WO2013020345A1 - All-in-one water-borne inorganic-organic hybrid architectural coating and method for preparing same - Google Patents

All-in-one water-borne inorganic-organic hybrid architectural coating and method for preparing same Download PDF

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WO2013020345A1
WO2013020345A1 PCT/CN2011/084865 CN2011084865W WO2013020345A1 WO 2013020345 A1 WO2013020345 A1 WO 2013020345A1 CN 2011084865 W CN2011084865 W CN 2011084865W WO 2013020345 A1 WO2013020345 A1 WO 2013020345A1
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parts
water
resistance
inorganic
tego
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PCT/CN2011/084865
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French (fr)
Chinese (zh)
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瞿金清
彭刚阳
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华南理工大学
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/028—Pigments; Filters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm

Definitions

  • the invention relates to the field of interior and exterior latex paints, in particular to inorganic high molecular polymers, in particular to inorganic-organic hybrid coatings.
  • Water-based inorganic coatings have attracted widespread attention due to their high hardness, excellent weather resistance, stain resistance, good gas permeability, long-term heat resistance and environmental friendliness.
  • Today's 'E-E' (Ecomomy, Efficiency, Energy, Ecology , that is, economic, efficient, energy-saving, ecological) has become the basic principle of human development, and the raw materials used in inorganic coatings come directly from nature, rich in source and low in price. Therefore, inorganic coatings have broad market prospects.
  • water-based inorganic coatings can be divided into three categories: alkali metal silicate coatings, silica sol coatings and phosphate coatings.
  • the coating is prepared by using silicate alone, the coating film has insufficient early water resistance, large shrinkage, and easy cracking.
  • the preparation of coatings with silica sol alone may have disadvantages such as poor decorativeness of the coating film, poor adhesion, and easy pulverization, which greatly hinder the application and promotion of inorganic coatings.
  • the water-based wall coating prepared by mixing silica sol with alkali metal silicate has excellent water resistance, fire resistance, abrasion resistance and stain resistance. However, its film forming property is poor, the film forming material is brittle, and easy to use. Fall off.
  • the use of organic polymer emulsion modification can improve the film formation of inorganic coatings, often resulting in reduced storage stability.
  • the invention adopts inorganic materials such as aqueous lithium silicate, potassium silicate and silica sol, and is blended with an organic polymer emulsion as a one-component inorganic material /
  • the organic hybrid base material prepares an inorganic material which is environmentally friendly, non-toxic, heat-insulating, super-scratch-resistant, wear-resistant, yellowing-resistant, anti-aging, lotus leaf anti-fouling, gas permeability and sound insulation.
  • Organic hybrid architectural coatings The invention overcomes the defects that the traditional two-component inorganic coating is easy to crack, poor in decorativeness and poor in storage stability, and has excellent properties of inorganic coating and organic coating.
  • the object of the present invention is to overcome the above-mentioned deficiencies in the prior art, and to provide a multi-effect water-based inorganic-organic hybrid architectural coating and a preparation method thereof, which are environmentally friendly, non-toxic, heat-insulating, super-scratch-resistant, Wear-resistant, yellowing-resistant, anti-aging, anti-fouling, breathable and sound-proof functions, while overcoming the shortcomings of traditional inorganic coatings, poor storage stability, easy cracking of coatings, poor decorativeness or the use of two-component packaging .
  • the object of the present invention is achieved by the following technical solutions.
  • the invention discloses a preparation method of multi-effect water-based inorganic-organic hybrid architectural coating, which uses inorganic film-forming material and organic polymer emulsion as a base material, and adds various pigment fillers or functional fillers and various auxiliary agents. Made by pulping, grinding and painting.
  • the preparation method comprises the following steps: 1) In terms of parts by weight, 20-30 parts of water, 0.1-0.5 parts of a wetting agent, 0-0.4 parts of a dispersing agent, 0-1 parts of a pH adjusting agent, 0.1-0.5 parts of an antifoaming agent are sequentially added.
  • the stirring speed in the step 1) is 300-500 rpm
  • the stirring time is 15-30 minutes
  • the stirring speed in the step 2) is 1000-1500 rpm, stirring.
  • the time is 15-30 minutes
  • the stirring speed is 300-500 rpm
  • the stirring time is 5-15 minutes.
  • the modulus of the lithium silicate is 3.6-4.8
  • the modulus of potassium silicate is 2.5-3.6
  • the average particle diameter of the silica sol is 7-30 nm
  • the organic polymer emulsion may be J-998A of Badrich, 296 DS of BASF, SD-2000 of Rohm and Haas, maincote 8104, one or more of TBH-1 of Jiangsu Sunrise Group.
  • the stabilizer may be DISPERSOGEN SPS, DISPERSOGEN of Clariant SPV, DM-042 of Hubei Debon Chemical Co., Ltd., one or more of DEGO-1300, TEGO-1400, TEGO-1500N of Degussa Company.
  • the organosiloxane may be Dynasylan Hydrosil 2926, Dynasylan of Degussa Corporation. GLYEO, KH560, KH570 of Hubei New Blue Sky New Materials Co., Ltd., one or more of Z-6040 and Z-6030 of Dow Corning Corporation of the United States.
  • auxiliaries of the present invention are similar to the conventional architectural latex paint, and as a further optimized technical solution of the above preparation method, specifically include:
  • the wetting agent may be one or a mixture of two or more of Degussa's TEGO-245, TEGO-500, BYK-346 of the German BAK company, and CO-630 of Rodia's company;
  • the agent may be one or more of Rohm and Haas OROTAN fast dispersing agent, sodium hexametaphosphate, BKY-151, BYK-154, BYK-155 of the German BAK company;
  • the pH adjuster It may be one or more of AMP-95, N,N-dimethylethanolamine (DMEA), aqueous ammonia, diethanolamine, and triethylamine.
  • the defoaming agent may be BYK-011, BYK-012 of German BAK, TEGO-800 of Degussa, TEGO-805, TEGO-810, DF-681 of Rodia, and Pispelair of Blackburn. CF439, Nopco of Haichuan Chemical a mixture of one or more of 267-A.
  • the film-forming auxiliary agent may be propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, tripropylene glycol butyl ether, propylene glycol methyl ether acetate, propylene glycol butyl ether acetate and dipropylene glycol methyl ether acetate. ,2, 2, 4-trimethyl-1, One or more of 3-pentanediol monoisobutyrate.
  • the antifreeze agent may be one or both of ethylene glycol and propylene glycol.
  • the thickener may be one or more of HYS-30000 of Clariant Co., Ltd., alkali swell thickeners TT-935, ASE-60 of Rohm and Haas Company.
  • the pigment filler may be one or more of titanium white powder, heavy calcium carbonate, kaolin, talc powder, hollow glass microbeads, and infrared ceramic powder.
  • the anti-mold fungicide may be a Clarien company Nipacide C 115, Nipacide CFX-3, Nipacide BIT 20, one or more of NB-200 and TB-203 of Guangdong Tianchen Biotechnology Co., Ltd.
  • Silicate inorganic coatings are also called water glass based inorganic coatings, and the molecular formula of water glass is M2O.m SiO2.
  • M can be four kinds of ions of sodium, potassium, lithium and ammonium, and m is a modulus.
  • the price of lithium water glass and ammonium water glass is too high, the price of sodium water glass is low, and the application range is the widest, but the water resistance of sodium water glass is very poor, and generally requires an external curing agent to meet the actual demand.
  • the film formation mechanism of this kind of inorganic coating is that the water glass reacts with CO2 in the air to form a silicic acid sol.
  • the silica sol coating is an inorganic coating prepared by mixing an aqueous dispersion of colloidal silica as a film-forming substance, mixing a pigment, a filler, and an auxiliary agent.
  • the film formation mechanism is that when the silica sol loses moisture, the monomeric silicic acid gradually polymerizes, and as the water evaporates, the colloidal molecules increase, and a strong Si-O-Si bond surface can be formed between the SiO2 particles, thereby forming a silicon oxide chain.
  • the mesh structure becomes a continuous coating film. Due to the low content of soluble salts in the silica sol, the coating film has good water resistance, and the silica sol is inexpensive, and has been widely used as an research and application of organic/inorganic hybrid coatings. Due to the capillary effect, silica sol alone is used as a film-forming material, which tends to cause poor adhesion, cracking, and even pulverization of the coating.
  • the novel environmentally-friendly inorganic architectural coating uses alkali metal silicate and silica sol as main film-forming substances, so that the total soluble salt content in the inorganic film-forming material is reduced, and the silica sol alone is prevented from being formed into a film.
  • the capillary effect improves the water resistance and film forming properties of the coating, and keeps the final cost of the coating low.
  • the early water resistance of the coating is further improved by a small amount of organic emulsion modification, so that the final prepared coating maintains ultra-high hardness and resistance.
  • the present invention has the following advantages and beneficial effects: (1)
  • the present invention adopts a compounding between silicate solutions and blends with a silica sol to modify, so that the inorganic film forming solution is broken when blended with the organic emulsion.
  • the milk, the anti-coarse, the viscosity is obviously increased, and the risk of the gel is greatly reduced, so that the finally obtained coating forms a micro-crystal structure with good waterproof and gas permeability, and has self-cleaning function and resistance due to the enrichment of silicon on the surface.
  • the invention adopts organic emulsion modification to prepare one-component inorganic architectural coatings, and at the same time adds appropriate stabilizers, which overcomes the problems of easy cracking, two-component, poor decoration and poor storage stability of traditional inorganic coatings. Disadvantages; (3)
  • the invention has the advantages of low thermal conductivity of the inorganic film-forming material by adding functional filler (glass microbead, infrared ceramic powder), and the final prepared coating has excellent thermal insulation performance; 4)
  • the invention improves the early resistance water and scrub resistance of the coating by adding silicone coupling modification;
  • the inorganic building coating provided by the invention has excellent performance , The VOC content is low, can be reduced or avoided coalescent content, simple process, low cost, excellent anti-aging properties.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, no added filming aids, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, fast drying speed, no need to add filming aids, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coating described in the present example has good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, good waterproof and gas permeability, no need to add a film forming auxiliary, and a total volatile organic compound content ( TVOC ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent stain resistance, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, extremely short surface drying time, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, and excellent thermal insulation performance, and the temperature difference can reach 15 °C, no added filming aid, low total volatile organic compound content (TVOC), can meet the environmental marking product certification technical requirements water-based paint GB24410-2009
  • the standard is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging and staining, good wear resistance, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent artificial aging resistance, no added filming aid, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
  • the inorganic architectural coating described in the present example has good storage stability, excellent washing resistance, good chemical resistance, excellent artificial aging resistance, good sound insulation effect, no addition of film forming auxiliary, and total volatile organic compound content ( TVOC ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.

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Abstract

An all-in-one water-borne inorganic-organic hybrid architectural coating and a method for preparing same. The all-in-one water-borne inorganic-organic hybrid architectural coating is prepared by taking a compounded product of a silica sol, silicate water-borne inorganic film-forming matter and an organic polymer emulsion as a base material through the steps of adding various pigments/fillers and auxiliaries into the base material, then carrying out beating, grinding and paint mixing on the obtained mixture. The coating has various functions such as environmental friendliness, non-toxicity, thermal insulation, ultra scrubbing resistance, abrasion resistance, yellowing resistance, ageing resistance, fouling resistance, good air permeability, and sound insulation.

Description

一种多效合一水性无机 - 有机杂化建筑涂料及其制备方法  Multi-effect integrated water-based inorganic-organic hybrid architectural coating and preparation method thereof
技术领域Technical field
本发明涉及内外墙乳胶漆领域，特别涉及到无机高分子聚合物，具体涉及无机 - 有机杂化涂料。  The invention relates to the field of interior and exterior latex paints, in particular to inorganic high molecular polymers, in particular to inorganic-organic hybrid coatings.
背景技术Background technique
水性无机涂料以其高硬度、优异的耐候性、耐沾污性、良好的透气性、长期的耐热性和环境友好性引起人们的广泛关注，现今'四 E '（ Ecomomy 、 Efficiency 、 Energy 、 Ecology ，即经济性、高效、节能、生态）已成为人类发展所共同遵循的基本原则，而无机涂料所用的原材料直接来自于自然界，来源丰富，价格低廉。因此，无机涂料具备广阔的市场前景。 Water-based inorganic coatings have attracted widespread attention due to their high hardness, excellent weather resistance, stain resistance, good gas permeability, long-term heat resistance and environmental friendliness. Today's 'E-E' (Ecomomy, Efficiency, Energy, Ecology , that is, economic, efficient, energy-saving, ecological) has become the basic principle of human development, and the raw materials used in inorganic coatings come directly from nature, rich in source and low in price. Therefore, inorganic coatings have broad market prospects.
水性无机涂料按照成膜物质种类可分为碱金属硅酸盐涂料、硅溶胶涂料、磷酸盐涂料三大类。单独用硅酸盐制备涂料时，涂膜存在早期耐水性不佳、收缩率大、易开裂等不足。单独用硅溶胶制备涂料则会出现涂膜装饰性不好、附着力差、易粉化等缺点，这些都极大阻碍了无机涂料的应用推广。硅溶胶与碱金属硅酸盐混合制备的水性墙体涂料，其涂膜具有优异的耐水、耐火、耐磨和耐沾污等特性，然其成膜性差，成膜物易脆，使用时易脱落。采用有机聚合物乳液改性可以提高无机涂料的成膜性，常常导致贮存稳定性降低。 According to the type of film-forming materials, water-based inorganic coatings can be divided into three categories: alkali metal silicate coatings, silica sol coatings and phosphate coatings. When the coating is prepared by using silicate alone, the coating film has insufficient early water resistance, large shrinkage, and easy cracking. The preparation of coatings with silica sol alone may have disadvantages such as poor decorativeness of the coating film, poor adhesion, and easy pulverization, which greatly hinder the application and promotion of inorganic coatings. The water-based wall coating prepared by mixing silica sol with alkali metal silicate has excellent water resistance, fire resistance, abrasion resistance and stain resistance. However, its film forming property is poor, the film forming material is brittle, and easy to use. Fall off. The use of organic polymer emulsion modification can improve the film formation of inorganic coatings, often resulting in reduced storage stability.
本发明采用水性硅酸锂、硅酸钾、硅溶胶等无机材料，与有机聚合物乳液共混作为单组份的无机 / 有机杂化基料，制备了一种环保无毒、保温隔热、超耐擦洗、耐磨、耐黄变、抗老化、荷叶抗污、透气性和隔音等多种功能的无机 - 有机杂化建筑涂料。本发明克服了传统双组份无机涂料易开裂、装饰性不佳和贮存稳定性差的缺点，兼具无机涂层和有机涂层优异性能。 The invention adopts inorganic materials such as aqueous lithium silicate, potassium silicate and silica sol, and is blended with an organic polymer emulsion as a one-component inorganic material / The organic hybrid base material prepares an inorganic material which is environmentally friendly, non-toxic, heat-insulating, super-scratch-resistant, wear-resistant, yellowing-resistant, anti-aging, lotus leaf anti-fouling, gas permeability and sound insulation. Organic hybrid architectural coatings. The invention overcomes the defects that the traditional two-component inorganic coating is easy to crack, poor in decorativeness and poor in storage stability, and has excellent properties of inorganic coating and organic coating.
发明内容Summary of the invention
本发明的目的在于克服现有技术存在的上述不足，提供一种多效合一水性无机-有机杂化建筑涂料及其制备方法，所述涂料具有环保无毒、保温隔热、超耐擦洗、耐磨、耐黄变、抗老化、荷叶抗污、透气性和隔音等多种功能，同时克服传统无机涂料储存稳定性差、涂膜易开裂、装饰性不佳或采用双组份包装等缺点。本发明的目的通过以下技术方案实现。The object of the present invention is to overcome the above-mentioned deficiencies in the prior art, and to provide a multi-effect water-based inorganic-organic hybrid architectural coating and a preparation method thereof, which are environmentally friendly, non-toxic, heat-insulating, super-scratch-resistant, Wear-resistant, yellowing-resistant, anti-aging, anti-fouling, breathable and sound-proof functions, while overcoming the shortcomings of traditional inorganic coatings, poor storage stability, easy cracking of coatings, poor decorativeness or the use of two-component packaging . The object of the present invention is achieved by the following technical solutions.
一种多效合一水性无机-有机杂化建筑涂料的制备方法，采用无机成膜物与有机聚合物乳液复配作为基料，并添加多种颜填料或功能性填料和各类助剂经打浆、研磨、调漆工艺制得。制备方法包括下列步骤： 1）以重量份计，依次加入20-30份的水、0.1-0.5份的润湿剂、0-0.4份的分散剂、0-1份的pH调节剂、0.1-0.5份的消泡剂、0-2份的成膜助剂、0.5-2份的防冻剂、0.1-0.4份的增稠剂、10-25份的硅溶胶、0-10份的硅酸锂溶液、0-5份的硅酸钾溶液、0.1-1份的稳定剂、0.1-1份的有机硅氧烷，搅拌； 2）加入30-45份的颜填料，搅拌； 3）依次加入0-5份的水、0.1-0.5份的防霉杀菌剂、5-15份的有机聚合物乳液、0.2-1.5份的增稠剂、0.1-0.5份的消泡剂，搅拌得所述建筑涂料。The invention discloses a preparation method of multi-effect water-based inorganic-organic hybrid architectural coating, which uses inorganic film-forming material and organic polymer emulsion as a base material, and adds various pigment fillers or functional fillers and various auxiliary agents. Made by pulping, grinding and painting. The preparation method comprises the following steps: 1) In terms of parts by weight, 20-30 parts of water, 0.1-0.5 parts of a wetting agent, 0-0.4 parts of a dispersing agent, 0-1 parts of a pH adjusting agent, 0.1-0.5 parts of an antifoaming agent are sequentially added. 0-2 parts of film-forming aid, 0.5-2 parts of antifreeze, 0.1-0.4 parts of thickener, 10-25 parts of silica sol, 0-10 parts of lithium silicate solution, 0-5 parts a potassium silicate solution, 0.1-1 part of a stabilizer, 0.1-1 part of an organosiloxane, and stirred; 2) Add 30-45 parts of pigment filler and stir; 3) sequentially adding 0-5 parts of water, 0.1-0.5 parts of mold-proof fungicide, 5-15 parts of organic polymer emulsion, 0.2-1.5 parts of thickener, 0.1-0.5 parts of antifoaming agent, stirring The architectural coating was obtained.
作为上述制备方法的进一步优化的技术方案，步骤1）中所述搅拌速度为300-500转/分，搅拌时间15-30分钟；步骤2）所述搅拌速度为1000-1500转/分，搅拌时间15-30分钟；步骤3）所述搅拌速度为300-500转/分，搅拌时间为5-15分钟。As a further optimized technical solution of the above preparation method, the stirring speed in the step 1) is 300-500 rpm, the stirring time is 15-30 minutes; the stirring speed in the step 2) is 1000-1500 rpm, stirring. The time is 15-30 minutes; the stirring speed is 300-500 rpm, and the stirring time is 5-15 minutes.
作为上述制备方法的进一步优化的技术方案：所述硅酸锂的模数为3.6-4.8，硅酸钾的模数为2.5-3.6，硅溶胶平均粒径为7-30nm； 所述的有机聚合物乳液可以是巴德富公司的J-998A、巴斯夫公司的296 DS、罗门哈斯的SD-2000、maincote 8104、江苏日出集团的TBH-1中的一种或多种。 所述的稳定剂可以是科莱恩公司的DISPERSOGEN SPS、DISPERSOGEN SPV、湖北德邦化工有限公司的DM-042、Degussa公司的TEGO-1300、TEGO-1400、TEGO-1500N中的一种或多种。 所述的有机硅氧烷可以是Degussa公司的Dynasylan Hydrosil 2926、Dynasylan GLYEO、湖北新蓝天新材料股份有限公司的KH560、KH570，美国道康宁公司的Z-6040、Z-6030的一种或多种。As a further optimized technical solution of the above preparation method, the modulus of the lithium silicate is 3.6-4.8, the modulus of potassium silicate is 2.5-3.6, and the average particle diameter of the silica sol is 7-30 nm; The organic polymer emulsion may be J-998A of Badrich, 296 DS of BASF, SD-2000 of Rohm and Haas, maincote 8104, one or more of TBH-1 of Jiangsu Sunrise Group. The stabilizer may be DISPERSOGEN SPS, DISPERSOGEN of Clariant SPV, DM-042 of Hubei Debon Chemical Co., Ltd., one or more of DEGO-1300, TEGO-1400, TEGO-1500N of Degussa Company. The organosiloxane may be Dynasylan Hydrosil 2926, Dynasylan of Degussa Corporation. GLYEO, KH560, KH570 of Hubei New Blue Sky New Materials Co., Ltd., one or more of Z-6040 and Z-6030 of Dow Corning Corporation of the United States.
本发明其他助剂与常规建筑乳胶漆类似，作为上述制备方法的进一步优化的技术方案，具体包括：The other auxiliaries of the present invention are similar to the conventional architectural latex paint, and as a further optimized technical solution of the above preparation method, specifically include:
所述的润湿剂可以是Degussa公司的TEGO-245、TEGO-500、德国比克公司的BYK－346和罗迪亚公司的CO-630中的一种或两种以上混合物；所述的分散剂可以是罗门哈斯公司的OROTAN快易分散剂、六偏磷酸钠、德国比克公司的BKY-151、BYK-154、BYK-155中的一种或多种；所述的pH调节剂可以是AMP-95、N，N-二甲基乙醇胺（DMEA）、氨水、二乙醇胺、三乙胺中的一种或多种。所述的消泡剂可以是德国比克公司的BYK-011、BYK-012、Degussa公司的TEGO－800、TEGO－805、TEGO－810、罗迪亚公司的DF-681、布莱克本公司的pispelair CF439、海川化工的Nopco 267-A中的一种或多种以上的混合物。所述的成膜助剂可以是丙二醇甲醚、丙二醇丁醚、二丙二醇甲醚、二丙二醇丁醚、三丙二醇丁醚、丙二醇甲醚醋酸酯、丙二醇丁醚醋酸酯和二丙二醇甲醚醋酸酯、2, 2, 4－三甲基－1, 3－戊二醇单异丁酸酯中的一种或两种以上。所述的防冻剂可以是乙二醇、丙二醇中的一种或两种。所述的增稠剂可以是科莱恩公司的HYS-30000、罗门哈斯公司的碱溶胀增稠剂TT-935、ASE-60中的一种或者两种以上。所述的颜填料可以是钛白粉、重质碳酸钙、高岭土、滑石粉、空心玻璃微珠、红外陶瓷粉中的一种或多种。所述的防霉杀菌剂可以是科莱恩公司的Nipacide C 115、Nipacide CFX-3、Nipacide BIT 20、广东天辰生物技术有限公司的NB-200、TB-203的一种或多种。 The wetting agent may be one or a mixture of two or more of Degussa's TEGO-245, TEGO-500, BYK-346 of the German BAK company, and CO-630 of Rodia's company; The agent may be one or more of Rohm and Haas OROTAN fast dispersing agent, sodium hexametaphosphate, BKY-151, BYK-154, BYK-155 of the German BAK company; the pH adjuster It may be one or more of AMP-95, N,N-dimethylethanolamine (DMEA), aqueous ammonia, diethanolamine, and triethylamine. The defoaming agent may be BYK-011, BYK-012 of German BAK, TEGO-800 of Degussa, TEGO-805, TEGO-810, DF-681 of Rodia, and Pispelair of Blackburn. CF439, Nopco of Haichuan Chemical a mixture of one or more of 267-A. The film-forming auxiliary agent may be propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, tripropylene glycol butyl ether, propylene glycol methyl ether acetate, propylene glycol butyl ether acetate and dipropylene glycol methyl ether acetate. ,2, 2, 4-trimethyl-1, One or more of 3-pentanediol monoisobutyrate. The antifreeze agent may be one or both of ethylene glycol and propylene glycol. The thickener may be one or more of HYS-30000 of Clariant Co., Ltd., alkali swell thickeners TT-935, ASE-60 of Rohm and Haas Company. The pigment filler may be one or more of titanium white powder, heavy calcium carbonate, kaolin, talc powder, hollow glass microbeads, and infrared ceramic powder. The anti-mold fungicide may be a Clarien company Nipacide C 115, Nipacide CFX-3, Nipacide BIT 20, one or more of NB-200 and TB-203 of Guangdong Tianchen Biotechnology Co., Ltd.
本发明的基本原理如下：The basic principles of the invention are as follows:
硅酸盐无机涂料也称水玻璃基无机涂料，水玻璃分子式的通式为M2O .m SiO2. nH2O，M可以是钠、钾、锂和铵4种离子，m为模数。其中，锂水玻璃和铵水玻璃价格太高，钠水玻璃的价格低廉，应用范围最广，但钠水玻璃的耐水性很差，一般需要外加固化剂才能满足实际的需求。此类无机涂料的成膜机理为水玻璃与空气中的CO2反应形成硅酸溶胶，随着水分的蒸发，脱水形成无机硅氧链网状大分子，但由于碱金属以离子形式分散在涂膜中，当涂膜遇水时，涂膜会因碱金属离子的离解而破坏，即造成涂膜的耐水性差。常用的改性方法有：水玻璃的酸改性、与合成树脂乳液复合使用、不同种类的水玻璃的共混改性等。 硅溶胶涂料是以胶体二氧化硅的水分散液为成膜物质，混以颜料、填料、助剂搅拌研磨分散调制而成的一种无机涂料。其成膜机理是，在硅溶胶失去水分时，单体硅酸逐渐聚合，随着水分蒸发，胶体分子增大，SiO2粒子间能形成牢固的Si-O-Si键面，继而形成硅氧链网状结构，成为连续涂膜。由于硅溶胶中可溶性的盐分含量低，因而使涂膜具有较好的耐水性，并且硅溶胶价格低廉，已经广泛用作有机/无机杂化涂料的研究和应用。由于毛细孔效应，单独用硅溶胶作为成膜物，容易发生涂层附着力差、开裂甚至是粉化等现象。 综上所述，本发明提供的新型环保无机建筑涂料以碱金属硅酸盐、硅溶胶为主要成膜物质，使得无机成膜物中的总可溶性盐含量降低，避免了硅溶胶单独成膜出现毛细孔效应，从而改善涂料的耐水性和成膜性能，并保持涂料最终成本低廉，同时通过少量的有机乳液改性，进一步提高涂料的早期耐水性，使最终制备的涂料保持超高硬度、耐磨、超耐擦洗、耐黄变、耐沾污、良好的透气性的同时，其机械性能以及热应变性能得到改善；利用无机成膜物导热系数低的特点，通过添加功能性填料（玻璃微珠、陶瓷粉）使涂料具备保温隔热、隔音等特性；涂料中的稳定剂因其特殊的分子结构，加大了SiO2聚集体表面空间位阻，能够有效的防止基料在储存或受热过程中的进一步缩合而凝胶，大大延长了基料的有效储存时间；通过添加有机硅氧烷，有效的提高了有机无机两相的相容性，避免了有机相在储存过程中破乳反粗引发凝胶，使有机成膜物和无机成膜物形成有效的穿插交互的网络结构，与此同时带来的疏水改性也进一步提高了涂料的对底材的附着、耐擦洗性能和荷叶抗污性能。Silicate inorganic coatings are also called water glass based inorganic coatings, and the molecular formula of water glass is M2O.m SiO2. nH2O, M can be four kinds of ions of sodium, potassium, lithium and ammonium, and m is a modulus. Among them, the price of lithium water glass and ammonium water glass is too high, the price of sodium water glass is low, and the application range is the widest, but the water resistance of sodium water glass is very poor, and generally requires an external curing agent to meet the actual demand. The film formation mechanism of this kind of inorganic coating is that the water glass reacts with CO2 in the air to form a silicic acid sol. As the water evaporates, it dehydrates to form an inorganic silicon oxide chain network macromolecule, but the alkali metal is dispersed in the coating film in the form of ions. In the case where the coating film is in contact with water, the coating film is destroyed by the dissociation of the alkali metal ions, that is, the water resistance of the coating film is poor. Commonly used modification methods include: acid modification of water glass, composite use with synthetic resin emulsion, and blending modification of different types of water glass. The silica sol coating is an inorganic coating prepared by mixing an aqueous dispersion of colloidal silica as a film-forming substance, mixing a pigment, a filler, and an auxiliary agent. The film formation mechanism is that when the silica sol loses moisture, the monomeric silicic acid gradually polymerizes, and as the water evaporates, the colloidal molecules increase, and a strong Si-O-Si bond surface can be formed between the SiO2 particles, thereby forming a silicon oxide chain. The mesh structure becomes a continuous coating film. Due to the low content of soluble salts in the silica sol, the coating film has good water resistance, and the silica sol is inexpensive, and has been widely used as an research and application of organic/inorganic hybrid coatings. Due to the capillary effect, silica sol alone is used as a film-forming material, which tends to cause poor adhesion, cracking, and even pulverization of the coating. In summary, the novel environmentally-friendly inorganic architectural coating provided by the invention uses alkali metal silicate and silica sol as main film-forming substances, so that the total soluble salt content in the inorganic film-forming material is reduced, and the silica sol alone is prevented from being formed into a film. The capillary effect improves the water resistance and film forming properties of the coating, and keeps the final cost of the coating low. At the same time, the early water resistance of the coating is further improved by a small amount of organic emulsion modification, so that the final prepared coating maintains ultra-high hardness and resistance. Grinding, super-resistance, yellowing resistance, stain resistance, good gas permeability, improved mechanical properties and thermal strain properties; using inorganic film-forming materials with low thermal conductivity, by adding functional fillers (glass micro Beads and ceramic powders make the coatings have the characteristics of heat insulation, sound insulation and the like; the stabilizer in the coating increases the steric hindrance of the surface of the SiO2 aggregate due to its special molecular structure, and can effectively prevent the base material from being stored or heated. Further condensation in the gel, greatly extending the effective storage time of the base; effectively increasing the addition of organosiloxane The compatibility of the inorganic two phases prevents the organic phase from breaking the emulsion and causing the gel during the storage process, so that the organic film-forming material and the inorganic film-forming material form an effective interpenetrating interaction network structure, at the same time Hydrophobic modification also further enhances the adhesion of the coating to the substrate, scrub resistance and leaf antifouling properties.
总体上，本发明具有如下优点及有益效果： （1）本发明采用硅酸盐溶液之间的复配，并与硅溶胶共混改性，使得无机成膜液与有机乳液共混时发生破乳、反粗、黏度明显上升乃至凝胶的风险大大降低，使最终制得的涂料形成具有良好的防水透气性的微晶体结构，同时由于硅在表面的富集而具有自洁功能和耐磨性能； （2）本发明采用有机乳液改性制备单组份无机建筑涂料，同时添加了适当的稳定剂，克服了传统无机涂料易开裂、双组份、装饰性不佳、储存稳定性差的缺点； （3）本发明通过添加功能性填料（玻璃微珠、红外陶瓷粉），同时利用无机成膜物自身低导热系数的优点，使最终制得的涂料具有优良的保温隔热性能； （4）本发明通过添加有机硅偶联改性，最终提高了涂料的早期耐性水和耐擦洗性能；（5）本发明提供的无机建筑涂料性能优异，VOC含量极低，可减少或避免成膜助剂的含量，工艺简单，成本低廉，抗老化性能优异。 In general, the present invention has the following advantages and beneficial effects: (1) The present invention adopts a compounding between silicate solutions and blends with a silica sol to modify, so that the inorganic film forming solution is broken when blended with the organic emulsion. The milk, the anti-coarse, the viscosity is obviously increased, and the risk of the gel is greatly reduced, so that the finally obtained coating forms a micro-crystal structure with good waterproof and gas permeability, and has self-cleaning function and resistance due to the enrichment of silicon on the surface. (2) The invention adopts organic emulsion modification to prepare one-component inorganic architectural coatings, and at the same time adds appropriate stabilizers, which overcomes the problems of easy cracking, two-component, poor decoration and poor storage stability of traditional inorganic coatings. Disadvantages; (3) The invention has the advantages of low thermal conductivity of the inorganic film-forming material by adding functional filler (glass microbead, infrared ceramic powder), and the final prepared coating has excellent thermal insulation performance; 4) The invention improves the early resistance water and scrub resistance of the coating by adding silicone coupling modification; (5) The inorganic building coating provided by the invention has excellent performance , The VOC content is low, can be reduced or avoided coalescent content, simple process, low cost, excellent anti-aging properties.
具体实施方式detailed description
以下是本发明的具体实施例，但本发明的实施和保护范围不限于所述实施例。The following are specific embodiments of the invention, but the scope of implementation and protection of the invention is not limited to the embodiments.
实施例1Example 1
（ A ）无机 - 有机杂化建筑涂料的制备方法(A) Preparation method of inorganic-organic hybrid architectural coating
1 ）以重量份计，依次加入 21.5 份的水、 0.1 份的润湿剂、 0.25 份的分散剂、 0.1 份的 PH 调节剂、 0.3 份的消泡剂、 0.5 的防冻剂、 0.2 份的增稠剂、 21 份的硅溶胶、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 7 份的钛白粉、 14 份的重质碳酸钙、 10 份的高岭土、 5 份的玻璃微珠、 1 份的红外陶瓷粉，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 3.5 份的水、 0.4 份的防霉杀菌剂、 14 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。  1) 21.5 parts by weight, 0.1 part of wetting agent, 0.25 parts of dispersing agent, 0.1 part by weight, in order PH regulator, 0.3 parts defoamer, 0.5 antifreeze, 0.2 parts thickener, 21 parts silica sol, 0.3 parts silicone, keep stirring at low speed 300-500 Continue to disperse for 15 minutes; 2) Add 7 parts of titanium dioxide, 14 parts of heavy calcium carbonate, 10 parts of kaolin, 5 parts of glass beads, 1 part of infrared ceramic powder, and keep stirring speed. 1000 rpm dispersion for 30 minutes; 3) Add 3.5 parts of water, 0.4 parts of mildew fungicide, 14 parts of organic emulsion, 0.75 parts of thickener, 0.1 The defoamer is kept at a low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 1 ）
水 21.5 高岭土 10 乙二醇 0.5 TB-203 0.2
CO-630 0.1 玻璃微珠 5 HYS-30000 0.2 Maincote 8104 14
OROTAN 快易分散剂 0.25 红外陶瓷粉 1 硅溶胶（ 7-9nm ） 21 TT-915 0.5
AMP-95 0.1 水 3.5 Z-6030 0.3 ASE-60 0.25
DF-681 0.3 NB-200 0.2 钛白粉 14 BYK-011 0.1
重质碳酸钙 7
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 1)
water 21.5 Kaolin 10 Ethylene glycol 0.5 TB-203 0.2
CO-630 0.1 Glass beads 5 HYS-30000 0.2 Maincote 8104 14
OROTAN quick dispersing agent 0.25 Infrared ceramic powder 1 Silica sol (7-9nm) twenty one TT-915 0.5
AMP-95 0.1 water 3.5 Z-6030 0.3 ASE-60 0.25
DF-681 0.3 NB-200 0.2 Titanium dioxide 14 BYK-011 0.1
Heavy calcium carbonate 7
（C ）无机 - 有机杂化建筑涂料的性能（见表 2 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥ 97 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 , 次 ≥ 10000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤ 15 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 2)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥ 97 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance, times ≥ 10000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤ 15 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的贮存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，没有添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, no added filming aids, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 2 Example 2
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 24.8 份的水、 0.1 份的润湿剂、 0.25 份的分散剂、 0.3 份的 PH 调节剂、 0.3 份的消泡剂、 0.5 份的防冻剂、 0.2 份的增稠剂、 14 份的硅溶胶、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 3.7 份的钛白粉、 14 份的重质碳酸钙、 10 份的高岭土、 5 份的玻璃微珠、 1 份的红外陶瓷粉，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 3.5 份的水、 0.4 份的防霉杀菌剂、 20.45 份的有机乳液、 1.1 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。(A) Preparation of inorganic-organic hybrid architectural coatings: 1) 24.8 parts by weight, 0.1 part by weight, in order a wetting agent, 0.25 parts of a dispersant, 0.3 parts of a pH adjuster, 0.3 parts of an antifoaming agent, 0.5 parts of an antifreeze, 0.2 parts of a thickener, 14 parts of a silica sol, 0.3 parts of silicone, kept at low speed for 300-500 rpm for 15 minutes; 2) 3.7 parts of titanium dioxide, 14 parts of heavy calcium carbonate, 10 parts of kaolin, 5 parts of glass beads, 1 part of infrared ceramic powder, keep stirring at 1000 rpm for 30 minutes; 3) Add 3.5 parts of water, 0.4 parts of mildew fungicide, 20.45 Part of the organic emulsion, 1.1 parts of thickener, 0.1 part of defoamer, keep stirring at low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 3 ）  (B) Composition of inorganic-organic hybrid architectural coatings (see Table 3)
水 water 24.8 24.8 高岭土 Kaolin 4.7 4.7 HYS-30000 HYS-30000 0.2 0.2 Maincote 8104 Maincote 8104 20.45 20.45
CO-630 CO-630 0.1 0.1 玻璃微珠 Glass beads 5 5 硅溶胶（ 20-30nm ） Silica sol (20-30nm) 14 14 TT-915 TT-915 0.8 0.8
OROTAN 快易分散剂 OROTAN quick dispersing agent 0.25 0.25 红外陶瓷粉 Infrared ceramic powder 1 1 Z-6040 Z-6040 0.3 0.3 ASE-60 ASE-60 0.3 0.3
DMEA DMEA 0.3 0.3 水 water 3.5 3.5 钛白粉 Titanium dioxide 9 9 pispelair CF439 Pispelair CF439 0.1 0.1
Nopco 267-A Nopco 267-A 0.3 0.3 NB-200 NB-200 0.2 0.2 重质碳酸钙 Heavy calcium carbonate 14 14
丙二醇 Propylene glycol 0.5 0.5 TB-203 TB-203 0.2 0.2
（ C ）无机 - 有机杂化建筑涂料的性能（见表 4 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥95 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 10min GB /T 1728-1979
耐洗刷性 ≥10000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤20 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 4)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥95 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 10min GB /T 1728-1979
Scrubbing resistance ≥10000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤20 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异、干燥速度快，无须添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, fast drying speed, no need to add filming aids, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 3Example 3
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 21 份的水、 0.1 份的润湿剂、 0.3 份的消泡剂、 0.5 份的防冻剂、 0.3 份的增稠剂、 21 份的硅溶胶、 3.5 份的硅酸钾、 3.5 份的硅酸锂、 0.45 份的稳定剂、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 7 份的钛白粉、 15 份的重质碳酸钙、 10 份的高岭土、 5 份的滑石粉，保持搅拌速度 1500 转分散 25 分钟； 3 ）依次加入 4 份的水、 0.2 份的防霉杀菌剂、 7 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 (A) Preparation of inorganic-organic hybrid architectural coatings: 1) Add 21 parts of water, 0.1 in parts by weight Parts of wetting agent, 0.3 parts of antifoaming agent, 0.5 parts of antifreeze, 0.3 parts of thickener, 21 parts of silica sol, 3.5 parts of potassium silicate, 3.5 parts of lithium silicate, 0.45 Part of the stabilizer, 0.3 parts of silicone, keep stirring at low speed for 300-500 rpm for 15 minutes; 2) Add 7 parts of titanium dioxide, 15 parts of heavy calcium carbonate, 10 Parts of kaolin, 5 parts of talcum powder, keep stirring speed 1500 rpm for 25 minutes; 3) Add 4 parts of water, 0.2 parts of mildew fungicide, 7 parts of organic emulsion, 0.75 parts thickener, 0.1 part defoamer, keep stirring at low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（表 5 ）
水 20.5 钛白粉 12 硅溶胶（ 20-30nm ） 21 NB-200 0.2
BYK － 346 0.1 重质碳酸钙 15 硅酸钾 3.5 Maincote 8104 7
Nopco 267-A 0.3 高岭土 5 硅酸锂 3.5 TT-915 0.5
丙二醇 0.5 滑石粉 5 DISPERSOGEN SPS 0.45 ASE-60 0.25
HYS-30000 0.3 水 3.5 Z-6030 0.3 BYK-011 0.1
(B) Composition of inorganic-organic hybrid architectural coatings (Table 5)
water 20.5 Titanium dioxide 12 Silica sol (20-30nm) twenty one NB-200 0.2
BYK - 346 0.1 Heavy calcium carbonate 15 Potassium silicate 3.5 Maincote 8104 7
Nopco 267-A 0.3 Kaolin 5 Lithium silicate 3.5 TT-915 0.5
Propylene glycol 0.5 talcum powder 5 DISPERSOGEN SPS 0.45 ASE-60 0.25
HYS-30000 0.3 water 3.5 Z-6030 0.3 BYK-011 0.1
（ C ）无机 - 有机杂化建筑涂料的性能（见表 6 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥95 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥10000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤10 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 6)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥95 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥10000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤10 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异、防水透气性好，无须添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coating described in the present example has good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, good waterproof and gas permeability, no need to add a film forming auxiliary, and a total volatile organic compound content ( TVOC ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 4Example 4
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 25 份的水、 0.3 份的润湿剂、 0.15 份的分散剂、 0.2 份的 PH 调节剂、 0.2 份的消泡剂、 1.4 份的成膜助剂、 0.8 的防冻剂、 0.2 份的增稠剂、 10 份的硅溶胶、 0.5 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 6.35 份的钛白粉、 20 份的重质碳酸钙、 10 份的高岭土、 5 份滑石粉，保持搅拌速度 1500 转分散 20 分钟； 3 ）依次加入 3.5 份的水、 0.4 份的防霉杀菌剂、 15 份的有机乳液、 0.9 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 (A) Preparation of inorganic-organic hybrid architectural coatings: 1) Add 25 parts of water, 0.3 in parts by weight a wetting agent, 0.15 parts of a dispersant, 0.2 parts of a pH adjuster, 0.2 parts of an antifoaming agent, 1.4 parts of a film forming aid, 0.8 antifreeze, 0.2 parts of a thickener, 10 parts of silica sol, 0.5 parts of silicone, kept at low speed for 300-500 rpm for 15 minutes; 2) 6.35 parts of titanium dioxide, 20 parts of heavy calcium carbonate, 10 parts of kaolin, 5 parts of talcum powder, keep stirring speed 1500 rpm for 20 minutes; 3) Add 3.5 parts of water, 0.4 parts of mildew fungicide, 15 Part of the organic emulsion, 0.9 parts of thickener, 0.1 part of defoamer, keep stirring at low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（表 7 ）
水 25 重质碳酸钙 10 乙二醇 0.8 J-998A 15
TEGO-270 0.3 高岭土 20 HYS-30000 0.2 TT-615 0.5
OROTAN 快易分散剂 0.15 滑石粉 5 硅溶胶（ 20-30nm ） 10 ASE-60 0.4
三乙胺 0.2 水 3.5 Dynasylan GLYEO 0.5 pispelair CF 439 0.1
TEGO-800 0.2 NB-200 0.2 钛白粉 6.35
2,2,4 －三甲基－ 1,3 －戊二醇单异丁酸酯 1.4 TB-203 0.2
(B) Composition of inorganic-organic hybrid architectural coatings (Table 7)
water 25 Heavy calcium carbonate 10 Ethylene glycol 0.8 J-998A 15
TEGO-270 0.3 Kaolin 20 HYS-30000 0.2 TT-615 0.5
OROTAN quick dispersing agent 0.15 talcum powder 5 Silica sol (20-30nm) 10 ASE-60 0.4
Triethylamine 0.2 water 3.5 Dynasylan GLYEO 0.5 Pispelair CF 439 0.1
TEGO-800 0.2 NB-200 0.2 Titanium dioxide 6.35
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 1.4 TB-203 0.2
（ C ）无机 - 有机杂化建筑涂料的性能（见表 8 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥97 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥8000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤10 GB /T 9780-2005
耐人工老化性（ 1500h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 8)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥97 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥8000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤10 GB / T 9780-2005
Artificial aging resistance (1500h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐沾污性能优异，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent stain resistance, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 5 Example 5
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 21.5 份的水、 0.1 份的润湿剂、 0.3 份的消泡剂、 0.3 份的成膜助剂、 0.5 的防冻剂、 0.2 份的增稠剂、 21 份的硅溶胶、 8.45 份的硅酸锂、 1.65 份的硅酸钾、 0.5 份的稳定剂、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 7 份的钛白粉、 14 份的重质碳酸钙、 15 份的滑石粉，保持搅拌速度 1500 转分散 30 分钟； 3 ）依次加入 3.5 份的水、 0.1 份的防霉杀菌剂、 5 份的有机乳液、 0.5 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 (A) Preparation of inorganic-organic hybrid architectural coatings: 1) 21.5 parts by weight, 0.1 part by weight, in order Moisturizer, 0.3 part defoamer, 0.3 part filming aid, 0.5 antifreeze, 0.2 part thickener, 21 parts silica sol, 8.45 parts lithium silicate, 1.65 Parts of potassium silicate, 0.5 parts of stabilizer, 0.3 parts of silicone, kept at low speed for 300-500 rpm for 15 minutes; 2) 7 parts of titanium dioxide, 14 Parts of heavy calcium carbonate, 15 parts of talcum powder, keep stirring speed 1500 rpm for 30 minutes; 3) Add 3.5 parts of water, 0.1 parts of mildew fungicide, 5 Part of the organic emulsion, 0.5 parts of thickener, 0.1 part of defoamer, keep stirring at low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 9 ）
水 21.5 Z-6030 0.3 HYS-30000 0.2 Nipacide CFX-3 0.2
CO-630 0.1 钛白粉 7 硅溶胶（ 7-9nm ） 21 296 DS 5
DF-681 0.3 重质碳酸钙 14 硅酸锂 8.45 TT-915 0.2
二丙二醇甲醚 0.3 滑石粉 15 硅酸钾 1.65 ASE-60 0.3
乙二醇 0.5 水 3.5 DM-042 0.5 Nopco 267-A 0.1
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 9)
water 21.5 Z-6030 0.3 HYS-30000 0.2 Nipacide CFX-3 0.2
CO-630 0.1 Titanium dioxide 7 Silica sol (7-9nm) twenty one 296 DS 5
DF-681 0.3 Heavy calcium carbonate 14 Lithium silicate 8.45 TT-915 0.2
Dipropylene glycol methyl ether 0.3 talcum powder 15 Potassium silicate 1.65 ASE-60 0.3
Ethylene glycol 0.5 water 3.5 DM-042 0.5 Nopco 267-A 0.1
（ C ）无机 - 有机杂化建筑涂料的性能（见表 10 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥95 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 8min GB /T 1728-1979
耐洗刷性 ≥10000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤10 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 10)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥95 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 8min GB /T 1728-1979
Scrubbing resistance ≥10000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤10 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，表干时间极短，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, extremely short surface drying time, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 6Example 6
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 29 份的水、 0.5 份的润湿剂、 0.3 份的消泡剂、 0.5 份的成膜助剂、 0.8 的防冻剂、 0.3 份的增稠剂、 10 份的硅溶胶、 5 份的硅酸钾、 0.3 份的稳定剂、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 7 份的钛白粉、 14 份的重质碳酸钙、 15 份的滑石粉、 5 份的玻璃微珠，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 3 份的水、 0.4 份的防霉杀菌剂、 7.75 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。(A) Preparation of inorganic-organic hybrid architectural coatings: 1) Add 29 parts of water, 0.5 in parts by weight Parts of wetting agent, 0.3 parts of antifoaming agent, 0.5 part of filming aid, 0.8 antifreeze, 0.3 parts of thickener, 10 parts of silica sol, 5 parts of potassium silicate, 0.3 Part of the stabilizer, 0.3 parts of silicone, keep stirring at low speed for 300-500 rpm for 15 minutes; 2) Add 7 parts of titanium dioxide, 14 parts of heavy calcium carbonate, 15 Talc powder, 5 parts of glass beads, keep stirring at 1000 rpm for 30 minutes; 3) Add 3 parts of water, 0.4 parts of mildew fungicide, 7.75 parts of organic emulsion, 0.75 parts thickener, 0.1 part defoamer, keep stirring at low speed for 300 rpm for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 11 ）
水 29 重质碳酸钙 14 HYS-30000 0.3 Nipacide CFX-3 0.2
BYK － 346 0.5 高岭土 5 硅溶胶（ 20-30nm ） 10 J-998A 7.75
DF-681 0.3 玻璃微珠 5 硅酸钾 5 TT-915 0.45
2,2,4 －三甲基－ 1,3 －戊二醇单异丁酸酯 0.5 水 3 TEGO-1300 0.3 TT-615 0.3
乙二醇 0.8 Nipacide C 115 0.2 Z-6030 0.3 Nopco 267-A 0.1
钛白粉 17
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 11)
water 29 Heavy calcium carbonate 14 HYS-30000 0.3 Nipacide CFX-3 0.2
BYK - 346 0.5 Kaolin 5 Silica sol (20-30nm) 10 J-998A 7.75
DF-681 0.3 Glass beads 5 Potassium silicate 5 TT-915 0.45
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 0.5 water 3 TEGO-1300 0.3 TT-615 0.3
Ethylene glycol 0.8 Nipacide C 115 0.2 Z-6030 0.3 Nopco 267-A 0.1
Titanium dioxide 17
（ C ）无机 - 有机杂化建筑涂料的性能（见表 12 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥97 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥8000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤20 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 12)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥97 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥8000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤20 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 7 Example 7
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 21.5 份的水、 0.2 份的润湿剂、 0.25 份的分散剂、 0.3 份的 PH 调节剂、 0.3 份的消泡剂、 0.5 的防冻剂、 0.2 份的增稠剂、 21 份的硅溶胶、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 21 份的钛白粉、 5 份的高岭土、 10 份的玻璃微珠、 0.7 份的红外陶瓷粉，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 3.5 份的水、 0.4 份的防霉杀菌剂、 14 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 (A) Preparation of inorganic-organic hybrid architectural coatings: 1) 21.5 parts by weight, 0.2 parts of wetting agent, 0.25 parts of dispersant, 0.3 parts of pH adjuster, 0.3 parts by weight, in order Defoamer, 0.5 antifreeze, 0.2 part thickener, 21 parts silica sol, 0.3 parts silicone, keep stirring at low speed for 300-500 rpm for 15 minutes; 2) Add 21 parts of titanium dioxide in sequence 5 parts of kaolin, 10 parts of glass beads, 0.7 parts of infrared ceramic powder, and keep stirring at 1000 rpm for 30 minutes; 3) Add 3.5 parts of water, 0.4 parts of anti-mold fungicide, 14 parts of organic emulsion, 0.75 parts of thickener, 0.1 part of defoamer, and keep stirring at low speed for 300 minutes for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 13 ）
水 21.5 高岭土 5 乙二醇 0.5 TB-203 0.2
CO-630 0.2 玻璃微珠 10 HYS-30000 0.2 Maincote 8104 14
OROTAN 快易分散剂 0.25 红外陶瓷粉 0.7 硅溶胶（ 20-30nm ） 21 HYS-30000 0.1
二乙醇胺 0.3 水 3.5 KH560 0.3 ASE-60 0.65
DF-681 0.3 NB-200 0.2 钛白粉 21 BYK-011 0.1
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 13)
water 21.5 Kaolin 5 Ethylene glycol 0.5 TB-203 0.2
CO-630 0.2 Glass beads 10 HYS-30000 0.2 Maincote 8104 14
OROTAN quick dispersing agent 0.25 Infrared ceramic powder 0.7 Silica sol (20-30nm) twenty one HYS-30000 0.1
Diethanolamine 0.3 water 3.5 KH560 0.3 ASE-60 0.65
DF-681 0.3 NB-200 0.2 Titanium dioxide twenty one BYK-011 0.1
（ C ）无机 - 有机杂化建筑涂料的性能（见表 14 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥97 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥8000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤10 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 14)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥97 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥8000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤10 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，而且保温隔热性能优异，温差可达 15 ℃，没有添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging, and excellent thermal insulation performance, and the temperature difference can reach 15 °C, no added filming aid, low total volatile organic compound content (TVOC), can meet the environmental marking product certification technical requirements water-based paint GB24410-2009 The standard is a green product.
实施例 8 Example 8
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 21.5 份的水、 0.1 份的润湿剂、 0.3 份的消泡剂、 0.5 份的成膜助剂、 0.5 的防冻剂、 0.2 份的增稠剂、 21 份的硅溶胶、 9 份的硅酸锂、 0.2 份的稳定剂、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 7 份的钛白粉、 14 份的重质碳酸钙、 10 份的高岭土、 5 份的玻璃微珠、 1 份的红外陶瓷粉，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 3.15 份的水、 0.4 份的防霉杀菌剂、 5 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 (A) Preparation of inorganic-organic hybrid architectural coatings: 1) 21.5 parts by weight, 0.1 part by weight, in order Moisturizer, 0.3 part defoamer, 0.5 part filming aid, 0.5 antifreeze, 0.2 part thickener, 21 parts silica sol, 9 parts lithium silicate, 0.2 Part of the stabilizer, 0.3 parts of silicone, keep stirring at low speed for 300-500 rpm for 15 minutes; 2) Add 7 parts of titanium dioxide, 14 parts of heavy calcium carbonate, 10 Parts of kaolin, 5 parts of glass beads, 1 part of infrared ceramic powder, keep stirring at 1000 rpm for 30 minutes; 3) Add 3.15 parts of water in sequence, 0.4 A portion of the mildew fungicide, 5 parts of the organic emulsion, 0.75 parts of the thickener, 0.1 part of the defoamer, and keep stirring at low speed for 300 minutes for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 15 ）
水 21.5 重质碳酸钙 14 HYS-30000 0.2 TB-203 0.2
TEGO-500 0.1 高岭土 10 硅溶胶（ 20-30nm ） 21 296 DS 5
pispelair CF 439 0.3 玻璃微珠 5 硅酸锂 9 HYS-30000 0.1
丙二醇丁醚醋酸酯 0.2 红外陶瓷粉 1 DISPERSOGEN SPV 0.2 ASE-60 0.65
二丙二醇甲醚醋酸酯 0.3 水 3.15 KH-570 0.3 pispelair CF 439 0.1
乙二醇 0.5 NB-200 0.2 钛白粉 7
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 15)
water 21.5 Heavy calcium carbonate 14 HYS-30000 0.2 TB-203 0.2
TEGO-500 0.1 Kaolin 10 Silica sol (20-30nm) twenty one 296 DS 5
Pispelair CF 439 0.3 Glass beads 5 Lithium silicate 9 HYS-30000 0.1
Propylene glycol butyl ether acetate 0.2 Infrared ceramic powder 1 DISPERSOGEN SPV 0.2 ASE-60 0.65
Dipropylene glycol methyl ether acetate 0.3 water 3.15 KH-570 0.3 Pispelair CF 439 0.1
Ethylene glycol 0.5 NB-200 0.2 Titanium dioxide 7
（ C ）无机 - 有机杂化建筑涂料的性能（见表 16 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥95 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥8000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤10 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 16)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥95 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥8000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤10 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化和耐沾污性能优异，耐磨性能好，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent resistance to artificial aging and staining, good wear resistance, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 9 Example 9
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 24.5 份的水、 0.4 份的润湿剂、 0.3 份的消泡剂、 1.3 份的成膜助剂、 0.5 的防冻剂、 0.2 份的增稠剂、 24 份的硅溶胶、 6 份的硅酸钾、 0.5 份的稳定剂、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 20 份的钛白粉、 8 份的高岭土，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 5 份的水、 0.2 份的防霉杀菌剂、 8 份的有机乳液、 0.5 份的增稠剂、 0.3 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。 （ B ）无机 - 有机杂化建筑涂料的组成（见表 17 ）
水 24.5 TEGO-1500N 0.5 丙二醇 0.5 NB-200 0.2
BYK － 346 0.4 Z-6030 0.3 HYS-30000 0.2 TBH-1 8
BYK-011 0.3 钛白粉 20 硅溶胶（ 20-30nm ） 24 TT-915 0.2
二丙二醇甲醚 0.6 高岭土 8 硅酸钾 6 ASE-60 0.3
二丙二醇丁醚 0.7 水 5 BYK-012 0.3
(A) Preparation of inorganic-organic hybrid architectural coatings: 1) In terms of parts by weight, 24.5 parts of water, 0.4 parts of wetting agent, 0.3 parts of antifoaming agent, 1.3 parts of film forming aid, 0.5 antifreeze, 0.2 parts thickener, 24 parts silica sol, 6 parts potassium silicate, 0.5 parts stabilizer, 0.3 parts silicone, keep stirring at low speed for 300-500 rpm for 15 minutes; 2 Add 20 parts of titanium dioxide and 8 parts of kaolin in turn, keep stirring at 1000 rpm for 30 minutes; 3) Add 5 parts of water, 0.2 parts of mildew fungicide, 8 parts of organic emulsion, 0.5 parts of increasing Thickener, 0.3 parts of defoamer, keep stirring at low speed for 300 minutes for 10 minutes. (B) Composition of inorganic-organic hybrid architectural coatings (see Table 17)
water 24.5 TEGO-1500N 0.5 Propylene glycol 0.5 NB-200 0.2
BYK - 346 0.4 Z-6030 0.3 HYS-30000 0.2 TBH-1 8
BYK-011 0.3 Titanium dioxide 20 Silica sol (20-30nm) twenty four TT-915 0.2
Dipropylene glycol methyl ether 0.6 Kaolin 8 Potassium silicate 6 ASE-60 0.3
Dipropylene glycol butyl ether 0.7 water 5 BYK-012 0.3
（ C ）无机 - 有机杂化建筑涂料的性能（见表 18 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥97 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥8000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤20 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 18)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥97 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥8000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤20 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，没有添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coatings described in this example have good storage stability, excellent washing resistance, good chemical resistance, excellent artificial aging resistance, no added filming aid, and total volatile organic compound content (TVOC). ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
实施例 10 Example 10
（ A ）无机 - 有机杂化建筑涂料的制备方法： 1 ）以重量份计，依次加入 18.5 份的水、 0.1 份的润湿剂、 0.25 份的分散剂、 0.3 份的 PH 调节剂、 0.3 份的消泡剂、 1.1 份的防冻剂、 0.2 份的增稠剂、 16.2 份的硅溶胶、 0.3 份的有机硅，保持低速搅拌 300-500 转持续分散 15 分钟； 2 ）依次加入 6 份的钛白粉、 24 份的重质碳酸钙、 10 份的高岭土、 5 份的玻璃微珠，保持搅拌速度 1000 转分散 30 分钟； 3 ）依次加入 2.5 份的水、 0.4 份的防霉杀菌剂、 14 份的有机乳液、 0.75 份的增稠剂、 0.1 份的消泡剂，保持低速搅拌 300 转持续 10 分钟即可。  (A) Preparation of inorganic-organic hybrid architectural coatings: 1) Add 18.5 parts of water, 0.1 in parts by weight a wetting agent, 0.25 parts of a dispersant, 0.3 parts of a pH adjuster, 0.3 parts of an antifoaming agent, 1.1 parts of an antifreeze, 0.2 parts of a thickener, 16.2 parts of a silica sol, 0.3 parts of silicone, kept at low speed for 300-500 rpm for 15 minutes; 2) 6 parts of titanium dioxide, 24 parts of heavy calcium carbonate, 10 parts of kaolin, 5 Part of the glass beads, keep stirring at 1000 rpm for 30 minutes; 3) Add 2.5 parts of water, 0.4 parts of mildew fungicide, 14 parts of organic emulsion, 0.75 Serve thickener, 0.1 part defoamer, keep stirring at low speed for 300 minutes for 10 minutes.
（ B ）无机 - 有机杂化建筑涂料的组成（见表 19 ）
水 18.5 重质碳酸钙 24 乙二醇 1.1 TB-203 0.2
CO-630 0.1 高岭土 10 HYS-30000 0.2 SD-2000 14
六偏磷酸钠 0.25 玻璃微珠 5 硅溶胶（ 20-30nm ） 16.2 TT-915 0.45
氨水 0.3 水 2.5 Hydrosil 2926 0.3 ASE-60 0.3
DF-681 0.3 Nipacide C 115 0.2 钛白粉 6 TEGO － 810 0.1
(B) Composition of inorganic-organic hybrid architectural coatings (see Table 19)
water 18.5 Heavy calcium carbonate twenty four Ethylene glycol 1.1 TB-203 0.2
CO-630 0.1 Kaolin 10 HYS-30000 0.2 SD-2000 14
Hexametaphosphate 0.25 Glass beads 5 Silica sol (20-30nm) 16.2 TT-915 0.45
ammonia 0.3 water 2.5 Hydrosil 2926 0.3 ASE-60 0.3
DF-681 0.3 Nipacide C 115 0.2 Titanium dioxide 6 TEGO - 810 0.1
（ C ）无机 - 有机杂化建筑涂料的性能（见表 20 ）
检测项目 无机 - 有机杂化建筑涂料 测试方法
涂膜外观 涂膜外观正常 --
对比率， % ≥95 GB /T 9270-1988
热储存稳定性 无结块、凝聚、霉变现象 GB /T 6753.3-86
低温储存稳定性 无结块、凝聚现象 --
表干时间 30min GB /T 1728-1979
耐洗刷性 ≥10000 GB /T 9266-1988
耐性水（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 1733-1993
耐碱性（ 168h ） 无起泡、裂痕、剥落，允许轻微掉粉 GB /T 9265-1988
耐温变性（ 10 次） 无起泡、裂痕、剥落，允许轻微掉粉 JG /T 25-1999
耐沾污性， % ≤20 GB /T 9780-2005
耐人工老化性（ 1800h ） 无起泡、裂痕、剥落、粉化、变色 GB /T 1865-1997
(C) Properties of inorganic-organic hybrid architectural coatings (see Table 20)
Test items Inorganic - Organic Hybrid Architectural Coatings testing method
Coating appearance The appearance of the film is normal --
Contrast ratio, % ≥95 GB /T 9270-1988
Thermal storage stability No agglomeration, cohesion, mildew GB /T 6753.3-86
Low temperature storage stability No agglomeration, agglomeration --
Dry time 30min GB /T 1728-1979
Scrubbing resistance ≥10000 GB /T 9266-1988
Resistant water ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 1733-1993
Alkali resistance ( 168h ) No blistering, cracking, flaking, allowing slight dusting GB /T 9265-1988
Temperature resistance (10 times) No blistering, cracking, flaking, allowing slight dusting JG /T 25-1999
Stain resistance, % ≤20 GB / T 9780-2005
Artificial aging resistance (1800h) No blistering, cracking, flaking, chalking, discoloration GB /T 1865-1997
本实例所述的无机建筑涂料的储存稳定性好、耐洗刷性能优异、耐化学品性好、耐人工老化优异，而且隔音效果良好，没有添加成膜助剂，总挥发性有机化合物的含量（ TVOC ）低，能满足环境标志产品认证技术要求水性涂料 GB24410-2009 标准，属于绿色环保产品。 The inorganic architectural coating described in the present example has good storage stability, excellent washing resistance, good chemical resistance, excellent artificial aging resistance, good sound insulation effect, no addition of film forming auxiliary, and total volatile organic compound content ( TVOC ) Low, can meet the requirements of environmental labeling product certification technology water-based coating GB24410-2009 standard, is a green product.
以上实施例的说明只是用于帮助理解本发明的方法及其核心思想。应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以对本发明进行若干改进和修饰，这些改进和修饰也落入本发明权利要求的保护范围内。 The above description of the embodiments is merely to assist in understanding the method of the present invention and its core idea. It should be noted that those skilled in the art can make various modifications and changes to the present invention without departing from the spirit and scope of the invention.

Claims (1)

1. 一种多效合一水性无机 - 有机杂化建筑涂料的制备方法，其特征在于包括下列步骤： A multi-effect one aqueous inorganic - organic hybrid method for preparing architectural coatings, comprising the steps of:
1 ）以重量份计，依次加入 20-30 份的水、 0.1-0.5 份的润湿剂、 0-0.4 份的分散剂、 0-1 份的 pH 调节剂、 0.1-0.5 份的消泡剂、 0-2 份的成膜助剂、 0.5-2 份的防冻剂、 0.1-0.4 份的增稠剂、 10-25 份的硅溶胶、 0-10 份的硅酸锂溶液、 0-5 份的硅酸钾溶液、 0.1-1 份的稳定剂、 0.1-1 份的有机硅氧烷，搅拌；1) In order to add 20-30 parts of water, 0.1-0.5 parts of wetting agent, 0-0.4 parts of dispersing agent, 0-1 parts by weight pH adjuster, 0.1-0.5 parts defoamer, 0-2 parts filming aid, 0.5-2 parts antifreeze, 0.1-0.4 parts thickener, 10-25 parts silica sol, 0-10 parts of lithium silicate solution, 0-5 parts of potassium silicate solution, 0.1-1 part of stabilizer, 0.1-1 part of organosiloxane, and stirred;
2 ）加入 30-45 份的颜填料，搅拌；2) Add 30-45 parts of pigment filler and stir;
3 ）依次加入 0-5 份的水、 0.1-0.5 份的防霉杀菌剂、 5-15 份的有机聚合物乳液、 0.2-1.5 份的增稠剂、 0.1-0.5 份的消泡剂，搅拌得所述建筑涂料。3) Add 0-5 parts of water, 0.1-0.5 parts of mildew fungicide, 5-15 parts of organic polymer emulsion, 0.2-1.5 A portion of the thickener, 0.1-0.5 parts of the antifoaming agent, is stirred to obtain the architectural coating.
2. 根据权利要求 1 所述的制备方法，其特征在于步骤 1 ）所述搅拌速度为 300-500 转 / 分，搅拌时间 15-30 分钟；步骤 2 ）所述搅拌速度为 1000-1500 转 / 分，搅拌时间 15-30 分钟；步骤 3 ）所述搅拌速度为 300-500 转 / 分，搅拌时间为 5-15 分钟。 The preparation method according to claim 1, wherein the stirring speed is 300-500 rpm, the stirring time is 15-30 minutes; and the stirring speed is 1000-1500 rpm. The stirring time is 15-30 minutes; the stirring speed is 300-500 rpm, and the stirring time is 5-15 minutes.
3. 根据权利要求 1 所述的制备方法，其特征在于所述硅酸锂的模数为 3.6-4.8 ，硅酸钾的模数为 2.5-3.6 ，硅溶胶平均粒径为 7-30nm 。 The method according to claim 1, wherein the lithium silicate has a modulus of 3.6 to 4.8, the potassium silicate has a modulus of 2.5 to 3.6, and the silica sol has an average particle diameter of 7 to 30 nm.
4. 根据权利要求 1 所述的制备方法，其特征在于所述的有机聚合物乳液为巴德富公司的 J-998A 、巴斯夫公司的 296 DS 、罗门哈斯的 SD-2000 、 maincote 8104 、江苏日出集团的 TBH-1 中的一种或多种。 4. The production method according to claim 1, wherein said organic polymer emulsion BATF's J-998A, BASF 296 DS, Rohm and Haas's SD-2000, maincote 8104, One or more of the TBH-1 of Jiangsu Sunrise Group.
5. 根据权利要求 1 所述的制备方法，其特征在于所述的稳定剂为科莱恩公司的 DISPERSOGEN SPS 、 DISPERSOGEN SPV 、湖北德邦化工有限公司的 DM-042 、 Degussa 公司的 TEGO-1300 、 TEGO-1400 、 TEGO-1500N 中的一种或多种。 The production method according to claim 1, characterized in that the DM-042 stabilizer is Clariant DISPERSOGEN SPS, DISPERSOGEN SPV, Hubei Chemical Co. Nadu, Degussa's TEGO-1300, TEGO One or more of -1400 and TEGO-1500N.
6. 根据权利要求 1 所述的制备方法，其特征在于所述的有机硅氧烷是 Degussa 公司的 Dynasylan Hydrosil 2926 、 Dynasylan GLYEO 、湖北新蓝天新材料股份有限公司的 KH560 、 KH570 ，美国道康宁公司的 Z-6040 、 Z-6030 的一种或多种。 6. The production method according to claim 1, wherein said organosiloxane is from Degussa Dynasylan Hydrosil 2926, Dynasylan GLYEO, Hubei blue New Material Co. of KH560, KH570, Dow Corning Company One or more of Z-6040 and Z-6030.
7. 根据权利要求 1 所述的制备方法，其特征在于所述的润湿剂为 Degussa 公司的 TEGO-245 、 TEGO-500 、德国比克公司的 BYK － 346 和罗迪亚公司的 CO-630 中的一种或两种以上混合物；所述的分散剂为罗门哈斯公司的 OROTAN 快易分散剂、六偏磷酸钠、德国比克公司的 BKY-151 、 BYK-154 、 BYK-155 中的一种或多种；所述的 pH 调节剂为 AMP-95 、 N ， N- 二甲基乙醇胺、氨水、二乙醇胺、三乙胺中的一种或多种；所述的消泡剂为德国比克公司的 BYK-011 、 BYK-012 、 Degussa 公司的 TEGO － 800 、 TEGO － 805 、 TEGO － 810 、罗迪亚公司的 DF-681 、布莱克本公司的 pispelair CF439 、海川化工的 Nopco 267-A 中的一种或多种以上的混合物；所述的成膜助剂为丙二醇甲醚、丙二醇丁醚、二丙二醇甲醚、二丙二醇丁醚、三丙二醇丁醚、丙二醇甲醚醋酸酯、丙二醇丁醚醋酸酯和二丙二醇甲醚醋酸酯、 2,2,4 －三甲基－ 1,3 －戊二醇单异丁酸酯中的一种或两种以上；所述的防冻剂为乙二醇、丙二醇中的一种或两种；所述的增稠剂为科莱恩公司的 HYS-30000 、罗门哈斯公司的碱溶胀增稠剂 TT-935 、 ASE-60 中的一种或者两种以上。 7. The production method according to claim 1, wherein said wetting agent is from Degussa TEGO-245, TEGO-500, Germany BAK of BYK - 346 and the CO-630 Rhodia Inc. One or more mixtures; the dispersant is Rohm and Haas OROTAN fast dispersing agent, sodium hexametaphosphate, BKY-151, BYK-154, BYK-155 of BAK One or more; the pH adjuster is one or more of AMP-95, N, N-dimethylethanolamine, ammonia, diethanolamine, triethylamine; the antifoaming agent is BYK-011, BYK-012 from Germany BAK, TEGO-800 from Degussa, TEGO-805, TEGO-810, DF-681 from Rodia, Pispelair CF439 from Blackburn, Nopco 267 from Haichuan Chemical a mixture of one or more of A; the film-forming aids are propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, tripropylene glycol butyl ether, propylene glycol methyl ether acetate, propylene glycol Butyl ether acetate and dipropylene glycol methyl ether acetate, 2, 2, 4 - three One or more of 1,3-1,3-pentanediol monoisobutyrate; the antifreeze agent is one or both of ethylene glycol and propylene glycol; the thickener is a family One or more of Ryan's HYS-30000 and Rohm and Haas's alkali-swelling thickeners TT-935 and ASE-60.
8. 根据权利要求 1 所述的制备方法，其特征在于所述的颜填料为是钛白粉、重质碳酸钙、高岭土、滑石粉、空心玻璃微珠、红外陶瓷粉中的一种或多种；所述的防霉杀菌剂为科莱恩公司的 Nipacide C 115 、 Nipacide CFX-3 、 Nipacide BIT 20 、广东天辰生物技术有限公司的 NB-200 、 TB-203 的一种或多种。 8. The production method according to claim 1, wherein said filler is titanium dioxide pigment, heavy calcium carbonate, kaolin, talc, hollow glass microspheres A ceramic powder or more infrared The antifungal fungicide is one or more of NL-200 and TB-203 of Clariant's Nipacide C 115, Nipacide CFX-3, Nipacide BIT 20 and Guangdong Tianchen Biotechnology Co., Ltd.
9. 由权利要求 1 所述制备方法制得的多效合一水性无机 - 有机杂化建筑涂料。 9. The aqueous inorganic one multi-effect of the preparation method claimed in claim 1 prepared by the - organic hybrid architectural coatings.
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