CN101696332B - Ultra-violet curing transfer ink - Google Patents

Ultra-violet curing transfer ink Download PDF

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CN101696332B
CN101696332B CN 200910186408 CN200910186408A CN101696332B CN 101696332 B CN101696332 B CN 101696332B CN 200910186408 CN200910186408 CN 200910186408 CN 200910186408 A CN200910186408 A CN 200910186408A CN 101696332 B CN101696332 B CN 101696332B
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acrylate
resin
ink
percent
transfer ink
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CN 200910186408
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CN101696332A (en
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傅炳炎
段利刚
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东周化学工业(昆山)有限公司
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Abstract

The invention relates to ultra-violet curing transfer ink, which comprises the following components in percentage by weight: 30 to 50 percent of resin, 5 to 15 percent of adhesion promoting resin, 20 to 30 percent of acrylate compound monomer, 2 to 6 percent of polymer dispersant, 5 to 9 percent of photo-initiator and 13 to 16 percent of color concentrate, wherein the resin is epoxy acrylate, urethane acrylate or a mixture of the epoxy acrylate and the urethane acrylate in any proportion; the adhesion promoting resin is any hydroxyl acrylate with a viscosity of lower than 3,000cps at below 25DEG C; and the polymer dispersant is a dicarboxylic ester solution of a polymer of which the molecular weight is between 4,000 and 25,000 and the pigment compatible group is an amine group. The ultra-violet curing transfer ink can replace the conventional solvent type ink, and can be printed on floors, furniture, decorating plates, and the like so as to provide more clear and vivid patterns. Moreover, the ultra-violet curing transfer ink has the advantages of high curing speed, high production efficiency, plate production cost reduction, environmental protection, and the like.

Description

紫外光固化转印油墨 UV-curable ink transfer

技术领域 FIELD

[0001] 本发明涉及一种可印刷于地板、家具、装饰板等上的转印油墨。 [0001] The present invention relates to a printable transfer ink on the floor, furniture, decorative panels. 背景技术 Background technique

[0002] 现有技术中,转印油墨是具有特殊性质的染料为主制成的印在特制纸上的图案、 文字等,可以因加热使之转移到其他基材上去的油墨。 [0002] In the prior art, the transfer printing ink is a dye having specific properties in a special paper is made based patterns, characters and the like by heat can be transferred to other substrates make up the ink. 当前市面上用于地板、家具、装饰板印刷的主要有两种油墨:水性油墨和油性油墨。 The current market for flooring, furniture, decorative plates, there are two main printing ink: water-based ink and oil-based inks. 两者的主要区别在于溶剂的不同,水性油墨以水为溶剂;油性油墨以有机溶剂(甲苯、二甲苯、工业酒精等)为溶剂;二者固化原理基本相同。 The main difference is that different, the aqueous ink using water as a solvent, the solvent; oil-based ink in an organic solvent (toluene, xylene, industrial alcohol, etc.) as the solvent; curing both basically the same principle. 其中,水性油墨由于以水为溶剂,因而挥发速度慢,影响生产速度;而油性油墨由于有机溶剂的使用对人体有害,此外,这两种油墨都有耐溶剂性能差,耐化学性能差,耐候性能差等缺点。 Wherein the aqueous ink since the solvent is water, so the slow evaporation rate, affecting production speed; since the oil ink using an organic solvent harmful to human beings, in addition, the difference between these two inks are solvent resistance, poor chemical resistance, weatherability defects and poor performance. 且由于不是100%固含,若溶剂未能及时挥发,则油墨印刷于油墨膜上会流动、 粘连,而使印刷纹理变得模糊。 And since not 100% solid content, if the failure to volatilize the solvent, the printing ink may flow in the ink film, the adhesion, the printing texture blurred.

发明内容 SUMMARY

[0003] 本发明所要解决的技术问题是为了克服现有技术的不足,提供一种紫外光固化转印油墨。 [0003] The present invention solves the technical problem is to overcome the shortcomings of the prior art, there is provided a UV-curable ink transfer.

[0004] 为解决以上技术问题,本发明采取如下技术方案: [0004] To solve the above technical problem, the present invention adopts the following technical solutions:

[0005] 一种紫外光固化转印油墨,该油墨由如下重量百分含量的组分组成:树脂30%〜 50% ;附着力促进树脂5%〜15% ;丙烯酸酯类化合物单体20%〜30% ;高分子分散剂2%〜6% ;光引发剂5%〜9% ;色粉13%〜16%,其中所述树脂为环氧丙烯酸酯,聚氨酯丙烯酸酯或它们的任意比例的混合物,所述附着力促进树脂为25°C下粘度小于3000cps的任意羟基丙烯酸酯,所述高分子分散剂为分子量在4000〜25000之间、颜料亲合基团为胺类基团的聚合物的二羧酸酯溶液。 [0005] A UV-curable transfer ink, which is the percentage by weight of the following component composition: 30% to 50% of the resin; resin adhesion promoter 5% ~ 15%; 20% monomer acrylate compound ~ 30%; the polymer dispersant 2% ~ 6%; photoinitiator ~ 9% 5%; 13% ~ 16% of the toner, wherein the resin is an epoxy acrylate, urethane acrylate, or any ratio thereof the mixture of the adhesion promoter resin is any hydroxy acrylate 25 ° C for a viscosity of less than 3000cps, the polymer dispersant having a molecular weight between 4000~25000 pigment affinic groups to an amine group of the polymer dicarboxylic acid ester solution.

[0006] 根据本发明,所述的树脂优选为环氧丙烯酸酯与聚氨酯丙烯酸酯按质量比0.25〜0.5 : 1组成的混合物。 [0006] According to the present invention, the resin is preferably an epoxy acrylate and a urethane acrylate mass ratio of 0.25~0.5: 1 mixture thereof. 所述的丙烯酸酯类化合物单体为丙烯酸2-乙基己酯、二羟甲基丙烷二丙烯酸酯及三羟甲基丙烷三丙烯酸酯中的一种或多种的混合物。 The acrylic compound monomer is 2-ethylhexyl acrylate A dimethylol propane diacrylate and trimethylolpropane triacrylate or more thereof. 所述高分子分散剂中聚合物的质量百分含量为20%〜40%。 Mass percentage of the polymer dispersant in the polymer is 20% ~ 40%. 所述光引发剂为2-羟基-2-甲基苯基丙烷-I-酮、1-羟基环己基苯基丙酮、2-甲基-1-(4-甲硫基苯基)-2-吗啉基-1-丙酮及2, 4,6_三甲基苯甲酰基-二苯基氧化膦、噻吨酮中的一种或多种的混合物。 The photoinitiator is 2-hydroxy-2-methyl propane -I- phenyl ketone, 1-hydroxy cyclohexyl phenyl, 2-methyl-1- (4-methylthiophenyl) -2- morpholino-1-propanone and 2, 4,6_-trimethyl benzoyl - diphenyl phosphine oxide a thioxanthone or more thereof. 所述色粉可以为黄色颜料、红色颜料、黑色颜料及白色颜料中的一种或多种的混合物。 The toner may be a mixture of one or more of the yellow pigment, a red pigment, a black pigment and a white pigment is.

[0007] 由于采取以上技术方案,本发明与现有技术相比具有如下优点: [0007] As a result of the above technical solutions, the prior art and the present invention has the following advantages:

[0008] 本发明紫外光固化转印油墨可代替传统的溶剂型油墨印刷于地板、家具、装饰板等上提供更清晰和逼真的图案,具有固化速度快、生产效率高、降低板材生产成本及环保等优点。 [0008] UV-curable transfer ink of the present invention can replace the conventional solvent-based printing inks provide vivid patterns clearer and on the floor, furniture, decorative panels, etc., having a fast curing, high production efficiency, reduce production costs and plate environmental protection and other advantages.

具体实施方式 Detailed ways

3[0009] 组成本发明的各种原料物质可以从市场上直接购买,或通过现有技术的手段制备。 3 [0009] The composition of the present invention, various raw materials can be purchased directly from the market, or can be prepared by means of the prior art. 现结合具体的实施例对本发明做进一步详细的描述。 Now with reference to specific embodiments of the present invention will be further described in detail.

[0010] 实施例1 [0010] Example 1

[0011] 按照本实施例的紫外光固化转印油墨,组成见表1。 [0011] UV-curable transferring ink according to the present embodiment, the composition shown in Table 1.

[0012]表 1 [0012] TABLE 1

[0013] [0013]

Figure CN101696332BD00041

[0014] 本实施例的转印油墨可通过如下方法制备:首先将色粉、一部分树脂、一部分单体、分散剂搅拌均勻,经过三辊筒研磨分散后,将剩余单体、剩余树脂及光引发剂加入,搅拌20min以上即得。 [0014] transferring ink according to the present embodiment can be prepared by: first toner, part of the resin, part of the monomers, dispersants stir, after triple roll milling dispersion tube, the remaining monomers, the remaining resin and light initiator is added, with stirring over 20min to obtain.

[0015] 实施例2 [0015] Example 2

[0016] 按照本实施例的紫外光固化转印油墨,组成见表2。 [0016] UV-curable transferring ink according to the present embodiment, the composition shown in Table 2.

[0017]表 2 [0017] TABLE 2

[0018] [0018]

Figure CN101696332BD00051

[0019] 实施例3 [0019] Example 3

[0020] 按照本实施例的紫外光固化转印油墨,组成见表3。 [0020] UV-curable transferring ink according to the present embodiment, the composition shown in Table 3.

[0021]表 3 [0021] TABLE 3

[0022] [0022]

Figure CN101696332BD00052

[0023] [0023]

Figure CN101696332BD00061

[0024] 实施例4 [0024] Example 4

[0025] 按照本实施例的紫外光固化转印油墨,组成见表4。 [0025] UV-curable transferring ink according to the present embodiment, the composition shown in Table 4.

[0026] 表4 [0026] TABLE 4

[0027] [0027]

Figure CN101696332BD00062

[0028] 实施例5 [0028] Example 5

[0029] 按照本实施例的紫外光固化转印油墨,组成见表5。 [0029] UV-curable transferring ink according to the present embodiment, the composition shown in Table 5.

[0030] 表5 [0030] TABLE 5

[0031] [0031]

Figure CN101696332BD00071

[0032] 实施例6 [0032] Example 6

[0033] 按照本实施例的紫外光固化转印油墨,组成如下见表6。 [0033] According to the present UV curable ink transferred embodiment, the composition shown in Table 6 below.

[0034]表 6 [0034] TABLE 6

[0035] [0035]

Figure CN101696332BD00081

[0036] 对实施例1至6的油墨进行了物性测试,结果见表7。 [0036] The ink of Example 1-6 were conducted embodiment test results shown in Table 7.

[0037] 表7 [0037] TABLE 7

[0038] [0038]

Figure CN101696332BD00082

[0039] 以上对本发明做了详尽的描述,其目的在于让熟悉此领域技术的人士能够了解本发明的内容并加以实施,并不能以此限制本发明的保护范围,凡根据本发明的精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围内。 [0039] more than to do a detailed description of the present invention, the purpose is to allow familiar with skilled people who can understand the content of the present invention and implemented, and not in order to limit the scope of the present invention, where the spirit of the invention essence made equivalent variations or modifications shall fall within the scope of the present invention.

Claims (5)

1. 一种紫外光固化转印油墨,其特征在于:该油墨由如下重量百分含量的组分组成: 树脂30%〜50% ;附着力促进树脂5%〜15% ;丙烯酸酯类化合物单体20%〜30% ;高分子分散剂2%〜6% ;光引发剂5%〜9% ;色粉13%〜16%,其中所述树脂为环氧丙烯酸酯,聚氨酯丙烯酸酯或它们的任意比例的混合物,所述附着力促进树脂为25°C下粘度小于3000cps的任意羟基丙烯酸酯,所述高分子分散剂为分子量在4000〜25000之间、颜料亲合基团为胺类基团的聚合物的二羧酸酯溶液,所述高分子分散剂中聚合物的质量百分含量为20%〜40%。 A UV-curable transfer ink, characterized in that: the weight percentage of ink from the components of the following composition: resin 30% ~ 50%; 5% adhesion promoter ~ 15% resin; acrylate compound single 20% ~ 30%; the polymer dispersant 2% ~ 6%; photoinitiator ~ 9% 5%; 13% ~ 16% of the toner, wherein the resin is an epoxy acrylate, urethane acrylate or a mixtures in any proportion, the adhesion promoter resin is any hydroxy acrylate 25 ° C for a viscosity of less than 3000cps, the polymer dispersant having a molecular weight between 4000~25000 pigment affinic groups to an amine group dicarboxylate solution of the polymer, the mass percentage of the polymer dispersant in the polymer is 20% ~ 40%.
2.根据权利要求1所述的紫外光固化转印油墨,其特征在于:所述的树脂为环氧丙烯酸酯与聚氨酯丙烯酸酯按质量比0.25〜0.5 : 1组成的混合物。 The UV curable transfer ink to claim 1, wherein: a mixture consisting of: said resin is an epoxy acrylate and urethane acrylate mass ratio 0.25~0.5.
3.根据权利要求1所述的紫外光固化转印油墨,其特征在于:所述的丙烯酸酯类化合物单体为丙烯酸2-乙基己酯、二羟甲基丙烷二丙烯酸酯及三羟甲基丙烷三丙烯酸酯中的一种或多种的混合物。 The UV curable ink transfer according to claim 1, wherein: the acrylate-based compound monomer is 2-ethylhexyl acrylate, dimethylol propane diacrylate and trimethylol a substrate propane triacrylate or more thereof.
4.根据权利要求1所述的紫外光固化转印油墨,其特征在于:所述光引发剂为2-羟基-2-甲基苯基丙烷-1-酮、1-羟基环己基苯基丙酮、2-甲基-1- (4-甲硫基苯基)-2-吗啉基-1-丙酮及2,4,6_三甲基苯甲酰基-二苯基氧化膦、噻吨酮中的一种或多种的混合物。 According to claim UV curable ink transferred to claim 1, wherein: said photoinitiator is 2-hydroxy-2-methyl-phenylpropane-1-one, 1-hydroxy cyclohexyl phenyl acetone 2-methyl-1- (4-methylthiophenyl) -2-morpholino-1-propanone and 2,4,6_ trimethyl benzoyl - diphenyl phosphine oxide, thioxanthone of one or more thereof.
5.根据权利要求1至4中任一项所述的紫外光固化转印油墨,其特征在于:所述色粉为黄色颜料、红色颜料、黑色颜料及白色颜料中的一种或多种的混合物。 The 1-4 UV-curable transfer ink according to any one of the preceding claims, characterized in that: said toner is a yellow pigment, a red pigment, a black pigment and a white pigment in one or more of mixture.
CN 200910186408 2009-10-28 2009-10-28 Ultra-violet curing transfer ink CN101696332B (en)

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CN102702848B (en) * 2012-06-05 2015-06-24 无锡金桥精细油墨有限公司 Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof
CN103666031B (en) * 2013-11-23 2016-05-04 铜陵方正塑业科技有限公司 One kind of UV-curable printing inks and preparation method
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CN104292970B (en) * 2014-10-28 2016-04-06 成都纳硕科技有限公司 One kind of UV-curable acrylic decorative panel for Screen Ink
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