CN103409003A - Waterborne interface treatment coating and preparation method thereof - Google Patents

Waterborne interface treatment coating and preparation method thereof Download PDF

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CN103409003A
CN103409003A CN2012105934456A CN201210593445A CN103409003A CN 103409003 A CN103409003 A CN 103409003A CN 2012105934456 A CN2012105934456 A CN 2012105934456A CN 201210593445 A CN201210593445 A CN 201210593445A CN 103409003 A CN103409003 A CN 103409003A
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water
agent
interface processing
based interface
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林杰生
黄莉恒
章毅
梁志豪
梁斌
杜光辉
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Carpoly Chemical Group Co., Ltd.
GUANGDONG CARPOLY SCIENCE & TECHNOLOGY MATERIAL CO., LTD.
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CARPOLY CHEMICAL GROUP Co Ltd
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Abstract

The invention discloses waterborne interface treatment coating, which is prepared from such components as styrene acrylic emulsion, a waterborne organosilicon waterproofing agent, an assistant, a dispersing agent, a wetting agent, a defoaming agent, a coalescing agent, an antifreezing agent, a thickening agent, a leveling agent, an antiseptic antimildew agent, titanium dioxide, coarse whiting, reinforcement fibers and water. The invention further discloses a preparation method of the water interface treatment coating. The waterborne interface treatment coating disclosed by the invention has the advantages that a surface with uniform rough effect can be formed and the roughness of the ceiling is obviously enhanced to reinforce the adhesive force between the coatings and avoid easy bulging and dropping of a putty layer.

Description

A kind of water-based interface processing coating and preparation method thereof
[technical field]
The present invention relates to paint field, be specifically related to a kind of water-based interface processing coating that is mainly used in the sheet materials such as plasterboard, inorganic fiberboard and woodboard and preparation method thereof.
[background technology]
The ceiling of furred ceiling is one of important decorative position of Indoor environment.In general house fitting-up, a large amount of plasterboard, inorganic fiberboard and woodboards of adopting, as furred ceiling, coordinate to criticize and scrape common inner wall putty, then the brushing wall paint; This is that a kind of cost is low, construction is simple, short decoration mode of duration.Yet, because the inner concealed space of the furred ceiling of new house is stuffy, the moisture weight, usually after finishing 1 year, more smooth because of cream plate, inorganic fiberboard and woodboard surface, humidity resistance is poor, wall paint yellowing and the problem that comes off occur.
[summary of the invention]
The object of the invention is to the defect existed for the above prior art, provide a kind of moistureproofness good, surperficial crude, putty strong adhesion, can guarantee effectively that paint film does not come off, not yellowing, extend the metope coating project life-span, and can save the water-based interface processing coating of recoat dress expense, the minimizing wasting of resources.
Another purpose of the present invention provides a kind of preparation method of interface processing coating.
For achieving the above object, technical scheme of the present invention is: water-based interface processing coating, and it is comprised of components such as water-soluble, film-forming material, watery water-proofing agent, pigment, filler, auxiliary agent and water, and it specifically comprises the component of following parts by weight:
Figure BDA00002690778900011
Figure BDA00002690778900021
In described powder, can need to comprise appropriate pigment by toning.
Described benzene emulsion can be selected from RS-998A benzene emulsion, the PRIMAL AS-2010EF benzene emulsion of Dow Chemical's product or the Acronal ECO 704 ap emulsions that BASF AG produces that the well-off industry of Ahmedabad company limited produces.
Described water-based organic silicon waterproof agent is the polysiloxane emulsion of functional group's silicone resin modification, can select Germany watt to digest and learn BS 1306 CN that trade (Shanghai) Co., Ltd. produces, and it has better waterproof and dampproof property, water tolerance and ventilation property.
Described defoamer is mineral oil defoaming agent, can be selected from the 681F defoamer that French Rhodia produces.
Described dispersion agent is the polyacrylic acid sodium salt waterborne pigment dispersant, can be optional Rhom and Hass's model of producing be the dispersion agent of the special TM 731A that falls apart well.
Described wetting agent is the alkyl polyoxyethylene ether wetting agent, the LCN407 that optional German Clariant company produces.
Wherein, cellulose thickener: acrylic thickener=1:1, such proportioning and Miscibility are good, and thickening efficiency is high, and levelling property is relatively good.Described cellulose thickener is for adopting Natvosol, can be selected from the HS30000YP2 that German Clariant company produces.This thickening material and system compatible stability are good, stable viscosity after storing.Described acrylic thickener adopts alkali swelling associative thickener, and the model that can select ROHM AND HAAS China Investment Ltd. to produce is the thickening material of TT-935.This thickening material and Miscibility are good, and thickening efficiency is high, and levelling property is relatively good, excellent storage stability.
Described flow agent adopts the polyurethanes flow agent, and the model that can select ROHM AND HAAS China Investment Ltd. to produce is the flow agent of RM-2020.The consistency of this flow agent and formula is good, and levelling is good.
Described Antisepticize and mildew preventive can be isothiazolinone, the MERGAL K14 that can select U.S. Troy company to produce.
Described film coalescence aid adopts 2,2,4-trimethylammonium-1, and 3-pentanediol-isopropylformic acid monoesters is selected the TEXANOL model of Eastman Chemical.This film coalescence aid film forming efficiency is high, and boiling point is high, does not belong to the category of VOC.
Described frostproofer adopts propylene glycol, the propylene glycol that can select Guangzhou rich chemical industry in morning company limited to produce.The antifreeze efficiency of this frostproofer is high, and cost performance is high.
Described titanium dioxide adopts rutile-type, and the model that can select Dong Jia group to produce is the titanium dioxide of SR-237.
The relative molecular weight 100.09 of described heavy calcium carbonate, its particle diameter were 150 mesh sieves, the 150 order coarse whitings that can select Guangfu Building Materials (Jiaoling) Fine Chemicals Industry Co., Ltd. to produce.
Described fortifying fibre adopts polypropylene fibre, the 3mm trilobal cross polypropylene fibre that can select Jiangsu shining sun silk ancient cooking vessel company to produce.
Another object of the present invention is to provide the preparation method of above-mentioned water-based interface processing coating.
The preparation method of above-mentioned water-based interface processing coating, it comprises the steps:
(1) pre-mixing: add the water of 17~20 parts in disperseing cylinder, the dispersion agent, wetting agent, film coalescence aid, frostproofer, cellulose thickener and the fortifying fibre that add again respectively above-mentioned parts by weight, the defoamer of defoamer total amount 2/3, fully be uniformly mixed the jellied mixture of shape, the rotating speed of mix and blend is controlled at 300~500rpm;
(2) high speed dispersion: add titanium dioxide and the heavy calcium carbonate of above-mentioned parts by weight in disperseing cylinder, control rotating speed and pulled an oar under 1500~2500rpm 20~25 minutes;
(3) add emulsion: in disperseing cylinder, add the water of 3~5 parts by weight and the Antisepticize and mildew preventive of above-mentioned parts by weight, then add benzene emulsion, be uniformly mixed, the stirring degree of turning of mixing is controlled at 800~1200rpm;
(4) add auxiliary agent: the acrylic thickener, water-based organic silicon waterproof agent, the flow agent that in disperseing cylinder, add successively above-mentioned parts by weight, and remaining defoamer and water, be uniformly mixed, the rotating speed of mix and blend is controlled at 800~1200rpm, obtains water-based interface processing coating.
(5) packing: as requested coating is contained in the Lacquered Tin Plate Can of different volumes.
Compared with prior art, the present invention has the following advantages: but the benzene emulsion of employing room-temperature self crosslinking, emulsion particle is tiny, and is uniformly distributed, and easily infiltrates base material, makes cohesive force extremely strong, and paint film is fine and smooth fine and close; Simultaneously, in coating, added the waterproofing agent of organosilicon of German Wa Ke company, thereby paint film has excellent hydrophobic moistureproofness; In the furred ceiling application, not only requiring has better protecting and decoration function, and its vapour permeability is had to higher requirement, and waterproofing agent of organosilicon not only can have excellent water-repellancy, but the moisture of base material is evaporated with very fast speed, avoid causing paint blister, coming off because of the delay of aqueous vapor; Paint film has added acrylic fibre and low mesh number powder, makes the surface of the even crude effect of coating formation, obviously improves the roughness of furred ceiling, to strengthen the sticking power that is coated with interlayer, makes putty layer be difficult for drum, come off.
[embodiment]
The present invention will be described in detail below in conjunction with specific embodiment.
Embodiment 1
Water-based interface processing coating, it specifically comprises the component of following parts by weight:
Figure BDA00002690778900041
Figure BDA00002690778900051
Embodiment 2
Water-based interface processing coating, it is comprised of components such as water-soluble, film-forming material, watery water-proofing agent, silica powder, pigment, filler, auxiliary agent and water, and it specifically comprises the component of following parts by weight:
Figure BDA00002690778900052
Embodiment 3
Water-based interface processing coating, it is comprised of components such as water-soluble, film-forming material, watery water-proofing agent, silica powder, pigment, filler, auxiliary agent and water, and it specifically comprises the component of following parts by weight:
Figure BDA00002690778900061
Embodiment 4
Water-based interface processing coating, it is comprised of components such as water-soluble, film-forming material, watery water-proofing agent, silica powder, pigment, filler, auxiliary agent and water, and it specifically comprises the component of following parts by weight:
Figure BDA00002690778900062
Embodiment 5
Water-based interface processing coating, it is comprised of components such as water-soluble, film-forming material, watery water-proofing agent, silica powder, pigment, filler, auxiliary agent and water, and it specifically comprises the component of following parts by weight:
Figure BDA00002690778900072
Figure BDA00002690778900081
In above-described water-based interface processing coating, in order to adapt to the demand of client to color, can be by the pigment in the 0%-2.5% scope that need to add the coating gross weight of mixing colours in formula, described pigment can add simultaneously when adding titanium dioxide and dicalcium powder.
Wherein, described benzene emulsion can be selected from RS-998A benzene emulsion, the PRIMAL AS-2010EF benzene emulsion of Dow Chemical's product or the Acronal ECO 704 ap emulsions that BASF AG produces that the well-off industry of Ahmedabad company limited produces.Described water-based organic silicon waterproof agent is the polysiloxane emulsion of silicone resin modification, can select Germany watt to digest and learn BS 1306 CN that trade (Shanghai) Co., Ltd. produces, and it has better waterproof and dampproof property, water tolerance and ventilation property.Described defoamer is mineral oil defoaming agent, can be selected from the 681F defoamer that French Rhodia produces.Described dispersion agent is the polyacrylic acid sodium salt waterborne pigment dispersant, can select the model that Rhom and Hass produces to be the special well dispersion agent of loose TM 731A.Described wetting agent is the alkyl polyoxyethylene ether wetting agent, the LCN407 that optional German Clariant company produces.Described cellulose thickener adopts Natvosol class thickening material, can be selected from the HS30000YP2 that German Clariant company produces; This thickening material and system compatible stability are good, stable viscosity after storing.Described acrylic thickener adopts alkali swelling associative thickener, and the model that can select ROHM AND HAAS China Investment Ltd. to produce is the thickening material of TT-935, and this thickening material and Miscibility are good, and thickening efficiency is high, and levelling property is relatively good, excellent storage stability.Described flow agent adopts the polyurethanes flow agent, and the model that can select ROHM AND HAAS China Investment Ltd. to produce is the flow agent of RM-2020; The consistency of this flow agent and formula is good, and levelling is good.Described Antisepticize and mildew preventive can isothiazolinone, the MERGAL K14 that can select U.S. Troy company to produce.Described film coalescence aid adopts 2,2,4-trimethylammonium-1, and 3-pentanediol-isopropylformic acid monoesters is selected the TEXANOL model of Eastman Chemical, and this film coalescence aid film forming efficiency is high, and boiling point is high, does not belong to the category of VOC.Described frostproofer adopts propylene glycol, the propylene glycol that can select Guangzhou rich chemical industry in morning company limited to produce, and the antifreeze efficiency of this frostproofer is high, and cost performance is high.Described titanium dioxide adopts rutile-type, and the model that can select Dong Jia group to produce is the titanium dioxide of SR-237.Described heavy calcium carbonate adopts 150 orders, the 150 order heavy calcium carbonates that can select Guangfu Building Materials (Jiaoling) Fine Chemicals Industry Co., Ltd. to produce.Described fortifying fibre adopts polypropylene fibre, the 3mm trilobal cross polypropylene fibre that can select Jiangsu shining sun silk ancient cooking vessel company to produce.
The preparation method of above-mentioned water-based interface processing coating, it comprises the steps:
(1) pre-mixing: add the water of 17~20 parts in disperseing cylinder, the dispersion agent, wetting agent, film coalescence aid, frostproofer, cellulose thickener and the fortifying fibre that add again respectively above-mentioned parts by weight, the defoamer of defoamer total amount 2/3, fully be uniformly mixed the jellied mixture of shape, the rotating speed of mix and blend is controlled at 300~500rpm; Wherein the rotating speed of mix and blend is preferably 350~450rpm
(2) high speed dispersion: add titanium dioxide and the heavy calcium carbonate of above-mentioned parts by weight in disperseing cylinder, control rotating speed and pulled an oar under 1500~2500rpm 20~25 minutes; Wherein, rotating speed is preferably at 2000~2200rpm
(3) add emulsion: in disperseing cylinder, add the water of 3~5 parts by weight and the Antisepticize and mildew preventive of above-mentioned parts by weight, then add benzene emulsion, be uniformly mixed, the stirring degree of turning of mixing is controlled at 800~1200rpm; Wherein, mixing speed is controlled at 1000~1100rpm;
(4) add auxiliary agent: the acrylic thickener, water-based organic silicon waterproof agent, the flow agent that in disperseing cylinder, add successively above-mentioned parts by weight, and remaining defoamer and water, be uniformly mixed, the rotating speed of mix and blend is controlled at 800~1200rpm, obtains water-based interface processing coating; Wherein, the rotating speed of mix and blend is controlled at 1000~1100rpm;
(5) packing: as requested coating is contained in the Lacquered Tin Plate Can of different volumes.
Performance Detection
The water-based interface processing coating fundamental property test that above embodiment obtains is as follows:
The index of (1) pressing SJT N 0.70 type of People's Republic of China's building industry industry standard " JG/T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS " detects, the above embodiment of the present invention detected result such as following table:
Figure BDA00002690778900091
Figure BDA00002690778900101
(2) strengthen sticking power, the slip-off preventing test
Select the interior wall R type putty of certain brand, with reference to the detection method of 6.12 cohesive strengths in " JG/T298-2010 architecture indoor putty ", detect respectively and take plasterboard, inorganic fiberboard and the woodboard putty layer cohesive strength X as test plate (panel) Before, Y BeforeAnd Z Before, then detect respectively coating that brushing the above embodiment of the present invention obtains the putty layer cohesive strength X on the maintenance plasterboard of 7 days, inorganic fiberboard and woodboard After, Y AfterAnd Z After, before and after contrast, variation per-cent and the basal plane situation of cohesive strength are as follows:
* cohesive strength variation=[(cohesive strength after processing-untreated front cohesive strength)/untreated front cohesive strength] * 100% cohesive strength on plasterboard improves obviously, causes test plate (panel) destruction also to fail to break the bonding of putty and interface coating coating.The bonding strength test contrast: interface coating of the present invention causes the plasterboard test block to destroy the bonding of also failing to break putty and interface agent coating, and the plasterboard test block of not brushing interfacial agents comes off at key coat.
(3) moistureproof test
Design moistureproof simulated experiment: get a 30mm * 40mm plasterboard, vertically half brushes interfacial agents of the present invention, half blank, laterally half batch Puttying, half blank; Make the synthetic glass case of 30mm * 40mm * 30mm, reserve an opening, and by the plasterboard front to inner cap on synthetic glass case opening, with the adhesive tape sealing, the plasterboard back is exposed, the synthetic glass case is placed on to fixed temperature and humidity (20 ℃ of temperature, relative humidity >=90%) under in trier, moisture, from the infiltration of plasterboard back, directly has influence on positive putty layer water ratio, thereby evaluates the moisture effect of interfacial agents.Model is placed 24h, takes out, and draws off plasterboard, tests immediately the front water ratio.Plasterboard different sites water ratio, as following table:
In sum, the protection against the tide of interface coating of the present invention, slip-off preventing performance are better compared to existing technology.
Described person, it is only preferred embodiment of the present invention, when not limiting scope of the invention process with this, the simple equivalence of namely generally doing according to the present patent application the scope of the claims and invention description content changes and modifies, and all still remains within the scope of the patent.

Claims (10)

1. water-based interface processing coating, is characterized in that, comprises the component of following parts by weight:
Figure 1
2. water-based interface processing coating according to claim 1, is characterized in that, includes pigment in described powder.
3. water-based interface processing coating according to claim 1, it is characterized in that, described benzene emulsion can be selected from RS-998A benzene emulsion, the PRIMAL AS-2010EF benzene emulsion of Dow Chemical's product or the Acronal ECO 704 ap emulsions that BASF AG produces that the well-off industry of Ahmedabad company limited produces.
4. water-based interface processing coating according to claim 1, is characterized in that, described water-based organic silicon waterproof agent digests and learns BS 1306 CN that trade (Shanghai) Co., Ltd. produces for Germany watt.
5. water-based interface processing coating according to claim 1, is characterized in that, described cellulose thickener adopts Natvosol class thickening material; Described Natvosol class thickening material is selected from the HS30000YP2 that German Clariant company produces.
6. water-based interface processing coating according to claim 5, is characterized in that, the model that described acrylic thickener adopts ROHM AND HAAS China Investment Ltd. to produce is the thickening material of TT-935.
7. water-based interface processing coating according to claim 1, is characterized in that, the model that described flow agent selects ROHM AND HAAS China Investment Ltd. to produce is the flow agent of RM-2020.
8. water-based interface processing coating according to claim 1, is characterized in that, described film coalescence aid adopts 2,2,4-trimethylammonium-1,3-pentanediol-isopropylformic acid monoesters.
9. water-based interface processing coating according to claim 1, is characterized in that, described fortifying fibre adopts polypropylene fibre.
10. according to the preparation method of the arbitrary described water-based interface processing coating of claim 1-9, it is characterized in that, it comprises the steps:
(1) pre-mixing: add the water of 17~20 parts in disperseing cylinder, the dispersion agent, wetting agent, film coalescence aid, frostproofer, cellulose thickener and the fortifying fibre that add again respectively above-mentioned parts by weight, the defoamer of defoamer total amount 2/3, fully be uniformly mixed the jellied mixture of shape, the rotating speed of mix and blend is controlled at 300~500rpm;
(2) high speed dispersion: add titanium dioxide and the heavy calcium carbonate of above-mentioned parts by weight in disperseing cylinder, control rotating speed and pulled an oar under 1500~2500rpm 20~25 minutes;
(3) add emulsion: in disperseing cylinder, add the water of 3~5 parts by weight and the Antisepticize and mildew preventive of above-mentioned parts by weight, then add benzene emulsion, be uniformly mixed, the stirring degree of turning of mixing is controlled at 800~1200rpm;
(4) add auxiliary agent: in disperseing cylinder, add successively acrylic thickener, water-based organic silicon waterproof agent, the flow agent of above-mentioned parts by weight, and remaining defoamer, being uniformly mixed, the rotating speed of mix and blend is controlled at 800~1200rpm.
CN2012105934456A 2012-12-31 2012-12-31 Waterborne interface treatment coating and preparation method thereof Pending CN103409003A (en)

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CN104193289A (en) * 2014-08-27 2014-12-10 辽宁一一三(集团)化工有限责任公司 Hydrophobic protective paint and preparation method thereof
CN104387515A (en) * 2014-11-13 2015-03-04 常熟市万象涂料有限公司 Interface agent and preparation method thereof
CN104861792A (en) * 2015-05-22 2015-08-26 营口象圆新材料工程技术有限公司 Special alkali-resisting interfacial agent for phenolic foam insulation board
CN105400432A (en) * 2015-12-07 2016-03-16 三棵树涂料股份有限公司 Computerized color mixing external wall flat-coating basic deep-foundation paint and preparation method thereof
CN105801739A (en) * 2016-04-11 2016-07-27 华南理工大学 Styrene acrylic emulsion and scrub-resistant high-PVC (pigment volume concentration) interior wall latex paint prepared from same
CN105968253A (en) * 2016-06-01 2016-09-28 嘉宝莉化工集团股份有限公司 Water-based self-extinction acrylic emulsion and preparation method and application thereof
CN106947302A (en) * 2017-04-06 2017-07-14 卢文书 A kind of net taste interfacial agents of net aldehyde and preparation method thereof
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CN110105819A (en) * 2019-05-08 2019-08-09 郑州大学 A kind of dedicated modifying interface agent of rock wool thin-coat plaster and preparation method thereof
CN110922821A (en) * 2019-12-17 2020-03-27 广东花王涂料有限公司 Moisture-proof, anti-falling and spot-rust-free interfacial agent and preparation method thereof
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CN104193289A (en) * 2014-08-27 2014-12-10 辽宁一一三(集团)化工有限责任公司 Hydrophobic protective paint and preparation method thereof
CN104387515A (en) * 2014-11-13 2015-03-04 常熟市万象涂料有限公司 Interface agent and preparation method thereof
CN104861792A (en) * 2015-05-22 2015-08-26 营口象圆新材料工程技术有限公司 Special alkali-resisting interfacial agent for phenolic foam insulation board
CN104861792B (en) * 2015-05-22 2018-04-03 营口象圆新材料工程技术有限公司 A kind of special alkaline-resisting interfacial agents of phenolic foam heat insulation plate
CN105400432A (en) * 2015-12-07 2016-03-16 三棵树涂料股份有限公司 Computerized color mixing external wall flat-coating basic deep-foundation paint and preparation method thereof
CN105801739B (en) * 2016-04-11 2018-09-14 华南理工大学 A kind of styrene-acrylic emulsion and the high PVC interiro wall latex paint of resistance to scrub prepared therefrom
CN105801739A (en) * 2016-04-11 2016-07-27 华南理工大学 Styrene acrylic emulsion and scrub-resistant high-PVC (pigment volume concentration) interior wall latex paint prepared from same
CN105968253A (en) * 2016-06-01 2016-09-28 嘉宝莉化工集团股份有限公司 Water-based self-extinction acrylic emulsion and preparation method and application thereof
CN105968253B (en) * 2016-06-01 2018-02-02 嘉宝莉化工集团股份有限公司 It is a kind of water-based from mat acrylic emulsion and preparation method and application
CN106947302A (en) * 2017-04-06 2017-07-14 卢文书 A kind of net taste interfacial agents of net aldehyde and preparation method thereof
CN107760230A (en) * 2017-11-15 2018-03-06 惠州市永耐宝新材料有限公司 A kind of waterproofing and leakage-stopping adhesive of high-bond and preparation method thereof
CN110105819A (en) * 2019-05-08 2019-08-09 郑州大学 A kind of dedicated modifying interface agent of rock wool thin-coat plaster and preparation method thereof
CN110922821A (en) * 2019-12-17 2020-03-27 广东花王涂料有限公司 Moisture-proof, anti-falling and spot-rust-free interfacial agent and preparation method thereof
CN112812633A (en) * 2020-12-28 2021-05-18 嘉宝莉化工集团股份有限公司 Direct-coating type multifunctional interface agent
CN112852245A (en) * 2021-03-17 2021-05-28 夏德斌 Gypsum board coating, preparation method and application
CN115216167A (en) * 2021-05-06 2022-10-21 湖南国彩新材料有限公司 Aluminum mould concrete interface agent and preparation method thereof
CN114525059A (en) * 2022-01-10 2022-05-24 上海三棵树防水技术有限公司 Waterproof coating with interface reinforcing effect and preparation method thereof
CN114702865A (en) * 2022-03-18 2022-07-05 贵州智慧快刻环保科技有限公司 Concrete interface agent for plastering gypsum and preparation and use methods thereof
CN115011191A (en) * 2022-05-11 2022-09-06 广东嘉宝莉科技材料有限公司 Interface treatment coating, preparation method thereof and building coating application

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