CN103756549A - Preparation method of UV (Ultraviolet) gloss paint for coating glass fiber reinforced plastic surface - Google Patents

Preparation method of UV (Ultraviolet) gloss paint for coating glass fiber reinforced plastic surface Download PDF

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CN103756549A
CN103756549A CN201410000802.2A CN201410000802A CN103756549A CN 103756549 A CN103756549 A CN 103756549A CN 201410000802 A CN201410000802 A CN 201410000802A CN 103756549 A CN103756549 A CN 103756549A
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parts
uv
surface
uv varnish
coated
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CN103756549B (en
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魏风军
贾秋丽
田艳丽
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河南科技大学
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Abstract

The invention relates to a preparation method of a UV (Ultraviolet) gloss paint for coating a glass fiber reinforced plastic surface. The preparation method comprises the concrete steps: respectively weighing nanometer silicon dioxide powder, nanometer aluminum oxide powder and absolute ethyl alcohol according to the weight part ratio of 1:1:10, and dispersing the nanometer silicon dioxide powder and the nanometer aluminum oxide powder into the absolute ethyl alcohol in a ball milling dispersion way to obtain slurry; adding 30-50 parts by weight of urethane acrylate and 10-20 parts by weight of epoxy acrylate into 2-5 parts of slurry, uniformly mixing, and then, adding 45-80 parts of reactive diluent, 12-20 parts of absolute ethyl alcohol, 0.2-1 part of defoaming agent and 0.2-1 part of flatting agent into the obtained mixture; and then, uniformly stirring and mixing to obtain the UV gloss paint for coating the glass fiber reinforced plastic surface. The preparation method is simple in preparation process and low in cost; and the prepared UV gloss paint is high in solid content, relatively good in glossiness, high in adhesive powder, good in self-cleaning effect and suitable for the field of glass fiber reinforced plastic surface protection and can be applied to the large-scale glossing.

Description

一种玻璃钢表面涂覆用的UV光油的制备方法 UV varnish coated with a preparation of the surface of FRP

技术领域 FIELD

[0001] 本发明涉及一种UV光油,具体的说是一种玻璃钢表面涂覆用的UV光油的制备方法。 [0001] The present invention relates to a UV varnish, specifically to the method for producing a steel surface coated with a glass of the UV varnish.

背景技术 Background technique

[0002] 现在玻璃钢生产出来后,玻璃钢的表面质量如耐候性、耐磨性差及硬度低等仍是影响玻璃钢制品进一步推广应用的因素。 [0002] Now the FRP produced, the surface quality of FRP such as weather resistance, low hardness and poor wear resistance of glass products is still further application of the influence factors. 尤其目前在一些特殊应用环境中要求玻璃钢的表面具有某些特殊的功能;外壳、容器、盖类、贴面板等对衷面质量要求高。 In particular, the steel surface of the glass present in some special application environments require some special features; high housing, a container, a cover type, etc. on the plywood surface co quality. 市场迫切需求外观好、性能价格比高的高性能玻璃钢制品及研发工艺简便,性能可靠的玻璃钢表面防护技术,以提高玻璃钢制品对其他材料的竞争力,是目前较紧迫的一个课题。 Easy urgent needs of the market good appearance, high performance and low cost, high-performance glass fiber reinforced plastic products and research and development technology, reliable performance fiberglass surface protection technology, to enhance the competitiveness of glass products to other materials, is more of a pressing issue.

发明内容 SUMMARY

[0003] 本发明目的是为解决上述技术问题的不足,提供一种玻璃钢表面涂覆用的UV光油的制备方法,制备工艺简单,所制备的UV光油固含量高,涂覆到玻璃钢表面具有较好的光泽度、抗黄变性、高附着力、自洁净,耐磨性好,耐划伤,干燥速度快等优点。 [0003] The object of the present invention to solve the above technical problem is insufficient, the UV varnish coated surface to provide a method for preparing a glass fiber reinforced plastic, the preparation process is simple, high solids content of the UV varnish is prepared, applied to the surface of the FRP It has good gloss, yellowing resistance, high adhesion, self-cleaning, abrasion resistance, scratch resistance, and fast drying and the like.

[0004] 本发明为解决上述技术问题所采用的技术方案是:一种玻璃钢表面涂覆用的UV光油的制备方法,其具体制备步骤为: [0004] Technical Solution The present invention to solve the above technical problem is: UV varnished surface coated with a preparation of FRP, specific preparation steps of:

步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; A step to prepare a slurry: 1: 1: 10 by weight ratio were taken nano silica powder, alumina powder and the nano ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner of anhydrous ethanol to give a slurry;

步骤二、按照重量份数,在2-5份浆料中添加30-50份聚氨酯丙烯酸酯和10-20份环氧丙烯酸酯,混合均匀后,在所得混合`物中,加入45-80份活性稀释剂、12-20份无水乙醇、 Step two, according to weight, adding 30-50 parts 10-20 parts of urethane acrylate and epoxy acrylate in 2-5 parts of the slurry, after mixing, the resulting mixture was' added 45-80 parts reactive diluents, 12-20 parts ethanol,

0.2-1份消泡剂和0.2-1份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; 0.2 parts of a defoaming agent and a leveling agent 0.2-1 parts, by stirring and mixing uniformly, i.e. the surface is coated with a UV varnish fiberglass;

所述的活性稀释剂为20-30份三羟甲基丙烷三丙烯酸酯、20-40份1,6_己二醇二丙烯酸酯和5-10份1-羟基环已基苯基酮的混合物。 The reactive diluent is 20 to 30 parts trimethylol propane triacrylate, and a mixture of 1-hydroxycyclohexyl phenyl ketone 1,6_ 5-10 parts 20-40 parts hexanediol diacrylate .

[0005] 所述的纳米二氧化硅粉末的颗粒粒径,优选为10-60nm; [0005] The particle size of nano silica powder, preferably 10-60 nm;

所述的消泡剂为有机硅消泡剂; The defoamer is a silicone defoamer;

所述的流平剂为有机硅流平剂。 The leveling agent is a silicone leveling agent.

[0006] 所制备的UV光油在玻璃钢表面制备防护层的方法为:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 [0006] UV varnish prepared in the process of preparing the surface of the protective layer is fiberglass: roller coating the UV varnish coated steel surface and leveling the glass and the UV cured varnish coating is irradiated with UV light, thereby forming a protective layer on the surface of FRP.

[0007] 有益效果 [0007] beneficial effects

1、本发明玻璃钢表面涂覆用的UV光油的制备方法,制备工艺简单,缩短了制造时间,成本低,采用纳米二氧化硅粉末、纳米二氧化铝粉末经无水乙醇球磨分散后与其他组分进行混合制备光油,避免了制备过程中所造成的环境污染。 1, UV varnish coated surface of the FRP production method of the present invention is used, the preparation process is simple, shortens the manufacturing time, low cost, nano silica powder, nano-alumina powder by milling a dispersion of absolute ethanol after the other Varnish prepared by mixing the components, to avoid environmental pollution caused by the manufacturing process. [0008] 2、本发明所制备的玻璃钢表面涂覆用的UV光油可以应用于大面积上光,适用于玻璃钢表面防护领域,具有高的附着力,自洁净效果;使用时,通过辊涂上光流平然后再经过紫外光照射快速固化,适用于玻璃钢表面的涂覆、可有效遮盖玻璃钢表面缺陷;本发明所制备的玻璃钢表面涂覆用的UV光油,固含量高,具有比较好的光泽度、抗黄变性、高附着力、自洁净,耐磨性好,耐划伤,干燥速度快,缩短了制造时间,减少了生产工序,生产成本低廉ο [0008] 2, coating the surface of the FRP of the present invention prepared with a UV varnish coating may be applied to a large area, it is suitable for surface protection field of fiberglass, with high adhesion, self-cleaning effect; use, light coated by a roll leveling and then irradiated with ultraviolet light through fast curing coating for steel surface of the glass, the glass can effectively cover the surface defects of steel; FRP surface coating of the present invention prepared with a UV varnish, high solid content, having good gloss degree, yellowing resistance, high adhesion, self-cleaning, abrasion resistance, scratch resistance, fast drying, shortens the manufacturing time and reducing production processes, production cost is low ο

具体实施方式 Detailed ways

[0009] 一种玻璃钢表面涂覆用的UV光油的制备方法,其具体制备步骤为: [0009] UV varnish method for producing a steel surface coated with glass, the specific preparation steps of:

步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; A step to prepare a slurry: 1: 1: 10 by weight ratio were taken nano silica powder, alumina powder and the nano ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner of anhydrous ethanol to give a slurry;

步骤二、按照重量份数,在2-5份浆料中添加30-50份聚氨酯丙烯酸酯和10-20份环氧丙烯酸酯,混合均匀后,在所得混合物中,加入45-80份活性稀释剂、12-20份无水乙醇、 Step two, according to weight, adding 30-50 parts 10-20 parts of urethane acrylate and epoxy acrylate in 2-5 parts of the slurry, uniformly mixed in the resultant mixture, 45-80 parts of a reactive diluent is added agent, 12-20 parts ethanol,

0.2-1份消泡剂和0.2-1份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; 0.2 parts of a defoaming agent and a leveling agent 0.2-1 parts, by stirring and mixing uniformly, i.e. the surface is coated with a UV varnish fiberglass;

所述的活性稀释剂为20-30份三羟甲基丙烷三丙烯酸酯、20-40份1,6_己二醇二丙烯酸酯和5-10份1-羟基环已基苯基酮的混合物。 The reactive diluent is 20 to 30 parts trimethylol propane triacrylate, and a mixture of 1-hydroxycyclohexyl phenyl ketone 1,6_ 5-10 parts 20-40 parts hexanediol diacrylate .

[0010] 所述的纳米二氧化硅粉末的颗粒粒径,优选为10-60nm; [0010] The particle size of nano silica powder, preferably 10-60 nm;

所述的消泡剂为有机硅消泡剂; The defoamer is a silicone defoamer;

所述的流平剂为有机硅流平剂。 The leveling agent is a silicone leveling agent.

[0011] 所制备的UV光油在玻璃钢表面制备防护层的方法为:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 [0011] UV varnish prepared in the process of preparing the surface of the protective layer is fiberglass: roller coating the UV varnish coated steel surface and leveling the glass and the UV cured varnish coating is irradiated with UV light, thereby forming a protective layer on the surface of FRP.

[0012] 实施例1 [0012] Example 1

一种玻璃钢表面涂覆用的UV光油的制备方法,其具体制备步骤为: A method UV varnish prepared steel surface coated with glass, the specific preparation steps of:

步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; A step to prepare a slurry: 1: 1: 10 by weight ratio were taken nano silica powder, alumina powder and the nano ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner of anhydrous ethanol to give a slurry;

步骤二、按照重量份数,在2份浆料中添加30份聚氨酯丙烯酸酯和10份环氧丙烯酸酯,混合均匀后,在所得混合物中,加入45份活性稀释剂、12份无水乙醇、0.2份消泡剂和 Step two, according to weight, 2 parts of the slurry was added 30 parts of urethane acrylate and 10 parts of epoxy acrylate mixed uniformly, the resulting mixture was added 45 parts of a reactive diluent, 12 parts of ethanol, 0.2 parts of a defoamer and

0.2份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; 0.2 parts of a leveling agent, and then mixed by stirring, that is, the surface is coated with a UV varnish fiberglass;

所述的活性稀释剂为20份三羟甲基丙烷三丙烯酸酯、20份1,6_己二醇二丙烯酸酯和5份1-羟基环已基苯基酮的混合物。 The reactive diluent 20 parts trimethylol propane triacrylate, and a mixture of 1-hydroxycyclohexyl phenyl ketone 20 parts 1,6_ 5 parts hexanediol diacrylate.

[0013] 所述的纳米二氧化硅粉末的颗粒粒径为IOnm; [0013] The particle size of nano silica powder is IONM;

所述的消泡剂为有机硅消泡剂; The defoamer is a silicone defoamer;

所述的流平剂为有机硅流平剂。 The leveling agent is a silicone leveling agent.

[0014] 所制备的UV光油在玻璃钢表面制备防护层的方法为:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 [0014] UV varnish prepared in the process of preparing the surface of the protective layer is fiberglass: roller coating the UV varnish coated steel surface and leveling the glass and the UV cured varnish coating is irradiated with UV light, thereby forming a protective layer on the surface of FRP.

[0015] 实施例2 [0015] Example 2

一种玻璃钢表面涂覆用的UV光油的制备方法,其具体制备步骤为: A method UV varnish prepared steel surface coated with glass, the specific preparation steps of:

步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; A step to prepare a slurry: 1: 1: 10 by weight ratio were taken nano silica powder, alumina powder and the nano ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner of anhydrous ethanol to give a slurry;

步骤二、按照重量份数,在4份浆料中添加40份聚氨酯丙烯酸酯和15份环氧丙烯酸酯,混合均匀后,在所得混合物中,加入60份活性稀释剂、18份无水乙醇、0.5份消泡剂和 Step two, according to parts by weight, the slurry is added 4 parts 40 parts 15 parts of urethane acrylate and epoxy acrylate mixed uniformly, the resulting mixture was added 60 parts of a reactive diluent, 18 parts of ethanol, 0.5 parts of a defoamer and

0.5份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; 0.5 parts of a leveling agent, and then mixed by stirring, that is, the surface is coated with a UV varnish fiberglass;

所述的活性稀释剂为25份三羟甲基丙烷三丙烯酸酯、25份1,6_己二醇二丙烯酸酯和5-10份1-羟基环已基苯基酮的混合物。 The reactive diluent 25 parts trimethylol propane triacrylate, and a mixture of 1-hydroxycyclohexyl phenyl ketone 25 parts 1,6_ 5-10 parts hexanediol diacrylate.

[0016] 所述的纳米二氧化硅粉末的颗粒粒径,优选50nm ; [0016] The particle size of nano silica powder, preferably 50 nm;

所述的消泡剂为有机硅消泡剂; The defoamer is a silicone defoamer;

所述的流平剂为有机硅流平剂。 The leveling agent is a silicone leveling agent.

[0017] 所制备的UV光油在玻璃钢表面制备防护层的方法为:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 [0017] UV varnish prepared in the process of preparing the surface of the protective layer is fiberglass: roller coating the UV varnish coated steel surface and leveling the glass and the UV cured varnish coating is irradiated with UV light, thereby forming a protective layer on the surface of FRP.

[0018] 实施例3 [0018] Example 3

一种玻璃钢表面涂覆用的UV光油的制备方法,其具体制备步骤为: A method UV varnish prepared steel surface coated with glass, the specific preparation steps of:

步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; A step to prepare a slurry: 1: 1: 10 by weight ratio were taken nano silica powder, alumina powder and the nano ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner of anhydrous ethanol to give a slurry;

步骤二、按照重量份数,在5份浆料中添加50份聚氨酯丙烯酸酯和20份环氧丙烯酸酯,混合均匀后,在所得混合物中,加入80份活性稀释剂、20份无水乙醇、1份消泡剂和1份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; Step two, according to parts by weight, the slurry was added 5 parts 50 parts 20 parts of urethane acrylate and epoxy acrylate mixed uniformly, the resulting mixture was added 80 parts of a reactive diluent, 20 parts of ethanol, 1 parts of a defoamer and 1 part of a leveling agent, and then mixed by stirring, that is, the surface is coated with a UV varnish fiberglass;

所述的活性稀释剂为30份三羟甲基丙烷三丙烯酸酯、40份1,6_己二醇二丙烯酸酯和10份1-羟基环已基苯基酮的混合物。 The reactive diluent 30 parts trimethylol propane triacrylate, and a mixture of 1-hydroxycyclohexyl phenyl ketone 10 parts 40 parts of hexanediol diacrylate 1,6_.

[0019] 所述的纳米二氧化硅粉末的颗粒粒径60nm ; [0019] The nano particle size of 60 nm silica powder;

所述的消泡剂为有机硅消泡剂; The defoamer is a silicone defoamer;

所述的流平剂为有机硅流平剂。 The leveling agent is a silicone leveling agent.

[0020] 所制备的UV光油在玻璃钢表面制备防护层的方法为:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 [0020] UV varnish prepared in the process of preparing the surface of the protective layer is fiberglass: roller coating the UV varnish coated steel surface and leveling the glass and the UV cured varnish coating is irradiated with UV light, thereby forming a protective layer on the surface of FRP.

[0021] 本发明所述的制备玻璃钢表面涂覆用的UV光油所需原料均为市售商品,可通过市场购买得到。 [0021] Preparation of the surface of the FRP of the present invention is coated with a UV varnish raw materials required are commercially available, may be obtained by purchase market.

Claims (5)

1.一种玻璃钢表面涂覆用的UV光油的制备方法,其特征在于:其具体制备步骤为: 步骤一、制备浆料:按1:1:10的重量份数比分别取纳米二氧化硅粉末、纳米氧化铝粉末和无水乙醇,将纳米二氧化硅粉末和纳米氧化铝粉末,以球磨分散的方式分散到无水乙醇中,得到浆料; 步骤二、按照重量份数,在2-5份浆料中添加30-50份聚氨酯丙烯酸酯和10-20份环氧丙烯酸酯,混合均匀后,在所得混合物中,加入45-80份活性稀释剂、12-20份无水乙醇、0.2-1份消泡剂和0.2-1份流平剂,然后通过搅拌混合均匀后,即为玻璃钢表面涂覆用的UV光油; 所述的活性稀释剂为20-30份三羟甲基丙烷三丙烯酸酯、20-40份1,6_己二醇二丙烯酸酯和5-10份1-羟基环已基苯基酮的混合物。 A UV varnish prepared steel surface coated with a glass, characterized in that: the specific preparation steps of: a step to prepare a slurry: 1: 1: 10 by weight ratio, respectively Dioxide Nano - silicon powder, alumina powder and nano-ethanol, nano silica powder and the nano-alumina powder to ball milling dispersion dispersed manner into absolute ethanol to give a slurry; step two, according to weight, 2 the slurry was added 5 parts 30-50 parts 10-20 parts of urethane acrylate and epoxy acrylate, uniformly mixed in the resultant mixture, 45-80 parts of reactive diluents, 12-20 parts ethanol, 0.2 parts of a defoaming agent and a leveling agent 0.2 parts, and then uniformly mixed by stirring, that is, the surface is coated with a UV varnish fiberglass; said reactive diluent is trimethylolpropane 20-30 parts propane triacrylate, and 1-hydroxycyclohexyl phenyl ketone in a mixture of 20-40 parts by 1,6_ 5-10 parts hexanediol diacrylate.
2.如权利要求1所述的一种玻璃钢表面涂覆用的UV光油的制备方法,其特征在于:所述的纳米二氧化硅粉末的颗粒粒径为10-60nm。 2. A glass as claimed in claim 1 coated steel surface preparation method with UV varnish, characterized in that: the nano-particle size silica powder is 10-60nm.
3.如权利要求1所述的一种玻璃钢表面涂覆用的UV光油的制备方法,其特征在于:所述的消泡剂为有机硅消泡剂。 The method of preparing a UV varnish coated surface of FRP as claimed in claim 1 with, wherein: said defoamer is a silicone defoamer.
4.如权利要求1所述的一种玻璃钢表面涂覆用的UV光油的制备方法,其特征在于:所述的流平剂为有机硅流平剂。 4. A method for preparing a steel surface coated with a glass of the UV varnish as claimed in claim 1, wherein: the leveling agent is a silicone leveling agent.
5.用权利要求1所制备的UV光油在玻璃钢表面制备防护层的方法,其特征在于:用涂布辊将所述UV光油涂在玻璃钢表面并流平,然后用紫外光照射使UV光油涂层固化,从而在玻璃钢表面形成防护层。 A UV varnish prepared according to claim 5. In the method of preparing the surface of the protective layer of fiberglass, wherein: the coating roll UV varnish coated steel surface and leveling the glass, then irradiated with UV light UV Varnish coating is cured to form a protective layer on the steel surface of the glass. ` `
CN201410000802.2A 2014-01-02 2014-01-02 uv varnish surface coated with a preparation of FRP CN103756549B (en)

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