CN108587263A - A kind of graphene inorganic interior wall coating and preparation method thereof - Google Patents
A kind of graphene inorganic interior wall coating and preparation method thereof Download PDFInfo
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- CN108587263A CN108587263A CN201810457714.3A CN201810457714A CN108587263A CN 108587263 A CN108587263 A CN 108587263A CN 201810457714 A CN201810457714 A CN 201810457714A CN 108587263 A CN108587263 A CN 108587263A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Inorganic Chemistry (AREA)
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Abstract
A kind of graphene inorganic interior wall coating of present invention proposition and preparation method thereof, belong to construction material technical field of coatings, the interior wall coating can remove formaldehyde and purifying formaldehyde effect is lasting, also performance is notable in terms of adhesive force and abrasion resistance for it, free formaldehyde is not contained simultaneously, can reach effect of safer environmental protection.The graphene inorganic interior wall coating is prepared by weight by following components：30 55 parts of 10 30 parts of inorganic bond material, 0.05 1 parts of anti-Formaldehyde as Additives, 0.05 0.5 parts of multifunctional assistant, 10 40 parts of deionized water, 0.05 1 parts of fungicide, 0.05 0.5 parts of antifoaming agent, 0.05 1 parts of dispersant, 0.05 1 parts of thickener, 0.05 1 parts of auxiliary rheological agents and color stuffing.The present invention can be applied in the painting of indoor wall, coating.
Description
Technical field
The invention belongs to construction material technical field of coatings more particularly to a kind of graphene inorganic interior wall coating and its preparations
Method.
Background technology
The pollution of house decorative material and furniture is to cause the main aspect of room air pollution at present, paint, glued board,
The materials such as wood shavings filler, interior wall coating, plastic facing contain the organic compounds such as formaldehyde, benzene, ethyl alcohol, chloroform, the above substance
All there is comparable carcinogenicity.Research finds that many civilian and commercial building room air pollution degree is outdoor empty
2-5 times of gas pollution, there are about 30% rooms to cause because using harmful chemical " new home syndrome ".Therefore, how to have
Effect ground removal formaldehyde, coating become the research of novel environment friendly building materials field as a kind of construction material being in direct contact room air
Focus.
Patent application 201611162668.1 discloses a kind of graphene modified inorganic coating and preparation method thereof, improves
The wearability and conductivity of coating, but it is to be improved in the aspect of performance such as water resistance and adhesive force.Patent application
201310158609.7 disclose a kind of mica and graphene is total to modified inorganic coating and its application method, improve inorganic coating
Adhesive force and high temperature resistance, but pertain only to addition lower content mica and graphene, when improve both content
When, the performance of coating is unstable, and there are still films crisp easy to crack, poor adhesive force defect.Patent application 201710403471.0
A kind of dope for inner wall of architecture and preparation method thereof is disclosed, is had except formaldehyde, ageing-resistant performance, but purifying formaldehyde effect persistence
It is to be improved with the aspect of performance such as adhesive force.Based on current present situation, how to provide a kind of with except formaldehyde and purifying formaldehyde effect
Persistently, the interior wall coating that adhesion performance is promoted will be emphasis that this field is urgently studied.
Invention content
A kind of graphene inorganic interior wall coating of present invention proposition and preparation method thereof, which can remove formaldehyde and formaldehyde
Clean-up effect is lasting, and also performance is notable in terms of adhesive force and abrasion resistance, while not containing free formaldehyde, can reach more
The effect of safety and environmental protection.
In order to achieve the above object, the present invention provides a kind of graphene inorganic interior wall coatings, by weight by following components
Part is prepared：
10-30 parts of inorganic bond material, Formaldehyde as Additives 0.05-1 parts anti-, 0.05-0.5 parts of multifunctional assistant, deionized water 10-
40 parts, 0.05-1 parts of fungicide, 0.05-0.5 parts of antifoaming agent, 0.05-1 parts of dispersant, 0.05-1 parts of thickener, auxiliary rheological agents
0.05-1 parts and 30-55 parts of color stuffing.
Preferably, the inorganic bond material is any one of potassium silicate, lithium metasilicate and Ludox or compares according to certain
Example compounding.
Preferably, the anti-Formaldehyde as Additives is the mixture of graphene and nano-titanium dioxide, mass ratio 1:10-
10:1。
Preferably, the multifunctional assistant is multifunction amine analog assistant.
Disappear preferably, the antifoaming agent is mineral hydrocarbon antifoaming agent and/or nonionic alkyl copolymer
Infusion；The dispersant is the anionic compound of polyphosphate and polyether phosphate system；The thickener is modified organic bentonite
Moisten one or both of soil, attapulgite, hydroxyethyl cellulose, hydroxymethyl cellulose and methyl hydroxyethylcellulose.
Preferably, the auxiliary rheological agents are that association type alkali soluble is swollen and/or polyurethane-type；The color stuffing be titanium dioxide,
At least one of powdered whiting, kaolin, talcum powder, ultra-fine calcite in powder, diatomite, barium sulfate and mica powder.
The preparation side for the graphene inorganic interior wall coating that the present invention provides a kind of as described in any of the above-described technical solution
Method includes the following steps：
Each component in formula is weighed according to formula ratio, then inorganic bond material is added in paint mixing cylinder 1, is warming up to 35-45
DEG C, state is stirred until homogeneous with the speed of 300-800rpm, obtains inorganic cementitious material, it is spare；
Deionized water, multifunctional assistant, fungicide, antifoaming agent, dispersant and thickener are added in paint mixing cylinder 2 successively,
10-20min is stirred with the speed of 800-1200rpm；Color stuffing is added in paint mixing cylinder 2 again, with the speed of 1200-1500rpm
20-30min is stirred, anti-Formaldehyde as Additives is then added and stirs to abundant dissolving, measures mill base fineness≤50 μm；
Slowly the inorganic cementitious material in paint mixing cylinder 1 is added in paint mixing cylinder 2,5- is stirred with the speed of 800-1200rpm
Auxiliary rheological agents are added in 10min, and 5-10min is stirred with the speed of 800-1200rpm, measure initial viscosity, and according to initial viscous
Degree adjusts viscosity to stormer viscosity meter 90-100KU at 25 DEG C using auxiliary rheological agents, obtains graphene inorganic interior wall coating.
Compared with prior art, the advantages and positive effects of the present invention are：
Interior wall coating provided by the invention can remove formaldehyde and purifying formaldehyde effect persistence is good, due to being used in formula
Conventional use of organic adhesive material is substituted in inorganic bond material, can also effectively improve the adhesive force between coating and painting face, from
And make its also significant effect in terms of water resistance and abrasion resistance.In addition, interior wall coating provided by the invention without organic principle,
Without volatile harmful gases such as free formaldehydes, paint film is ageing-resistant, persistence is good, can reach effect of safer environmental protection.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
An embodiment of the present invention provides a kind of graphene inorganic interior wall coatings, are prepared by weight by following components：
10-30 parts of inorganic bond material, Formaldehyde as Additives 0.05-1 parts anti-, 0.05-0.5 parts of multifunctional assistant, deionized water 10-
40 parts, 0.05-1 parts of fungicide, 0.05-0.5 parts of antifoaming agent, 0.05-1 parts of dispersant, 0.05-1 parts of thickener, auxiliary rheological agents
0.05-1 parts and 30-55 parts of color stuffing.
It is substituted using inorganic bond material in graphene inorganic interior wall coating formula provided in this embodiment conventional use of
Organic adhesive material, while improving the ingredient and ratio of anti-Formaldehyde as Additives so that the formula improves first while except formaldehyde
Aldehyde clean-up effect persistence.The inorganic bond material used in formula can penetrate into bottom concrete basal plane, react life
At firm silicate layer, therefore the adhesive force between coating and painting face can be effectively improved, to make it in water resistance and resistance to
Significant effect in terms of scrubbing property.In addition, inorganic material of the interior wall coating provided by the invention due to the use of environmental protection, is free of organic conjunction
At material so that do not contain free formaldehyde, effect of safer environmental protection can be reached.It is understood that inorganic in above-mentioned formula
The parts by weight that binding material is added can also be any point in 12,14,16,18,20,22,24,26,28 parts or above range
It is worth number, the parts by weight that anti-Formaldehyde as Additives is added can also be 0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9 part
Or any point value number in above range, those skilled in the art can within the above range close according to practical condition
Reason adjustment.
In a preferred embodiment, the inorganic bond material is any one of potassium silicate, lithium metasilicate and Ludox or presses
It is compounded according to certain proportion.Inorganic bond material provided in this embodiment can according to the performances needs such as the water-fast of formulation for coating material, washability,
It can be to be used alone, can also be used in compounding.Wherein, when being used in compounding, the common mode that compounds can be selected 1:1、7:3 or 3:2
Potassium silicate：Ludox, 1:1、7:3 or 3:2 lithium metasilicate：Ludox, 2:2:1 potassium silicate：Lithium metasilicate：Ludox, etc..
In a preferred embodiment, the anti-Formaldehyde as Additives is the mixture of graphene and nano-titanium dioxide, quality
Than being 1:10-10:1.The anti-Formaldehyde as Additives provided in the present embodiment is the mixture of graphene and nano-titanium dioxide, wherein
The graphene of the high transparency of addition can be used as photocatalysis carrier, greatly improve the efficiency of light-catalyzed reaction.Meanwhile graphene
It is effective compound with Nano titanium dioxide, the dispersibility of photo-catalytic nano particle on the surface of graphene is not only improved, and
By reducing the compound of photo-generate electron-hole, the photocatalytic activity of photocatalyst is improved.At the same time, due to band structure
Adjustment, graphene will also play the effect of photosensitizer, so that the absorption region of photocatalyst is extended to visible light region, effectively increase
Photocatalyst removes aldehyde efficiency and persistence to the utilization rate of sunlight to improve.It is understood that the matter of above-mentioned two component
Amount is than that can also be 2:8、3:7、4:6、1:1、6:4、7:3、8:2 or above range in arbitrary ratio, those skilled in the art
Use can be adjusted according to actual conditions.
In a preferred embodiment, the multifunctional assistant is multifunction amine analog assistant.In a preferred embodiment, described
Antifoaming agent is mineral hydrocarbon antifoaming agent and/or nonionic alkyl copolymer antifoaming agent；The dispersant is more phosphorus
The anionic compound of hydrochlorate and polyether phosphate system；The thickener is organic modified bentonite, attapulgite, ethoxy fibre
One or both of dimension element, hydroxymethyl cellulose and methyl hydroxyethylcellulose.In a preferred embodiment, the rheology helps
Agent is that association type alkali soluble is swollen and/or polyurethane-type；The color stuffing is titanium dioxide, powdered whiting, kaolin, talcum powder, surpasses
At least one of thin calcite in powder, diatomite, barium sulfate and mica powder.
Multifunctional assistant, antifoaming agent, dispersant, thickener, auxiliary rheological agents and face mentioned in above-described embodiment are filled out
Material can be not limited to cited by above-described embodiment, can also be that those skilled in the art are rationally replaced according to actual conditions
It changes, but it is understood that, the component cited by selection above-described embodiment, which is more advantageous to be prepared, meets estimated performance
Graphene inorganic interior wall coating.
The embodiment of the present invention additionally provides a kind of preparation method of graphene inorganic interior wall coating, includes the following steps：
Each component in formula is weighed according to formula ratio, then inorganic bond material is added in paint mixing cylinder 1, is warming up to 35-45
DEG C, state is stirred until homogeneous with the speed of 300-800rpm, obtains inorganic cementitious material, it is spare；
Deionized water, multifunctional assistant, fungicide, antifoaming agent, dispersant and thickener are added in paint mixing cylinder 2 successively,
10-20min is stirred with the speed of 800-1200rpm；Color stuffing is added in paint mixing cylinder 2 again, with the speed of 1200-1500rpm
20-30min is stirred, anti-Formaldehyde as Additives is then added and stirs to abundant dissolving, measures mill base fineness≤50 μm；
Slowly the inorganic cementitious material in paint mixing cylinder 1 is added in paint mixing cylinder 2,5- is stirred with the speed of 800-1200rpm
Auxiliary rheological agents are added in 10min, and 5-10min is stirred with the speed of 800-1200rpm, measure initial viscosity, and according to initial viscous
Degree adjusts viscosity to 25 DEG C, stormer viscosity meter 90-100KU using auxiliary rheological agents, obtains graphene inorganic interior wall coating.
Graphene inorganic interior wall coating preparation method provided in this embodiment is easy to operate, and each component is added simultaneously by priority
Viscosity, which is adjusted, using auxiliary rheological agents can be obtained required graphene inorganic interior wall coating.The coating being prepared by this method
Formaldehyde can be removed and purifying formaldehyde effect persistence is good, since the adhesive force between coating and painting face effectively improves, made
Its also significant effect in terms of water resistance and abrasion resistance.In addition, interior wall coating provided in this embodiment does not contain free first
Aldehyde can reach effect of safer environmental protection.
The graphene inorganic interior wall coating and its preparation side that the embodiment of the present invention is provided are introduced in detail in order to become apparent from
Method is described below in conjunction with specific embodiment.
Embodiment 1
Graphene inorganic interior wall coating formula：Inorganic cementitious material 10, deionized water 35, multifunctional assistant 0.1, fungicide
0.1, antifoaming agent 0.2, dispersant 0.3, thickener 0.5, auxiliary rheological agents 1, anti-Formaldehyde as Additives 0.3, titanium dioxide 22.5, kaolin
15, barium sulfate 15；
Preparation method：Inorganic bond material is added in paint mixing cylinder 1,35-45 DEG C is warming up to, is stirred with the speed of 300-800rpm
It mixes to uniform state, obtains inorganic cementitious material, it is spare；
Deionized water, multifunctional assistant, fungicide, antifoaming agent, dispersant and thickener are added in paint mixing cylinder 2 successively,
10-20min is stirred with the speed of 800-1200rpm；Color stuffing is added in paint mixing cylinder 2 again, with the speed of 1200-1500rpm
20-30min is stirred, anti-Formaldehyde as Additives is then added and stirs to abundant dissolving, measures mill base fineness≤50 μm；
Slowly the inorganic cementitious material in paint mixing cylinder 1 is added in paint mixing cylinder 2,5- is stirred with the speed of 800-1200rpm
Auxiliary rheological agents are added in 10min, and 5-10min is stirred with the speed of 800-1200rpm, measure initial viscosity, and according to initial viscous
Degree adjusts viscosity to stormer viscosity meter 90-100KU at 25 DEG C using auxiliary rheological agents, obtains graphene inorganic interior wall coating.
Embodiment 2
The preparation method is the same as that of Example 1, and difference lies in graphene inorganic interior wall coating formulas to be：Inorganic cementitious material 20 is gone
Ionized water 35.2, multifunctional assistant 0.2, fungicide 0.1, antifoaming agent 0.5, dispersant 0.3, thickener 0.8, auxiliary rheological agents 0.6,
Anti- Formaldehyde as Additives 0.3, titanium dioxide 22, calcium carbonate 20.
Embodiment 3
The preparation method is the same as that of Example 1, and difference lies in graphene inorganic interior wall coating formulas to be：Inorganic cementitious material 20 is gone
Ionized water 34.5, multifunctional assistant 0.2, fungicide 0.1, antifoaming agent 0.5, dispersant 0.3, thickener 0.8, auxiliary rheological agents 0.6,
Anti- Formaldehyde as Additives 1, titanium dioxide 22, calcium carbonate 20.
Comparative example 1
The same embodiment of preparation method, difference lies in interior wall coating formulas to be：It is polymer emulsion 30, deionized water 20.7, more
Function additive 0.3, fungicide 0.2, antifoaming agent 0.2, wetting dispersing agent 0.5, thickener 0.5, auxiliary rheological agents 0.3, anti-formaldehyde help
Agent 0.3, titanium dioxide 22, calcium carbonate 25.
Performance test
The interior wall coating that there is provided embodiment 1-3 and comparative example 1 and certain commercially available brand except the effect of aldehyde paint is into detection,
Middle purifying formaldehyde rate test method executes JC/T1074-2008《Function of purifying indoor air coating material purification function》It is defined
Ι classes require to be tested, and interior wall coating performance is according to JC/T 423-91《Water-soluble interior wall coating》Defined Ι classes require to carry out
Test, free formaldehyde content is according to GB 18582-2008《Limits of harmful substances in indoor decorating and refurnishing materials interior wall coating》, inspection
Survey the results are shown in Table 1.
Interior wall coating and certain commercially available brand that 1 embodiment 1-3 of table and comparative example 1 provide remove the testing result of aldehyde paint
It can be seen that the polymer organic class interior wall coating that is provided compared to comparative example and commercially available have by 1 result of table
For machine class removes aldehyde paint, inorganic interior wall coating provided in an embodiment of the present invention shows it in terms of adhesive force and abrasion resistance
Unique superiority is free of organic synthesis material simultaneously because having used environment friendly inorganic material, and therefore, which does not contain trip yet
From formaldehyde, effect of safer environmental protection can be reached.
Claims (7)
1. a kind of graphene inorganic interior wall coating, which is characterized in that be prepared by weight by following components：
10-30 parts of inorganic bond material, Formaldehyde as Additives 0.05-1 parts anti-, 0.05-0.5 parts of multifunctional assistant, deionized water 10-40
Part, 0.05-1 parts of fungicide, 0.05-0.5 parts of antifoaming agent, 0.05-1 parts of dispersant, 0.05-1 parts of thickener, auxiliary rheological agents
0.05-1 parts and 30-55 parts of color stuffing.
2. graphene inorganic interior wall coating according to claim 1, which is characterized in that the inorganic bond material is silicic acid
Any one of potassium, lithium metasilicate and Ludox compound according to a certain percentage.
3. graphene inorganic interior wall coating according to claim 1, which is characterized in that the anti-Formaldehyde as Additives is graphene
With the mixture of nano-titanium dioxide, mass ratio 1:10-10:1.
4. graphene inorganic interior wall coating according to claim 1, which is characterized in that the multifunctional assistant is multi-functional
Amine auxiliary agent.
5. graphene inorganic interior wall coating according to claim 1, which is characterized in that the antifoaming agent is mineral hydrocarbonization
Close species antifoaming agent and/or nonionic alkyl copolymer antifoaming agent；The dispersant is polyphosphate and polyether phosphate system
Anionic compound；The thickener is organic modified bentonite, attapulgite, hydroxyethyl cellulose, hydroxymethyl cellulose
One or both of with methyl hydroxyethylcellulose.
6. graphene inorganic interior wall coating according to claim 1, which is characterized in that the auxiliary rheological agents are association type alkali
Swelling and/or polyurethane-type；The color stuffing is titanium dioxide, powdered whiting, kaolin, talcum powder, ultra-fine calcite in powder, silicon
At least one of diatomaceous earth, barium sulfate and mica powder.
7. according to the preparation method of claim 1-6 any one of them graphene inorganic interior wall coatings, which is characterized in that including
Following steps：
Each component in formula is weighed according to formula ratio, then inorganic bond material is added in paint mixing cylinder 1, is warming up to 35-45 DEG C, with
The speed of 300-800rpm is stirred until homogeneous state, obtains inorganic cementitious material, spare；
Deionized water, multifunctional assistant, fungicide, antifoaming agent, dispersant and thickener are added in paint mixing cylinder 2 successively, with
The speed of 800-1200rpm stirs 10-20min；Color stuffing is added in paint mixing cylinder 2 again, is stirred with the speed of 1200-1500rpm
20-30min is mixed, anti-Formaldehyde as Additives is then added and stirs to abundant dissolving, measures mill base fineness≤50 μm；
Slowly the inorganic cementitious material in paint mixing cylinder 1 is added in paint mixing cylinder 2,5- is stirred with the speed of 800-1200rpm
Auxiliary rheological agents are added in 10min, and 5-10min is stirred with the speed of 800-1200rpm, measure initial viscosity, and according to initial viscous
Degree adjusts viscosity to stormer viscosity meter 90-100KU at 25 DEG C using auxiliary rheological agents, obtains graphene inorganic interior wall coating.
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| CN109651857A (en) * | 2018-11-23 | 2019-04-19 | 烟台大学 | A kind of heat-resisting and anticorrosive flexible coating and preparation method thereof |
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