CN104927419B - One kind reaction film-forming inorganic dry powder paint and its production method - Google Patents
One kind reaction film-forming inorganic dry powder paint and its production method Download PDFInfo
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- CN104927419B CN104927419B CN201510414725.XA CN201510414725A CN104927419B CN 104927419 B CN104927419 B CN 104927419B CN 201510414725 A CN201510414725 A CN 201510414725A CN 104927419 B CN104927419 B CN 104927419B
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- 239000000843 powder Substances 0.000 title claims abstract description 131
- 239000003973 paint Substances 0.000 title claims abstract description 61
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 50
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 33
- 239000002994 raw material Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 25
- 230000000694 effects Effects 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 61
- 239000003638 reducing agent Substances 0.000 claims description 33
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 32
- 235000019353 potassium silicate Nutrition 0.000 claims description 29
- 239000001023 inorganic pigment Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 10
- 238000007130 inorganic reaction Methods 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 235000015450 Tilia cordata Nutrition 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 238000007761 roller coating Methods 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J Potassium alum Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 4
- 235000011126 aluminium potassium sulphate Nutrition 0.000 claims description 4
- 229960000892 attapulgite Drugs 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- 229940050271 potassium alum Drugs 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000011164 primary particle Substances 0.000 claims description 3
- 229910021487 silica fume Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000011068 load Methods 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 60
- 239000000454 talc Substances 0.000 description 30
- 235000012222 talc Nutrition 0.000 description 30
- 229910052623 talc Inorganic materials 0.000 description 30
- 239000004408 titanium dioxide Substances 0.000 description 30
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 13
- 229910000460 iron oxide Inorganic materials 0.000 description 13
- 238000010433 powder painting Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000007792 addition Methods 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 239000010456 wollastonite Substances 0.000 description 4
- 229910052882 wollastonite Inorganic materials 0.000 description 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N Chromium(III) oxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- -1 aluminum silicon Chemical compound 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004642 transportation engineering Methods 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000001680 brushing Effects 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052803 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 230000003247 decreasing Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Abstract
The present invention provides a kind of reaction film-forming inorganic dry powder paint and its production method, belongs to technical field of coatings.The coating that the present invention is provided, it is made up of inorganic filmogen, filler and auxiliary material, and the inorganic filmogen accounts for the 20 50% of the dry powder paint gross mass；The filler accounts for the 20 70% of the gross mass of the dry powder paint；Surplus is auxiliary material；The siliceous and/or sa raw material and calcareous raw material that the inorganic filmogen has high pozzolanic activity by nanometer or submicron-scale are constituted, the calcareous raw material has adhesivity after adding water, described siliceous and/or sa raw material accounts for the 20 50% of the inorganic filmogen gross mass, and surplus is the calcareous raw material.Compared with existing coating, the stirring that adds water of the coating scene that provides of the present invention can be brushed, easy construction, water-alkali resistance is excellent, drying time is short, adhesion strength is high, abrasion resistance is good.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of reaction film-forming inorganic dry powder paint for inner wall decoration and its
Production method.
Background technology
With society and the development and progress of modern science and technology, people increasingly pay close attention to shadow of the living environment for health
Ring.It is more and more high for the cry of the low emission even zero-emission of indoor coating VOC (VOC).All buildings
Coating is all made up of three parts：Film forming matter, filler and auxiliary agent.Film forming matter plays a part of bonding agent, and its function is shape
Into continuous or quasi-continuous film；Filling packing plays wear-resisting, scratch resistance in film forming matter, reduces the effect such as cost；Auxiliary agent is then
Play some performances of adjusting coating（Such as rheological characteristic, mildew resistance）Effect.Now widely used interior wall coating is emulsion paint, nothing
By which kind of emulsion paint using high molecular synthetic resin as film forming matter, low VOC indexs are extremely difficult to.In the market also has some low
The VOC even naval stores of Diamond Search, but it is all expensive.In addition, emulsion paint is suspended liquid system, solid content is mostly left 50%
The right side, remaining is water or other solvents.Therefore, the cost of transportation of at least half has been used to carry the water or molten finally to be vapored away
Agent.Inorganic dry powder painting can overcome above-mentioned deficiency.Lime and its derivative（Sierozem power, calcium hydroxide powder）It is about earliest
Inorganic dry powder painting, its film forming mechanism is the carbonization by lime, haves the shortcomings that ash is serious, has essentially dropped out application field.
In recent years under the urging of environmental requirement, occur in that inorganic dry powder painting develops upsurge, there is many documents and patent to disclose.Summarize
Come, developing inorganic dry powder painting substantially there are three class thin film-forming methods：1. using organic redisperse rubber powder as main film forming substance, such as
CN2009101933522.Such an approach achieves no longer carrying water or solvent, but for reduction VOC without too many constructive work
With；2. using the hydraulicity such as portland cement inorganic coagulation material as film forming matter, such as CN2013104093689.This method
Diamond Search can be realized while cost of transportation is saved, but hydrated cementitious, setting time are shorter, and coating must make immediately after mixing and stirring
With, it is impossible to place.3. film forming matter, such as CN2011104466990 are used as using alkali silicate and curing agent.This method
Principle is that alkali silicate forms indissoluble silicate colloid so as to film forming with curing agent chemically reactive, due in aqueous
The reaction speed of alkali silicate and curing agent is very fast, therefore thickening just occurs in work progress, and workability is poor.Such as
The slow coating of fruit speed of application even lumps failure.In addition to above-mentioned three basic forms of it, be more 1. with combination 2., 3.,
Such as CN2006100366259, CN2014108540807, CN2014108540760 etc..This combination reduces organic tree
Fat addition, the VOC of coating is also decreased, but can not be referred to as really purely inorganic coating, and its VOC value still relies on tree
The quality of fat.
The content of the invention
The purpose of invention is in view of the shortcomings of the prior art, providing a kind of inorganic dry powder painting for reacting film forming.The present invention
Raw materials used is inorganic material, in the absence of volatile organic matter.Institute's invention coating is the height using nanometer or submicron-scale
Pozzolanic activity sa raw material and calcareous raw material reacts in the case where there is water condition generates silicate gel and film forming.This was both realized
Pure inorganic reaction film forming, overcome that background technology addresses again because condense it is fast the workability brought it is not good and after adding water
The shortcomings of can not depositing in short term.The coating scene stirring that adds water can be brushed, and easy construction, water-alkali resistance is excellent, dry
Time is short, adhesion strength is high, abrasion resistance good.
To achieve the above object, a kind of reaction film-forming inorganic dry powder paint, it is by inorganic filmogen, filler and auxiliary material
Material composition, the inorganic filmogen accounts for the 20-50% of the dry powder paint gross mass；The filler accounts for the dry powder paint
The 20-70% of gross mass；Surplus is auxiliary material；
The inorganic filmogen has the siliceous and/or sa of high pozzolanic activity former by nanometer or submicron-scale
Material and calcareous raw material composition, described siliceous and/or sa raw material account for the 20-50% of the inorganic filmogen gross mass, surplus
For the calcareous raw material.
Further, the siliceous raw material be white carbon, SILICA FUME, superfine glass beads, the dry colloidal sol of silica in extremely
Few one kind, particle diameter≤1 micron of its primary particle.The sa raw material includes superfine calcined kaolin, nanotube-shaped sial
At least one of powder, particle diameter≤1 micron of its primary particle.Described siliceous and/or sa raw material summation accounts for the nothing
Machine reacts the 20-50% of filmogen gross weight.
Further, the calcareous raw material is any one or a few the mixing in sierozem power, calcium lime powder, hydrated lime in powder
Thing.
The filler is dry powder（Powdered whiting, wollastonite in powder）, talcum powder, titanium dioxide, it accounts for the reaction respectively
15-45%, 5-20%, 1-4% of film-forming inorganic dry powder paint gross weight, wherein dry powder, powdered whiting, wollastonite in powder both may be used
Individually addition, can also be used in any combination.
The auxiliary material has activator, thickener, water reducer, defoamer and inorganic pigment.Above auxiliary material be by
It is added according to being actually needed, addition species can be a kind of or multiple combinations.
Further, the activator is any one or a few the mixture in waterglass, sodium metasilicate, potassium alum, this
With the siliceous raw material with pozzolanic activity, sa raw material hydration reaction can occur for a little materials in the presence of water, by
It is short in the hydrated product setting time of formation, be conducive to improving the early stage adhesion strength of inorganic dry powder painting, so as to effectively solve
This inorganic filmogen the problem of early stage aquation film forming is more slow, adhesion strength is inadequate, its account for the reaction film forming without
The 0-1% of machine dry powder paint gross weight.
Further, the thickener is any one or a few the mixture in diatomite, attapulgite, bentonite,
These materials have good suspension and dispersiveness, have both been avoided that the sagging phenomenon occurred in construction, can have coating again
Good mechanical performance and bin stability, account for the 0-8% of the reaction film-forming inorganic dry powder paint gross weight, wherein diatomite
Due to its special loose structure so that the coating possesses the damping and sound insulating and absorbing effect similar with diatom ooze, so that overall
Function is identical with diatom ooze.
Further, the water reducer, defoamer are that the inorganic dry powder painting well known to those skilled in the art that can be used as adds
Plus the conventional material of agent, those skilled in the art can voluntarily choose whether addition and it is determined that during addition selection it is corresponding suitable
Material is added in reaction film-forming inorganic dry powder paint of the present invention, and the purpose of the present invention can be achieved, the water reducer, disappears
Infusion accounts for 0-2%, 0-2% of the reaction film-forming inorganic dry powder paint gross weight respectively.
Further, the inorganic pigment is iron oxide red, cadmium red, barba hispanica, cobalt blue, cadmium yellow, iron oxide yellow, zinc yellow, lead
Chrome yellow, chrome oxide green, chrome green, iron oxide brown, carbon black, etc. in any one material, account for it is described reaction film-forming inorganic dry powder
The 0-8% of coating gross weight.
Following preparation method and technique should be used to obtain the reaction film-forming inorganic dry powder paint（Its flow chart such as accompanying drawing
It is shown）：
1. weigh siliceous raw material and（Or）Ball milling after sa raw material and calcareous raw material, mixing.Ball milling is by inorganic reaction
While the granularity of filmogen is ground thinner, also it is sufficiently mixed inorganic reaction filmogen, each other uniform contact, so as to carry
The pozzolanic reaction activity of height reaction film-forming inorganic dry powder paint；
2. load weighted filler and auxiliary material are added into the inorganic reaction film forming compound after ball milling, and continues ball
Mill, so as to obtain the reaction film-forming inorganic dry powder paint of the present invention.
Directly add water and stir when using, blade coating, roller coating or be sprayed on interior wall.
Coating is watered ratio, during blade coating, coating：Water=1:When 0.5-1.0, roller coating and spraying, coating：Water=1:1.0-1.5.
The advantage of the invention is that：
1st, the present invention is the high pozzolanic activity of nanometer or submicron-scale in pure inorganic reaction thin film-forming method, coating
Sa raw material and calcareous raw material reacts generation silicate gel in the case where there is water condition and film forming, over time, cohesive
Intensity meeting more and more higher, it is durable.
2nd, too fast shortcoming is condensed instant invention overcomes inorganic dry powder painting, workability is excellent, and can be with after adding water
Storage.
3rd, raw materials used is all nontoxic inorganic mineral material, and without brushing emulsion paint, so that it may reach interior wall
The effect of decoration, will not be polluted to environment, and also health will not be caused harm.
4th, the cost of raw material of the invention is low, simple production process, and the coating scene stirring that adds water can be brushed, and be used
It is convenient.
Brief description of the drawings
The preparation method process chart for the reaction film-forming inorganic dry powder paint that Fig. 1 provides for the present invention.
Embodiment
Illustrate the present invention program below in conjunction with the accompanying drawings and by embodiment.It is to be appreciated that following examples are
Preferred embodiment, it is only to illustrate this programme to be used.
Embodiment 1：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic pigment
0。
Embodiment 2：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 22%, sierozem power 10%, dry powder
44%th, talcum powder 5%, titanium dioxide 2.5%, waterglass 0.5%, diatomite 6%, water reducer 1.4%, defoamer 1.5%, iron oxide red
7.1%。
Embodiment 3：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 4%, sierozem power 26%, dry powder
45%th, talcum powder 16%, titanium dioxide 2%, waterglass 0.7%, diatomite 2.8%, water reducer 0.8%, defoamer 1.8%, iron oxide red
0.9%。
Embodiment 4：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 7%, sierozem power 33%, dry powder
30%th, talcum powder 12%, titanium dioxide 3%, waterglass 0.1%, diatomite 8%, water reducer 1.8%, defoamer 2%, iron oxide red 3.1%.
Embodiment 5：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 19%, sierozem power 14%, dry powder
27%th, talcum powder 20%, titanium dioxide 4%, waterglass 0.9%, diatomite 6.8%, water reducer 1.4%, defoamer 1.1%, iron oxide red
5.8%。
Embodiment 6：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 14%, sierozem power 23%, dry powder
30%th, talcum powder 17%, titanium dioxide 1%, waterglass 0.6%, diatomite 3.2%, water reducer 1.8%, defoamer 1.4%, iron oxide red
8%。
Embodiment 7：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 25%, sierozem power 25%, dry powder
15%th, talcum powder 19%, titanium dioxide 2.8%, waterglass 0.1%, diatomite 4.5%, water reducer 1.3%, defoamer 1.9%, iron oxide red
5.4%。
Embodiment 8：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 10%, sierozem power 32%, dry powder
35%th, talcum powder 13%, titanium dioxide 1.9%, waterglass 0, diatomite 4.8%, water reducer 1.8%, defoamer 0, iron oxide red 1.5%.
Embodiment 9：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 11%, sierozem power 37%, dry powder
29%th, talcum powder 9%, titanium dioxide 1.4%, waterglass 1%, diatomite 5.9%, water reducer 0, defoamer 0.9%, iron oxide red 4.8%.
Embodiment 10：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 9%, sierozem power 40%, dry powder
19%th, talcum powder 18%, titanium dioxide 2.6%, waterglass 0.5%, diatomite 6.5%, water reducer 0.9%, defoamer 0.6%, iron oxide red
2.9%。
Embodiment 11：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 34%, dry powder
33%th, talcum powder 7%, titanium dioxide 3.1%, waterglass 0.8%, diatomite 0, water reducer 2%, defoamer 1.3%, iron oxide red 3.8%.
Embodiment 12：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：SILICA FUME 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic pigment
0。
Embodiment 13：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：Superfine glass beads 15%, sierozem power 30%,
Dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, nothing
Machine pigment 0.
Embodiment 14：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：The dry colloidal sol 15% of silica, sierozem power
30%th, dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 15：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：Superfine calcined kaolin 15%, sierozem power
30%th, dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 16：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：Nanotube-shaped aluminum silicon powder 15%, sierozem power
30%th, dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 17：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, calcium lime powder 30%, round trip flight
Powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic face
Material 0.
Embodiment 18：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, hydrated lime in powder 30%, round trip flight
Powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic face
Material 0.
Embodiment 19：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, heavy carbon
Sour calcium 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, it is inorganic
Pigment 0.
Embodiment 20：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, wollastonite
Powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic face
Material 0.
Embodiment 21：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, sodium metasilicate 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic pigment
0。
Embodiment 22：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, potassium alum 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic pigment
0。
Embodiment 23：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, attapulgite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic face
Material 0.
Embodiment 24：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, bentonite 2.8%, water reducer 0.5%, defoamer 0.7%, inorganic pigment
0。
Embodiment 25：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 7%, nanotube-shaped aluminum silicon powder 8%,
Sierozem power 30%, dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, disappear
Infusion 0.7%, inorganic pigment 0.
Embodiment 26：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 15%, quick lime
Powder 15%, dry powder 33%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 27：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
16%th, wollastonite in powder 17%, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 28：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.1%, potassium alum 0.1%, diatomite 2.8%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
Embodiment 29：
The component and content of the reaction film-forming inorganic dry powder paint of this example be：White carbon 15%, sierozem power 30%, dry powder
33%th, talcum powder 14%, titanium dioxide 3.8%, waterglass 0.2%, diatomite 1.4%, attapulgite 1.4%, water reducer 0.5%, defoamer
0.7%, inorganic pigment 0.
The reaction film-forming inorganic dry powder paint of 29 embodiments of the invention is in use, the dry powder paint prepared is added water mixed
Close, the electric blender for being 1000r/min with rotating speed is stirred 5-10 minute, then standing 5 minutes, then with rotating speed be 1000r/
Min electric blender is stirred 5-10 minutes, and wherein coating is watered ratio, during blade coating, coating：Water=1:0.5-1.0, roller coating and
During spraying, coating：Water=1:1.0-1.5.
According to national standard, some experimental data such as following table of the present invention is obtained after testing：
Finally, should illustrate that the present invention is to the description of embodiment can for ease of those skilled in the art
It is well understood by and using the present invention, but the invention is not restricted to embodiment here, and there is no need and unable to all
Embodiment is exhaustive；Those skilled in the art do not depart from the improvement done in scope according to the prompting of the present invention
All should be within protection scope of the present invention with modification.
Claims (5)
1. one kind reaction film-forming inorganic dry powder paint, it is made up of inorganic filmogen, filler and auxiliary material, it is described it is inorganic into
Membrane material accounts for the 20-50% of the dry powder paint gross mass；The filler accounts for the 20-70% of the gross mass of the dry powder paint；It is remaining
Measure as auxiliary material；
The inorganic filmogen is had the siliceous raw material and calcareous raw material group of high pozzolanic activity by nanometer or submicron-scale
Into the siliceous raw material accounts for the 20-50% of the inorganic filmogen gross mass, and surplus is the calcareous raw material；
Particle diameter≤1 micron of the primary particle of the siliceous raw material；
The auxiliary material is by any one or more in thickener, water reducer, defoamer and inorganic pigment and activator group
Conjunction is obtained；
The activator is any one or a few the mixture in waterglass, sodium metasilicate, potassium alum；
The siliceous raw material is at least one of white carbon, SILICA FUME, superfine glass beads, the dry colloidal sol of silica；
The calcareous raw material is at least one of sierozem power, calcium lime powder, hydrated lime in powder.
2. a kind of reaction film-forming inorganic dry powder paint according to claim 1, it is characterised in that the thickener is diatom
Any one or a few mixture in soil, attapulgite, bentonite.
3. reacting the production method of film-forming inorganic dry powder paint described in a kind of claim 1, it comprises the following steps：
Step（1）Siliceous raw material and calcareous raw material, ball milling mixing are weighed in proportion；
Step（2）Load weighted filler and auxiliary material are added into the inorganic reaction film forming compound after ball milling, and continues ball
Mill, obtains described reaction film-forming inorganic dry powder paint.
4. the application method of film-forming inorganic dry powder paint is reacted described in a kind of claim 1, by the reaction film-forming inorganic dry powder
Coating, which adds water, to stir, and blade coating, roller coating or is sprayed on interior wall.
5. application method according to claim 4, it is characterised in that the coating is watered ratio and is,
During blade coating, coating：Water=1:0.5-1.0；
When roller coating and spraying, coating：Water=1:1.0-1.5.
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| CN107021725B (en) * | 2017-05-16 | 2018-05-15 | 成都森态源环保科技有限公司 | A kind of purely inorganic coating |
| CN109437812B (en) * | 2018-12-05 | 2021-11-05 | 武汉鑫奥捷新型建材有限公司 | Heat-insulating coating and preparation method thereof |
| CN111560178B (en) * | 2020-07-04 | 2021-11-23 | 信息产业电子第十一设计研究院科技工程股份有限公司 | zero-VOC inorganic fire-resistant functional coating suitable for electronic clean workshop and preparation method thereof |
| CN112409827A (en) * | 2020-11-18 | 2021-02-26 | 广东菲力绿色板业有限公司 | Coating material for heat-insulating fire protection, heat-insulating fire-resistant system and use thereof |
| CN112625472B (en) * | 2020-12-02 | 2022-05-10 | 武汉佳碧源科技有限责任公司 | Double-component reaction film-forming inorganic dry powder coating and application method thereof |
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| CN101302363B (en) * | 2008-01-24 | 2011-06-15 | 广西启利新材料科技股份有限公司 | Coating material with metakaolin as film forming substance and preparation thereof |
| CN103497545A (en) * | 2013-10-10 | 2014-01-08 | 苏州弗克新型建材有限公司 | Inorganic coating, and preparation method and application thereof |
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