum plating paint of the present invention.
Embodiment 3:
A kind of water-based UV vacuum plating paint and preparation method thereof, comprises the raw material of following parts by weight proportioning: liquid photosensitive resin 32 parts, urea-formaldehyde resin 14 parts, water-based gloss oil 13 parts, aqueous polyethylene emulsion 8 parts, silicone grease 9 parts, ACRYLIC EMULSION 12 parts, silicone emulsion 5 parts, ethylene glycol monobutyl ether 6 parts, ethanol 12 parts, 184 light trigger 7 parts, refinery coke 3 parts, methacrylic acid-2-hydroxy methacrylate monomer 15 parts and diethylamine 3 parts.
A preparation method for water-based UV vacuum plating paint, comprises the following steps:
1) 184 light trigger 7 parts, refinery coke 3 parts, methacrylic acid-2-hydroxy methacrylate monomer 15 parts and diethylamine 3 parts are carried out mix and blend, for subsequent use;
2) be poured in resistance furnace by mixture obtained for step 1) and carry out pyrotic smelting 120 minutes, the black object of obtained caking, is then again poured into obtained caking black object in pulverizer and carries out pulverization process, obtained dark tan powder, for subsequent use;
3) rear obtained brown paste is stirred by being poured in vessel together with silicone grease 9 parts and silicon silicone emulsion 5 parts, for subsequent use;
4) liquid photosensitive resin 32 parts, water-based gloss oil 13 parts are poured in container together with aqueous polyethylene emulsion 8 parts, are heated to 60 DEG C, and constantly stir, until temperature is down to normal temperature, obtained mixing liquid, for subsequent use;
5) ethanol 12 parts is poured in reaction vessel, then slowly pours ethylene glycol monobutyl ether 6 parts into, pour in process and constantly stir, until dissolve completely to ethylene glycol monobutyl ether 6 parts, obtained ethylene glycol monobutyl ether solution, for subsequent use;
6) urea-formaldehyde resin 13-15 part is placed in pulverizer and is ground into powder, be then poured in boiler together with ACRYLIC EMULSION 12 parts and be heated to 95 DEG C, be then poured in agitator kettle and urea-formaldehyde resin 14 parts is fully dissolved, obtained mixed emulsion, for subsequent use;
7) by brown paste obtained for step 3) and step 2) obtained dark brown mixed powder is poured into after fully stirring in the obtained mixing liquid of step 4) and stirs, and obtains suspension liquid, for subsequent use;
8) be poured in mulser together with the mixed emulsion that ethylene glycol monobutyl ether solution step 5) obtained is obtained with step 6) and carry out emulsification 60 minutes, then the suspension liquid that step 7) is obtained is added, again carry out emulsification 30 minutes, obtain water-based UV vacuum plating paint of the present invention.
Experimental example:
Experimental subjects: 120 pieces of metal sheets, random approach is divided into 3 groups: control group one, control group two and experimental group, often organizes 40 pieces.
Test method: control group one uses water-based UV vacuum plating paint high-end on the market, control group two uses water-based UV vacuum plating paint general on the market, experimental group uses water-based UV vacuum plating paint of the present invention, and control group one, control group two and experimental group all carry out same wear resisting property test, anti-scratch performance test, acid-proof alkaline test and weather resistance test.
Judging criterion:
Unusual effect: after making use UV vacuum plating paint, wear resisting property, antifraying property, anti-scratch performance significantly promote, and stable chemical nature is good, weathering excellent performance.
Effective: after making use UV vacuum plating paint, wear resisting property, antifraying property obviously promote, but easily by acid and alkali corrosion, weather resistance is general.
Invalid: after making use UV vacuum plating paint, integration capability promotes very micro-, and easily comes off.
The wear resisting property test of the metal sheet of 3 groups, anti-scratch performance test, acid-proof alkaline test and weather resistance test effectiveness comparison, the results are shown in following table:
Group | Unusual effect | Effectively | Invalid | Efficient |
Control group one | 11 | 14 | 15 | 62.5% |
Control group two | 8 | 10 | 22 | 45% |
Experimental group | 30 | 3 | 7 | 82.5% |
The invention has the beneficial effects as follows: make water-based UV vacuum plating paint have excellent gloss and antiblocking performance by being added with water-based gloss oil and being combined with ACRYLIC EMULSION, silicone emulsion can make water-based UV vacuum plating paint obtain excellent chemical stability, heat-resisting winter hardiness, weather resisteant, hydrophobic nature, is combined with urea-formaldehyde resin and then can improves overall wear resistance and scratch resistance performance.
Typical case:
Lee, a vacuum plating factory has been offered in Guangzhou, Lee due to company newly formed, assets deficiency, so Lee has just chosen water-based UV vacuum plating paint general on the market, the business of Lee having got well gradually, but the problem with regard to plated film is often subject to the complaint of client, so Lee just determines the water-based UV vacuum plating paint choosing other high-qualitys, but but be not still settled properly with regard to the quality problems of plated film, but after Lee employs water-based UV vacuum plating paint of the present invention, the complaint that Lee receives decreasing gradually, but also obtain the praise of client.
The above, be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any change of expecting without creative work or replacement, all should be encompassed in protection scope of the present invention.
Claims (5)
1. water-based UV vacuum plating paint and preparation method thereof, it is characterized in that, comprise the raw material of following parts by weight proportioning: liquid photosensitive resin 30-33 part, urea-formaldehyde resin 13-15 part, water-based gloss oil 12-14 part, aqueous polyethylene emulsion 7-9 part, silicone grease 6-11 part, ACRYLIC EMULSION 11-13 part, silicone emulsion 3-6 part, ethylene glycol monobutyl ether 3-8 part, ethanol 11-13 part, 184 light trigger 5-10 parts, refinery coke 2-4 part, methacrylic acid-2-hydroxy methacrylate monomer 10-25 part and diethylamine 2-4 part.
2. a kind of water-based UV vacuum plating paint as claimed in claim 1 and preparation method thereof, it is characterized in that, comprise the raw material of following parts by weight proportioning: liquid photosensitive resin 30 parts, urea-formaldehyde resin 13 parts, water-based gloss oil 12 parts, aqueous polyethylene emulsion 7 parts, silicone grease 6 parts, ACRYLIC EMULSION 11 parts, silicone emulsion 3 parts, ethylene glycol monobutyl ether 3 parts, ethanol 11 parts, 184 light trigger 5 parts, refinery coke 2 parts, methacrylic acid-2-hydroxy methacrylate monomer 10 parts and diethylamine 2 parts.
3. a kind of water-based UV vacuum plating paint as claimed in claim 1 and preparation method thereof, it is characterized in that, comprise the raw material of following parts by weight proportioning: liquid photosensitive resin 33 parts, urea-formaldehyde resin 15 parts, water-based gloss oil 14 parts, aqueous polyethylene emulsion 9 parts, silicone grease 11 parts, ACRYLIC EMULSION 13 parts, silicone emulsion 6 parts, ethylene glycol monobutyl ether 8 parts, ethanol 3 parts, 184 light trigger 10 parts, refinery coke 4 parts, methacrylic acid-2-hydroxy methacrylate monomer 25 parts and diethylamine 4 parts.
4. a kind of water-based UV vacuum plating paint as claimed in claim 1 and preparation method thereof, it is characterized in that, comprise the raw material of following parts by weight proportioning: liquid photosensitive resin 32 parts, urea-formaldehyde resin 14 parts, water-based gloss oil 13 parts, aqueous polyethylene emulsion 8 parts, silicone grease 9 parts, ACRYLIC EMULSION 12 parts, silicone emulsion 5 parts, ethylene glycol monobutyl ether 6 parts, ethanol 12 parts, 184 light trigger 7 parts, refinery coke 3 parts, methacrylic acid-2-hydroxy methacrylate monomer 15 parts and diethylamine 3 parts.
5. a preparation method for water-based UV vacuum plating paint, is characterized in that, comprises the following steps:
1) 184 light trigger 5-10 parts, refinery coke 2-4 part, methacrylic acid-2-hydroxy methacrylate monomer 10-25 part and diethylamine 2-4 part are carried out mix and blend, for subsequent use;
2) be poured in resistance furnace by mixture obtained for step 1) and carry out pyrotic smelting 120 minutes, the black object of obtained caking, is then again poured into obtained caking black object in pulverizer and carries out pulverization process, obtained dark tan powder, for subsequent use;
3) silicone grease 6-11 part is poured in vessel together with silicon silicone emulsion 3-6 part stirs rear obtained brown paste, for subsequent use;
4) liquid photosensitive resin 30-33 part, water-based gloss oil 12-14 part are poured in container together with aqueous polyethylene emulsion 7-9 part, are heated to 60 DEG C, and constantly stir, until temperature is down to normal temperature, obtained mixing liquid, for subsequent use;
5) ethanol 11-13 part is poured in reaction vessel, then slowly pours ethylene glycol monobutyl ether 3-8 part into, pour in process and constantly stir, until dissolve completely to ethylene glycol monobutyl ether 3-8 part, obtained ethylene glycol monobutyl ether solution, for subsequent use;
6) urea-formaldehyde resin 13-15 part is placed in pulverizer and is ground into powder, be then poured in boiler together with ACRYLIC EMULSION 11-13 part and be heated to 95 DEG C, be then poured in agitator kettle and urea-formaldehyde resin 13-15 part is fully dissolved, obtained mixed emulsion, for subsequent use;
7) by brown paste obtained for step 3) and step 2) obtained dark brown mixed powder is poured into after fully stirring in the obtained mixing liquid of step 4) and stirs, and obtains suspension liquid, for subsequent use;
8) be poured in mulser together with the mixed emulsion that ethylene glycol monobutyl ether solution step 5) obtained is obtained with step 6) and carry out emulsification 60 minutes, then the suspension liquid that step 7) is obtained is added, again carry out emulsification 30 minutes, obtain water-based UV vacuum plating paint of the present invention.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510648147.6A CN105273632B (en) | 2015-10-09 | 2015-10-09 | A kind of water-based UV vacuum coatings paint and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510648147.6A CN105273632B (en) | 2015-10-09 | 2015-10-09 | A kind of water-based UV vacuum coatings paint and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105273632A true CN105273632A (en) | 2016-01-27 |
CN105273632B CN105273632B (en) | 2017-12-26 |
Family
ID=55143492
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510648147.6A Expired - Fee Related CN105273632B (en) | 2015-10-09 | 2015-10-09 | A kind of water-based UV vacuum coatings paint and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105273632B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106543784A (en) * | 2016-11-25 | 2017-03-29 | 江苏环宇纺织科技有限公司 | A kind of preparation method of the high surely Waterproof gum of high rapidity |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030022985A1 (en) * | 2000-01-15 | 2003-01-30 | Ulrike Rockrath | Pseudoplastic powdered lacquer slurry free of organic solvents method for production and the use thereof |
CN101157808A (en) * | 2007-11-01 | 2008-04-09 | 凌云剑 | Highly wearable vacuum coating ultraviolet curing coatings |
EP1942162A1 (en) * | 2006-12-29 | 2008-07-09 | Eternal Chemical Co., Ltd. | Anti-UV coating composition and the use thereof |
CN101787240A (en) * | 2009-01-23 | 2010-07-28 | 东莞市至诚涂料有限公司 | Top-coated coating of water-based UV-light curing vacuum coating |
CN102108252A (en) * | 2011-03-09 | 2011-06-29 | 上虞市佑谦特种材料有限公司 | Waterborne vacuum film-coated finish paint |
CN102107548A (en) * | 2010-07-30 | 2011-06-29 | 张锦碧 | 9000UV vacuum coating paint |
-
2015
- 2015-10-09 CN CN201510648147.6A patent/CN105273632B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030022985A1 (en) * | 2000-01-15 | 2003-01-30 | Ulrike Rockrath | Pseudoplastic powdered lacquer slurry free of organic solvents method for production and the use thereof |
EP1942162A1 (en) * | 2006-12-29 | 2008-07-09 | Eternal Chemical Co., Ltd. | Anti-UV coating composition and the use thereof |
CN101157808A (en) * | 2007-11-01 | 2008-04-09 | 凌云剑 | Highly wearable vacuum coating ultraviolet curing coatings |
CN101787240A (en) * | 2009-01-23 | 2010-07-28 | 东莞市至诚涂料有限公司 | Top-coated coating of water-based UV-light curing vacuum coating |
CN102107548A (en) * | 2010-07-30 | 2011-06-29 | 张锦碧 | 9000UV vacuum coating paint |
CN102108252A (en) * | 2011-03-09 | 2011-06-29 | 上虞市佑谦特种材料有限公司 | Waterborne vacuum film-coated finish paint |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106543784A (en) * | 2016-11-25 | 2017-03-29 | 江苏环宇纺织科技有限公司 | A kind of preparation method of the high surely Waterproof gum of high rapidity |
Also Published As
Publication number | Publication date |
---|---|
CN105273632B (en) | 2017-12-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101457005B (en) | Method for preparing hydroxyl acrylic acid water dispersoid | |
TWI428403B (en) | Pigment dispersants, their production process, and their use | |
CN101935425B (en) | Modified polyurethane (PU) acrylic resin and preparation method thereof | |
CN101775109B (en) | Epoxy modified silicon-contained waterborne acrylic resin and coating thereof | |
CN104356320B (en) | Waterborne epoxy ester-acrylic hybrid resin and preparation method thereof | |
CN102827325B (en) | Preparation method and application of core-shell polyurethane/acrylic acid composite emulsion | |
CN102617771A (en) | Aqueous printing ink binding agent and ink as well as preparation methods thereof | |
CN103725146A (en) | Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed | |
CN113308180B (en) | Bi-component water-based hydroxyl acrylic polyurethane finish emulsion and preparation method thereof | |
CN100473670C (en) | Alcohol water-soluble resin and method for making the same | |
CN101412781A (en) | Hydroxy acrylic ester emulsion containing phosphoester group | |
CN103773151A (en) | High temperature resistance acid-proof alkali-proof coating | |
CN106349899A (en) | Waterborne automotive axle paint and preparation method thereof | |
CN104072665B (en) | Water-based paint compositions and preparation method thereof | |
CN105199049B (en) | A kind of hydroxyl acrylic emulsion with core shell structure and preparation method thereof | |
CN101412864B (en) | Self-drying glass ink and preparation thereof | |
CN105837757B (en) | Microgel aqueous acrylic acid shell-core resin emulsion and preparation method thereof | |
CN105273632A (en) | Water-based UV vacuum coating paint and preparation method thereof | |
CN102492100B (en) | Water-dispersed fluorine-containing hydroxyl acrylic-epoxy ester heterozygous body resin and coating thereof | |
CN107325217B (en) | Method for preparing water-based solid styrene-acrylic resin | |
CN104017457B (en) | Coating composition containing modified tung oil and preparation method thereof | |
CN111116831A (en) | Preparation method of hydroxyl acrylic emulsion | |
CN103725086A (en) | High-performance water-based golden ink for gravure printing and preparation method thereof | |
CN107573738A (en) | A kind of aqueous glass acrylic resin and preparation method thereof | |
CN102010559B (en) | Carboxylic acid-modified acrylic polymer solid composition and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171226 Termination date: 20181009 |