CN103497545A - Inorganic coating, and preparation method and application thereof - Google Patents
Inorganic coating, and preparation method and application thereof Download PDFInfo
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- CN103497545A CN103497545A CN201310468832.1A CN201310468832A CN103497545A CN 103497545 A CN103497545 A CN 103497545A CN 201310468832 A CN201310468832 A CN 201310468832A CN 103497545 A CN103497545 A CN 103497545A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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Abstract
The invention discloses a calcium silicate hydrate artificial stone material which is insoluble in water, is generated by carrying out an air hardening reaction on liquid silica sol and calcium carbonate with a certain fineness, and has strength; in addition, the artificial stone material is used as a substrate material for the preparation of inorganic coatings, namely that on the basis of the substrate, various inorganic coatings can be prepared through adding filler, a proper amount of high-molecular polymer, pigment or color paste and various coating additives for modifying. In addition, the substrate material further can be used for refractory materials, colorful thin decorative surface mortar, artificial stone materials and the like. By adoption of the scheme of the inorganic coating disclosed by the invention, after the coating is coated on a wall and dried in the air, the coating with a surface decoration effect is formed; the inorganic coating has the characteristics of aging resistance, weather resistance, high chemical bonding capacity with a cement base layer, no scaling, heat resistance, fire resistance, no toxicity, no pollution, energy conservation and the like; furthermore, the inorganic coating does not contain strong basic ions such as potassium, sodium and the like, the pH (potential of hydrogen) value is less than 10, the compatibility with the pigment is good, the salt petering phenomenon is avoided, and inorganic coatings with various colors can be manufactured.
Description
Technical field
The present invention relates to a kind of novel body material that is mainly used in inorganic paint and preparation method thereof, the extensible fields such as veneer coating, refractory materials and rostone that are applied to, belong to the material engineering category.
Background technology
Classification according to national sector standard JG/26-2002 to inorganic architectural coatings, the one, take water glass (alkalimetal silicate) as the main binding agent, add pigment, filler and auxiliary agent formulated; The 2nd, take silicon sol as the main binding agent, add appropriate synthetic resin emulsion, pigment, filler and auxiliary agent formulated.Conventional as shown in the table for the preparation of potassium silicate and its main physical and chemical indexes of silicon sol of inorganic paint:
.From the composition of potassium silicate and silicon sol, both key distinctions are at alkalinity.Although the former also can with calcium carbonate generation calcify reaction, lower shrinking percentage is even arranged, but because its free alkali content is higher, silicification reaction is had to inhibition, therefore larger on the water tolerance impact of final product, and the accumulation of salt in the surface soil phenomenon of association also can affect painted homogeneity, practical application has been formed to bottleneck.And latter's alkalinity is extremely low, the silication degree is higher, so water tolerance and also better with the consistency of pigment.It is to be noted: the major cause that silicon sol is not concerned is not find that silicon sol can generate the hydrated calcium silicate rostone with gelling material character with calcium carbonate reaction.Simultaneously, silicon sol on the high side, its price several times of water glass often, also, far above the synthetic emulsion of same concentration, used so usually it is used as to auxiliary agent all the time.But in recent years along with silica flour one one-step hydrolysis method has been produced since silicon sol technique progressively replaces traditional ion exchange method and produce silicon sol technique, the price of silicon sol progressively drops to the level lower than water glass, so silicon sol of today has become a kind of basic chemical raw materials that have a extensive future.And calcium carbonate belongs to a kind of slightly soluble salt, its carbonic acid ion that dissociates can be replaced by silicate ion, thereby forms the insoluble and better Calucium Silicate powder of over-all properties, and it also has certain covering effect in whitewash, can replace the titanium dioxide of most.
Summary of the invention
Active demand in view of above-mentioned prior art to inorganic architectural coatings, purpose of the present invention is intended to propose a kind of inorganic paint and method for making and application, to complying with the paces of modern architecture coating.
For realizing above-mentioned first purpose, technical scheme of the present invention is: a kind of inorganic paint, by body material, with the auxiliary material liquid combo of joining, become, it is characterized in that: the hydrated calcium silicate of described body material for being generated through the air-setting reaction by liquid-state silicon colloidal sol and calcium carbonate, the compound proportion of described liquid-state silicon colloidal sol and calcium carbonate is between 1:3～6:4 by weight; The described auxiliary mixture that material is the high molecular polymer of inorganic paint total mass below 20%, filler, pigment, paint additive of joining.
Further, the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, pH value and is less than 11, and particle diameter is less than 100 nanometers.
Further, described calcium carbonate is the powder of purity more than 95%, more than fineness 200 orders.
Further, high molecular polymer is at least the EVA redispersable latex powder of MFT in the zero degree left and right, the esters of acrylic acid redispersable latex powder, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion through plasticising, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, one of aqueous alkide resin or multiple combination.
Further, described filler is at least one of titanium dioxide, mica, kaolin or multiple combination.
Further, described pigment is pigment dyestuff, mineral dye or the liquid color paste of being made by various pigment.
Further, described paint additive is at least one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas or multiple combination.
Above-mentioned second purpose of the present invention, a kind of method for making of inorganic paint, it is characterized in that comprising step: the liquid-state silicon colloidal sol of I, weighing by mass percentage 25%～60%, 40%～75% calcium carbonate and the 20% following auxiliary material of joining, the described auxiliary material of joining is comprised of high molecular polymer, filler, pigment, paint additive; II, liquid-state silicon colloidal sol is joined in the speed governing Scattered Kettle, stir also and slowly add calcium carbonate and the auxiliary material of joining under vacuum, accelerate after interpolation to be stirred to evenly, make soup compound and sealing is preserved.
The technical solution of above-mentioned the 3rd purpose of the present invention is, a kind of body material of inorganic paint, and its application at least comprises inorganic paint, refractory materials, colored thin layer facing mortar and artificial stone material.
Apply the technical scheme of inorganic paint of the present invention and novel body material thereof, comparing to existing inorganic silicate coating has advantages of outstanding: it has ageing-resistant, the characteristics such as weathering resistance strong, with cement basic layer, Chemical bond power is arranged, do not peel, heat-resisting, fire prevention, nontoxic, pollution-free and save energy, and it is not containing strong basicity ions such as potassium, sodium, the pH value is less than 10, good with the consistency of pigment, accumulation of salt in the surface soil phenomenon can be do not produced, versicolor inorganic paint can be made.
The accompanying drawing explanation
Fig. 1 is the XRD diffractogram of silicon sol.
Fig. 2 is that silicon sol and weight of calcium carbonate are than the XRD diffractogram of about 1:1 gas mixture hardened product.
Embodiment
The present invention has disclosed a kind of of great value gelling chemical reaction, the characteristics of this chemical reaction are that silica sol liquid can generate water insoluble, as to have intensity hydrated calcium silicate artificial stone material with the calcium carbonate generation air-setting reaction of certain fineness, and this material can be applicable to the body material of inorganic paint.This chemical reaction can be proven by the XRD diffractogram.As shown in Figure 1 to Figure 2: the XRD diffractogram that Fig. 1 is raw materials of silica sol, it is a kind of unformed silicon-dioxide; Fig. 2 is placed on the XRD diffractogram of the hardened product after 3 days in air after silicon sol and calcium carbonate (the about 1:1 of weight ratio) mix, wherein can find that unformed silicon-dioxide all disappears, and has generated and has had hydrated calcium silicate and the unreacted calcium carbonate of part that crystalline structure is good.From mechanism, unformed active silica in silica aqueous solution and the lip-deep calcium water generation reaction of calcium carbonate granule Calucium Silicate powder, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is joined by hydrated calcium silicate glue, in the time of in being put in air, the evaporation of water in system, separate out the hydrated calcium silicate crystal, and that to form hydrated calcium silicate crystal/calcium carbonate be main component, water-fast, rostone structure with mechanical strength.
The present invention has disclosed the scheme that adopts this novel gelled material to make inorganic paint simultaneously, comprise essentially consist of body material and preparation method thereof, on the basis of this body material, add appropriate high molecular polymer, filler, pigment (or mill base) and various paint additive and can be mixed with inorganic paint.
From should being used for of inorganic paint, inorganic paint of the present invention comprises the silicon sol solution of 25%-60% weight ratio, the calcium carbonate of 40%-75% weight ratio, the auxiliary materials of joining such as high molecular polymer of 1%-20% weight ratio.
The silicon sol of above indication can be: the dispersion liquid of active silica colloid in water that the pH value is greater than 8, its range of solid content is 30-40%.
The calcium carbonate of above indication can be: the powder formed through pulverizing, grinding by the natural whiting ore, or the calcium carbonate of synthetic, and its calcium carbonate content is no less than 95%, and whiteness is not less than 85%, and fineness is not less than 200 orders.Especially, the density that adopts water-ground limestone to obtain than light calcium carbonate is larger, performance is better.
The high molecular polymer of above indication can be has flexible latex powder, emulsion and aqueous resin dispersion, comprising the EVA redispersable latex powder, the esters of acrylic acid redispersable latex powder, through fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion, the benzene emulsion of plasticising, reach aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin etc.Adopt the effect of high molecular polymer can improve stability and the application property of " silicon sol-calcium carbonate " system, and can increase splitting resistance and the snappiness of its hardened material.
The auxiliary material of joining of other of above indication, pigment, filler, paint additive have multiple washability, and wherein filler is at least one of titanium dioxide, mica, kaolin or multiple combination; Pigment is pigment dyestuff, mineral dye or the liquid color paste of being made by various pigment; Paint additive is at least one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas or multiple combination.The various auxiliary materials of joining can require according to the use properties of coating to be adjusted.
Preparation technology from inorganic paint of the present invention, it comprises step: the liquid-state silicon colloidal sol of I, weighing by mass percentage 25%～60%, 40%～75% calcium carbonate and the 20% following auxiliary material of joining, the described auxiliary material of joining is comprised of high molecular polymer, filler, pigment, paint additive; II, liquid-state silicon colloidal sol is joined in the speed governing Scattered Kettle, stirring also slowly adds calcium carbonate and the auxiliary material of joining under vacuum, after interpolation, acceleration is stirred to evenly, makes color or white soup compound sealing preservation, and this coating at least can be preserved 2 months under the condition in sealing and cool place.
Adopt above-mentioned body material as basic gelling material, add various additives (as high molecular polymer, filamentary material, porous filler, fire retardant etc.) and can make various Calucium Silicate powder artificial stone material and goods with gelling material character, as fire-resistant coating, refractory mortar binding agent, frie retardant coating, corrosion-resistant mortar putty etc.
The inorganic paint body material that adopts the inventive method to prepare is after painting brushes wall, when air drying, unformed silicon sol (silicon-dioxide) will with calcium carbonate reaction, crosslinked webbed " hydrated calcium silicate " structure after dehydration, thus the rostone coating with resistance to compression, tensile strength formed.Its final product be take ionic linkage and covalent linkage as main, and the Van der Waals key is auxiliary, and its performance is similar to rock forming mineral.After this inorganic paint is painted on the cement based metope (as concrete, cement based putty, cement based insulation surface layer etc.), can penetrate into cement foundation wall surface, and generate water-fast Calucium Silicate powder with the calcareous material reaction in cement, form anchoring effect, coating and metope are combined as a whole securely.
Below introduce in detail product performance and the manufacture process of this kind of silicate inorganic coating by a plurality of embodiment.
embodiment mono-,compound proportion 1: liquid-state silicon colloidal sol (solid content=30% that first takes respectively 100 grams, hereinafter to be referred as silicon sol, the powder calcium carbonate of 300 grams down together),, then silicon sol is injected to the speed governing Scattered Kettle, progressively adding calcium carbonate and the auxiliary material of joining, then high-speed stirring is uniformly dispersed, after barrelling, period of storage reaches 6 months, the ultimate compression strength of test in its seven days is greater than 12MPa, and whiteness is greater than 85%, and Mohs' hardness is greater than 5.
embodiment bis-,compound proportion 2: first by the silicon sol of 100 grams, approximately the pearlstone of powder calcium carbonate, 20 grams of 200 grams and the MFT of 10 grams in kind are uniformly dispersed after the EVA redispersable latex powder of zero degree left and right mixes in the speed governing Scattered Kettle, this product can be used as a kind of inorganic fire thermal insulation coatings and uses, and after the use barrelling, period of storage reaches 6 months.With embodiment mono-product, compare, its splitting resistance power improves.
embodiment tri-,compound proportion 3: first by the silicon sol of 100 grams, approximately the iron oxide pigment of the Acrylic emulsion powder of titanium dioxide, 10 grams of powder calcium carbonate, 30 grams of 150 grams and 2 grams is uniformly dispersed after mixing in the speed governing Scattered Kettle, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.With embodiment bis-products, compare, it can present abundant color.Products obtained therefrom adopts JG/T 26-2002 " exterior wall inorganic architectural coatings " standard test, obtains technical indicator as shown in table 1,
.
embodiment tetra-,compound proportion 4: first by the silicon sol of 100 grams, approximately the hydrophobic type redispersable latex powder of the powder calcium carbonate of 250 grams and 15 grams is uniformly dispersed and is thick pulpous state after mixing in the speed governing Scattered Kettle, this product can be used as a kind of rigidity water-proofing material and uses, and its impermeability can reach 0.3MPa.
embodiment five,compound proportion 5: first the iron oxide pigment of the Acrylic emulsion powder of the graded sand and stone of the powder calcium carbonate of the silicon sol of 100 grams, 250 grams, 100 grams, 10 grams and 4 grams and appropriate densification powder (slurry), lignocellulose etc. are mixed and are the thixotropy mortar, the colored finish mortar that this material can be used as a kind of not accumulation of salt in the surface soil, process without cover is used.
embodiment six,compound proportion 6: first by the silicon sol of 100 grams, approximately the iron oxide pigment of EVA redispersable latex powder, 4 grams of graded sand and stone, 20 grams of powder calcium carbonate, 150 grams of 200 grams and appropriate flow agent are uniformly dispersed and are the rheological mortar after mixing in the speed governing Scattered Kettle, then pour in artificial stone plate's mould, reinforcement vibrating forming, the demoulding can obtain a kind of artificial stone plate of light by surface finish.
Above-mentioned those embodiment; used different compound proportions according to the application difference of this inorganic paint; though it is not exhaustive; but through putting into practice the present invention's compound proportion required for protection; i.e. 25%～60% liquid-state silicon colloidal sol by mass; the auxiliary material of joining below 40%～75% calcium carbonate and 20% is for conscientiously can meet the rational proportion that desired properties requires, and product is tentatively tried out stable performance.
By above-mentioned detailed description and embodiment introduction, can find out, apply technical scheme of the present invention, comparing to existing inorganic silicate coating has advantages of outstanding: it has ageing-resistant, weathering resistance is strong, with cement basic layer, Chemical bond power is arranged, do not peel, heat-resisting, fire prevention, nontoxic, the characteristics such as pollution-free and save energy, and it is not containing potassium, the strong basicity ions such as sodium, the pH value is less than 10, good with the consistency of pigment, can not produce accumulation of salt in the surface soil phenomenon, can make versicolor inorganic paint, it has realized a kind of alkali-free and the controlled inorganic coagulation material of open season, and there is good tint permanence, can be used for inorganic paint, the industries such as colored finish mortar and artificial platen.
In addition to the implementation, the present invention can also have other embodiment, and all employings are equal to the technical scheme of replacement or equivalent transformation formation, within all dropping on the present invention's scope required for protection.
Claims (9)
1. an inorganic paint, by body material, with the auxiliary material liquid combo of joining, become, it is characterized in that: the hydrated calcium silicate of described body material for being generated through the air-setting reaction by liquid-state silicon colloidal sol and calcium carbonate, the compound proportion of described liquid-state silicon colloidal sol and calcium carbonate is between 1:3～6:4 by weight; The described auxiliary mixture that material is the high molecular polymer of inorganic paint total mass below 20%, filler, pigment, paint additive of joining.
2. inorganic paint according to claim 1, it is characterized in that: the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, pH value and is less than 11, and particle diameter is less than 100 nanometers.
3. inorganic paint according to claim 1 is characterized in that: described calcium carbonate is purity more than 95%, the above powder of fineness 200 orders.
4. inorganic paint according to claim 1, it is characterized in that: described high molecular polymer is at least the EVA redispersable latex powder of MFT in the zero degree left and right, the esters of acrylic acid redispersable latex powder, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion through plasticising, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, one of aqueous alkide resin or multiple combination.
5. inorganic paint according to claim 1, it is characterized in that: described filler is at least one of titanium dioxide, mica, kaolin or multiple combination.
6. inorganic paint according to claim 1, it is characterized in that: described pigment is pigment dyestuff, mineral dye or the liquid color paste of being made by various pigment.
7. inorganic paint according to claim 1, it is characterized in that: described paint additive is at least one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas or multiple combination.
8. the method for making of an inorganic paint is characterized in that comprising step:
The liquid-state silicon colloidal sol of I, weighing by mass percentage 25%～60%, 40%～75% calcium carbonate and the 20% following auxiliary material of joining, the described auxiliary material of joining is comprised of high molecular polymer, filler, pigment, paint additive;
II, liquid-state silicon colloidal sol is joined in the speed governing Scattered Kettle, stir also and slowly add calcium carbonate and the auxiliary material of joining under vacuum, accelerate after interpolation to be stirred to evenly, make soup compound and sealing is preserved.
9. the described a kind of inorganic paint of claim 1, it is characterized in that: the application of wherein said body material at least comprises inorganic paint, refractory materials, colored thin layer facing mortar and artificial stone material.
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| CN201310468832.1A CN103497545A (en) | 2013-10-10 | 2013-10-10 | Inorganic coating, and preparation method and application thereof |
| PCT/CN2014/070123 WO2015051598A1 (en) | 2013-10-10 | 2014-01-03 | Base material of inorganic coating and application thereof |
| CN201410003196.XA CN103725051B (en) | 2013-10-10 | 2014-01-03 | A kind of body material of inorganic paint and application thereof |
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| CN103483884B (en) * | 2013-09-25 | 2015-12-09 | 上海新安纳电子科技有限公司 | A kind of High-performance waterborne inorganic paint and preparation method thereof |
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2013
- 2013-10-10 CN CN201310468832.1A patent/CN103497545A/en active Pending
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2014
- 2014-01-03 CN CN201410003196.XA patent/CN103725051B/en active Active
- 2014-01-03 WO PCT/CN2014/070123 patent/WO2015051598A1/en active Application Filing
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| CN110423495A (en) * | 2019-09-17 | 2019-11-08 | 郑州艾比利特节能科技有限公司 | A kind of bi-component inorganic floor coatings |
| CN113789092A (en) * | 2020-12-25 | 2021-12-14 | 优威康涂层科技(青岛)有限公司 | Nano inorganic antibacterial mildew-proof stain-resistant coating |
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| CN116218293A (en) * | 2023-05-05 | 2023-06-06 | 山东新广恒节能科技有限公司 | High weather-resistant exterior wall coating |
| CN116715982A (en) * | 2023-06-09 | 2023-09-08 | 江苏苏博特新材料股份有限公司 | Inorganic exterior wall building coating with high color retention and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103725051A (en) | 2014-04-16 |
| CN103725051B (en) | 2016-04-13 |
| WO2015051598A1 (en) | 2015-04-16 |
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