CN103725051B - A kind of body material of inorganic paint and application thereof - Google Patents
A kind of body material of inorganic paint and application thereof Download PDFInfo
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- CN103725051B CN103725051B CN201410003196.XA CN201410003196A CN103725051B CN 103725051 B CN103725051 B CN 103725051B CN 201410003196 A CN201410003196 A CN 201410003196A CN 103725051 B CN103725051 B CN 103725051B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a kind of body material and application thereof of inorganic paint, described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, described liquid-state silicon colloidal sol in the mass ratio of solid content and calcium carbonate for 1: 3 ~ 10.The auxiliary of less than 20% of inorganic paint total mass is added on described body material basis and joins material, can inorganic paint be obtained.Inorganic paint of the present invention have ageing-resistant, weathering resistance strong, have chemical binding force with cement basic layer, do not peel, heat-resisting, prevent fires, the feature such as nontoxic, pollution-free and save energy, and it is not containing the strong basic ion such as potassium, sodium, pH value is less than 10, good with the consistency of pigment, accumulation of salt in the surface soil phenomenon can not be produced, the inorganic paint of shades of colour can be made.Body material of the present invention also can be used for preparing rigidity water-proofing material, colored finish mortar, artificial stone material and art painting.
Description
Technical field
The present invention relates to a kind of inorganic paint, be specifically related to a kind of inorganic paint adopting silicon sol and its preparation method and application.
Background technology
According to national sector standard JG/26-2002, inorganic architectural coatings can be divided into two classes by main binding agent kind, and one is that it is formulated to add pigment, filler and auxiliary agent with water glass (alkalimetal silicate) for main binding agent; Two is be main binding agent with silicon sol, and it is formulated to add appropriate synthetic resin emulsion, pigment, filler and auxiliary agent.
The conventional potassium silicate for the preparation of inorganic paint and its main physical and chemical indexes of silicon sol as shown in the table:
。
From the composition of potassium silicate and silicon sol, both key distinctions are at alkalinity.Although the former also can with calcium carbonate generation calcify reaction, even there is lower shrinking percentage, but because its free alkali content is higher, inhibition is had to silicification reaction, therefore larger on the water tolerance impact of final product, and the accumulation of salt in the surface soil phenomenon of association also can affect painted homogeneity, bottleneck is constituted to practical application.And the latter's alkalinity is extremely low, silication degree is higher, so water tolerance and also better with the consistency of pigment.
But, when being used alone silicon sol, often there is the critical defect such as crackle, internal capillary in ambient cure film forming, meanwhile, and silicon sol on the high side, the several times of its price water glass often all the time, also far above the synthetic emulsion of same concentration, therefore usual auxiliary agent of being used as by silicon sol uses at present, is usually add organic polymer emulsion to obtain organic-inorganic compoiste coating, and the coating adding organic polymer material acquisition is easily aging, weathering resistance is poor.Also have report to adopt watersoluble melamine and polyvalent alcohol to carry out modification to silicon sol, but this kind of process can increase the complicacy of preparation.
In recent years, traditional ion exchange method production silicon sol technique is progressively replaced along with silica flour one one-step hydrolysis method produces silicon sol technique, the price of silicon sol progressively drops to the level lower than water glass, so silicon sol of today has become a kind of basic chemical raw materials had a extensive future.Therefore, if silicon sol film forming can be overcome there is the problem such as crackle, internal capillary, inorganic paint of good performance can be obtained.
Summary of the invention
Goal of the invention of the present invention overcomes above shortcomings in prior art, provides a kind of body material of inorganic paint, and the application of this body material.
To achieve the above object of the invention, the technical solution used in the present invention is: a kind of body material of inorganic paint, and described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, described liquid-state silicon colloidal sol in the mass ratio of solid content and calcium carbonate for 1: 3 ~ 10.
Preferred technical scheme, described liquid-state silicon colloidal sol in the mass ratio of solid content and calcium carbonate for 1: 5 ~ 8.
In technique scheme, the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, and pH value is less than 11.
Described calcium carbonate is the powder of more than purity more than 95%, fineness 200 order.
One as above-mentioned body material is applied, the invention provides a kind of inorganic paint, become with auxiliary material liquid combo of joining by above-mentioned body material, described auxiliary join that material is inorganic paint total mass less than 20%, auxiliary material of joining is selected from one or more combination in high molecular polymer, filler, pigment, paint additive.
The preparation method of above-mentioned inorganic paint, comprises the following steps:
I, weigh liquid-state silicon colloidal sol, calcium carbonate by above-mentioned mass ratio and auxiliaryly join material, described auxiliary material of joining is made up of high molecular polymer, filler, pigment, paint additive;
II, liquid-state silicon colloidal sol is joined in speed governing Scattered Kettle, stir and slowly add calcium carbonate and auxiliaryly join material, accelerate after interpolation to be stirred to evenly, make soup compound and seal preservation.
During use, the liquid-state silicon colloidal sol in the inorganic paint of coating and calcium carbonate generation air-setting are reacted, and generate hydrated calcium silicate.Its process is, unformed active silica in silica aqueous solution and the calcium water generation reaction Calucium Silicate powder on calcium carbonate granule surface, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is got up by hydrated calcium silicate glue connection, when in air, water evaporation in system, separates out hydrated calcium silicate crystal, and to form hydrated calcium silicate crystal/calcium carbonate be imitation stone structures that is main component, water-fast, that have mechanical strength.Make coating and cement basic layer have stronger chemical binding force thus, and make coating problems of crack can not occur.
In technique scheme, described high molecular polymer is one of EVA redispersable latex powder, acrylic emulsion and redispersable latex powder thereof, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin or multiple combination; Described filler is one of titanium dioxide, mica, kaolin or multiple combination; Described pigment is pigment dyestuff, mineral dye or the liquid color paste that is mixed into by multiple pigment; Described paint additive is one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas, calcium containing compound, zinc compound or multiple combination.Metal ion in calcium containing compound and zinc compound can react with silicon sol and generate silicate nonsoluble, can promote the setting rate of inorganic paint, improves the rupture strength of inorganic paint.
Preferably, the minimum film-forming temperature (MFT) of high molecular polymer is about zero degree.
The present invention provides the body material of above-mentioned inorganic paint preparing the application in rigidity water-proofing material, colored finish mortar, artificial stone material simultaneously.
Add less than 20% pigment in above-mentioned body material, can use as art painting, for drawing the picture of similar oil painting.
Because technique scheme is used, the present invention compared with prior art has following advantages:
1, present invention is disclosed a kind of of great value gelling chemical reaction, the feature of this chemical reaction is that silica sol liquid can generate water insoluble, to have intensity hydrated calcium silicate artificial stone material with the calcium carbonate generation air-setting reaction of certain fineness, and construct a kind of body material of inorganic paint accordingly, by limiting the ratio of silica sol liquid and calcium carbonate, obtain significant technique effect.
2, inorganic paint of the present invention compares to existing inorganic silicate coating and has outstanding advantage: it have ageing-resistant, weathering resistance strong, have chemical binding force with cement basic layer, do not peel, heat-resisting, prevent fires, the feature such as nontoxic, pollution-free and save energy, and it is not containing the strong basic ion such as potassium, sodium, pH value is less than 10, good with the consistency of pigment, accumulation of salt in the surface soil phenomenon can not be produced, the inorganic paint of shades of colour can be made.
3, the calcium carbonate that the present invention utilizes belongs to a kind of slightly soluble salt, its carbonate ions that dissociates can be replaced by silicate ion, thus forming the insoluble and better Calucium Silicate powder of over-all properties, it also has certain covering effect in whitewash, can replace the effect of the titanium dioxide of most.
Accompanying drawing explanation
Fig. 1 is the XRD diffractogram of silicon sol in embodiment one.
Fig. 2 is the XRD diffractogram of silicon sol and calcium carbonate gas mixture hardened product in embodiment one.
Embodiment
Below in conjunction with drawings and Examples, the invention will be further described:
Embodiment one: a kind of body material of inorganic paint, described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, take 100 grams of liquid-state silicon colloidal sols (solid content is 30%), 100 grams of powder calcium carbonate respectively, silicon sol is injected speed governing Scattered Kettle, add calcium carbonate while stirring, then high-speed stirring is uniformly dispersed.
Fig. 1 is the XRD diffractogram of raw materials of silica sol, and it is a kind of unformed silicon-dioxide; Fig. 2 is the XRD diffractogram of the hardened product of product placement in atmosphere after 3 days of the present embodiment, wherein can find that unformed silicon-dioxide all disappears, generate and have the good hydrated calcium silicate of crystalline structure, the unreacted calcium carbonate of remaining portion.From mechanism, unformed active silica in silica aqueous solution and the calcium water generation reaction Calucium Silicate powder on calcium carbonate granule surface, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is got up by hydrated calcium silicate glue connection, when being put in air, water evaporation in system, separates out hydrated calcium silicate crystal, and to form hydrated calcium silicate crystal/calcium carbonate be imitation stone structures that is main component, water-fast, that have mechanical strength.
In following examples, the silicon sol of use can be: the dispersion liquid of reactive silica colloidal silica in water that pH value is greater than 8, and its range of solid content is 30-40%.
Calcium carbonate can be: by natural whiting ore through the powder pulverized, grind, or the calcium carbonate of synthetic, and its calcium carbonate content is no less than 95%, and whiteness is not less than 85%, and fineness is not less than 200 orders.Especially, the density adopting water-ground limestone to obtain than light calcium carbonate is larger, performance is better.
High molecular polymer can be has flexible latex powder, emulsion and aqueous resin dispersion, comprising EVA redispersable latex powder, esters of acrylic acid redispersable latex powder, fluorine carbon emulsion (fluorine carbon emulsion through plasticising is good), organosilicon crylic acid latex, pure-acrylic emulsion, benzene emulsion, and aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin etc.Adopt the effect of high molecular polymer can improve stability and the application property of " silicon sol-calcium carbonate " system, and splitting resistance and the snappiness of its hardened material can be increased.
The auxiliary material of joining such as pigment, filler, paint additive can require to adjust according to the use properties of coating.
Embodiment two: first take the liquid-state silicon colloidal sol (solid content=30%, hereinafter referred to as silicon sol, lower same) of 100 grams, the powder calcium carbonate of 300 grams respectively, then silicon sol is injected speed governing Scattered Kettle, progressively add calcium carbonate again and auxiliaryly join material, auxiliary join that material usage is not more than total mass 20%, then high-speed stirring is uniformly dispersed, make soup compound, after barrelling, sealing is preserved, and period of storage reaches 6 months, and the ultimate compression strength of test in its seven days is greater than 12MPa, whiteness is greater than 85%, and Mohs' hardness is greater than 5.
Embodiment three: be first in kind uniformly dispersed after the EVA redispersable latex powder mixing of the second-order transition temperature MFT of the powder calcium carbonate of the silicon sol of 100 grams, about 200 gram, the pearlstone of 20 grams and 10 grams about zero degree in speed governing Scattered Kettle, this product can be used as a kind of inorganic fire thermal insulation coatings and uses, and after using barrelling, period of storage reaches 6 months.Compared with embodiment two product, its anti-cracking performance improves.
Embodiment four: be first uniformly dispersed after the iron oxide pigment mixing of the powder calcium carbonate of the silicon sol of 100 grams, about 150 gram, the titanium dioxide of 30 grams, the Acrylic emulsion powder of 10 grams and 2 grams in speed governing Scattered Kettle, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment two, three products, it can present abundant color.
Products obtained therefrom adopts JG/T26-2002 " exterior wall inorganic architectural coatings " standard test, obtains technical indicator as shown in table 1,
。
Adopt inorganic paint prepared by embodiment two to four, after being coated with and brushing wall, time dry in atmosphere, unformed silicon sol (silicon-dioxide) will with calcium carbonate reaction, crosslinked webbed " hydrated calcium silicate " structure after dehydration, thus form the rostone coating with resistance to compression, tensile strength.Its final product is based on ionic linkage and covalent linkage, and Van der Waals key is auxiliary, and its performance is similar to rock forming mineral.After this inorganic paint is painted on cement based metope (as concrete, cement based putty, cement based insulation surface layer etc.), cement foundation wall surface can be penetrated into, and generate water-fast Calucium Silicate powder with the calcareous material reaction in cement, form anchoring effect, coating and metope are combined as a whole securely.
Embodiment five: be first uniformly dispersed after the chrome green pigment mixing of the powder calcium carbonate of the silicon sol of 100 grams, about 200 gram, the titanium dioxide of 20 grams, the fluorine carbon emulsion of 20 grams and 3 grams in speed governing Scattered Kettle, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment two, three products, it can present green color.
Embodiment six: be first uniformly dispersed after the ultramarine blue pigment mixing of the powder calcium carbonate of the silicon sol of 100 grams, about 250 gram, the kaolin of 20 grams, the benzene emulsion of 20 grams and 5 grams in speed governing Scattered Kettle, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment two, three products, it can present blue color.
Embodiment seven: be first uniformly dispersed after the ferric oxide red colorant mixing of the powder calcium carbonate of the silicon sol of 100 grams, about 150 gram, the ACRYLIC EMULSION of 20 grams and 100 grams in speed governing Scattered Kettle, this product can be used as a kind of art painting and uses, and after barrelling, period of storage reaches 6 months.
Embodiment eight: be uniformly dispersed in thick pulpous state after first the powder calcium carbonate of the silicon sol of 100 grams, about 250 gram and the hydrophobic type redispersable latex powder of 15 grams being mixed in speed governing Scattered Kettle, this product can be used as a kind of rigidity water-proofing material and uses, and its impermeability can reach 0.3MPa.
Embodiment nine: first mix in thixotropy mortar by the iron oxide pigment of the silicon sol of 100 grams, the powder calcium carbonate of 250 grams, the graded sand and stone of 100 grams, the Acrylic emulsion powder of 10 grams and 4 grams and appropriate densification powder (slurry), lignocellulose etc., this material can be used as a kind of not accumulation of salt in the surface soil, uses without the need to the colored finish mortar of overlay treatment.
Embodiment ten: be uniformly dispersed in rheological mortar after first the powder calcium carbonate of the silicon sol of 100 grams, about 200 gram, the graded sand and stone of 150 grams, the EVA redispersable latex powder of 20 grams, the iron oxide pigment of 4 grams and appropriate flow agent being mixed in speed governing Scattered Kettle, then pour in the mould of artificial stone plate, reinforcement vibrating forming, can obtain a kind of artificial stone plate of light through surface finish after the demoulding.
Embodiment 11: first take two samples respectively, the liquid-state silicon colloidal sol of 100 grams, the powder calcium carbonate of 200 grams, then inject speed governing Scattered Kettle by silicon sol, more progressively add calcium carbonate.Add 1 gram of calcium chloride in a sample, another sample does not add, then high-speed stirring is uniformly dispersed simultaneously, makes soup compound, and after barrelling, sealing is preserved, and period of storage reaches 6 months.Found that, the setting rate on the sample adding calcium chloride after wall is greater than the sample not adding calcium chloride.
Apply technical scheme of the present invention, compare to existing inorganic silicate coating and there is outstanding advantage: it has ageing-resistant, weathering resistance is strong, chemical binding force is had with cement basic layer, do not peel, heat-resisting, fire prevention, nontoxic, the features such as pollution-free and save energy, and it is not containing potassium, the strong basic ion such as sodium, pH value is less than 10, good with the consistency of pigment, accumulation of salt in the surface soil phenomenon can not be produced, the inorganic paint of shades of colour can be made, it achieve a kind of alkali-free and the controlled inorganic coagulation material of open season, and there is good tint permanence, can be used for inorganic paint, colored finish mortar, the industries such as artificial platen and art painting.
Claims (9)
1. a body material for inorganic paint, is characterized in that: described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, described liquid-state silicon colloidal sol in the mass ratio of solid content and calcium carbonate for 1: 3 ~ 10; Described calcium carbonate is the powder of more than purity more than 95%, fineness 200 order; This mixture adopts following preparation method to obtain, silicon sol is injected speed governing Scattered Kettle, add calcium carbonate while stirring, high-speed stirring is uniformly dispersed again, unformed active silica in silica aqueous solution and the calcium water generation reaction Calucium Silicate powder on calcium carbonate granule surface, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is got up by hydrated calcium silicate glue connection.
2. the body material of inorganic paint according to claim 1, is characterized in that: described liquid-state silicon colloidal sol in the mass ratio of solid content and calcium carbonate for 1: 5 ~ 8.
3. the body material of inorganic paint according to claim 1, is characterized in that: the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, and pH value is less than 11.
4. an inorganic paint, it is characterized in that: become with auxiliary material liquid combo of joining by body material described in claim 1, described auxiliary join that material is inorganic paint total mass less than 20%, auxiliary material of joining is selected from one or more combination in high molecular polymer, filler, pigment, paint additive.
5. inorganic paint according to claim 4, is characterized in that: described high molecular polymer is one of EVA redispersable latex powder, esters of acrylic acid redispersable latex powder, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin or multiple combination; Described filler is one of titanium dioxide, mica, kaolin or multiple combination; Described pigment is pigment dyestuff, mineral dye or the liquid color paste that is mixed into by multiple pigment; Described paint additive is one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas, calcium containing compound, zinc compound, water glass or multiple combination.
6. the application in rigidity water-proofing material prepared by the body material of inorganic paint described in claim 1.
7. the application in colored finish mortar prepared by the body material of inorganic paint described in claim 1.
8. the application in artificial stone material prepared by the body material of inorganic paint described in claim 1.
9. the application in art painting prepared by the body material of inorganic paint described in claim 1.
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Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114956828B (en) * | 2022-05-17 | 2023-08-15 | 合肥商德应用材料有限公司 | Silicon carbide ceramic and preparation method and application thereof |
| CN116218293B (en) * | 2023-05-05 | 2023-07-07 | 山东新广恒节能科技有限公司 | High weather-resistant exterior wall coating |
| CN116715982A (en) * | 2023-06-09 | 2023-09-08 | 江苏苏博特新材料股份有限公司 | Inorganic exterior wall building coating with high color retention and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007911A (en) * | 2006-01-27 | 2007-08-01 | 章浩龙 | Water-based paint and preparation method thereof |
| CN102408220A (en) * | 2011-08-08 | 2012-04-11 | 华南理工大学 | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof |
| CN102533028A (en) * | 2011-12-29 | 2012-07-04 | 陕西宝塔山油漆股份有限公司 | Water-based, primer-free and high-performance exterior water coating |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5296634A (en) * | 1976-02-10 | 1977-08-13 | Kikusui Kagaku Kogyo Kk | Inorganic paint composition |
| CN101560113B (en) * | 2008-04-19 | 2014-01-08 | 黄定忠 | Hard surface treatment composition and application thereof, cladding formed after hard surface treatment and hard surface material with same |
| KR101284143B1 (en) * | 2011-08-03 | 2013-07-10 | 주식회사 엘에이치 | Ceramic paint for non-sliding |
| CN102898902A (en) * | 2012-10-26 | 2013-01-30 | 合众（佛山）化工有限公司 | Method for preparing composite multifunctional moisture-adjusting antibacterial interior wall coating |
| CN103483883B (en) * | 2013-09-05 | 2016-04-13 | 鳄鱼制漆(上海)有限公司 | A kind of High-performance silica sol inorganic exterior coating |
| CN103483884B (en) * | 2013-09-25 | 2015-12-09 | 上海新安纳电子科技有限公司 | A kind of High-performance waterborne inorganic paint and preparation method thereof |
-
2013
- 2013-10-10 CN CN201310468832.1A patent/CN103497545A/en active Pending
-
2014
- 2014-01-03 CN CN201410003196.XA patent/CN103725051B/en active Active
- 2014-01-03 WO PCT/CN2014/070123 patent/WO2015051598A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007911A (en) * | 2006-01-27 | 2007-08-01 | 章浩龙 | Water-based paint and preparation method thereof |
| CN102408220A (en) * | 2011-08-08 | 2012-04-11 | 华南理工大学 | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof |
| CN102533028A (en) * | 2011-12-29 | 2012-07-04 | 陕西宝塔山油漆股份有限公司 | Water-based, primer-free and high-performance exterior water coating |
Non-Patent Citations (1)
| Title |
|---|
| "无机硅溶胶外墙涂料的研制";王律;《上海涂料》;20120930;第50卷(第9期);第8-9页 * |
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| CN103725051A (en) | 2014-04-16 |
| WO2015051598A1 (en) | 2015-04-16 |
| CN103497545A (en) | 2014-01-08 |
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