CN107021725B - A kind of purely inorganic coating - Google Patents
A kind of purely inorganic coating Download PDFInfo
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- CN107021725B CN107021725B CN201710355836.7A CN201710355836A CN107021725B CN 107021725 B CN107021725 B CN 107021725B CN 201710355836 A CN201710355836 A CN 201710355836A CN 107021725 B CN107021725 B CN 107021725B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of purely inorganic coating, mainly it is made of the raw material of following weight parts：100 parts of 55 parts of calcium hydroxide, 8 parts of SILICA FUME, 20 parts of Ludox, 2 parts of sodium chloride, 3 parts of aluminium hydroxide, 4 parts of attapulgite, 4 parts of sepiolite, 4 parts of bentonite and water, it is finished product after mixing, high speed dispersion and filtering that above-mentioned each raw material is pressed respective parts by weight.The present invention is compounded the 3 D stereo silico-calcium structure for forming solid by calcium hydroxide, SILICA FUME and Ludox, realizes huge breakthrough in intensity and workability etc., and fire-protection rating can reach A1 grades, and pH value is 13 or so, super antibacterial.The present invention provides a kind of high-environmental wall covering formed completely using inorganic mineral powder, and really realization is entirely free of organic chemical industry's component for it, possesses a variety of advantages such as environmental protection, fire prevention, humidity, fungus-resistant.The present invention reaches the toxin such as formaldehydeless VOC free truly.
Description
Technical field
The invention belongs to inorganic coating technical field, particularly relates to a kind of purely inorganic coating.
Background technology
Most of coating of the prior art is the mixed mode appearance with organic-inorganic, and organic matter is generally all poisonous,
So coating of the prior art all do not accomplish usually really it is nontoxic.Coating of the prior art is easily sent out in wet environment
Mould, mould virus is that another kind of important environment is poisoned.When hot environment particularly fire, have with the rising of temperature
The gas that machine thing volatilizes is inflammable and can become severe toxicity.Coating containing organic matter is not only easy to cause the sprawling of fire, at the same time
Or the main reason for fire is lethal.In conclusion only purely inorganic coating can realize environmental protection, fire prevention truly
And fungus-resistant.
Although inorganic coating patent of the prior art is named with inorganic coating, it is most of also to add it is organic into
Point, do not reach it is purely inorganic so that being beaten greatly the advantages that environmental protection index, weather resistance, fire prevention, mould proof, anti-aging and humidity
Discount.Although sub-fraction inorganic coating patent possesses purely inorganic standard, but poor there are workability, can only scratch mostly,
Or there are many problems such as film is easy to crack, easy dry linting and Storage period are limited, cause patent actual product convert it is very poor.
Most of conventional patent is all proved without third party's data in the prior art, and practical study is found, existing pure
Inorganic coating be formulated it is incomplete in the case of construction and the performance of product be most crucial the problem of.In the presence of hardly possible construction, smear by force
The shortcomings of spending inadequate, easy to crack and easy dry linting, or existence foundation color whiteness is not enough and the problems such as later stage color representation force difference,
Basic neither one patent is caused to realize successful commodity conversion and promote.What it is with inorganic coating name is organic-inorganic mostly
Compo, it is most of still to be formed a film with organic emulsion or rubber powder, substantially with emulsion paint without too big difference, so inorganic
The top environmental protection of coating, A grade prevent fires, the advantages that anti-mildew is antibacterial, water-fast and ageing-resistant, does not embody at all.
Applicant retrieved five coating patents containing calcium hydroxide：1st, CN1179449A, calcium hydroxide ratio 80~
90%；2nd, CN101591481A, calcium hydroxide ratio 60~80%；3rd, CN101899232A, calcium hydroxide ratio 10~15%；
4th, CN102092989A, calcium hydroxide ratio 12~15%；5th, CN103709799A, calcium hydroxide ratio 10~22%.Wherein
Preceding two patents are because of calcium hydroxide too high levels, so as to cause that insufficient strength, difficulty of construction are big, easily precipitate and there are colour-difference
The problems such as, the formula of rear three patents is generally not then the actual proportioning based on calcium hydroxide, so the painting made
Material is all difficult to reach ideal effect.
The content of the invention
The present invention is in order to overcome the shortcomings of the prior art, there is provided a kind of to realize truly environmentally friendly, anti-
The purely inorganic coating of fire and fungus-resistant, really is able to realize that the top environmental protection of inorganic coating, A grades of fire prevention, anti-mildews are antibacterial, resistance to
Water and ageing-resistant performance.
The present invention is achieved by the following technical solutions：A kind of purely inorganic coating, it is mainly by the original of following weight parts
Material composition：30~60 parts of calcium hydroxide, 5~15 parts of SILICA FUME, 10~35 parts of Ludox, 0.1~3 part of sodium chloride, aluminium hydroxide 3
100 parts of~8 parts, 3~8 parts of attapulgite, 3~8 parts of sepiolite, 3~8 parts of bentonite and water, by above-mentioned each raw material by respective
Parts by weight are finished product after mixing, high speed dispersion and filtering.
As the preferred embodiment of the present invention, purely inorganic coating of the invention is mainly by the raw material group of following weight parts
Into：Hydroxide Ca45~55 part, 7~12 parts of SILICA FUME, 15~30 parts of Ludox, 1~2.5 part of sodium chloride, aluminium hydroxide 3~6
Part, 4~5 parts of attapulgite, 4~7 parts of sepiolite, 4~6 parts of bentonite and 100 parts of water.
As the preferred forms of the present invention, purely inorganic coating of the invention is mainly by the raw material group of following weight parts
Into：55 parts of calcium hydroxide, 8 parts of SILICA FUME, 20 parts of Ludox, 2 parts of sodium chloride, 3 parts of aluminium hydroxide, 4 parts of attapulgite, sepiolite
100 parts of 4 parts, 4 parts of bentonite and water.
Wherein Ludox is the Ludox that concentration is more than 30%；Calcium hydroxide is purity higher than 99% and mesh number is more than 2000
Purpose calcium hydroxide；SILICA FUME is the SILICA FUME that mesh number is more than 6000 mesh.
Table one：Traditional inorganic coating, which forms scheme, in the prior art substantially following four pattern：
By being can be found that in table one：The coating main film forming substance of false inorganic compounding be all lotion and rubber powder etc. it is organic into
Point, substantially it is exactly emulsion paint.The coating of only calcium hydroxide component has the utilization of more than 1,000 years in the coating of purely inorganic formula
History, can have larger development space at many aspects such as construction, storage, toning.It is so main for calcium hydroxide coating
Strength problem is overcome to have very big development prospect, his superpower bactericidal property and water resistance also necessarily have wider fortune
With.
The beneficial effects of the invention are as follows：The present invention provides a kind of high-environmental wall formed completely using inorganic mineral powder
Coating materials, really realization is entirely free of organic chemical industry's component for it, and it is a variety of excellent to possess environmental protection, fire prevention, humidity, fungus-resistant etc.
Gesture.Purely inorganic coating in the present invention is made of inorganic constituents completely, is not added any organic principle, is reached truly
The toxin such as formaldehydeless VOC free.Purely inorganic coating fire-protection rating in the present invention can reach A1 grades, and pH value is super 13 or so
Antibacterial.The present invention is compounded the 3 D stereo silico-calcium structure for forming solid by calcium hydroxide, SILICA FUME and Ludox.The pure nothing of the present invention
The ratio of each raw material and each raw material is the core in the present invention in machine coating, and a small amount of inorganic constituents changes and addition is included in
In protection scope of the present invention.
Research is found, single to be extremely difficult to ideal tensile strength by calcium hydroxide intensity, when calcium hydroxide and superfine
Excellent performance is shown after silica flour and Ludox mixing, special silico-calcium 3 D stereo net can be formed.To realize at the same time
The performances such as the antisolvent precipitation of coating, plumpness, anti-dry linting and the cracking resistance smeared also need to coordinate concave convex rod, sepiolite and bentonit
Etc. purely inorganic component.The present invention be using high-purity calcium hydroxide micro mist, SILICA FUME, Ludox as main film forming substance, in intensity and
Workability etc. realizes huge breakthrough.The main production process of the purely inorganic coating of the present invention is relatively simple, mainly
Filtering is stirred to various mineral dusts.
The present invention is a kind of purely inorganic coating that can realize environmental protection truly, fire prevention and fungus-resistant, very
Can just realize the top environmental protection of inorganic coating, A grade prevent fires, anti-mildew is antibacterial, water-fast and ageing-resistant performance.The present invention is through country
The examining report that level testing agency provides is as follows：
Table two：Testing agency：National building materials test center
Table three：Testing agency：National building materials Quality Supervision and Inspection Center
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1：A kind of purely inorganic coating, it is mainly by 30 parts of calcium hydroxide, 5 parts of SILICA FUME, 10 parts of Ludox, chlorination
100 parts of 0.1 part of sodium, 3 parts of aluminium hydroxide, 3 parts of attapulgite, 3 parts of sepiolite, 3 parts of bentonite and water compositions, by above-mentioned each raw material
By respective parts by weight after mixing, high speed dispersion and filtering i.e. finished product.Wherein Ludox is that concentration is more than 30%
Ludox；Calcium hydroxide is purity higher than 99% and mesh number is more than the calcium hydroxide of 2000 mesh；SILICA FUME is that mesh number is more than 6000
Purpose SILICA FUME.
Embodiment 2：A kind of purely inorganic coating, it is mainly by 55 parts of calcium hydroxide, 8 parts of SILICA FUME, 15 parts of Ludox, chlorination
100 parts of 2 parts of sodium, 3 parts of aluminium hydroxide, 4 parts of attapulgite, 4 parts of sepiolite, 4 parts of bentonite and water compositions, above-mentioned each raw material is pressed
Respective parts by weight are finished product after mixing, high speed dispersion and filtering.
Embodiment 3：A kind of purely inorganic coating, it is mainly by 60 parts of calcium hydroxide, 15 parts of SILICA FUME, 35 parts of Ludox, chlorine
Change 100 parts of 3 parts of sodium, 8 parts of aluminium hydroxide, 8 parts of attapulgite, 8 parts of sepiolite, 8 parts of bentonite and water compositions, by above-mentioned each raw material
By respective parts by weight after mixing, high speed dispersion and filtering i.e. finished product.
Finally it should be noted that above content is merely illustrative of the technical solution of the present invention, rather than the present invention is protected
The limitation of scope, formula components and ratio scope and prioritization scheme comprising the present invention in claim, this area it is general
The simple modification or equivalent substitution that logical technical staff carries out technical scheme, all without departing from technical solution of the present invention
Spirit and scope.
Claims (5)
- A kind of 1. purely inorganic coating, it is characterised in that：The purely inorganic coating is mainly made of the raw material of following weight parts：Hydrogen-oxygen Change Ca45~55 part, 7~12 parts of SILICA FUME, 15~30 parts of Ludox, 1~2.5 part of sodium chloride, 3~6 parts of aluminium hydroxide, bumps 100 parts of 4~5 parts of rod soil, 4~7 parts of sepiolite, 4~6 parts of bentonite and water, above-mentioned each raw material is passed through by respective parts by weight It is finished product after mixing, high speed dispersion and filtering.
- A kind of 2. purely inorganic coating according to claim 1, it is characterised in that：The purely inorganic coating is mainly by following heavy Measure the raw material composition of part：55 parts of calcium hydroxide, 8 parts of SILICA FUME, 20 parts of Ludox, 2 parts of sodium chloride, 3 parts of aluminium hydroxide, concave convex rod 100 parts of 4 parts of soil, 4 parts of sepiolite, 4 parts of bentonite and water.
- A kind of 3. purely inorganic coating according to claim 1 or 2, it is characterised in that：The Ludox is that concentration is more than 30% Ludox.
- A kind of 4. purely inorganic coating according to claim 1 or 2, it is characterised in that：The calcium hydroxide is that purity is higher than 99% and mesh number be more than 2000 mesh calcium hydroxide.
- A kind of 5. purely inorganic coating according to claim 1 or 2, it is characterised in that：The SILICA FUME is that mesh number is more than The SILICA FUME of 6000 mesh.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710355836.7A CN107021725B (en) | 2017-05-16 | 2017-05-16 | A kind of purely inorganic coating |
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| CN201710355836.7A CN107021725B (en) | 2017-05-16 | 2017-05-16 | A kind of purely inorganic coating |
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| CN107021725A CN107021725A (en) | 2017-08-08 |
| CN107021725B true CN107021725B (en) | 2018-05-15 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111808466A (en) * | 2020-07-17 | 2020-10-23 | 成都森态源环保科技有限公司 | Anion functional inorganic pigment |
| CN111808442A (en) * | 2020-07-17 | 2020-10-23 | 成都森态源环保科技有限公司 | Novel inorganic pigment and production process thereof |
| CN111808440A (en) * | 2020-07-17 | 2020-10-23 | 成都森态源环保科技有限公司 | Stable inorganic pigment and preparation process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101538424A (en) * | 2009-04-15 | 2009-09-23 | 毛仕龙 | High-performance inorganic coating |
| CN103911025B (en) * | 2014-04-09 | 2016-08-17 | 宜兴市官林镇政宇涂料厂 | A kind of aqueous fire-proof coating |
| CN104927637A (en) * | 2015-06-11 | 2015-09-23 | 阜南县中泰工艺品有限公司 | Flame-retardant wood product coating |
| CN104927419B (en) * | 2015-07-15 | 2017-09-01 | 武汉佳碧源科技有限责任公司 | One kind reaction film-forming inorganic dry powder paint and its production method |
| CN105255225B (en) * | 2015-11-28 | 2017-11-07 | 辽宁石油化工大学 | A kind of ageing-resistant exterior coating of inorganic water-proof and preparation method thereof |
| CN105504903B (en) * | 2015-12-31 | 2018-03-23 | 肖昌义 | Inorganic coating and preparation method thereof |
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