CN113717564A - Double-component luminous decorative material - Google Patents
Double-component luminous decorative material Download PDFInfo
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- CN113717564A CN113717564A CN202111021805.0A CN202111021805A CN113717564A CN 113717564 A CN113717564 A CN 113717564A CN 202111021805 A CN202111021805 A CN 202111021805A CN 113717564 A CN113717564 A CN 113717564A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a two-component luminous decorative material, which can simultaneously solve the problems that the luminous powder with the coarse particle size is difficult to stably distribute, and the coating is limited in construction. The double-component luminous decorative material is composed of a dry powder component and an emulsion component, the emulsion and the dry powder are added into a stirring barrel according to the proportion before use, after the emulsion and the dry powder are uniformly stirred, tools such as a plaster knife are adopted to coat the stirred slurry on a base surface, and the slurry can be made into various shapes.
Description
Technical Field
The invention relates to the technical field of luminous coatings, in particular to a double-component luminous decorative material.
Background
Nowadays, with the rapid development of science and technology, the varieties of building decoration materials are also in the endlessly. Color mortar, colorful paint and waterproof material, which are different from each other. With the gradual and intensive research on environment-friendly luminescent materials, more and more types of coating products are produced by adopting the luminescent materials for luminescent decoration.
With the increasing practical application scenes of the luminescent materials, the defects of the luminescent materials are gradually revealed: for example, it is difficult to stably distribute the particles in the emulsion for a long period of time, the high-brightness period is short, and the brightness is lower as the particle size is smaller at the same amount.
The particle size of the luminescent powder has obvious influence on the luminescent brightness. The larger the particle size is, the higher the luminous brightness is; however, the thicker the particle size, the more difficult the phosphor powder is to be stably distributed in the coating, and the phosphor powder is difficult to be uniformly distributed on the base surface in the construction process, which has higher requirements on the construction process.
Disclosure of Invention
The invention aims to provide a two-component luminous decorative material which can simultaneously solve the problems that the luminous powder with the coarse particle size is difficult to stably distribute in the coating and the construction is limited.
In order to achieve the purpose, the invention adopts the following technical scheme: a two-component luminous decorative material comprises a dry powder component and an emulsion component, wherein the dry powder component comprises the following components in parts by weight:
the emulsion component comprises the following components in parts by weight:
further, the ratio of the dry powder component to the emulsion component is 1: 0.3-0.5.
Further, the emulsion is any one of silicone-acrylate emulsion, styrene-acrylate emulsion, organic silicon emulsion, pure acrylic emulsion, polyurea resin and epoxy resin.
Further, the cellulose ether is hydroxymethyl cellulose ether.
Further, the first defoaming agent is a dry powder defoaming agent.
Further, the preservative is a cason preservative.
Further, the second antifoaming agent is a nopinaceae NXZ antifoaming agent.
Further, the dispersing agent is a hydrophobic modified acrylic acid ammonium salt copolymer dispersing agent.
Further, the wetting agent is a hesbaumi wetting agent.
Further, the thickening agent is a hydrophobically modified alkali swelling thickening agent.
Compared with the prior art, the invention has the following beneficial effects:
the invention can solve the problems that the luminescent powder with coarse particle size is difficult to stably distribute, and the coating is limited in construction through the double-component luminescent decorative material. The double-component luminous decorative material is composed of a dry powder component and an emulsion component, the emulsion and the dry powder are added into a stirring barrel according to the proportion before use, after the emulsion and the dry powder are uniformly stirred, tools such as a plaster knife are adopted to coat the stirred slurry on a base surface, and the slurry can be made into various shapes.
In addition, the invention also has the following technical effects:
(1) and (3) prolonging the storage period: the two-component luminous decorative material consists of a dry powder component and an emulsion component, wherein the luminous powder exists in the dry powder component, and the dry powder component is stored as long as the conditions of drying, shade and ventilation are met, so that the dry powder component cannot form agglomeration, and the quality of the product can be ensured;
(2) the luminous brightness of the decorative material is improved: the test shows that: the larger the particle size of the material, the more energy is required and the higher the brightness is emitted.
(3) The construction is quick and simple: the decorative material is added into the stirring barrel in proportion before being used, and the mortar knife can be adopted for construction after being uniformly stirred, so that the construction method is popular, simple, fast and easy to control.
Detailed Description
The invention aims to provide a two-component luminous decorative material which can simultaneously solve the problems that the luminous powder with the coarse particle size is difficult to stably distribute in the coating and the construction is limited.
In order to make the objects, features and advantages of the present invention more obvious and understandable, the embodiments of the present invention will be described in detail and fully with reference to the accompanying drawings. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
a two-component luminous decorative material comprises a dry powder component and an emulsion component, wherein the dry powder component comprises the following components in parts by weight:
the emulsion component comprises the following components in parts by weight:
specifically, the ratio of the dry powder component to the emulsion component is 1:0.3, and the dry powder component and the emulsion component need to be mixed and stirred in proportion before use to form a uniform paste.
Example two:
the emulsion comprises a dry powder component and an emulsion component, wherein the dry powder component comprises the following components in parts by weight:
the emulsion component comprises the following components in parts by weight:
specifically, the ratio of the dry powder component to the emulsion component is 1:0.5, and the dry powder component and the emulsion component need to be mixed and stirred in proportion before use to form a uniform paste.
Energy storage luminescent powder, also known as noctilucent powder or long afterglow luminescent material, the basic process of preparation and general classification of the product: firstly, raw materials such as aluminum oxide, strontium carbonate and the like are uniformly mixed according to a certain proportion and then are loaded into a sagger, and the mixture is fired at high temperature in a reducing atmosphere to prepare a noctilucent block which is then processed into a particle size product required by customers through physical processes such as crushing, rail alignment, ball milling, screening and the like. The luminous powder can be generally divided into the following parts in terms of luminous color: yellow-green, blue-green, sky-blue, purple, red and white. The energy-storing luminescent powder can store luminescent energy and slowly release luminescence after a light source is turned off, particularly the afterglow time of the rare earth activated alkaline earth aluminate long afterglow material can reach more than 12 hours, and the energy-storing luminescent powder has the characteristics of light storage in the daytime and long-term circulating light storage and luminescence emitted at night. The fluorescent powder has the advantages of no toxicity, no harm and no radioactivity, and has wide application prospect, and luminous ceramics, luminous glass, luminous labels, luminous films, luminous plastics, luminous rubber, luminous (oil-based and water-based) coatings, luminous printing ink, printing paste and the like are developed at present.
In the dry powder components of the embodiment of the invention, the energy storage luminescent powder is used as a functional substance of the decorative material, the mesh number of the selected luminescent powder can be selected according to requirements, and the thickness of the particle diameter is not limited.
The glass powder is inorganic amorphous hard superfine particle powder and is white powder in appearance. In the production process, raw materials such as high-temperature high-purity silicon oxide, aluminum oxide and the like are used, and then an ultra-clean production process is carried out to form a glass transparent powder with a disordered structure, and the super-weather-resistant powder material has stable chemical property, acid and alkali resistance, chemical inertia and low expansion coefficient; the glass powder is a scratch-resistant high-transparency powder, and has small particle size, good dispersibility, high transparency and good anti-settling effect; the crystal transparent primer has good affinity and strong steric hindrance ability after surface improvement, can be conveniently dispersed in the coating, can increase the fullness of the coating after film forming, and can keep clear transparency and provide good scratch resistance. The glass powder is used as one of the filling aggregates, has high hardness, good transparency and small water absorption, has low influence on the brightness and the whole construction effect of the luminescent material, and in addition, the luminescent material cannot be mixed with non-transparent materials for use, otherwise, the bright light can be covered by the non-transparent materials.
The transparent powder is used as the filling aggregate 2, is a non-metallic mineral, has good flexibility and high transparency, and has the functions of improving the flexibility and the crack resistance of a finished product when being used in the decorative material. In addition, the transparent powder is a non-metallic mineral, has high hardness, low oil absorption, easy dispersion, strong stability, no toxicity, no odor, acid resistance and corrosion resistance. The high-transparency high-performance light-resistant and high-scratch-resistant composite material has high transparency, and the refractive index of the filler is very close to that of most of synthetic resins, so that the transparency of a finished product is not influenced by the filling amount of the filler, the surface smoothness and the scratch resistance of the product can be improved, and the manufacturing cost of the product can be reduced. The transparent powder is not a single powder, and is prepared by adding special synthetic auxiliary materials to natural ore rocks as main components, mixing, grinding, modifying and modulating. The main component is composite silicate containing Mg, Al and Ca, and belongs to inorganic salt. In addition, the transparent powder contains partial sulfate and impurities, is a novel functional transparent filling material, and has the characteristics of high transparency, good hardness, good hue, high gloss, good collapse resistance, less dust emission in use and the like.
Cellulose ether: the viscosity of the cellulose ether is 20000S, and the selected cellulose ether is hydroxymethyl cellulose ether. The main function of the addition of the cellulose ether is to increase the workability of the dry powder component, so that the slurry mixed with the emulsion component has certain stability and good application property, and the cellulose ether with high purity and low viscosity is selected from the material. The defoaming agent is a common additive in mortar, and has the function of eliminating bubbles in the paste in the construction process and ensuring the construction effect.
Preferably, the emulsion is any one of silicone-acrylic emulsion, styrene-acrylic emulsion, silicone emulsion, pure acrylic emulsion, polyurea resin and epoxy resin. As the emulsion component in the luminescent material, the emulsion is selected to have excellent transparency and wrapping property, the high transparency can ensure the luminescent brightness of the luminescent material, the good wrapping property can completely wrap the dry powder component to form a paste, and the smooth construction surface is ensured; secondly, the self-weatherability, flexibility, wear resistance and impact resistance are good, and finally, the selected emulsion or resin should meet the requirement of limited amount of substances. The emulsion can be selected from silicone-acrylic emulsion, styrene-acrylic emulsion, silicone emulsion, pure acrylic emulsion, polyurea resin, epoxy resin, etc.
The luminescent material is applied to different scenes, and has different emphasis requirements on the requirements of emulsion.
For example:
the application scene one:
when the luminescent decorative material is applied to floor decoration, emulsion (such as polyurea resin and epoxy resin) with relatively excellent performances such as weather resistance, impact resistance, wear resistance, water resistance, alkali resistance and the like needs to be selected so as to prolong the service life of the decorative material;
application scenario two:
when the luminescent decorative material is used for a wall, an emulsion (such as silicone-acrylic emulsion, silicone emulsion and pure acrylic emulsion) with better weather resistance, flexibility, water resistance and stain resistance is required to be selected.
In addition, the additive sterilization preservative of the emulsion component is mainly a kasong preservative which is non-toxic and has good sterilization effect.
Preferably, the first defoaming agent is a dry powder defoaming agent.
Specifically, the dry powder defoaming agent is a mixture, and the defoaming agent is selected according to the used emulsion or resin, so that the mixture has an excellent defoaming effect when the emulsion and the dry powder are mixed and stirred, and the main purpose is to eliminate pores on the surface of the slurry.
Preferably, the preservative is a cason preservative; the second antifoaming agent is NXZ antifoaming agent of Nopochaceae.
Preferably, the dispersing agent is a hydrophobically modified acrylic acid ammonium salt copolymer dispersing agent, and the dispersing agent and the wetting agent are mainly selected according to the used emulsion or resin, so as to provide guarantee for the subsequent mixing of a dry powder component and an emulsion component to form a uniform paste; the wetting agent is a husky wetting agent; the thickening agent is a hydrophobic modified alkali swelling thickening agent, and is used for adjusting the viscosity of the emulsion component and helping the emulsion component to keep a uniform and stable state; the film-forming assistant can be added or not added according to the film-forming temperature of the emulsion, and the main function is to reduce the film-forming temperature of the emulsion and prevent the finished product from cracking, peeling and the like.
TABLE 1 Properties of two-component light-emitting device materials prepared in examples 1-2
In conclusion, the embodiment of the invention can simultaneously solve the problems that the luminescent powder with the coarse particle size is difficult to stably distribute, the coating is difficult to be applied and the construction is limited through the double-component luminescent decorative material. The double-component luminous decorative material is composed of a dry powder component and an emulsion component, the emulsion and the dry powder are added into a stirring barrel according to the proportion before use, after the emulsion and the dry powder are uniformly stirred, tools such as a plaster knife are adopted to coat the stirred slurry on a base surface, and the slurry can be made into various shapes.
The above-mentioned embodiments are only used for illustrating the technical solutions of the present invention, and not for limiting the same; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
1. The two-component luminous decorative material is characterized by comprising a dry powder component and an emulsion component, wherein the dry powder component comprises the following components in parts by weight:
the emulsion component comprises the following components in parts by weight:
2. the two-component luminescent decorative material as claimed in claim 1, wherein the ratio of the dry powder component to the emulsion component is 1: 0.3-0.5.
3. The two-component luminous decorative material of claim 1, wherein the emulsion is any one of silicone-acrylic emulsion, styrene-acrylic emulsion, silicone emulsion, pure acrylic emulsion, polyurea resin and epoxy resin.
4. The two-component luminescent decorative material of claim 1 wherein the cellulose ether is a hydroxymethyl cellulose ether.
5. The two-component luminescent decorative material of claim 1, wherein the first defoamer is a dry powder defoamer.
6. The two-component luminescent decorative material of claim 1, wherein the preservative is a kasong-type preservative.
7. The two-component luminescent decorative material according to claim 1, wherein the second antifoaming agent is nopinaceae NXZ antifoaming agent.
8. The two-component luminescent decorative material of claim 1, wherein the dispersant is a hydrophobically modified ammonium acrylate copolymer dispersant.
9. The two-component luminescent decorative material of claim 1, wherein the wetting agent is a hesbaumi wetting agent.
10. The two-component luminescent decorative material of claim 1, wherein the thickener is a hydrophobically modified alkali swellable thickener.
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| CN202111021805.0A CN113717564B (en) | 2021-09-01 | 2021-09-01 | Double-component luminous decorative material |
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| CN202111021805.0A CN113717564B (en) | 2021-09-01 | 2021-09-01 | Double-component luminous decorative material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114381186A (en) * | 2022-01-19 | 2022-04-22 | 惠州Tcl移动通信有限公司 | Paint and method for applying paint on surface of product |
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2021
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114381186A (en) * | 2022-01-19 | 2022-04-22 | 惠州Tcl移动通信有限公司 | Paint and method for applying paint on surface of product |
| CN114381186B (en) * | 2022-01-19 | 2023-08-15 | 惠州Tcl移动通信有限公司 | Paint and method for applying paint on product surface |
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