CN104046184B - Water-based sliver multi-color lacquer - Google Patents
Water-based sliver multi-color lacquer Download PDFInfo
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- CN104046184B CN104046184B CN201410226196.6A CN201410226196A CN104046184B CN 104046184 B CN104046184 B CN 104046184B CN 201410226196 A CN201410226196 A CN 201410226196A CN 104046184 B CN104046184 B CN 104046184B
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Abstract
The invention discloses a kind of water-based sliver multi-color lacquer, comprise the raw material of following weight part: organosilicon crylic acid latex 30-40, wetting agent 0.03-0.05, sanitas 1-3, defoamer 0.02-0.04, neopentyl glycol 1-2, carboxymethyl cellulose 0.03-0.05, pH value conditioning agent 0.03-0.05, propylene glycol 1-2, film coalescence aid 1.2-2, thickening material 0.3-0.8, polyamide wax 1.5-2.5, colorful sliver 15-20, Radix Aucklandiae oil 2-3, myo-Inositol hexaphosphate 1-2, composite nano powder 5-10.The present invention adopts organosilicon crylic acid latex and composite nano powder to cooperatively interact, can effectively improve its glossiness, weathering resistance and weather resistance, adopt colorful sliver, while providing the decorative effect identical with traditional multi-color lacquer, very convenient in production technique, reduce production cost, and the optimization of production formula, fundamentally solve floating layer, the bleeding problem of traditional aqueous colorful paint, easy construction in addition, does not need to adopt special preparation of construction.
Description
Technical field
The present invention relates to a kind of water-based sliver multi-color lacquer, belong to building coating technical field.
Background technology
Aqueous colorful paint is the decorative effect of a kind of energy reduction marble true to nature, grouan, and because quality is light, being specially adapted to the interior/exterior decoration of all kinds of buildings, is the economical alternative of high-grade stone.But aqueous colorful paint in the market adopts water-water pattern substantially, and there is complex manufacturing, the storage time is short, the problem of construction inconvenience.
Summary of the invention
The present invention seeks to the defect existed to solve prior art, providing one to be convenient to produce, storing, the water-based sliver multi-color lacquer of construction.
In order to achieve the above object, the present invention adopts following technical scheme:
A kind of water-based sliver multi-color lacquer, comprises the raw material of following weight part: organosilicon crylic acid latex 30-40, wetting agent 0.03-0.05, sanitas 1-3, defoamer 0.02-0.04, neopentyl glycol 1-2, carboxymethyl cellulose 0.03-0.05, pH value conditioning agent 0.03-0.05, propylene glycol 1-2, film coalescence aid 1.2-2, thickening material 0.3-0.8, polyamide wax 1.5-2.5, colorful sliver 15-20, Radix Aucklandiae oil 2-3, myo-Inositol hexaphosphate 1-2, composite nano powder 5-10;
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 5-10:4-8:3-6, mixes, and 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieve; (2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add the diallyl dimethyl ammoniumchloride of sodium polystyrene sulfonate, the trolamine of 3-5%, the citric acid of 1.5-2.5%, the tripoly phosphate sodium STPP of 2-3% and the 3-6% being equivalent to suspension weight 4-8% again, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries; (3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2-3 times amount, add the nano zinc powder of tetraethoxy, the vinyltriethoxysilane of 5-10%, the polyvinylpyrrolidone of 3-6%, the tannic acid of 2-4% and the 1-3% being equivalent to mixed solution weight 15-20%, ultrasonic disperse 20-30min, then by acetic acid or ammoniacal liquor adjust ph to 4-5, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries; (4) by step (3) dry after powder dispersion in 2-3 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 80-90 DEG C is warming up under nitrogen protection; add the methyl methacrylate, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1% that are equivalent to mixed solution weight 10-15%; stir 1-2h; filter; washing, dries.
Described wetting agent is that Changfeng Chemical Plant, Shanghai produces, and model is TX-10.
Described sanitas is that Changfeng Chemical Plant, Shanghai produces, and model is CFX-3.
Described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028.
Described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-105.
Described pH value conditioning agent is selected from the one in 2-amino-2-methyl-1-propanol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
Described film coalescence aid is selected from the one in ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester.
The present invention has the following advantages compared to existing technology: the present invention adopts organosilicon crylic acid latex and composite nano powder to cooperatively interact, can effectively improve its glossiness, weathering resistance and weather resistance, adopt colorful sliver, while providing the decorative effect identical with traditional multi-color lacquer, very convenient in production technique, reduce production cost, and the optimization of production formula, fundamentally solve floating layer, the bleeding problem of traditional aqueous colorful paint, easy construction in addition, does not need to adopt special preparation of construction.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Water-based sliver multi-color lacquer is configured by the raw material of following weight part and forms: organosilicon crylic acid latex 30, wetting agent 0.03, sanitas 1, defoamer 0.02, neopentyl glycol 1, carboxymethyl cellulose 0.03, pH value conditioning agent 0.03-0.05, propylene glycol 1, film coalescence aid 1.2, thickening material 0.3, polyamide wax 1.5, colorful sliver 15, Radix Aucklandiae oil 2, myo-Inositol hexaphosphate 1, composite nano powder 5.
The preparation method of composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 8:6:4, mixes, and 860 DEG C of calcining 1.5h, are cooled to room temperature, are ground into nano-powder, sieve; (2) powder after sieving adds water and makes the suspension that concentration is 45%, add again be equivalent to suspension weight 6% sodium polystyrene sulfonate, 4% trolamine, the citric acid of 2%, the tripoly phosphate sodium STPP of 2.5% and 4% diallyl dimethyl ammoniumchloride, 4000rpm speed lapping 0.5h, filter, washing, dries; (3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2 times amount, add be equivalent to mixed solution weight 15% tetraethoxy, 10% vinyltriethoxysilane, the polyvinylpyrrolidone of 5%, the tannic acid of 3% and 2% nano zinc powder, ultrasonic disperse 25min, then by acetic acid or ammoniacal liquor adjust ph to 4.5, be heated to 75 DEG C, stir 2h, filter, washing, dries; (4) by step (3) dry after powder dispersion in 3 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 90 DEG C are warming up under nitrogen protection; add be equivalent to mixed solution weight 15% methyl methacrylate, 10% vinylformic acid, the vinylbenzene of 10%, maleic anhydride, the Vinylstyrene of 4%, the benzoyl peroxide of 0.5% of 6%; stir 2h; filter; washing, dries.
Embodiment 2
Water-based sliver multi-color lacquer is configured by the raw material of following weight part and forms: organosilicon crylic acid latex 35, wetting agent 0.04, sanitas 2, defoamer 0.03, neopentyl glycol 1.5, carboxymethyl cellulose 0.04, pH value conditioning agent 0.04, propylene glycol 1.5, film coalescence aid 1.8, thickening material 0.5, polyamide wax 2, colorful sliver 16, Radix Aucklandiae oil 2.5, myo-Inositol hexaphosphate 1.5, composite nano powder 8.
The preparation method of composite nano powder is with embodiment 1.
Embodiment 3
Water-based sliver multi-color lacquer is configured by the raw material of following weight part and forms: organosilicon crylic acid latex 40, wetting agent 0.05, sanitas 3, defoamer 0.04, neopentyl glycol 2, carboxymethyl cellulose 0.05, pH value conditioning agent 0.05, propylene glycol 2, film coalescence aid 2, thickening material 0.8, polyamide wax 2.5, colorful sliver 20, Radix Aucklandiae oil 3, myo-Inositol hexaphosphate 2, composite nano powder 10.
The preparation method of composite nano powder is with embodiment 1.
The water-based sliver multi-color lacquer that above-described embodiment prepares meets industry service requirements, and production technique is simple, and stability in storage is good, easy construction.The performance test results is as shown in the table:
Claims (7)
1. a water-based sliver multi-color lacquer, it is characterized in that, comprise the raw material of following weight part: organosilicon crylic acid latex 30-40, wetting agent 0.03-0.05, sanitas 1-3, defoamer 0.02-0.04, neopentyl glycol 1-2, carboxymethyl cellulose 0.03-0.05, pH value regulator 0.03-0.05, propylene glycol 1-2, film coalescence aid 1.2-2, thickening material 0.3-0.8, polyamide wax 1.5-2.5, colorful sliver 15-20, Radix Aucklandiae oil 2-3, myo-Inositol hexaphosphate 1-2, composite nano powder 5-10;
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 5-10:4-8:3-6, mixes, and 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieve; (2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add the diallyl dimethyl ammoniumchloride of sodium polystyrene sulfonate, the trolamine of 3-5%, the citric acid of 1.5-2.5%, the tripoly phosphate sodium STPP of 2-3% and the 3-6% being equivalent to suspension weight 4-8% again, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries; (3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2-3 times amount, add the nano zinc powder of tetraethoxy, the vinyltriethoxysilane of 5-10%, the polyvinylpyrrolidone of 3-6%, the tannic acid of 2-4% and the 1-3% being equivalent to mixed solution weight 15-20%, ultrasonic disperse 20-30min, then by acetic acid or ammoniacal liquor adjust ph to 4-5, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries; (4) by step (3) dry after powder dispersion in 2-3 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 80-90 DEG C is warming up under nitrogen protection; add the methyl methacrylate, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1% that are equivalent to mixed solution weight 10-15%; stir 1-2h; filter; washing, dries.
2. water-based sliver multi-color lacquer according to claim 1, is characterized in that, described wetting agent is that Changfeng Chemical Plant, Shanghai produces, and model is TX-10.
3. water-based sliver multi-color lacquer according to claim 1, is characterized in that, described sanitas is that Changfeng Chemical Plant, Shanghai produces, and model is CFX-3.
4. water-based sliver multi-color lacquer according to claim 1, is characterized in that, described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028.
5. water-based sliver multi-color lacquer according to claim 1, is characterized in that, described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-105.
6. water-based sliver multi-color lacquer according to claim 1, it is characterized in that, described pH value regulator is selected from the one in 2-amino-2-methyl-1-propanol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
7. water-based sliver multi-color lacquer according to claim 1, it is characterized in that, described film coalescence aid is selected from the one in ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410226196.6A CN104046184B (en) | 2014-05-23 | 2014-05-23 | Water-based sliver multi-color lacquer |
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| CN201410226196.6A CN104046184B (en) | 2014-05-23 | 2014-05-23 | Water-based sliver multi-color lacquer |
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| CN104046184B true CN104046184B (en) | 2016-04-13 |
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| CN104974619A (en) * | 2015-08-03 | 2015-10-14 | 苏州舒而适纺织新材料科技有限公司 | Methyl cellulose multicolor paint |
| CN105111873A (en) * | 2015-10-09 | 2015-12-02 | 张家口家诚首佳新型建材有限公司 | Method for improving storage time of faux marble paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649142A (en) * | 2009-05-14 | 2010-02-17 | 鳄鱼制漆(上海)有限公司 | Colourful interior wall decorative coating, manufacturing method and construction technology thereof |
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5635799B2 (en) * | 2010-04-16 | 2014-12-03 | 関西ペイント株式会社 | Emulsion resin paint |
| JP2012045520A (en) * | 2010-08-30 | 2012-03-08 | Fujikura Kasei Co Ltd | Method of forming designable coating film, coating material for forming the designable coating film, and roller surface treatment liquid |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649142A (en) * | 2009-05-14 | 2010-02-17 | 鳄鱼制漆(上海)有限公司 | Colourful interior wall decorative coating, manufacturing method and construction technology thereof |
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
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Effective date of registration: 20180720 Address after: 523000 Industrial Park, tea mountain, Dongguan, Guangdong Province, 2B District Patentee after: Ou Lisheng donautex (Dongguan) Co. Ltd. Address before: 241100 Sunshine Avenue, Wuhu County Economic Development Zone, Wuhu, Anhui Patentee before: Wuhu Lang Run novel material company limited |