CN107083086B - A kind of high purely inorganic functional paint of air purifying property - Google Patents
A kind of high purely inorganic functional paint of air purifying property Download PDFInfo
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- CN107083086B CN107083086B CN201710356235.8A CN201710356235A CN107083086B CN 107083086 B CN107083086 B CN 107083086B CN 201710356235 A CN201710356235 A CN 201710356235A CN 107083086 B CN107083086 B CN 107083086B
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- chlorine dioxide
- aqueous solution
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high purely inorganic functional paints of air purifying property, are mainly made of the raw material of following weight parts：0~8 part of 0~15 part of 0~15 part of 0~15 part of 0.3~3 part of 5~35 parts of 3~15 parts of 30~60 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME, Ludox, sodium chloride, diatomite, attapulgite, sepiolite, bentonite and 0~25 part of inorganic filler containing chlorine dioxide, it is finished product after mixing, high speed dispersion and filtering that above-mentioned each raw material is pressed respective parts by weight.The present invention be it is a kind of can with it is long-acting it is micro release chlorine dioxide purification air and sterilization purely inorganic functional paint, diatomite, attapulgite and sepiolite in formula etc., which possess multiple hole structure, can largely store chlorine dioxide, and the solution of the present invention is made perfectly to be realized.The present invention is entirely free of organic chemical industry's ingredient, possesses a variety of advantages such as environmental protection, highly effective air purification air, fire prevention, humidity and fungus-resistant.
Description
Technical field
The invention belongs to purification type inorganic coating technical fields, particularly relate to a kind of high pure nothing of air purifying property
Machine functional paint.
Background technology
Chlorine dioxide is internationally recognized safe and nontoxic disinfectant, and without " three cause " effect, both carcinogenic, teratogenesis causes to dash forward
Become, while chlorination does not also occur with organic matter in disinfecting process and generates the organic chloride or its that can generate three-induced effect
Its toxic class substance.Will not generate any influence to human body during below 100ppm, including Physiology and biochemistry in terms of influence.In sky
It is most widely applied in gas purification, tap water purifying, food sterilization.However utilization of the chlorine dioxide in coating does not have but
It was found that, it traces it to its cause and is primarily present following technological difficulties：
1st, chlorine dioxide is readily volatilized：Cause people custom think chlorine dioxide be most efficiently however be again it is most short-acting,
Row such as air purification industry can carry out second with the latter week left and right of chlorine dioxide purification in first time and purify with cumulative effects,
It is accumulated once again after two months and reaches promising result, long-term micro chlorine dioxide release is asked as the bottleneck of purification industry
Topic.If wall covering will be able to be the once great leap of indoor purifying as the release carrier of chlorine dioxide, he is by pole
It is big to surmount the passive adsorption function of diatom ooze or even much surmount the purification function of photocatalyst.
2nd, chlorine dioxide has strong oxidizing property：Existing coating mostly occurs with the mixed mode of organic-inorganic, and organic matter can not
The strong oxidizing property of chlorine dioxide is resistant to, and organic matter is generally all toxic, does not accomplish really nontoxic.In wet environment organic matter
Easily mouldy, mould virus is that another kind of important environment is poisoned.When high temperature particularly fire, have with the rising of temperature
The gas that machine object volatilizes is inflammable and becomes severe toxicity, does not only result in the sprawling of fire, while is the main reason for fire is lethal.
Only purely inorganic coating just can be as the dependable carriers of chlorine dioxide, so as to fulfill environmental protection, fire prevention and anti-truly
It is mould antibacterial.
3rd, the control of optimal burst size：Optimal situation is that the chlorine dioxide of release is just anti-with the toxin such as indoor formaldehyde
Should complete or toxic gas be reduced to it is up to standard in the case of react complete.Actually since the high security of chlorine dioxide, he
The amount that can allow in air is very high.It is internationally recognized when concentration be less than 500ppm when, the influence to human body can
To ignore, any influence will not be generated during below 100ppm to human body, including Physiology and biochemistry in terms of influence.To skin also without
Any sensitization, in fact our release concentration will be well below 500ppm, normally only in below 20ppm, therefore, two
Chlorine monoxid is also known as safe and nontoxic green disinfectant in the world.
Although inorganic coating patent of the prior art is named with inorganic coating, it is most of also to add it is organic into
Point, be not achieved it is purely inorganic so that big discounting the advantages that environmental protection index, weather resistance, fire prevention, mould proof, anti-aging and humidity
Button, organic-compound system can not also be resistant to the strong oxidizing property of chlorine dioxide at all.Although sub-fraction inorganic coating patent possesses pure
Inorganic standard, but there are workability it is poor the shortcomings that, it is most of can only scratch or there are film is easy to crack, easy picking and
The limited many problems of grade of Storage period, the actual product conversion for causing patent is very poor, does not see that popularization is successful substantially on the market
Purely inorganic coating, what it is with inorganic coating name is organic-inorganic compo mostly, substantially with emulsion paint without too big difference.
And 11-13 is not achieved in the most pH value of formula of existing inorganic system, and it is particularly optimal 13 or so.
Applicant retrieved five coating patents containing calcium hydroxide：1st, CN1179449A, calcium hydroxide ratio 80~
90%；2nd, CN101591481A, calcium hydroxide ratio 60~80%；3rd, CN101899232A, calcium hydroxide ratio 10~15%；
4th, CN102092989A, calcium hydroxide ratio 12~15%；5th, CN103709799A, calcium hydroxide ratio 10~22%.Wherein
Preceding two patents are because of calcium hydroxide too high levels, and so as to cause insufficient strength, difficulty of construction is big, easily precipitate and there are colour-differences
The problems such as, the formula of rear three patents is generally not then the actual proportioning based on calcium hydroxide, so the painting made
Material is all difficult to reach ideal effect.
The content of the invention
The present invention provides a kind of purely inorganic function of high air purifying property and applies to overcome the shortcomings of the prior art
Material, the present invention is a kind of complete high-environmental wall covering formed using inorganic mineral powder, is entirely free of organic chemical industry's ingredient,
Possess a variety of advantages such as environmental protection, highly effective air purification air, fire prevention, humidity and fungus-resistant.
The present invention is achieved by the following technical solutions：A kind of high purely inorganic functional paint of air purifying property, master
It to be made of the raw material of following weight parts：30~60 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME 3 containing chlorine dioxide
~15 parts, 5~35 parts of Ludox, 0.3~3 part of sodium chloride, 0~15 part of diatomite, 0~15 part of attapulgite, sepiolite 0~15
0~25 part of part, 0~8 part of bentonite and inorganic filler, by above-mentioned each raw material by respective parts by weight by mixing, high speed dispersion
With after filtering be finished product.
As the preferred embodiment of the present invention, the high purely inorganic functional paint of air purifying property of the present invention is mainly by following
The raw material composition of parts by weight：4~10 parts of 40~55 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME containing chlorine dioxide,
15~30 parts of Ludox, 1~2 part of sodium chloride, 2~10 parts of diatomite, 3~8 parts of attapulgite, 4~9 parts of sepiolite, bentonite 2
~4 parts and 15~22 parts of inorganic filler.
As the preferred forms of the present invention, the high purely inorganic functional paint of air purifying property of the present invention is mainly by following
The raw material composition of parts by weight：5 parts of 50 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME, Ludox 25 containing chlorine dioxide
Part, 2 parts of sodium chloride, 6 parts of diatomite, 4 parts of attapulgite, 5 parts of sepiolite, 3 parts of bentonite and 20 parts of inorganic filler.
Alkaline inorganic material is calcium hydroxide, calcium oxide, potassium hydroxide, potassium oxide, sodium hydroxide, sodium oxide molybdena, hydroxide
Barium, barium monoxide, cobalt hydroxide, cobalt oxide, magnesium hydroxide, magnesia, lithium hydroxide, lithia, cement, gypsum, silicate, silicon
One or more mixtures in colloidal sol, sodium carbonate, sodium acid carbonate, calcium bicarbonate and magnesium chloride class inorganic alkaline material.
Aqueous solution containing chlorine dioxide is the aqueous solution of chlorine dioxide that concentration range is 0.001%~20%.Preferably,
Aqueous solution containing chlorine dioxide is the aqueous solution of chlorine dioxide that concentration range is 0.1%~1%.Ludox is that concentration is more than 30%
Ludox, SILICA FUME be mesh number be more than 6000 mesh SILICA FUME.
Table one：Traditional inorganic coating, which forms scheme, in the prior art substantially following four pattern：
By being can be found that in table one：The coating main film forming substance of false inorganic compounding be all lotion and rubber powder etc. it is organic into
Point, substantially it is exactly emulsion paint.The coating of only calcium hydroxide ingredient has the utilization of more than 1,000 years in the coating of purely inorganic formula
History can have larger development space at many aspects such as construction, storage, toning.It is so main for calcium hydroxide coating
Overcome strength problem that there must be very big development prospect, his superpower bactericidal property and water resistance also necessarily have wider fortune
With.
The study found that single be extremely difficult to ideal tensile strength by calcium hydroxide intensity, when calcium hydroxide and superfine
Excellent performance is shown after silica flour and Ludox mixing, forms special silico-calcium 3 D stereo net.To realize coating simultaneously
Antisolvent precipitation, that plumpness, anti-picking and the performances such as cracking resistance smeared also need to cooperation concave convex rod, sepiolite and bentonit etc. is pure
Inorganic constituents.
Previous patent is proved mostly without third party's data, and practical study finds existing purely inorganic coating, is being formulated
The problem of performance difference of construction and product is most crucial in the case of incomplete.In the presence of hardly possible construction, smear insufficient strength, Yi Kai
It splits, easily picking, basic color whiteness not enough and the defects of later stage color representation force difference, causes basic neither one patent to realize
Successful commodity conversion and popularization.It is existing with promoted most of of inorganic coating name or with organic emulsion or rubber powder
Film forming, is basically emulsion paint.The top environmental protection of inorganic coating, A grade prevent fires, the advantages that anti-mildew is antibacterial, water-fast and ageing-resistant
It does not embody at all, and organic-compound system can not also be resistant to the strong oxidizing property of chlorine dioxide at all.
The beneficial effects of the invention are as follows：The present invention is that one kind can be with long-acting micro release chlorine dioxide purification air and sterilization
Purely inorganic functional paint, in order to realize above-mentioned target, applicant has found chlorine dioxide in the pure of pH value 11-13 through studying for a long period of time
Can realize micro slow release under inorganic environment, at the same diatomite, attapulgite and sepiolite in being formulated etc. possess it is porous
Hole structure can also largely store chlorine dioxide, this scheme is made perfectly to be realized.The present invention is with high-purity calcium hydroxide
Micro mist, SILICA FUME and Ludox are main film forming substance, and huge breakthrough is realized in intensity and workability etc..This hair
It is bright to be made of completely inorganic constituents, any organic principle is not added, reaches the toxin such as the formaldehydeless VOC free of real meaning, is prevented fires
Grade reaches A1 grades, and pH value is in 11-13 or so, super antibacterial.
The main production process of inorganic coating of the present invention is relatively simple, mainly being stirred to various mineral dusts
Filter.Previous purification type coating in the prior art, such as the passive adsorption function of diatom ooze, photocatalyst needs light irradiation, and just some is urged
It is weaker to change the functions such as reaction, so the slow release method of chlorine dioxide of the present invention can not surmount substantially, the security of chlorine dioxide
By verifying for a long time.The present invention is a kind of complete high-environmental wall covering formed using inorganic mineral powder, completely not
Containing organic chemical components, possess a variety of advantages such as environmental protection, highly effective air purification air, fire prevention, humidity and fungus-resistant.Present invention warp
The examining report that national testing agency provides is as follows：
Table two：Testing agency：National building materials test center
Table three：Testing agency：National building materials Quality Supervision and Inspection Center
Table four：Testing agency：National Fire building materials quality Supervision Test Center
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1：A kind of high purely inorganic functional paint of air purifying property, mainly by the raw material group of following weight parts
Into：0.3 part of 5 parts of 3 parts of 30 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME, Ludox, sodium chloride containing chlorine dioxide,
10 parts of 2 parts of diatomite, 1 part of attapulgite, 3 parts of sepiolite, 8 parts of bentonite and inorganic filler, by above-mentioned each raw material by respective
Parts by weight are finished product after mixing, high speed dispersion and filtering.Wherein alkaline inorganic material is calcium hydroxide, containing titanium dioxide
The aqueous solution of chlorine is the aqueous solution of chlorine dioxide that concentration range is 0.1%.Ludox be concentration be more than 30% Ludox, micro- silicon
Powder is the SILICA FUME that mesh number is more than 6000 mesh.
Embodiment 2：A kind of high purely inorganic functional paint of air purifying property, mainly by the raw material group of following weight parts
Into：2 parts of 25 parts of 5 parts of 50 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME, Ludox, sodium chloride, silicon containing chlorine dioxide
20 parts of 6 parts of diatomaceous earth, 4 parts of attapulgite, 5 parts of sepiolite, 3 parts of bentonite and inorganic filler, by above-mentioned each raw material by respective heavy
It is finished product after mixing, high speed dispersion and filtering to measure part.Alkaline inorganic material is calcium oxide, potassium hydroxide and sodium carbonate
Mixture, the aqueous solution containing chlorine dioxide be concentration range be 1% aqueous solution of chlorine dioxide, Ludox is that concentration is more than
30% Ludox, SILICA FUME are the SILICA FUMEs that mesh number is more than 6000 mesh.
Embodiment 3：A kind of high purely inorganic functional paint of air purifying property, mainly by the raw material group of following weight parts
Into：3 parts of 35 parts of 15 parts of 60 parts of 100 parts of aqueous solution, alkaline inorganic material, SILICA FUME, Ludox, sodium chloride containing chlorine dioxide,
15 parts of 15 parts of diatomite, 14 parts of attapulgite, 13 parts of sepiolite, 5 parts of bentonite and inorganic filler, by above-mentioned each raw material by respective
Parts by weight after mixing, high speed dispersion and filtering i.e. finished product.Alkaline inorganic material is calcium hydroxide, containing chlorine dioxide
Aqueous solution be concentration range be 0.01% aqueous solution of chlorine dioxide, Ludox be concentration be more than 30% Ludox, micro- silicon
Powder is the SILICA FUME that mesh number is more than 6000 mesh.
The present invention is compounded by calcium hydroxide, SILICA FUME and Ludox forms three-dimensional 3 D stereo silico-calcium structure, with top
Divide and ratio is core, the change and addition of a small amount of inorganic constituents are included in patent claims protection domain, skill
Art scheme include the present invention whole formula components, ratio scope and prioritization scheme, do not rise on a small quantity main binding effect and
The ingredient of catharsis changes, and is also contained in the claims of the present invention.
Finally it should be noted that more than content is merely illustrative of the technical solution of the present invention rather than the present invention is protected
The limitation of scope, simply modification or the equivalent substitution that those of ordinary skill in the art carry out technical scheme,
All without departing from the spirit and scope of technical solution of the present invention.
Claims (5)
1. a kind of high purely inorganic functional paint of air purifying property, it is characterised in that：The high purely inorganic work(of air purifying property
Energy coating is made of the raw material of following weight parts：100 parts of aqueous solution, high-purity calcium hydroxide micro mist 40~55 containing chlorine dioxide
Part, 4~10 parts of SILICA FUME, 15~30 parts of Ludox, 1~2 part of sodium chloride, 2~10 parts of diatomite, 3~8 parts of attapulgite, sea
15~22 parts of 4~9 parts of afrodite, 2~4 parts of bentonite and inorganic filler, above-mentioned each raw material is mixed by respective parts by weight process,
It is finished product after high speed dispersion and filtering.
2. a kind of high purely inorganic functional paint of air purifying property according to claim 1, it is characterised in that：The high-altitude
The purely inorganic functional paint of gas purifying property is made of the raw material of following weight parts：100 parts of the aqueous solution containing chlorine dioxide, High Purity Hydrogen
50 parts of calcium oxide micro mist, 5 parts of SILICA FUME, 25 parts of Ludox, 2 parts of sodium chloride, 6 parts of diatomite, 4 parts of attapulgite, sepiolite 5
20 parts of part, 3 parts of bentonite and inorganic filler.
3. a kind of high purely inorganic functional paint of air purifying property according to claim 1, it is characterised in that：It is described to contain two
The aqueous solution of chlorine monoxid is the aqueous solution of chlorine dioxide that concentration range is 0.001%~20%.
4. a kind of high purely inorganic functional paint of air purifying property according to claim 3, it is characterised in that：It is described to contain two
The aqueous solution of chlorine monoxid is the aqueous solution of chlorine dioxide that concentration range is 0.1%~1%.
5. a kind of high purely inorganic functional paint of air purifying property according to claim 1, it is characterised in that：The silicon is molten
Glue is the Ludox that concentration is more than 30%, and the SILICA FUME is the SILICA FUME that mesh number is more than 6000 mesh.
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| CN201710356235.8A CN107083086B (en) | 2017-05-16 | 2017-05-16 | A kind of high purely inorganic functional paint of air purifying property |
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| CN201710356235.8A CN107083086B (en) | 2017-05-16 | 2017-05-16 | A kind of high purely inorganic functional paint of air purifying property |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107376831A (en) * | 2017-09-05 | 2017-11-24 | 大连沐美科技有限公司 | The compound air purification material of the purification factor containing CLO receives net stone and preparation method thereof |
| CN107903774A (en) * | 2017-11-10 | 2018-04-13 | 陈建峰 | A kind of flame retardant type wire enamel |
| CN109794218A (en) * | 2017-11-16 | 2019-05-24 | 陈文泉 | Composite air purifying agent and preparation method thereof |
| CN108782552A (en) * | 2018-08-09 | 2018-11-13 | 中昊(大连)化工研究设计院有限公司 | The new process for producing of chlorine dioxide slow-release piece |
| CN109046227A (en) * | 2018-08-28 | 2018-12-21 | 黄志伟 | A kind of natural mineral matter air purifying composition and preparation method thereof |
| CN111808466A (en) * | 2020-07-17 | 2020-10-23 | 成都森态源环保科技有限公司 | Anion functional inorganic pigment |
| CN111808440A (en) * | 2020-07-17 | 2020-10-23 | 成都森态源环保科技有限公司 | Stable inorganic pigment and preparation process thereof |
| CN115058195A (en) * | 2022-06-15 | 2022-09-16 | 重庆兴渝涂料股份有限公司 | Anion formaldehyde-removing inorganic coating for internal and external coating of building and preparation method thereof |
| CN116120771B (en) * | 2023-01-12 | 2024-01-30 | 上海正欧实业有限公司 | Inorganic mineral coating and preparation method thereof |
| CN117024112B (en) * | 2023-10-10 | 2023-12-19 | 淄博木烯新材料科技有限公司 | Long-acting slow-release acidic water neutralization ceramic material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709799A (en) * | 2013-12-13 | 2014-04-09 | 广州市维多纳环保科技有限公司 | Inorganic multifunctional paint taking potassium silicate as film-forming substance, and preparation method thereof |
| CN103911025A (en) * | 2014-04-09 | 2014-07-09 | 无锡市全发化工有限公司 | Water-based fireproof coating |
-
2017
- 2017-05-16 CN CN201710356235.8A patent/CN107083086B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709799A (en) * | 2013-12-13 | 2014-04-09 | 广州市维多纳环保科技有限公司 | Inorganic multifunctional paint taking potassium silicate as film-forming substance, and preparation method thereof |
| CN103911025A (en) * | 2014-04-09 | 2014-07-09 | 无锡市全发化工有限公司 | Water-based fireproof coating |
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