CN107141926A - A kind of printing coatings of self-luminescence advertisement and preparation method thereof - Google Patents
A kind of printing coatings of self-luminescence advertisement and preparation method thereof Download PDFInfo
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- CN107141926A CN107141926A CN201710540652.8A CN201710540652A CN107141926A CN 107141926 A CN107141926 A CN 107141926A CN 201710540652 A CN201710540652 A CN 201710540652A CN 107141926 A CN107141926 A CN 107141926A
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- printing coatings
- luminescence
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of printing coatings of self-luminescence advertisement, include following raw material according to parts by weight：25 parts of acrylic resin, 3 parts of rare earth luminous powder, 10 parts of Tissuemat E, 5 parts of propyl acetate, 5 parts of epoxy resin, 2 parts of propylene glycol methyl ether acetate, 1 part of dimethyl carbonate, 2 parts of thickener, 2 parts of reactive diluent, 1 part of levelling agent, 2 parts of preservative, 20 parts of organic solvent, 1.5 parts of the anti-stick auxiliary agent of surface hydrophobicity.The present invention provides a kind of printing coatings of self-luminescence advertisement and preparation method thereof, obtained printing coatings are not easy to crack, crack resistance is strong, stand expose to wind and rain and rainwater erosion, the coating uses acrylic resin and rare earth luminous powder as carrier, and using organic solvent as solvent, adds the anti-stick auxiliary agent of surface hydrophobicity after its film forming, its surface contact angle is small, and anti-stick patch property is good.
Description
Technical field
The invention belongs to advertising and printing field, and in particular to a kind of printing coatings of self-luminescence advertisement and its preparation side
Method.
Background technology
Self-luminous paint is to utilize self-luminous principle, when having light, and coating storage light can reach that luminous energy is satisfied for 1 hour
With.No bright when, self-luminous coating was using the luminous energy self-luminescence stored more than 12 hours, and it widely is answered
Used in fields such as outdoor billboard, means of transportation direction boards.
However, existing billboard surface self-luminous paint generally existing poor adhesive force, the weak shortcoming of weatherability.Due to
Billboard is leaked in sunlight or rainy day cruelly for a long time, is exposed to the weather, rain erosion, the film on surface is easy to ftracture and taken off
Fall, especially the film in parts such as bending sections is easy to come off, it is necessary to open in order to solve this shortcoming of self-luminous paint
Send adhesive force strong, the self-luminous paint product of good weatherability.
The content of the invention
In view of the above-mentioned problems, the technical problem to be solved in the present invention is to provide a kind of printing coatings of self-luminescence advertisement and
Its preparation method.
To achieve the above object, the technical scheme is that：A kind of printing coatings of self-luminescence advertisement, according to weight
Part includes following raw material：25 ~ 35 parts of acrylic resin, 3 ~ 9 parts of rare earth luminous powder, 10 ~ 20 parts of Tissuemat E, propyl acetate 5 ~
15 parts, 5 ~ 12 parts of epoxy resin, 2 ~ 8 parts of propylene glycol methyl ether acetate, 1 ~ 5 part of dimethyl carbonate, 2 ~ 7 parts of thickener, activity it is dilute
Release 2 ~ 5 parts of agent, 1 ~ 10 part of levelling agent, 2 ~ 6 parts of preservative, 20 ~ 30 parts of organic solvent, the anti-stick auxiliary agent 1.5 ~ 2.5 of surface hydrophobicity
Part.
Further, following raw material is included according to parts by weight：25 parts of acrylic resin, 3 parts of rare earth luminous powder, Tissuemat E
10 parts, 5 parts of propyl acetate, 5 parts of epoxy resin, 2 parts of propylene glycol methyl ether acetate, 1 part of dimethyl carbonate, 2 parts of thickener, activity
2 parts of diluent, 1 part of levelling agent, 2 parts of preservative, 20 parts of organic solvent, 1.5 parts of the anti-stick auxiliary agent of surface hydrophobicity.
Further, the atent solvent is made up of DAA, butyl ester and ethyl ester.
Further, the mass ratio of the DAA, butyl ester and ethyl ester is 2 ~ 3:5~7:1.
Further, the reactive diluent is pressed by trimethylolpropane trimethacrylate and tripropylene glycol diacrylate
According to 3:2 mass ratio composition.
Further, the organic solvent is selected from styrene, perchloroethylene, trichloro ethylene, ethylene glycol ether and three second
One or more in hydramine.
A kind of preparation method of the printing coatings of self-luminescence advertisement, is mainly included the following steps that：
Step 1：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin, the third two are equipped with according to the above ratio
Alcohol methyl ether acetate, dimethyl carbonate, thickener, reactive diluent, levelling agent, preservative, organic solvent, surface hydrophobicity are anti-stick
Auxiliary agent；
Step 2：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin are added in pre-emulsification kettle, so
After carry out pre-emulsification, the pre-emulsification time is 30 ~ 90min, obtains pre-emulsion；
Step 3：Propylene glycol methyl ether acetate, dimethyl carbonate are added in dissolving tank, and pre-emulsion will be crossed provisioned in step 2
Add in dissolving tank, be then stirred, speed of agitator is 100 ~ 150r/min, raw material is fully dissolved, obtains mixed emulsion；
Step 4：Mixed emulsion in step 3 is all put into reactor, 10 ~ 15min is stirred for, remaining original is added
Material, heating causes the temperature in reactor to maintain 80 ~ 100 DEG C, and is incubated after 5 ~ 15min, be cooled to normal temperature produce it is spontaneous
The printing coatings of light advertisement.
Further, it is described to be cooled to the natural type of cooling.
The beneficial effects of the present invention are：The present invention provides printing coatings and its preparation side of a kind of self-luminescence advertisement
Method, obtained printing coatings are not easy to crack, and crack resistance is strong, stand expose to wind and rain and rainwater erosion, the coating uses third
Olefin(e) acid resin and rare earth luminous powder add the anti-stick auxiliary agent of surface hydrophobicity and worked as carrier, and using organic solvent as solvent
After its film forming, its surface contact angle is small, and anti-stick patch property is good.
The present invention is from two kinds of reactive diluents, i.e. trimethylolpropane trimethacrylate and tripropylene glycol diacrylate
Ester.Trimethylolpropane trimethacrylate can provide relatively good hardness and curing rate to the printing coatings, and 3 the third two
The flexibility that alcohol diacrylate has had, can reduce the viscosity of coating, also have attachment facilitation well, and two kinds of activity are dilute
Release agent does not influence the performance of integral formula also with the use of the cost for both controlling printing coatings.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is described in further detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, do not limit
The fixed present invention.
Embodiment 1
A kind of printing coatings of self-luminescence advertisement, include following raw material according to parts by weight：25 parts of acrylic resin, rare earth hair
3 parts of light powder, 10 parts of Tissuemat E, 5 parts of propyl acetate, 5 parts of epoxy resin, 2 parts of propylene glycol methyl ether acetate, dimethyl carbonate 1
Part, 2 parts of thickener, 2 parts of reactive diluent, 1 part of levelling agent, 2 parts of preservative, 20 parts of organic solvent, the anti-stick auxiliary agent of surface hydrophobicity
1.5 part.
The atent solvent is made up of DAA, butyl ester and ethyl ester.
The mass ratio of the DAA, butyl ester and ethyl ester is 2:5:1.
The reactive diluent is by trimethylolpropane trimethacrylate and tripropylene glycol diacrylate according to 3:2 matter
Amount is than composition.
The organic solvent in styrene, perchloroethylene, trichloro ethylene, ethylene glycol ether and triethanolamine one
Plant or a variety of.
A kind of preparation method of the printing coatings of self-luminescence advertisement, is mainly included the following steps that：
Step 1：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin, the third two are equipped with according to the above ratio
Alcohol methyl ether acetate, dimethyl carbonate, thickener, reactive diluent, levelling agent, preservative, organic solvent, surface hydrophobicity are anti-stick
Auxiliary agent；
Step 2：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin are added in pre-emulsification kettle, so
After carry out pre-emulsification, the pre-emulsification time is 30min, obtains pre-emulsion；
Step 3：Propylene glycol methyl ether acetate, dimethyl carbonate are added in dissolving tank, and pre-emulsion will be crossed provisioned in step 2
Add in dissolving tank, be then stirred, speed of agitator is 100r/min, raw material is fully dissolved, and obtains mixed emulsion；
Step 4：Mixed emulsion in step 3 is all put into reactor, 10min is stirred for, remaining raw material is added, risen
Temperature causes the temperature in reactor to maintain 80 DEG C, and is incubated after 5min, is cooled to the print that normal temperature produces self-luminescence advertisement
Swabbing.
It is described to be cooled to the natural type of cooling.
Embodiment 2
A kind of printing coatings of self-luminescence advertisement, include following raw material according to parts by weight：30 parts of acrylic resin, rare earth hair
6 parts of light powder, 15 parts of Tissuemat E, 10 parts of propyl acetate, 7 parts of epoxy resin, 6 parts of propylene glycol methyl ether acetate, dimethyl carbonate 3
Part, 4 parts of thickener, 3 parts of reactive diluent, 7 parts of levelling agent, 4 parts of preservative, 25 parts of organic solvent, the anti-stick auxiliary agent of surface hydrophobicity
2.0 part.
Further, the atent solvent is made up of DAA, butyl ester and ethyl ester.
Further, the mass ratio of the DAA, butyl ester and ethyl ester is 2:6:1.
Further, the reactive diluent is pressed by trimethylolpropane trimethacrylate and tripropylene glycol diacrylate
According to 3:2 mass ratio composition.
Further, the organic solvent is selected from styrene, perchloroethylene, trichloro ethylene, ethylene glycol ether and three second
One or more in hydramine.
A kind of preparation method of the printing coatings of self-luminescence advertisement, is mainly included the following steps that：
Step 1：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin, the third two are equipped with according to the above ratio
Alcohol methyl ether acetate, dimethyl carbonate, thickener, reactive diluent, levelling agent, preservative, organic solvent, surface hydrophobicity are anti-stick
Auxiliary agent；
Step 2：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin are added in pre-emulsification kettle, so
After carry out pre-emulsification, the pre-emulsification time is 60min, obtains pre-emulsion；
Step 3：Propylene glycol methyl ether acetate, dimethyl carbonate are added in dissolving tank, and pre-emulsion will be crossed provisioned in step 2
Add in dissolving tank, be then stirred, speed of agitator is 120r/min, raw material is fully dissolved, and obtains mixed emulsion；
Step 4：Mixed emulsion in step 3 is all put into reactor, 12min is stirred for, remaining raw material is added, risen
Temperature causes the temperature in reactor to maintain 90 DEG C, and is incubated after 10min, is cooled to the print that normal temperature produces self-luminescence advertisement
Swabbing.
It is described to be cooled to the natural type of cooling.
Embodiment 3
A kind of printing coatings of self-luminescence advertisement, include following raw material according to parts by weight：35 parts of acrylic resin, rare earth hair
9 parts of light powder, 20 parts of Tissuemat E, 15 parts of propyl acetate, 12 parts of epoxy resin, 8 parts of propylene glycol methyl ether acetate, dimethyl carbonate
5 parts, 7 parts of thickener, 5 parts of reactive diluent, 10 parts of levelling agent, 6 parts of preservative, 30 parts of organic solvent, surface hydrophobicity is anti-stick helps
2.5 parts of agent.
Further, the atent solvent is made up of DAA, butyl ester and ethyl ester.
Further, the mass ratio of the DAA, butyl ester and ethyl ester is 3:7:1.
Further, the reactive diluent is pressed by trimethylolpropane trimethacrylate and tripropylene glycol diacrylate
According to 3:2 mass ratio composition.
Further, the organic solvent is selected from styrene, perchloroethylene, trichloro ethylene, ethylene glycol ether and three second
One or more in hydramine.
A kind of preparation method of the printing coatings of self-luminescence advertisement, is mainly included the following steps that：
Step 1：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin, the third two are equipped with according to the above ratio
Alcohol methyl ether acetate, dimethyl carbonate, thickener, reactive diluent, levelling agent, preservative, organic solvent, surface hydrophobicity are anti-stick
Auxiliary agent；
Step 2：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin are added in pre-emulsification kettle, so
After carry out pre-emulsification, the pre-emulsification time is 90min, obtains pre-emulsion；
Step 3：Propylene glycol methyl ether acetate, dimethyl carbonate are added in dissolving tank, and pre-emulsion will be crossed provisioned in step 2
Add in dissolving tank, be then stirred, speed of agitator is 150r/min, raw material is fully dissolved, and obtains mixed emulsion；
Step 4：Mixed emulsion in step 3 is all put into reactor, 15min is stirred for, remaining raw material is added, risen
Temperature causes the temperature in reactor to maintain 100 DEG C, and is incubated after 15min, is cooled to normal temperature and produces self-luminescence advertisement
Printing coatings.
It is described to be cooled to the natural type of cooling.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of printing coatings of self-luminescence advertisement, it is characterised in that include following raw material according to parts by weight：Acrylic acid tree
25 ~ 35 parts of fat, 3 ~ 9 parts of rare earth luminous powder, 10 ~ 20 parts of Tissuemat E, 5 ~ 15 parts of propyl acetate, 5 ~ 12 parts of epoxy resin, the third two
It is 2 ~ 8 parts of alcohol methyl ether acetate, 1 ~ 5 part of dimethyl carbonate, 2 ~ 7 parts of thickener, 2 ~ 5 parts of reactive diluent, 1 ~ 10 part of levelling agent, anti-
Rotten 2 ~ 6 parts of agent, 20 ~ 30 parts of organic solvent, 1.5 ~ 2.5 parts of the anti-stick auxiliary agent of surface hydrophobicity.
2. the printing coatings of a kind of self-luminescence advertisement according to claim 1, it is characterised in that include according to parts by weight
Following raw material：25 parts of acrylic resin, 3 parts of rare earth luminous powder, 10 parts of Tissuemat E, 5 parts of propyl acetate, 5 parts of epoxy resin, third
2 parts of glycol methyl ether acetate, 1 part of dimethyl carbonate, 2 parts of thickener, 2 parts of reactive diluent, 1 part of levelling agent, 2 parts of preservative,
1.5 parts of the anti-stick auxiliary agent of 20 parts of organic solvent, surface hydrophobicity.
3. a kind of printing coatings of self-luminescence advertisement according to claim 1, it is characterised in that the atent solvent by
DAA, butyl ester and ethyl ester composition.
4. a kind of printing coatings of self-luminescence advertisement according to claim 3, it is characterised in that the DAA,
The mass ratio of butyl ester and ethyl ester is 2 ~ 3:5~7:1.
5. a kind of printing coatings of self-luminescence advertisement according to claim 1, it is characterised in that the reactive diluent
By trimethylolpropane trimethacrylate and tripropylene glycol diacrylate according to 3:2 mass ratio composition.
6. a kind of printing coatings of self-luminescence advertisement according to claim 1, it is characterised in that the organic solvent choosing
One or more from styrene, perchloroethylene, trichloro ethylene, ethylene glycol ether and triethanolamine.
7. a kind of preparation method of the printing coatings of self-luminescence advertisement, it is characterised in that mainly include the following steps that：
Step 1：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin, the third two are equipped with according to the above ratio
Alcohol methyl ether acetate, dimethyl carbonate, thickener, reactive diluent, levelling agent, preservative, organic solvent, surface hydrophobicity are anti-stick
Auxiliary agent；
Step 2：Acrylic resin, rare earth luminous powder, Tissuemat E, propyl acetate, epoxy resin are added in pre-emulsification kettle, so
After carry out pre-emulsification, the pre-emulsification time is 30 ~ 90min, obtains pre-emulsion；
Step 3：Propylene glycol methyl ether acetate, dimethyl carbonate are added in dissolving tank, and pre-emulsion will be crossed provisioned in step 2
Add in dissolving tank, be then stirred, speed of agitator is 100 ~ 150r/min, raw material is fully dissolved, obtains mixed emulsion；
Step 4：Mixed emulsion in step 3 is all put into reactor, 10 ~ 15min is stirred for, remaining original is added
Material, heating causes the temperature in reactor to maintain 80 ~ 100 DEG C, and is incubated after 5 ~ 15min, be cooled to normal temperature produce it is spontaneous
The printing coatings of light advertisement.
8. the preparation method of the printing coatings of a kind of self-luminescence advertisement according to claim 7, it is characterised in that described
It is cooled to the natural type of cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710540652.8A CN107141926A (en) | 2017-07-05 | 2017-07-05 | A kind of printing coatings of self-luminescence advertisement and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710540652.8A CN107141926A (en) | 2017-07-05 | 2017-07-05 | A kind of printing coatings of self-luminescence advertisement and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107141926A true CN107141926A (en) | 2017-09-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710540652.8A Withdrawn CN107141926A (en) | 2017-07-05 | 2017-07-05 | A kind of printing coatings of self-luminescence advertisement and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674527A (en) * | 2017-11-21 | 2018-02-09 | 马鞍山松鹤信息科技有限公司 | A kind of billboard printing coatings and its preparation technology |
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| CN101550303A (en) * | 2009-05-08 | 2009-10-07 | 广东华润涂料有限公司 | High hydrophobic anti pasting poster paint |
| CN102234480A (en) * | 2010-04-20 | 2011-11-09 | 东莞市佩琦涂料有限公司 | Ultraviolet light solidified antibiosis paint |
| CN103509429A (en) * | 2013-09-17 | 2014-01-15 | 浙江天蓝环保技术股份有限公司 | Anticorrosive paint with good oxidation resistance and acid-base corrosion resistance as well as preparation method thereof |
| CN104761961A (en) * | 2015-03-28 | 2015-07-08 | 桐城市福润包装材料有限公司 | Thermal-insulation paint for packaging products |
| CN104804589A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Self-luminous advertising printing coating |
-
2017
- 2017-07-05 CN CN201710540652.8A patent/CN107141926A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550303A (en) * | 2009-05-08 | 2009-10-07 | 广东华润涂料有限公司 | High hydrophobic anti pasting poster paint |
| CN102234480A (en) * | 2010-04-20 | 2011-11-09 | 东莞市佩琦涂料有限公司 | Ultraviolet light solidified antibiosis paint |
| CN103509429A (en) * | 2013-09-17 | 2014-01-15 | 浙江天蓝环保技术股份有限公司 | Anticorrosive paint with good oxidation resistance and acid-base corrosion resistance as well as preparation method thereof |
| CN104761961A (en) * | 2015-03-28 | 2015-07-08 | 桐城市福润包装材料有限公司 | Thermal-insulation paint for packaging products |
| CN104804589A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Self-luminous advertising printing coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674527A (en) * | 2017-11-21 | 2018-02-09 | 马鞍山松鹤信息科技有限公司 | A kind of billboard printing coatings and its preparation technology |
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Application publication date: 20170908 |
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