CN103480253B - Passive negative-ion catalyst purificant and preparation method thereof - Google Patents

Passive negative-ion catalyst purificant and preparation method thereof Download PDF

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CN103480253B
CN103480253B CN201210241734.XA CN201210241734A CN103480253B CN 103480253 B CN103480253 B CN 103480253B CN 201210241734 A CN201210241734 A CN 201210241734A CN 103480253 B CN103480253 B CN 103480253B
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purificant
powder
dispersant
ion catalyst
passive negative
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CN103480253A (en
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尹风兰
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Beijing Shines East Scientific And Technological Development Co Ltd
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Beijing Shines East Scientific And Technological Development Co Ltd
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Abstract

The invention mainly aims at providing a passive negative-ion catalyst purificant and a preparation method thereof. Multiple natural inorganic materials are subjected to ultrafine processing for preparation of the passive negative-ion catalyst purificant, and when the purificant contacts with water molecules in air, the purificant is ionized and releases a large amount of hydroxyl negative ions (H3O2<->), and the hydroxyl negative ions contact with free harmful gas in air, and thus, through comprehensive effects of oxygenolysis, physical adsorption, electric property neutralization, chemical reaction and the like, the purpose of air purifying is realized. The passive negative-ion catalyst purificant is composed of the following raw materials in percents by weight: 4.67-6.78% of ultrafine decoloured tourmalinite powder, 0.93-1.93% of far-infrared ceramic powder, 0.093-0.065% of silver zinc ion powder, 0.093-0.058% of a dispersant, 0.46-0.78% of carboxymethylcellulose sodium, 0.74-0.19% of polyvinyl alcohol and 93-96.9% of purified water.

Description

Passive negative-ion catalyst purificant and preparation method thereof
Technical field
The present invention relates to chemical material field, particularly relate to passive negative-ion catalyst purificant and preparation method.
Background technology
Along with prosperity and the fast development in decorations market, the air pollution that decorating and renovating material brings to indoor, becomes the focus that the whole society pays close attention to.According to international related organization investigation statistics, 30% newly-built and rebuilding in building in the world, find unwholesome room air, room air pollution has been listed in and has been endangered one of 5 kinds of maximum environmental factors to public health.Even it is classified as after " coal-smoke pollution " and " pollution of photochemical fog type " in the world, third time that the mankind experience pollutes period, and air pollution is mainly reflected in three aspects and chemical contamination, biologic contamination (i.e. the pollution such as microorganism, fungi), radioactive pollution.A recent interior decoration market survey result shows, the house decorative material having poisonous gas accounts for 68%, VOC is contained up to 300 kinds in these materials, and in these organic compounds, obviously sensation and poisonous and harmful organic compound are produced to human body, surely belongs to formaldehyde, benzene, ammonia etc. the most outstanding.
People more and more pay attention to indoor air quality (IAQ), IAQ problem has become a study hotspot in current architectural environment field, room air pollution can produce larger harm to the respiratory system of human body, cardiovascular system and nervous system, even also can be carcinogenic, be the main cause causing Cure of Sick Building Syndrome, therefore remove the pernicious gas of decorating and renovating material release fast and effectively, optimize the target that indoor air environment has become people's effort.The present invention develops passive negative-ion catalyst purificant and preparation method thereof, can effectively overcome the above problems.
Therefore, prior art existing defects, needs to improve.
Summary of the invention
For overcoming the above problems, main purpose of the present invention is to provide passive negative-ion catalyst purificant and preparation method thereof, this passive negative-ion catalyst purificant forms through explained hereafter such as super-fine processing, scientific formula and mixtures with multiple natural inorganic material, it is that carrier is sprayed on wall with aqueous inner wall paint, can ionize and discharge a large amount of hydroxyl group anion (H after it contacts with water in air molecule 3o 2 -), after these hydroxyl group anions contact with pernicious gas free in air by the comprehensive function of the processes such as oxidation Decomposition physisorption, electrical counteract effect, chemical reaction to reach the object purified air.
The invention provides passive negative-ion catalyst purificant, wherein, its percentage by weight is made up of following raw material: ultra-fine decolouring tourmaline powder: 4.65 ~ 6.78%; Far-infared ceramic powder: 0.93 ~ 1.93%; Silver zinc ion powder: 0.093 ~ 0.065%; Dispersant: 0.093 ~ 0.058%; Sodium carboxymethylcellulose: 0.46 ~ 0.78%; Polyvinyl alcohol 0.74 ~ 0.19%; Pure water 93 ~ 96.9%.
Described passive negative-ion catalyst purificant, wherein, described dispersant be at least waterglass, sodium phosphate trimer, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester one of them.
Described passive negative-ion catalyst purificant, wherein, described sodium carboxymethylcellulose concentration is 1% ~ 2%.
Described passive negative-ion catalyst purificant, wherein, described ultra-fine decolouring tourmaline powder be at least monocrystal tourmaline powder, raphioid fiber tourmaline powder, polycrystal tourmaline powder one of them.
Described passive negative-ion catalyst purificant, wherein, described silver-colored zinc ion powder at least comprise zinc ion, silver ion one of them.
Described passive negative-ion catalyst purificant, wherein, the degree of polymerization of described polyvinyl alcohol is at least the superelevation degree of polymerization (molecular weight 25 ~ 300,000), high polymerization degree (molecular weight 17-22 ten thousand), the middle degree of polymerization (molecular weight 12 ~ 150,000) and low polymerization degree (molecular weight 2.5 ~ 3.5 ten thousand).
Wherein said dispersant is the interfacial agent simultaneously in molecule with lipophile and hydrophily two kinds of opposite nature, can homogeneous dispersion those be difficult to be dissolved in the solid particle of inorganic, the organic pigment of liquid, also can prevent sedimentation and the cohesion of solid particle simultaneously, form stable medicament needed for suspension, and the dispersant in the present invention is preferably calgon.
The preparation method of described passive negative-ion catalyst purificant, is characterized in that, comprises the following steps:
A, polyvinyl alcohol is added in pure water, be heated to particle after stirring and dissolve completely;
B, input sodium carboxymethylcellulose, stir and filter, obtaining mother liquor;
C, put into excess water by ultra-fine decolouring tourmaline powder, far-infared ceramic powder, silver-colored zinc ion powder, first time adds after dispersant stirs, then second time adds after dispersant stirs, and filters and removes bulky grain powder, obtain functional liquid;
D, above-mentioned mother liquor is mixed with functional liquid after, add after dispersant stirs, obtained finished product.
In described step C: described first time adds dispersant and stirs at least 30 minutes, and mixer rotating speed is 6000 ~ 8000 revs/min.
In described step C: described filtration is removed bulky grain powder and filtered with 1000 eye mesh screens.
In described step D: stir at least 15 minutes, mixer rotating speed is 4000 ~ 6000 revs/min.
Wherein, in above-mentioned preparation process, the addition that can adjust sodium cellulose glycolate and polyvinyl alcohol according to actual conditions controls the viscosity of product.When using above-mentioned passive negative-ion catalyst purificant, spraying method can be adopted.
The invention provides passive negative-ion catalyst purificant, there is following remarkable beneficial effect:
Efficiently, detect through detecting unit, this passive anion media cleanser take coating as carrier, when the original concentration of formaldehyde, benzene, ammonia exceedes international standard 8 times, removal efficiency is respectively 93%, 86%, 85%, within its concentration can being dropped to international standard after four days;
Wide spectrum, its mechanism that purifies air of this passive negative-ion catalyst purificant is realized by various ways such as electrical counteract, physical absorption and chemical reactions, therefore can remove multiple toxic gas simultaneously;
Safety, this passive negative-ion catalyst purificant is all made up of natural inorganic material, nontoxic, harmless, have no side effect, and radiological safety detects and reaches national A grade standard, and its scope of application is unrestricted;
Lastingly, the electric energy material decay phase adopted in this passive negative-ion catalyst purificant formula exceedes several thousand, as long as therefore carrier exists, its function would not disappear;
Convenient, this passive negative-ion catalyst purificant can directly be added in various water paint in proportion, uses very convenient;
Health, this passive negative-ion catalyst purificant can forever discharge the very useful hydroxyl group anion of health and far infrared, has obvious effect to raising human immunological competence, enhancing passive protective physical fitness.
Accompanying drawing explanation
Fig. 1 is passive negative-ion catalyst purificant preparation method flow chart of the present invention.
Detailed description of the invention
Embodiment 1
Passive negative-ion catalyst purificant of the present invention is respectively by following component raw materials weighing: ultra-fine decolouring tourmaline powder 55g; Far-infared ceramic powder 15g; Silver zinc ion powder 3g; Dispersant 4g; Sodium carboxymethylcellulose 6g; Polyvinyl alcohol 10g;
The polyvinyl alcohol of above-mentioned weight is fed in 850g pure water, is heated to particle after stirring and dissolves completely, in cooled poly-vinyl alcohol solution, drop into sodium carboxymethylcellulose, stir with dispersant and filter, obtaining mother liquor for subsequent use; Get 150g pure water again, and then add the ultra-fine decolouring tourmaline powder of above-mentioned weight, far-infared ceramic powder, silver-colored zinc ion powder put into excess water, and stir at least 30 minutes with dispersant, rotating speed is 6500 revs/min, and then add calgon and stir a little again, filter with 1000 eye mesh screens again and remove bulky grain powder, obtain functional liquid; Finally mixed with functional liquid by above-mentioned mother liquor, then stir 15 minutes with dispersant, rotating speed is 4500 revs/min, obtained finished product, and form is the tasteless outstanding mixed liquid of white.During use, it is that carrier is sprayed on wall with aqueous inner wall paint, discharges the anion useful to human body in the passive state, can remove the cigarette taste in daily life and other tastes of life quickly and effectively, improve the air quality of living environment, its anion emission ability reaches 8000/cm 3above, and energy emission wavelength is the far infrared be easily absorbed by the body of 2 ~ 18 microns, and its emissivity, up to 90%, can also have very strong antibacterial and antibacterial effect to Escherichia coli, Staphylococcus aureus etc.
Embodiment 2
Passive negative-ion catalyst purificant of the present invention is respectively by following component raw materials weighing: ultra-fine decolouring tourmaline powder 50g; Far-infared ceramic powder 20g; Silver zinc ion powder 2g; Dispersant 2g; Sodium carboxymethylcellulose 8g; Polyvinyl alcohol 12g;
The polyvinyl alcohol of above-mentioned weight is fed in 750g pure water, is heated to particle after stirring and dissolves completely, in cooled poly-vinyl alcohol solution, drop into sodium carboxymethylcellulose, stir with dispersant and filter, obtaining mother liquor for subsequent use; Get 250g pure water again, and then add the ultra-fine decolouring tourmaline powder of above-mentioned weight, far-infared ceramic powder, silver-colored zinc ion powder put into excess water, and stir at least 30 minutes with dispersant, rotating speed is 6000 revs/min, and then add calgon and stir a little again, filter with 1000 eye mesh screens again and remove bulky grain powder, obtain functional liquid; Finally mixed with functional liquid by above-mentioned mother liquor, then stir 15 minutes with dispersant, rotating speed is 4000 revs/min, obtained finished product, and form is the tasteless outstanding mixed liquid of white.During use, it is that carrier is sprayed on wall with aqueous inner wall paint, discharges the anion useful to human body in the passive state, can remove the cigarette taste in daily life and other tastes of life quickly and effectively, improve the air quality of living environment, its anion emission ability reaches 8000/cm 3above, and energy emission wavelength is the far infrared be easily absorbed by the body of 2 ~ 18 microns, and its emissivity, up to 90%, can also have very strong antibacterial and antibacterial effect to Escherichia coli, Staphylococcus aureus etc.
Embodiment 3
Passive negative-ion catalyst purificant of the present invention is respectively by following component raw materials weighing: ultra-fine decolouring tourmaline powder 68g; Far-infared ceramic powder 10g; Silver zinc ion powder 1g; Dispersant 3g; Sodium carboxymethylcellulose 7g; Polyvinyl alcohol 18g;
The polyvinyl alcohol of above-mentioned weight is fed in 700g pure water, is heated to particle after stirring and dissolves completely, in cooled poly-vinyl alcohol solution, drop into sodium carboxymethylcellulose, stir with dispersant and filter, obtaining mother liquor for subsequent use; Get 300g pure water again, and then add the ultra-fine decolouring tourmaline powder of above-mentioned weight, far-infared ceramic powder, silver-colored zinc ion powder put into excess water, and stir at least 30 minutes with dispersant, rotating speed is 8000 revs/min, and then add calgon and stir a little again, filter with 1000 eye mesh screens again and remove bulky grain powder, obtain functional liquid; Finally mixed with functional liquid by above-mentioned mother liquor, then stir 15 minutes with dispersant, rotating speed is 6000 revs/min, obtained finished product, and form is the tasteless outstanding mixed liquid of white.During use, it is that carrier is sprayed on wall with aqueous inner wall paint, discharges the anion useful to human body in the passive state, can remove the cigarette taste in daily life and other tastes of life quickly and effectively, improve the air quality of living environment, its anion emission ability reaches 8000/cm 3above, and energy emission wavelength is the far infrared be easily absorbed by the body of 2 ~ 18 microns, and its emissivity, up to 90%, can also have very strong antibacterial and antibacterial effect to Escherichia coli, Staphylococcus aureus etc.
Embodiment 4
Passive negative-ion catalyst purificant of the present invention is respectively by following component raw materials weighing: ultra-fine decolouring tourmaline powder 70g; Far-infared ceramic powder 20g; Silver zinc ion powder 7g; Dispersant 6g; Sodium carboxymethylcellulose 8g; Polyvinyl alcohol 20g;
The polyvinyl alcohol of above-mentioned weight is fed in 700g pure water, is heated to particle after stirring and dissolves completely, in cooled poly-vinyl alcohol solution, drop into sodium carboxymethylcellulose, stir with dispersant and filter, obtaining mother liquor for subsequent use; Get 300g pure water again, and then add the ultra-fine decolouring tourmaline powder of above-mentioned weight, far-infared ceramic powder, silver-colored zinc ion powder put into excess water, and stir at least 30 minutes with dispersant, rotating speed is 8000 revs/min, and then add calgon and stir a little again, filter with 1000 eye mesh screens again and remove bulky grain powder, obtain functional liquid; Finally mixed with functional liquid by above-mentioned mother liquor, then stir 15 minutes with dispersant, rotating speed is 6000 revs/min, obtained finished product, and form is the tasteless outstanding mixed liquid of white.During use, it is that carrier is sprayed on wall with aqueous inner wall paint, discharges the anion useful to human body in the passive state, can remove the cigarette taste in daily life and other tastes of life quickly and effectively, improve the air quality of living environment, its anion emission ability reaches 8000/cm 3above, and energy emission wavelength is the far infrared be easily absorbed by the body of 2 ~ 18 microns, and its emissivity, up to 90%, can also have very strong antibacterial and antibacterial effect to Escherichia coli, Staphylococcus aureus etc.
Embodiment 5
Passive negative-ion catalyst purificant of the present invention is respectively by following component raw materials weighing: ultra-fine decolouring tourmaline powder 50g; Far-infared ceramic powder 10g; Silver zinc ion powder 1; Dispersant 1g; Sodium carboxymethylcellulose 5g; Polyvinyl alcohol 8g;
The polyvinyl alcohol of above-mentioned weight is fed in 700g pure water, is heated to particle after stirring and dissolves completely, in cooled poly-vinyl alcohol solution, drop into sodium carboxymethylcellulose, stir with dispersant and filter, obtaining mother liquor for subsequent use; Get 300g pure water again, and then add the ultra-fine decolouring tourmaline powder of above-mentioned weight, far-infared ceramic powder, silver-colored zinc ion powder put into excess water, and stir at least 30 minutes with dispersant, rotating speed is 8000 revs/min, and then add calgon and stir a little again, filter with 1000 eye mesh screens again and remove bulky grain powder, obtain functional liquid; Finally mixed with functional liquid by above-mentioned mother liquor, then stir 15 minutes with dispersant, rotating speed is 6000 revs/min, obtained finished product, and form is the tasteless outstanding mixed liquid of white.During use, it is that carrier is sprayed on wall with aqueous inner wall paint, discharges the anion useful to human body in the passive state, can remove the cigarette taste in daily life and other tastes of life quickly and effectively, improve the air quality of living environment, its anion emission ability reaches 8000/cm 3above, and energy emission wavelength is the far infrared be easily absorbed by the body of 2 ~ 18 microns, and its emissivity, up to 90%, can also have very strong antibacterial and antibacterial effect to Escherichia coli, Staphylococcus aureus etc.
Embodiment 6
The invention provides passive negative-ion catalyst purificant, wherein, its percentage by weight is made up of following raw material: ultra-fine decolouring tourmaline powder: 4.65 ~ 6.78%; Far-infared ceramic powder: 0.93 ~ 1.93%; Silver zinc ion powder: 0.093 ~ 0.065%; Dispersant: 0.093 ~ 0.058%; Sodium carboxymethylcellulose: 0.46 ~ 0.78%; Polyvinyl alcohol 0.74 ~ 0.19%; Pure water 93 ~ 96.9%.
Embodiment 7
As shown in Figure 1, the preparation method of described passive negative-ion catalyst purificant, is characterized in that, comprises the following steps:
A, polyvinyl alcohol is added in pure water, be heated to particle after stirring and dissolve completely;
B, input sodium carboxymethylcellulose, stir and filter, obtaining mother liquor;
C, put into excess water by ultra-fine decolouring tourmaline powder, far-infared ceramic powder, silver-colored zinc ion powder, first time adds after dispersant stirs, then second time adds after dispersant stirs, and filters and removes bulky grain powder, obtain functional liquid;
D, above-mentioned mother liquor is mixed with functional liquid after, add after dispersant stirs, obtained finished product.
In described step C: described first time adds dispersant and stirs at least 30 minutes, and mixer rotating speed is 6000 ~ 8000 revs/min.
In described step C: described filtration is removed bulky grain powder and filtered with 1000 eye mesh screens.
In described step D: stir at least 15 minutes, mixer rotating speed is 4000 ~ 6000 revs/min.
Wherein, in above-mentioned preparation process, the addition that can adjust sodium cellulose glycolate and polyvinyl alcohol according to actual conditions controls the viscosity of product.When using above-mentioned passive negative-ion catalyst purificant, spraying method can be adopted.
In above-described embodiment, described dispersant be at least waterglass, sodium phosphate trimer, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester one of them.
In above-described embodiment, described sodium carboxymethylcellulose concentration is 1% ~ 2%.
In above-described embodiment, described ultra-fine decolouring tourmaline powder be at least monocrystal tourmaline powder, raphioid fiber tourmaline powder, polycrystal tourmaline powder one of them.
In above-described embodiment, described silver-colored zinc ion powder at least comprise zinc ion, silver ion one of them.
In above-described embodiment, the degree of polymerization of described polyvinyl alcohol is at least the superelevation degree of polymerization (molecular weight 25 ~ 300,000), high polymerization degree (molecular weight 17-22 ten thousand), the middle degree of polymerization (molecular weight 12 ~ 150,000) and low polymerization degree (molecular weight 2.5 ~ 3.5 ten thousand).
In above-described embodiment, described dispersant is the interfacial agent simultaneously in molecule with lipophile and hydrophily two kinds of opposite nature, can homogeneous dispersion those be difficult to be dissolved in the solid particle of inorganic, the organic pigment of liquid, also can prevent sedimentation and the cohesion of solid particle simultaneously, form stable medicament needed for suspension, and the dispersant in the present invention is preferably calgon.
Passive negative-ion catalyst purificant of the present invention forms through explained hereafter such as super-fine processing, scientific formula and mixtures with multiple natural inorganic material, it is that carrier is sprayed on wall with aqueous inner wall paint, can ionize and discharge a large amount of hydroxyl group anion (H after it contacts with water in air molecule 3o 2 -), after these hydroxyl group anions contact with pernicious gas free in air by the comprehensive function of the processes such as oxidation Decomposition physisorption, electrical counteract effect, chemical reaction to reach the object purified air.During use, be that carrier is sprayed on wall with aqueous inner wall paint by passive negative-ion catalyst purificant provided by the invention, can ionize after it contacts with water in air molecule and discharge a large amount of hydroxyl group anions, after these hydroxyl group anions contact with pernicious gas free in air by the comprehensive function of the processes such as oxidation Decomposition physisorption, electrical counteract effect, chemical reaction to reach the object purified air.
Above to the explanation of its summary of the invention, for persons skilled in the art, without prejudice under the prerequisite of the principle of the invention to any apparent change that it does, the protection domain exceeding the application's claims can be regarded as.

Claims (8)

1. passive negative-ion catalyst purificant, is characterized in that, its percentage by weight is made up of following raw material: ultra-fine decolouring tourmaline powder: 4.65 ~ 6.78%; Far-infared ceramic powder: 0.93 ~ 1.93%; Silver zinc ion powder: 0.093 ~ 0.065%; Dispersant: 0.093 ~ 0.058%; Sodium carboxymethylcellulose: 0.46 ~ 0.78%; Polyvinyl alcohol 0.74 ~ 0.19%; Pure water 93 ~ 96.9%;
Described dispersant be at least waterglass, sodium phosphate trimer, calgon, sodium pyrophosphate, triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivative, polyacrylamide, guar gum, fatty acid polyethylene glycol ester one of them.
2. passive negative-ion catalyst purificant according to claim 1, is characterized in that, described sodium carboxymethylcellulose concentration is 1% ~ 2%.
3. passive negative-ion catalyst purificant according to claim 1, is characterized in that, described ultra-fine decolouring tourmaline powder be at least monocrystal tourmaline powder, raphioid fiber tourmaline powder, polycrystal tourmaline powder one of them.
4. passive negative-ion catalyst purificant according to claim 1, it is characterized in that, the degree of polymerization of described polyvinyl alcohol is the low polymerization degree of the superelevation degree of polymerization of molecular weight 25 ~ 300,000, the high polymerization degree of molecular weight 17-22 ten thousand, the middle degree of polymerization of molecular weight 12 ~ 150,000 or molecular weight 2.5 ~ 3.5 ten thousand.
5. the preparation method of passive negative-ion catalyst purificant as claimed in claim 1, is characterized in that, comprise the following steps:
A, polyvinyl alcohol is added in pure water, be heated to particle after stirring and dissolve completely;
B, input sodium carboxymethylcellulose, stir and filter, obtaining mother liquor;
C, put into excess water by ultra-fine decolouring tourmaline powder, far-infared ceramic powder, silver-colored zinc ion powder, first time adds after dispersant stirs, then second time adds after dispersant stirs, and filters and removes bulky grain powder, obtain functional liquid;
D, above-mentioned mother liquor is mixed with functional liquid after, add after dispersant stirs, obtained finished product.
6. preparation method as claimed in claim 5, is characterized in that, in described step C: described first time adds dispersant and stirs at least 30 minutes, and mixer rotating speed is 6000 ~ 8000 revs/min.
7. preparation method as claimed in claim 5, is characterized in that, in described step C: described filtration is removed bulky grain powder and filtered with 1000 eye mesh screens.
8. preparation method as claimed in claim 5, it is characterized in that, in described step D: stir at least 15 minutes, mixer rotating speed is 4000 ~ 6000 revs/min.
CN201210241734.XA 2012-07-13 2012-07-13 Passive negative-ion catalyst purificant and preparation method thereof Expired - Fee Related CN103480253B (en)

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