CN107376831A - The compound air purification material of the purification factor containing CLO receives net stone and preparation method thereof - Google Patents
The compound air purification material of the purification factor containing CLO receives net stone and preparation method thereof Download PDFInfo
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- CN107376831A CN107376831A CN201710792196.6A CN201710792196A CN107376831A CN 107376831 A CN107376831 A CN 107376831A CN 201710792196 A CN201710792196 A CN 201710792196A CN 107376831 A CN107376831 A CN 107376831A
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- 238000000746 purification Methods 0.000 title claims abstract description 84
- 239000000463 material Substances 0.000 title claims abstract description 80
- 239000004575 stone Substances 0.000 title claims abstract description 66
- 238000004887 air purification Methods 0.000 title claims abstract description 61
- 150000001875 compounds Chemical class 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 38
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 52
- 239000004113 Sepiolite Substances 0.000 claims abstract description 51
- 229960000892 attapulgite Drugs 0.000 claims abstract description 51
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 51
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 51
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 41
- 229940070527 tourmaline Drugs 0.000 claims abstract description 41
- 239000011032 tourmaline Substances 0.000 claims abstract description 41
- 239000002994 raw material Substances 0.000 claims abstract description 40
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000001179 sorption measurement Methods 0.000 claims abstract description 17
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 15
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims description 80
- 230000004913 activation Effects 0.000 claims description 41
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 238000012545 processing Methods 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000004088 foaming agent Substances 0.000 claims description 21
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 238000001354 calcination Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 238000005469 granulation Methods 0.000 claims description 8
- 230000003179 granulation Effects 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 239000004745 nonwoven fabric Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 5
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 230000009881 electrostatic interaction Effects 0.000 claims description 2
- -1 methacryloxy Chemical group 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims 3
- 229910052710 silicon Inorganic materials 0.000 claims 3
- 239000010703 silicon Substances 0.000 claims 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 21
- 238000000354 decomposition reaction Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 5
- 230000002045 lasting effect Effects 0.000 abstract description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 230000000505 pernicious effect Effects 0.000 description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 6
- 230000003213 activating effect Effects 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011941 photocatalyst Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
Abstract
Net stone and preparation method thereof is received the present invention relates to a kind of compound air purification material of purification factor containing CLO, and net stone of receiving includes the first component and the second component；Wherein, the raw material components of the first component include solid preparation of chlorine dioxide；The raw material components of second component by weight, including：The parts by weight of attapulgite 38~49, the parts by weight of sepiolite 23~29, the parts by weight of diatomite 20~25 and the parts by weight of tourmaline 3~7；The mass ratio of first component and the second component is (5~7):1.The present invention is by using materials such as chlorine dioxide, attapulgite and sepiolites as raw material, it is strong that the compound air purification material for the purification factor containing CLO being prepared receives net stone adsorption capacity and capacity of decomposition, purification efficiency is high, the harmful substance such as formaldehyde, Benzene and Homologues in purification air that can be lasting for a long time.
Description
Technical field
The present invention relates to technical field of air purification, and in particular to a kind of compound air purification material of purification factor containing CLO
Material receives net stone and preparation method thereof.
Background technology
In recent years, room air pollution situation was more and more common caused by finishing problem, and in these finishing pollutions,
Formaldehyde pollution, benzene homologues pollution etc., the health hazard to human body is very big, causes the attention of people from all walks of life.In the market
Air purifying preparation is mainly based on activated carbon and photocatalyst spray, and activated carbon improvement pernicious gas is not thorough, because adsorption saturation
Afterwards, it is particularly easy to pernicious gas occur to overflow again, the situation for causing air secondary to pollute；Photocatalyst spray cost is high, and
And photocatalyst is that spray is aerial, can only solve the pernicious gases such as the formaldehyde for being discharged into air for the moment, can not solve Interior Space
Gas pollutant acquisition time is up to the fundamental issue of 3~15 years.Therefore, it is also desirable to new material for air purification is developed, to keep away
Exempt from insufficient existing for current material.
The content of the invention
For in the prior art the defects of, present invention aims at providing, a kind of composite air of the purification factor containing CLO is net
Change material and receive net stone and preparation method thereof, be used as raw material by using chlorine dioxide, attapulgite and sepiolite etc., be prepared into
To the compound air purification material of the purification factor containing CLO to receive net stone adsorption capacity and capacity of decomposition strong, purification efficiency is high, can be with
The harmful substances such as formaldehyde, Benzene and Homologues in purification air lasting for a long time.
To achieve the above object, technical scheme provided by the invention is：
In a first aspect, receive net stone the invention provides a kind of compound air purification material of purification factor containing CLO, net stone is received
Including the first component and the second component；Wherein, the raw material components of the first component include solid preparation of chlorine dioxide；Second component
Raw material components by weight, including：The parts by weight of attapulgite 38~49, the parts by weight of sepiolite 23~29, diatomite 20~25
Parts by weight and the parts by weight of tourmaline 3~7；The mass ratio of first component and the second component is (5~7):1.It should be noted that the
In one raw material components, solid preparation of chlorine dioxide is that polymeric adsorbent and Helper vectors are added in ClO 2 solution, is prepared
Obtain gel solid preparation of chlorine dioxide.Wherein, polymeric adsorbent can select high-hydroscopicity polyacrylic resin, agar and carboxylic
The materials such as methylcellulose.
The present invention further embodiment in, the raw material components of the second component by weight, including：Attapulgite
38 parts by weight, the parts by weight of sepiolite 25, the parts by weight of diatomite 22 and the parts by weight of tourmaline 5；The matter of first component and the second component
Amount is than being 6:1.
The present invention further embodiment in, the raw material components of the second component by weight, including：Attapulgite
42 parts by weight, the parts by weight of sepiolite 27, the parts by weight of diatomite 21 and the parts by weight of tourmaline 3；The matter of first component and the second component
Amount is than being 6:1.
The present invention further embodiment in, the raw material components of the second component by weight, including：Attapulgite
40 parts by weight, the parts by weight of sepiolite 23, the parts by weight of diatomite 25 and the parts by weight of tourmaline 7；The matter of first component and the second component
Amount is than being 6:1.
In the further embodiment of the present invention, the preparation method of the second component comprises the following steps：S1：Selection has
Attapulgite, sepiolite, the diatomite natural minerals of adsorption capacity, and the Tourmaline Mineral Material with electrostatic interaction；
S2：Polished respectively again after attapulgite, sepiolite, diatomite to be carried out to purification processes respectively, it is standby then to cross 325 mesh sieves；Will
Tourmaline is polished after carrying out purification processes, and it is standby then to cross 400 mesh sieves；S3：To the attapulgite after step S2 processing, sepiolite
It is modified processing respectively with diatomite, then activates reaming；S4：By the attapulgite after step S3 processing, sepiolite, diatom
Soil is sufficiently mixed with tourmaline, is then placed in high intensity comminutor and is granulated；S5：The particle that granulation obtains is done
It is dry；S6：Dried particle is subjected to calcination for activation, obtains the second component.
The present invention further embodiment in, in step S3, modification be using surfactant, modifying agent and
The mixed solution of foaming agent is carried out；Wherein, the mass ratio of surfactant, modifying agent and foaming agent is 1:(0.8~1.2):
(0.2~0.4).
In the further embodiment of the present invention, surfactant is 1227 surfactants, and modifying agent is mass ratio
For 1:1 methacryloxypropyl trimethoxy silane and the mixture to the third diphenol, foaming agent are dodecyl sulphate
Sodium.
In the further embodiment of the present invention, in step S2, attapulgite, sepiolite, diatomite after purification and
In tourmaline, active principle purity reaches more than 90%；In step S3, the temperature for activating reaming is 300~350 DEG C；Step S5
In, drying is dried using drying oven, and the dry time is more than 2h, and dry temperature is 100~120 DEG C.
In the further embodiment of the present invention, in step S6, calcination for activation is carried out using high-temperature activation stove, activation
Temperature is 400~480 DEG C, and the time of activation is 1~2h.
Second aspect, receives the preparation method of net stone the invention provides the compound air purification material of the purification factor containing CLO,
Comprise the following steps：First component and the second component are well mixed, then wrapped up using wrappage, wrappage is preferably
Non-woven fabrics, the compound air purification material for obtaining the purification factor containing CLO receive net stone.
The present invention also protects the compound air purification material of the above-mentioned purification factor containing CLO to receive net stone in preparation purification air production
Application in product.
Technical scheme provided by the invention, there is following beneficial effect：(1) present invention is using chlorine dioxide, concave convex rod
Soil and sepiolite etc. are used as raw material, and the compound air purification material of the purification factor containing CLO being prepared receives net stone energy of adsorption
Power and capacity of decomposition are strong, and purification efficiency is high；(2) the compound air purification material of the purification factor provided by the invention containing CLO is received only
Stone long shelf-life, formaldehyde, the harmful substance such as Benzene and Homologues in purification air that can be lasting for a long time；(3) present invention carries
Supply the purification factor containing CLO compound air purification material receive net stone the first component (white particle) molecule outer layer carry 19
Individual electronics, pernicious gas can be resolved into carbon dioxide and water, the second component (black particle) surface has nanoscale hole,
There is the adsorption effect better than activated carbon；The present invention changes traditional sorbing material without capacity of decomposition, or some have capacity of decomposition
Material but the problem of poor adsorption capacity；The compound air purification material of the purification factor provided by the invention containing CLO receives net stone
Due to non-volatility, non-corrosiveness is nontoxic, is that pernicious gas very outstanding at present removes material；(4) present invention provides
The purification factor containing CLO compound air purification material receive net stone preparation method it is simple, production cost is low, has good business
Industry prospect.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description
Obtain substantially, or recognized by the practice of the present invention.
Embodiment
Below in conjunction with the embodiment of the present invention, technical scheme is clearly and completely described.Implement below
Example is only used for clearly illustrating technical scheme, therefore be intended only as example, and can not limit this hair with this
Bright protection domain.
Experimental method in following embodiments, it is conventional method unless otherwise specified.Examination used in following embodiments
Material is tested, is to be commercially available from regular shops unless otherwise specified.Quantitative test in following examples, is respectively provided with three
Secondary to repeat to test, data are to repeat the average value or mean+SD of experiment three times.
The present invention provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and net stone of receiving includes first group
Divide the quality of (white particle) and the second component (black particle), the first component (white particle) and the second component (black particle)
Than for (5~7):1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 38~49, Hai Pao
The parts by weight of stone 23~29, the parts by weight of diatomite 20~25 and the parts by weight of tourmaline 3~7；The preparation of second component (black particle)
Method comprises the following steps：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activation is expanded
Hole, the temperature for activating reaming are 300~350 DEG C；Modification is molten using the mixing of surfactant, modifying agent and foaming agent
Liquid is carried out；The mass ratio of surfactant, modifying agent and foaming agent is 1:(0.8~1.2):(0.2~0.4), surfactant
For 1227 surfactants, modifying agent is that mass ratio is 1:1 methacryloxypropyl trimethoxy silane and to the third two
The mixture of phenol, foaming agent are lauryl sodium sulfate；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
100~120 DEG C；
S6：Dried particle is carried out to use high-temperature activation stove calcination for activation, activation temperature is 400~480 DEG C, activation
Time be 1~2h, obtain the second component (black particle).
In addition, receiving the preparation side of net stone present invention also offers the compound air purification material of the above-mentioned purification factor containing CLO
Method, comprise the following steps：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using wrappage
Wrap up in, wrappage is preferably non-woven fabrics, and the compound air purification material for obtaining the purification factor containing CLO receives net stone.
Net stone is received to the compound air purification material of the purification factor provided by the invention containing CLO with reference to specific embodiment
And preparation method thereof be described further.
Embodiment one
The present embodiment provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and raw material components are by weight
Part meter, including：First component (white particle) and the second component (black particle), the first component (white particle) and the second component
The mass ratio of (black particle) is 6:1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 38, sepiolite 25
Parts by weight, the parts by weight of diatomite 22 and the parts by weight of tourmaline 5；The preparation method of second component (black particle) includes following step
Suddenly：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activation is expanded
Hole, the temperature for activating reaming are 325 DEG C；Modification is entered using the mixed solution of surfactant, modifying agent and foaming agent
OK；The mass ratio of surfactant, modifying agent and foaming agent is 1:1:0.3, surfactant is 1227 surfactants, modified
Agent is that mass ratio is 1:1 methacryloxypropyl trimethoxy silane and the mixture to the third diphenol, foaming agent ten
Sodium dialkyl sulfate；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
110℃；
S6：Dried particle use high-temperature activation stove calcination for activation, activation temperature is 440 DEG C, activation when
Between be 1.5h, obtain the second component (black particle).
By above-mentioned raw material, net stone is received using the compound air purification material of the purification factor provided by the invention containing CLO
Preparation method, the compound air purification material for preparing the purification factor containing CLO receive net stone：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using non-woven fabrics
Wrap up in, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
Embodiment two
The present embodiment provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and raw material components are by weight
Part meter, including：First component (white particle) and the second component (black particle), the first component (white particle) and the second component
The mass ratio of (black particle) is 6:1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 42, sepiolite 27
Parts by weight, the parts by weight of diatomite 21 and the parts by weight of tourmaline 3；The preparation method of second component (black particle) includes following step
Suddenly：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activation is expanded
Hole, the temperature for activating reaming are 300 DEG C；Modification is entered using the mixed solution of surfactant, modifying agent and foaming agent
OK；The mass ratio of surfactant, modifying agent and foaming agent is 1:0.8:0.2, surfactant is 1227 surfactants, is changed
Property agent be mass ratio be 1:1 methacryloxypropyl trimethoxy silane and the mixture to the third diphenol, foaming agent are
Lauryl sodium sulfate；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
100℃；
S6：Dried particle use high-temperature activation stove calcination for activation, activation temperature is 400 DEG C, activation when
Between be 1h, obtain the second component (black particle).
By above-mentioned raw material, net stone is received using the compound air purification material of the purification factor provided by the invention containing CLO
Preparation method, the compound air purification material for preparing the purification factor containing CLO receive net stone：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using non-woven fabrics
Wrap up in, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
Embodiment three
The present embodiment provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and raw material components are by weight
Part meter, including：First component (white particle) and the second component (black particle), the first component (white particle) and the second component
The mass ratio of (black particle) is 6:1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 40, sepiolite 23
Parts by weight, the parts by weight of diatomite 25 and the parts by weight of tourmaline 7；The preparation method of second component (black particle) includes following step
Suddenly：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activation is expanded
Hole, the temperature for activating reaming are 350 DEG C；Modification is entered using the mixed solution of surfactant, modifying agent and foaming agent
OK；The mass ratio of surfactant, modifying agent and foaming agent is 1:1.2:0.4, surfactant is 1227 surfactants, is changed
Property agent be mass ratio be 1:1 methacryloxypropyl trimethoxy silane and the mixture to the third diphenol, foaming agent are
Lauryl sodium sulfate；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
120℃；
S6：Dried particle use high-temperature activation stove calcination for activation, activation temperature is 480 DEG C, activation when
Between be 2h, obtain the second component (black particle).
By above-mentioned raw material, net stone is received using the compound air purification material of the purification factor provided by the invention containing CLO
Preparation method, the compound air purification material for preparing the purification factor containing CLO receive net stone：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using non-woven fabrics
Wrap up in, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
Comparative example one
This comparative example provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and raw material components are by weight
Part meter, including：First component (white particle) and the second component (black particle), the first component (white particle) and the second component
The mass ratio of (black particle) is 6:1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 38, sepiolite 25
Parts by weight, the parts by weight of diatomite 22 and the parts by weight of tourmaline 5；The preparation method of second component (black particle) includes following step
Suddenly：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activation is expanded
Hole, the temperature for activating reaming are 325 DEG C；Modification is entered using the mixed solution of surfactant, modifying agent and foaming agent
OK；The mass ratio of surfactant, modifying agent and foaming agent is 1:1:0.3, surfactant is 1227 surfactants, modified
Agent is methacryloxypropyl trimethoxy silane, and foaming agent is lauryl sodium sulfate；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
110℃；
S6：Dried particle use high-temperature activation stove calcination for activation, activation temperature is 440 DEG C, activation when
Between be 1.5h, obtain the second component (black particle).
By above-mentioned raw material, net stone is received using the compound air purification material of the purification factor provided by the invention containing CLO
Preparation method, the compound air purification material for preparing the purification factor containing CLO receive net stone：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using non-woven fabrics
Wrap up in, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
Comparative example two
This comparative example provides a kind of compound air purification material of the purification factor containing CLO and receives net stone, and raw material components are by weight
Part meter, including：First component (white particle) and the second component (black particle), the first component (white particle) and the second component
The mass ratio of (black particle) is 6:1；
Wherein, the raw material components of the first component (white particle) include solid preparation of chlorine dioxide；
The raw material components of second component (black particle) by weight, including：The parts by weight of attapulgite 38, sepiolite 25
Parts by weight, the parts by weight of diatomite 22 and the parts by weight of tourmaline 5；The preparation method of second component (black particle) includes following step
Suddenly：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and make with electrostatic
Tourmaline Mineral Material；
S2：Attapulgite, sepiolite, diatomite are subjected to purification processes respectively, make active principle purity reach 90% with
On, then polish respectively, it is standby after 325 mesh sieves；By tourmaline progress purification processes make active principle purity reach 90% with
On, then polish, it is standby after 400 mesh sieves；
S3：Activation reaming is carried out respectively to attapulgite, sepiolite and the diatomite after step S2 processing, activates reaming
Temperature is 325 DEG C；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, Ran Houfang
Enter high intensity comminutor to be granulated；
S5：The particle that granulation obtains is dried using drying oven, the dry time is more than 2h, and dry temperature is
110℃；
S6：Dried particle use high-temperature activation stove calcination for activation, activation temperature is 440 DEG C, activation when
Between be 1.5h, obtain the second component (black particle).
By above-mentioned raw material, net stone is received using the compound air purification material of the purification factor provided by the invention containing CLO
Preparation method, the compound air purification material for preparing the purification factor containing CLO receive net stone：
First component (white particle) and the second component (black particle) is well mixed, then wrapped using non-woven fabrics
Wrap up in, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
The compound air purification material for the purification factor containing CLO that the embodiment of the present invention one is prepared to embodiment three is received
Net stone, by function assessment experiment come its effect of system evaluation, and purified with what comparative example one and comparative example two were prepared containing CLO
The compound air purification material of the factor receives net masonry as control.
1st, formaldehyde in air purifying rate situation
By GB/T 16129-1995 residential areas Formaldehyde in Atmosphere health test method, what measure had just been painted contains
The interior of HEB-01 coating, the interior containing fat-soluble organic varnish, the interior containing big precious paint and the indoor formaldehyde containing Nippon contain
Amount；Then the CLO that contains that the embodiment of the present invention one to embodiment three, comparative example one and comparative example two is prepared is respectively put into purify
The compound air purification material of the factor receives net stone 2 days, determines each indoor content of formaldehyde again, each indoor formaldehyde is calculated
Purifying rate, concrete outcome is as shown in table 1.
The purifying rate of each indoor formaldehyde of table 1
2nd, the efficiency of harmful substance is converted after different time
Purified respectively by what the embodiment of the present invention one to embodiment three, comparative example one and comparative example two were prepared containing CLO
The compound air purification material of the factor receives net stone and carries out removing first under the conditions of humidity is 65%, room temperature, concentration of formaldehyde are 100ppm
Aldehyde is tested, and illumination condition is identical, determines the different efficiency for receiving net stone conversion formaldehyde and benzene after different time.
Net stone of being received after the different time of table 2 converts the efficiency of formaldehyde and benzene
It should be noted that except the situation that above-described embodiment one is enumerated to embodiment three, from other raw material components
Proportioning and preparation method parameter are also feasible.
Technical scheme provided by the invention, there is following beneficial effect：(1) present invention is using chlorine dioxide, concave convex rod
Soil and sepiolite etc. are used as raw material, and the compound air purification material of the purification factor containing CLO being prepared receives net stone energy of adsorption
Power and capacity of decomposition are strong, and purification efficiency is high；(2) the compound air purification material of the purification factor provided by the invention containing CLO is received only
Stone long shelf-life, formaldehyde, the harmful substance such as Benzene and Homologues in purification air that can be lasting for a long time；(3) present invention carries
Supply the purification factor containing CLO compound air purification material receive net stone the first component (white particle) molecule outer layer carry 19
Individual electronics, pernicious gas can be resolved into carbon dioxide and water, the second component (black particle) surface has nanoscale hole,
There is the adsorption effect better than activated carbon；The present invention changes traditional sorbing material without capacity of decomposition, or some have capacity of decomposition
Material but the problem of poor adsorption capacity；The compound air purification material of the purification factor provided by the invention containing CLO receives net stone
Due to non-volatility, non-corrosiveness is nontoxic, is that pernicious gas very outstanding at present removes material；(4) present invention provides
The purification factor containing CLO compound air purification material receive net stone preparation method it is simple, production cost is low, has good business
Industry prospect.
It should be noted that unless otherwise indicated, technical term or scientific terminology used in this application should be this hair
The ordinary meaning that bright one of ordinary skill in the art are understood.Unless specifically stated otherwise, otherwise illustrate in these embodiments
Part and relative step, numerical expression and the numerical value of step are not limit the scope of the invention.It is illustrated and described herein
In all examples, unless otherwise prescribed, any occurrence should be construed as merely exemplary, not as limitation, because
This, other examples of exemplary embodiment can have different values.
In the description of the invention, it is to be understood that term " first ", " second " are only used for describing purpose, and can not
It is interpreted as indicating or implies relative importance or imply the quantity of the technical characteristic indicated by indicating.Thus, define " the
One ", one or more this feature can be expressed or be implicitly included to the feature of " second ".In the description of the invention,
" multiple " are meant that two or more, unless otherwise specifically defined.
Finally it should be noted that：Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations；To the greatest extent
The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that：Its according to
The technical scheme described in foregoing embodiments can so be modified, either which part or all technical characteristic are entered
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme, it all should cover among protection scope of the present invention.
Claims (10)
1. a kind of compound air purification material of purification factor containing CLO receives net stone, it is characterised in that described to receive net stone and include first
Component and the second component；
Wherein, the raw material components of first component include solid preparation of chlorine dioxide；
The raw material components of second component by weight, including：The parts by weight of attapulgite 38~49, the weight of sepiolite 23~29
Measure part, the parts by weight of diatomite 20~25 and the parts by weight of tourmaline 3~7；
The mass ratio of first component and second component is (5~7):1.
2. the compound air purification material of the purification factor according to claim 1 containing CLO receives net stone, it is characterised in that：
The raw material components of second component by weight, including：The parts by weight of attapulgite 38, the parts by weight of sepiolite 25, silicon
The parts by weight of diatomaceous earth 22 and the parts by weight of tourmaline 5；
The mass ratio of first component and second component is 6:1.
3. the compound air purification material of the purification factor according to claim 1 containing CLO receives net stone, it is characterised in that：
The raw material components of second component by weight, including：The parts by weight of attapulgite 42, the parts by weight of sepiolite 27, silicon
The parts by weight of diatomaceous earth 21 and the parts by weight of tourmaline 3；
The mass ratio of first component and second component is 6:1.
4. the compound air purification material of the purification factor according to claim 1 containing CLO receives net stone, it is characterised in that：
The raw material components of second component by weight, including：The parts by weight of attapulgite 40, the parts by weight of sepiolite 23, silicon
The parts by weight of diatomaceous earth 25 and the parts by weight of tourmaline 7；
The mass ratio of first component and second component is 6:1.
5. the compound air purification material of the purification factor containing CLO according to claim any one of 1-4 receives net stone, its feature
It is, the preparation method of second component comprises the following steps：
S1：Attapulgite, sepiolite, diatomite natural minerals of the selection with adsorption capacity, and with electrostatic interaction
Tourmaline Mineral Material；
S2：Polished respectively again after attapulgite, sepiolite, diatomite to be carried out to purification processes respectively, it is standby then to cross 325 mesh sieves
With；Polished after tourmaline is carried out into purification processes, it is standby then to cross 400 mesh sieves；
S3：Processing is modified respectively to attapulgite, sepiolite and the diatomite after step S2 processing, then activates reaming；
S4：Attapulgite, sepiolite, diatomite and tourmaline after step S3 processing is sufficiently mixed, is then placed in height
Intensity comminutor is granulated；
S5：The particle that the granulation obtains is dried；
S6：The dried particle is subjected to calcination for activation, obtains second component.
6. the compound air purification material of the purification factor according to claim 5 containing CLO receives net stone, it is characterised in that：
In step S3, the modification is carried out using the mixed solution of surfactant, modifying agent and foaming agent；Wherein,
The mass ratio of the surfactant, modifying agent and foaming agent is 1:(0.8~1.2):(0.2~0.4).
7. the compound air purification material of the purification factor according to claim 6 containing CLO receives net stone, it is characterised in that：
The surfactant is 1227 surfactants, and the modifying agent is that mass ratio is 1:1 methacryloxy third
Base trimethoxy silane and the mixture to the third diphenol, the foaming agent are lauryl sodium sulfate.
8. the compound air purification material of the purification factor according to claim 5 containing CLO receives net stone, it is characterised in that：
In step S2, in the attapulgite, sepiolite, diatomite and tourmaline after the purification, active principle purity reaches
More than 90%；
In step S3, the temperature of the activation reaming is 300~350 DEG C；
In step S5, the drying is dried using drying oven, and the dry time is more than 2h, dry temperature is 100~
120℃。
9. the compound air purification material of the purification factor according to claim 5 containing CLO receives net stone, it is characterised in that：
In step S6, the calcination for activation is carried out using high-temperature activation stove, and activation temperature is 400~480 DEG C, the time of activation
For 1~2h.
10. the compound air purification material of the purification factor containing CLO described in claim any one of 1-9 receives the preparation side of net stone
Method, it is characterised in that comprise the following steps：
First component and second component are well mixed, then wrapped up using wrappage, the wrappage is excellent
Elect non-woven fabrics as, the compound air purification material for obtaining the purification factor containing CLO receives net stone.
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| CN108126669A (en) * | 2017-12-25 | 2018-06-08 | 佛山市中环环境检测中心 | A kind of disinfection type air purification material and preparation method thereof |
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| CN110026084A (en) * | 2019-04-28 | 2019-07-19 | 芜湖深奥环保科技有限公司 | A kind of air purifying composition of the pure anionic particle containing diatom and preparation method thereof |
| CN110075796A (en) * | 2019-04-28 | 2019-08-02 | 芜湖深奥环保科技有限公司 | It is a kind of to receive net stone and preparation method thereof with the CLO purification factor for actively adsorbing micropore |
| CN110882623A (en) * | 2018-09-07 | 2020-03-17 | 乐腾达(深圳)日用品有限公司 | Composite air purification material Dianjing stone containing BAO purification factor and preparation method thereof |
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