CN105694550A - Single-component waterborne inorganic terrace paint formula and manufacturing technology - Google Patents
Single-component waterborne inorganic terrace paint formula and manufacturing technology Download PDFInfo
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- CN105694550A CN105694550A CN201610148726.9A CN201610148726A CN105694550A CN 105694550 A CN105694550 A CN 105694550A CN 201610148726 A CN201610148726 A CN 201610148726A CN 105694550 A CN105694550 A CN 105694550A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses a single-component waterborne inorganic terrace paint formula and a manufacturing technology. A waterborne inorganic film-forming curing agent silicate and a small amount of organic silicon polymer emulsion serve as base materials, various kinds of pigment filler, quartz powder and an auxiliary are added, dispersed, ground and mixed, and single-component waterborne inorganic terrace paint is obtained. The bottom and the surface of the paint are combined, and the paint has the advantages that the paint is single in component and free of toxin and smell, does not contain formaldehyde, benzene, heavy metal and harmful matter, and is fireproof, retardant to flame, high in adhesive force and hardness, resistant to chemical corrosion, impact force, friction and washing, anti-slip, long in service life and easy and convenient to construct. The complicated technical operation that traditional terrace paint has two components and needs diluents, curing agents and the like is changed, the defects that the traditional terrace paint is inflammable, toxic and harmful and pollutes the environment are overcome, the complex technologies of bottom coating, middle coating and surface coating are simplified, and the single-component waterborne inorganic terrace paint is wide in application range, easy to maintain and high in cost performance.
Description
Technical field
The present invention relates to a kind of inorganic polymer, particularly relate to a kind of single-component water-based inorganic floor coatings formula and manufacturing technology。
Background technology
Current floor coatings is the employing raw material such as polyurethane resin, alcohol ester is host, adds pigment, solvent, and auxiliary agent, firming agent are through the floor decorative material of allotment, for instance the floor coatings such as epoxide terrace paint。Floor coatings, for beautifying, protecting ground, plays dust-proof, wear-resisting, cleaning, and moistureproof effect, so by modern industry ground, commercial ground, garage floor etc. widely uses and promotes。But floor coatings abnormal smells from the patient of the prior art weight, fire resistance property is poor, poor adhesive force, easy season cracking, flake, and can discharge, after particularly meeting high temperature, the ketone gas that a kind of toxicity is very big, a small amount of suction can make people poisoning；Because must use firming agent or diluent during two-component materials construction, operative's difficulty, hardening time is long；And needing the complicated technologies such as primary coat, middle painting, topcoating, the cycle that survives is long, time-consuming。Accordingly, it would be desirable to a kind of new coating is born。
Summary of the invention
The purpose of the present invention is that provides a kind of single-component water-based inorganic floor coatings formula and manufacturing technology to solve the problems referred to above。
The present invention is achieved through the following technical solutions above-mentioned purpose:
The present invention comprises the following steps:
(1) with parts by weight, the water of 20 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant is added successively in blender, speed is 300 revs/min, mixing time stirring in 15 minutes；
(2) adding the color stuffing of 20 parts, mixing speed is 1300 revs/min, mixing time stirring in 15 minutes；
(3) adding 15 parts of silica flours, mixing speed is 1300 revs/min, stirs stirring in 15 minutes；
(4) adding the organic silican polymer emulsion of 8 parts, speed 300 revs/min, mixing time is stirring in 15 minutes；
(5) add the redispersion latex powder of 3 parts, speed 300 revs/min, stir 10 minutes；
(6) add that 5 parts of terraces are green or 3 parts of terrace ashes, speed 300 revs/min, stir 10 minutes；
(7) add the thickening agent of 0.5 part, the defoamer of 0.2 part, speed 300 revs/min, stir 10 minutes, grind after obtain inorganic floor coatings。
Further, the modulus of described Lithium metasilicate is 3.6-4.0, and the modulus of described potassium silicate is 2.5-3.0, and described Ludox mean diameter is 7-10nm, and described silica flour is more than 120 orders
Further, described organic silicon emulsion is the silicone acrylic emulsion of model 996KD, and described inorganic dispersant is the silicate paint dispersant of model DISPERSOGENSPS, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Described redispersion latex powder is U.S. Yi Laitai 2350, and described color stuffing is made up of rutile titanium white lead, kaolin powder, Pulvis Talci, mica powder and wollastonite in powder, and in described step (6), toning pigment is that terrace is green or the grey inorganic mill base of terrace。
The beneficial effects of the present invention is:
The present invention is a kind of single-component water-based inorganic floor coatings formula and manufacturing technology, and compared with prior art, the present invention has the following technical effect that
(1) present invention adopts silicate solutions to have the compatibility natural with cement, concrete, can permeate basal plane, and basal plane solidifies one, makes film have superpower adhesive force, does not fall off, peeling, cracking。
(2) what the present invention adopted between silicate solutions is composite, and with Ludox blending and modifying, breakdown of emulsion occurs when making inorganic film forming liquid and organic silicon emulsion blended, anti-thick, viscosity substantially rises or even the risk of gel is substantially reduced, and makes the final coating prepared have good stability。
(3) present invention adopts the modified inorganic floor coatings of one-component of preparing of organic silicon emulsion, the shortcoming that use inorganic dispersant overcomes poor storage stability。The shortcoming using redispersion latex powder to overcome conventional inorganic coating easy to crack, increases hardness and the resistance to water of film simultaneously。
(3) present invention is by adding the functional materials such as titanium dioxide, Kaolin, Pulvis Talci, Muscovitum, wollastonite, silica flour, improves fire-retardant, hardness, rub resistance, scrubbing resistance, impact resistance and the chemical resistance of film。
(4) by the present invention in that with silicone acrylic emulsion, silicate is modified, make the final coating prepared form the microcrystalline texture with good water-proof breathable properties, simultaneously because silicon has self-cleaning function and anti-wear performance in the enrichment on surface。
(5) by the present invention in that with inorganic pigment terrace ash or the green toning of terrace, it is ensured that the feature of environmental protection and weatherability。
(6) inorganic floor coatings provided by the invention is fire-retardant, superpower hardness and adhesive force, rub resistance, scrubbing resistance, chemical resistance, VOC content is extremely low, and without harmful substances such as formaldehyde, stupid, heavy metals, technique is simple, with low cost。
Detailed description of the invention
The invention will be further described below:
The present invention comprises the following steps:
(1) with parts by weight, the water of 20 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant is added successively in blender, speed is 300 revs/min, mixing time stirring in 15 minutes；
(2) adding the color stuffing of 20 parts, mixing speed is 1300 revs/min, mixing time stirring in 15 minutes；
(3) adding 15 parts of silica flours, mixing speed is 1300 revs/min, stirs stirring in 15 minutes；
(4) adding the organic silican polymer emulsion of 8 parts, speed 300 revs/min, mixing time is stirring in 15 minutes；
(5) add the redispersion latex powder of 3 parts, speed 300 revs/min, stir 10 minutes；
(6) add that 5 parts of terraces are green or 3 parts of terrace ashes, speed 300 revs/min, stir 10 minutes；
(7) add the thickening agent of 0.5 part, the defoamer of 0.2 part, speed 300 revs/min, stir 10 minutes, grind after obtain inorganic floor coatings。,
Further, the modulus of described Lithium metasilicate is 3.6-4.0, and the modulus of described potassium silicate is 2.5-3.0, and described Ludox mean diameter is 7-10nm, and described silica flour is more than 120 orders
Further, described organic silicon emulsion is the silicone acrylic emulsion of model 996KD, and described inorganic dispersant is the silicate paint dispersant of model DISPERSOGENSPS, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Described redispersion latex powder is U.S. Yi Laitai 2350, and described color stuffing is made up of rutile titanium white lead, kaolin powder, Pulvis Talci, mica powder and wollastonite in powder, and in described step (6), toning pigment is that terrace is green or the grey inorganic mill base of terrace。
The present invention adopts Lithium metasilicate, potassium silicate, Ludox, modifiies the inorganic floor coatings making one-component with organic silicon emulsion, overcomes double; two groups or many component coatings complex process such as conventional epoxy terrace, becomes live time long, and the construction requirement time is long, the shortcoming that cost is high。Silicate and cement, concrete, the base materials such as polymers have the natural compatibility, can interpenetrate and combine together, adhesive force is superpower。The silica flour increase coating that the present invention adopts is hard, wear-resisting, the performance of impact resistance, stable chemical performance。The color stuffing that the present invention adopts is titanium dioxide, shape cloud powder, wollastonite in powder, kaolin powder, interacts, and after film forming, film is fine and close, and hydrone not easily permeates。The redispersion latex powder that the present invention adopts can increase hardness and the resistance to water of film。The pigment that the present invention adopts is inorganic pigment, without harmful substances such as heavy metals, colour-fast。Aqueous inorganic floor coatings is with its fire protection flame retarding, weatherability nonpoisonous and tasteless, superpower and adhesive force, hardness, impact resistance, rub resistance, scrubbing resistance, particularly do not produce electrostatic, adapt to various cement, concrete, the material basal planes such as polymers, can be used for the decoration in the various places such as office, family, factory, hospital, school, use scope widely。Raw material used arises directly from nature, and abundance is cheap。Also can select the difference of glossiness according to user, at film aqueous applied over or oiliness gloss oil。Therefore, inorganic floor coatings possesses wide market prospect。
The ultimate principle of the present invention is as follows: silicate is also referred to as waterglass, and the formula of waterglass molecular formula is M2O.mSiO2.nH2O, M can be sodium, potassium, lithium and 4 kinds of ions of ammonium, and m is modulus。(wherein, ammonium waterglass price is too high, sodium silicate cheap, but the resistance to water of sodium silicate is very poor, it is generally required to external reinforcement agent could meet the demand of reality。) membrane formation mechanism is waterglass and the CO2 in air reacts formation silica sol, evaporation along with moisture, dehydration forms inorganic silica link network shape macromole, but it is dispersed in the form of an ion in film due to alkali metal, when film meets water, film can destroy because of the dissociation of alkali metal ion, namely causes the poor water resistance of film。Conventional method of modifying has: the acid of waterglass is modified and the blending and modifying etc. of synthetic resin emulsion compound use, different types of waterglass。The present invention adopts organic silicon emulsion and silicate blending and modifying, the shortcoming overcoming its independent film forming poor water resistance。
Ludox membrane formation mechanism is, when Ludox dries out, monomeric silicic acid is polymerized gradually, and along with moisture evaporates, colloid molecules increases, and can form firmly Si-O-Si keyboard between SiO2 particle, then forms silica chain network structure, becomes continuous film。Owing in Ludox, the salt content of solubility is low, thus make film have good resistance to water, and Ludox is cheap。But due to pore effect, independent Ludox is as film forming matter, it is easy to occur that coating adhesion is poor, ftracture or even the phenomenon such as efflorescence。By adding a small amount of silicone acrylic emulsion by adding silicone acrylic emulsion, effectively raise the compatibility that organic-inorganic is biphase, avoid the Organic substance anti-thick initiated gel of breakdown of emulsion in storage process, make organic binder and inorganic filming substance form effective mutual network structure of interting, carry film-formation result further。
Owing to silicate and Ludox have very strong permeability, basal plane and cement can be permeated, concrete curing combine together, have superpower adhesive force。
Titanium dioxide, mica powder, kaolin powder, wollastonite in powder, the stable chemical natures such as Pulvis Talci and silicate have the natural compatibility, titanium dioxide improves the covering power of film, mica powder has good elasticity, toughness, insulating properties, high temperature resistant, acid and alkali-resistance, corrosion-resistant, the characteristics such as adhesive force is strong, Kaolin has very strong associativity, viscosity, suspension, its feature of wollastonite is nontoxic, resistance to chemical attack, heat stability and dimensionally stable are good, there are glass and pearly luster, low water absorption and oil factor, mechanical property and electrical property are excellent and have certain strengthening action, Pulvis Talci Talcum has lubricity, anti-glutinous, fluidizer, fire resistance, acid-resisting, insulating properties, fusing point is high, chemical torpescence, covering power is good, soft, good luster, the excellent physics such as absorption affinity is strong, chemical characteristic, these material mixing are mutually supplemented together and are defined one and have fire protection flame retarding, hardness is high, rub resistance, the coating of the functions such as antiacid alkali。
Silica flour is the silicate mineral of a kind of hard, wear-resisting, stable chemical performance。For the aggregate element of floor coatings, the further hardness increasing film and wearability。
Silicate is modified by silicone acrylic emulsion, makes the final coating prepared form the microcrystalline texture with good water-proof breathable properties, simultaneously because silicon has self-cleaning function and anti-wear performance in the enrichment on surface。
Terrace is green or terrace grey be ferrum oxide inorganic pigment, stable in properties, invariant color。
In sum, the inorganic floor coatings of novel environment friendly provided by the invention is with alkali silicate, Ludox is main film forming substance, total soluble-salt content in inorganic filming substance is reduced, avoid silicate poor water resistance, there is pore effect in the independent film forming of Ludox, thus improving resistance to water and the filming performance of coating, and keep coating ultimate cost cheap, modifiied by a small amount of organic silicon emulsion simultaneously, improve the early stage resistance to water of coating further, the coating making final preparation keeps ultrahigh hardness, rub resistance, super scrubbing resistance, impact resistance, stain resistant, good breathability；The inorganic powders such as titanium dioxide, Muscovitum, Kaolin, wollastonite combine, and make various performance optimize further；It is sterically hindered that the addition of inorganic dispersant increases SiO2 aggregate surface, it is possible to effectively prevent coating store or thermal histories in further condensation and gel, substantially prolongs effective storage time of coating；By adding silicone acrylic emulsion, effectively raise the compatibility that organic-inorganic is biphase, avoid the Organic substance anti-thick initiated gel of breakdown of emulsion in storage process, make organic binder and inorganic filming substance form effective mutual network structure of interting, carry film-formation result further。
The performance of the present invention such as following table:
The content (VOC) of total volatile organic compound is low, can meet environmental labelling product authentication techniques and require water paint GB24410-2009 standard, belong to Green Product。Owing to the compatibility of silicate is wide, the further brightening of the gloss oil such as aqueous, oiliness can be used above film or beautify。
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described。Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; described in above-described embodiment and description is that principles of the invention is described; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements both fall within the claimed scope of the invention。Claimed scope is defined by appending claims and equivalent thereof。
Claims (3)
1. a single-component water-based inorganic floor coatings formula and manufacturing technology, it is characterised in that comprise the following steps:
(1) with parts by weight, the water of 20 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant is added successively in blender, speed is 300 revs/min, mixing time stirring in 15 minutes；
(2) adding the color stuffing of 20 parts, mixing speed is 1300 revs/min, mixing time stirring in 15 minutes；
(3) adding 15 parts of silica flours, mixing speed is 1300 revs/min, stirs stirring in 15 minutes；
(4) adding the organic silican polymer emulsion of 8 parts, speed 300 revs/min, mixing time is stirring in 15 minutes；
(5) add the redispersion latex powder of 3 parts, speed 300 revs/min, stir 10 minutes；
(6) add that 5 parts of terraces are green or 3 parts of terrace ashes, speed 300 revs/min, stir 10 minutes；
(7) add the thickening agent of 0.5 part, the defoamer of 0.2 part, speed 300 revs/min, stir 10 minutes, grind after obtain single-component water-based inorganic floor coatings。
2. single-component water-based inorganic floor coatings formula according to claim 1 and manufacture method, it is characterized in that: the modulus of described Lithium metasilicate is 3.6-4.0, the modulus of described potassium silicate is 2.5-3.0, and described Ludox mean diameter is 7-10nm, and described silica flour is more than 120 orders。
3. single-component water-based inorganic floor coatings formula according to claim 1 and manufacturing technology, it is characterized in that: described organic silicon emulsion is the silicone acrylic emulsion of model 996KD, described inorganic dispersant is the silicate paint dispersant of model DISPERSOGENSPS, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Described redispersion latex powder is U.S. Yi Laitai 2350, and described color stuffing is made up of rutile titanium white lead, kaolin powder, Pulvis Talci, mica powder and wollastonite in powder, and in described step (6), toning pigment is that terrace is green or the grey inorganic mill base of terrace。
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| CN107779090A (en) * | 2017-10-18 | 2018-03-09 | 厦门固克涂料集团有限公司 | Coating of the compound organic fluorinated silicone of inorganic silicic acid lithium potassium solution and preparation method thereof |
| CN108441080A (en) * | 2018-04-25 | 2018-08-24 | 上海嘉柏丽实业有限公司 | A kind of pseudo-classic floor coatings of aqueous inorganic |
| CN108912755A (en) * | 2018-05-29 | 2018-11-30 | 佛山市顺德区雅成化工有限公司 | A kind of preparation method of aqueous inorganic paint |
| CN109651856A (en) * | 2017-10-12 | 2019-04-19 | 石河子大学 | A kind of novel inorganic expansion fire-resistant coating for steel structure and preparation method thereof |
| EP3301138B1 (en) | 2016-09-30 | 2019-05-08 | Daw Se | Aqueous treatment mass for building walls, ceilings or floors |
| CN111019415A (en) * | 2019-12-23 | 2020-04-17 | 广州市维思涂料科技有限公司 | Water-based inorganic mineral composite floor coating and preparation method thereof |
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| CN111647329A (en) * | 2020-07-14 | 2020-09-11 | 上海保立佳新材料有限公司 | Single-component waterproof high-hardness water-based floor paint and preparation method thereof |
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| CN112662211A (en) * | 2021-01-18 | 2021-04-16 | 河南圣德哥尔无机水性涂料有限公司 | Inorganic floor gloss oil, inorganic floor gloss oil dispersion method and dispersion equipment |
| CN113278313A (en) * | 2021-04-29 | 2021-08-20 | 亚士创能科技(乌鲁木齐)有限公司 | Single-component water-based inorganic coating and preparation method and application thereof |
| CN114989643A (en) * | 2022-05-22 | 2022-09-02 | 中德新亚建筑材料有限公司 | Single-component wear-resistant anticorrosion water-based inorganic terrace composite material and preparation method thereof |
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