CN106396599A - Two-component luminescent inorganic coating - Google Patents

Two-component luminescent inorganic coating Download PDF

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Publication number
CN106396599A
CN106396599A CN201610856064.0A CN201610856064A CN106396599A CN 106396599 A CN106396599 A CN 106396599A CN 201610856064 A CN201610856064 A CN 201610856064A CN 106396599 A CN106396599 A CN 106396599A
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CN
China
Prior art keywords
component
inorganic coating
double
parts
luminescent material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610856064.0A
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Chinese (zh)
Inventor
彭晓光
杨辉
樊先平
姜译翔
姜益群
徐意
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zigong Innovation Center of Zhejiang University
Original Assignee
Zigong Innovation Center of Zhejiang University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zigong Innovation Center of Zhejiang University filed Critical Zigong Innovation Center of Zhejiang University
Priority to CN201610856064.0A priority Critical patent/CN106396599A/en
Publication of CN106396599A publication Critical patent/CN106396599A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • C04B14/106Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/807Luminescent or fluorescent materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the technical field of building materials and provides a two-component luminescent inorganic coating. The coating comprises a component A and a component B. The component A comprises, by weight, 10 to 30 parts of metakaolin, 1 to 5 parts of dispersible adhesive powder, 5 to 22 parts of a filler, 1 to 5 parts of a material, 3 to 10 parts of luminescent powder and 2.3 to 4.4 parts of an assistant. The component B comprises, by weight, 10 to 50 parts of sodium silicate. The two-component luminescent inorganic coating has good decorative performances, and is particularly suitable for residential buildings, commercial buildings and industrial factory buildings and has a broad application prospect.

Description

A kind of double-component light-emitting inorganic coating
Technical field
The invention belongs to building material field, particularly to a kind of double-component light-emitting inorganic coating.
Background technology
Inorganic coating, as ornament materials, has the advantages that fire-retardant, durable, VOC free, has higher development prospect.Pass , with cement-based material as binding agent, raw material sources are wide for the inorganic coating of system, and process is simple is preferably developed.Patent of invention 201310428927.0 applications disclose a kind of Ecotype inorganic paint for internal wall and external wall and its using method, including white silicic acid Salt cement, calcium sulfate crystal whiskers, SILICA FUME, rubber powder, calcium hydroxide, nano titanium oxide, water-retaining agent and glass bead, gained is inorganic Coating have ecological, environmental protective, insulation, cracking resistance antibacterial, decorative effect preferable the features such as.
But the preparation process of cement-based material has the characteristics that high energy consumption, it is extensively applied and is unfavorable for energy-saving and emission-reduction.Cause This, the inorganic filming substance matter developing low energy consumption has become the new trend of inorganic coating.And with the higher territory of inorganic active filler Double-component inorganic coating for film forming matter is one of important channel of solving the above problems.Meanwhile, the double of functional type are developed Component inorganic coating also becomes new challenge.
Content of the invention
The technical problem to be solved in the present invention is to overcome deficiency of the prior art, provides a kind of double-component light-emitting inorganic Coating.This coating, with inorganic active filler metakaolin as film forming matter, reaches raw material low energy consumption, lighting function, height use the longevity The purpose of life.
For solving technical problem, the solution of the present invention is:
A kind of double-component light-emitting inorganic coating is provided, is to be mixed by the raw material of following weight percentage:
Component A:
B component:
10~50 parts of waterglass;
In the present invention, described filler is in silicon powder, feldspar powder, Calcium Carbonate, montmorillonite, aluminium oxide or aluminium silicate Plant or two or more.
In the present invention, described pigment is in titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, chrome green or cobalt blue One or more.
In the present invention, described luminescent powder is halogen-phosphate luminescent material, phosphate luminescent material, silicate luminescent material One of material, aluminate luminescent material or vanadate luminescent material or two or more.
In the present invention, described auxiliary agent is air entraining agent, water reducer, defoamer, thickening agent, antifungus agent, antibacterial, cellulose One of ether, wood fibre or starch ether or two or more;
In the present invention, described waterglass is one of sodium silicate, KP1 or two kinds.
As a kind of preferred version, described double-component light-emitting inorganic coating, is by the raw material of following weight percentage Mix:
Component A:
B component:
10~50 parts of waterglass.
Under the group subassembly of above-mentioned further preferred each weight portion, the double-component light-emitting inorganic coating of preparation being capable of body Reveal optimal performance, there is good illumination effect and high service life.
Compared with prior art, the invention has the advantages that:
Double-component light-emitting inorganic coating of the present invention is with higher territory as film forming matter, it is possible to decrease the energy consumption of raw material;And adopt Luminescent powder is decorative effect, can obtain special illumination effect under sunlight.Additionally, double-component light-emitting inorganic of the present invention applies VOC (i.e. VOC) content of material is relatively low, and environmental pollution, environmental friendliness can be greatly reduced.
Double-component light-emitting inorganic coating of the present invention has good decoration performance, is particularly well-suited to civil construction, commercially builds Build, the occasion such as industrial premises, have broad application prospects.
Specific embodiment
With reference to case study on implementation, the present invention is further described." part " in the following example refers both to weight portion.
Embodiment 1
20 parts of metakaolin, 3 parts of Rutile type titanium dioxide, 2 parts of iron oxide red, Calcium Carbonate 10 is added toward in dispersing apparatus Part, 1 part of kieselguhr, 5 parts of silicon powder, 3 parts of luminescent powder, 0.1 part of water reducer, 0.2 part of defoamer, 0.5 part of cellulose ether, starch 0.2 part of ether, 1 part of antibacterial, 0.3 part of antifungus agent and 3 parts of re-dispersible glue powder, stir and through screen filtration, obtain this The component A of bright double-component light-emitting inorganic coating products.30 parts of moduluses are 3.2, the sodium silicate of solid content 30% can be directly as The B component of double-component light-emitting inorganic coating products of the present invention.
Embodiment 2
10 parts of metakaolin, 1 part of iron oxide red, 2 parts of Calcium Carbonate, 3 parts of silicon powder, luminescent powder is added toward in dispersing apparatus 6 parts, 0.3 part of water reducer, 0.1 part of defoamer, 1 part of cellulose ether, 1 part of antibacterial, 0.2 part of antifungus agent and re-dispersible glue powder 1 Part, stir and through screen filtration, obtain the component A of double-component light-emitting inorganic coating products of the present invention.10 parts of moduluses are 2.0th, the sodium silicate of solid content 30% can be directly as the B component of double-component light-emitting inorganic coating products of the present invention.
Embodiment 3
30 parts of metakaolin, 1 part of Rutile type titanium dioxide, 3 parts of iron oxide yellow, Calcium Carbonate 15 is added toward in dispersing apparatus Part, 3 parts of kieselguhr, 4 parts of silicon powder, 10 parts of luminescent powder, 0.5 part of water reducer, 1 part of defoamer, 0.6 part of cellulose ether, starch 0.1 part of ether, 2 parts of antibacterial, 0.2 part of antifungus agent and 5 parts of re-dispersible glue powder, stir and through screen filtration, obtain this The component A of bright double-component light-emitting inorganic coating products.50 parts of moduluses are 3.2, the KP1 of solid content 30% can be directly as The B component of double-component light-emitting inorganic coating products of the present invention.
Embodiment 4
15 parts of metakaolin, 3 parts of iron oxide black, 6 parts of Calcium Carbonate, 2 parts of kieselguhr, silicon powder 7 is added toward in dispersing apparatus Part, 5 parts of luminescent powder, 0.2 part of water reducer, 0.6 part of defoamer, 0.1 part of cellulose ether, 1.5 parts of antibacterial, 0.3 part of antifungus agent With 3 parts of re-dispersible glue powder, stir and through screen filtration, obtain the A group of double-component light-emitting inorganic coating products of the present invention Point.20 parts of moduluses are 2.0, the KP1 of solid content 30% can be directly as double-component light-emitting inorganic coating products of the present invention B component.
Comparative example 1
20 parts of metakaolin, 3 parts of Rutile type titanium dioxide, 2 parts of iron oxide red, Calcium Carbonate 10 is added toward in dispersing apparatus Part, 1 part of kieselguhr, 5 parts of silicon powder, 0.1 part of water reducer, 0.2 part of defoamer, 0.5 part of cellulose ether, 0.2 part of starch ether, antibacterial 1 part of agent, 0.3 part of antifungus agent and 3 parts of re-dispersible glue powder, stir and through screen filtration, obtain double-component of the present invention and light The component A of inorganic coating product.30 parts of moduluses are 3.2, the sodium silicate of solid content 30% can be directly as double-component of the present invention The B component of light-emitting inorganic coating products.
Using method explanation:
Toward in component A, under the conditions of 5~45 DEG C, add the water of 20% weight ratio, stir 3 minutes.Add corresponding weight The B component of ratio, stirring can be criticized and scrape or spray for 5 minutes.Require body of wall clean, every thickness degree must not exceed 1mm, surface drying rear applies Cover lower one.Configurable coating needs to be finished in 2 hours.
The double-component light-emitting inorganic coating products test illumination effect of the present invention that embodiment 1~4 is obtained, result such as table 1 Shown.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Comparative example 1
Illumination effect Luminescence phenomenon Luminescence phenomenon Luminescence phenomenon Luminescence phenomenon No luminescence phenomenon
From table 1, by double-component light-emitting inorganic coating products of the present invention prepared by luminescent powder, there is illumination effect, Double-component light-emitting inorganic coating of the present invention can be made to have special decorative effect it is adaptable to civil construction, commercial building, industrial factory The occasions such as room.

Claims (8)

1. a kind of double-component light-emitting inorganic coating is it is characterised in that be to be mixed by the raw material of following weight percentage:
Component A:
B component:
10~50 parts of waterglass.
2. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that described filler is silicon powder, length One of stone powder, Calcium Carbonate, montmorillonite, aluminium oxide or aluminium silicate or two or more.
3. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that described pigment is titanium dioxide, oxygen Change one of iron oxide red, iron oxide yellow, iron oxide black, chrome green or cobalt blue or two or more.
4. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that described luminescent powder is halogen phosphoric acid In salt luminescent material, phosphate luminescent material, silicate luminescent material, aluminate luminescent material or vanadate luminescent material one Plant or two or more.
5. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that described auxiliary agent is air entraining agent, subtracts One of water preparation, defoamer, thickening agent, antifungus agent, antibacterial, cellulose ether, wood fibre or starch ether or two or more.
6. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that described waterglass is sodium water glass One of glass, KP1 or two kinds.
7. double-component light-emitting inorganic coating according to claim 1 is it is characterised in that be by following weight percentage Raw material mixes:
Component A:
B component:
10~50 parts of waterglass.
8. double-component light-emitting inorganic coating according to claim 7 is it is characterised in that described luminescent powder is halogen phosphoric acid In salt luminescent material, phosphate luminescent material, silicate luminescent material, aluminate luminescent material, vanadate luminescent material one Plant or two or more;Described pigment be one of iron oxide red, iron oxide yellow, iron oxide black, chrome green, cobalt blue or two kinds with On;Described waterglass is one of sodium silicate, KP1 or two kinds.
CN201610856064.0A 2016-09-28 2016-09-28 Two-component luminescent inorganic coating Pending CN106396599A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610856064.0A CN106396599A (en) 2016-09-28 2016-09-28 Two-component luminescent inorganic coating

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Application Number Priority Date Filing Date Title
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CN106396599A true CN106396599A (en) 2017-02-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717564A (en) * 2021-09-01 2021-11-30 广东青筑科技有限公司 Double-component luminous decorative material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015051598A1 (en) * 2013-10-10 2015-04-16 弗克科技(苏州)有限公司 Base material of inorganic coating and application thereof
CN104529300A (en) * 2014-12-23 2015-04-22 广西启利新材料科技股份有限公司 Geopolymer-base sea-base concrete protective coating
CN105949826A (en) * 2016-05-21 2016-09-21 浙江大学自贡创新中心 Double-component inorganic heat-insulation coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015051598A1 (en) * 2013-10-10 2015-04-16 弗克科技(苏州)有限公司 Base material of inorganic coating and application thereof
CN104529300A (en) * 2014-12-23 2015-04-22 广西启利新材料科技股份有限公司 Geopolymer-base sea-base concrete protective coating
CN105949826A (en) * 2016-05-21 2016-09-21 浙江大学自贡创新中心 Double-component inorganic heat-insulation coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘栋等: "《功能涂料配方设计与制造技术》", 31 January 2009 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717564A (en) * 2021-09-01 2021-11-30 广东青筑科技有限公司 Double-component luminous decorative material
CN113717564B (en) * 2021-09-01 2022-08-05 广东青筑科技有限公司 Double-component luminous decorative material

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Application publication date: 20170215

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