CN104449167A - Alkaline-resistant anti-cracking paint for exterior wall - Google Patents

Alkaline-resistant anti-cracking paint for exterior wall Download PDF

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Publication number
CN104449167A
CN104449167A CN201410714473.8A CN201410714473A CN104449167A CN 104449167 A CN104449167 A CN 104449167A CN 201410714473 A CN201410714473 A CN 201410714473A CN 104449167 A CN104449167 A CN 104449167A
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parts
exterior wall
alkali resistant
wall paint
water
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CN201410714473.8A
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CN104449167B (en
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胡信友
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Guangdong Qiaoben new material development Co., Ltd
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QBON CHEMICAL INDUSTRY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an alkaline-resistant anti-cracking paint for an exterior wall. The paint is prepared from the following raw materials in parts by weight: 30-36 parts of a modified composite emulsion, 0.2-0.5 part of modified linen fibers, 0.5-0.7 part of hydroxyethyl cellulose, 1.5-2 parts of 2, 2, 4-trimethyl-1, 3 pentanediol monoisobutyrate, 1.5-2 parts of propylene glycol, 0.15-0.25 part of 2-amino-2-methyl-1-propanol, 40-60 parts of pigments and filler, 0.4-0.6 part of a defoamer, 0.3-0.8 part of a mildew preventive, 0.2-0.3 part of a preservative and 10-12 parts of water. According to the alkaline-resistant anti-cracking paint for the exterior wall disclosed by the invention, the modified linen fibers and the modified composite emulsion are added, so that the film has anti-cracking and alkaline-resistant effects simultaneously.

Description

A kind of alkali resistant anticracking exterior wall paint
Technical field
The invention belongs to paint field, be specifically related to a kind of alkali resistant anticracking exterior wall paint.
Background technology
Up to now, the building external paint ubiquity accumulation of salt in the surface soil, ftracture, come off, the easy problem such as variable color, have a strong impact on the decorations effect of exterior wall and the waste of resource.Exterior coating should possess two basic functions: one is defencive function; Two is decoration functions, therefore need after a house brushes exterior coating not the accumulation of salt in the surface soil, do not ftracture, protect look, waterproof, anti-powdering, anti-carbonization, antipollution, do not come off, goodlooking, up to the present, most of exterior wall paint product can not reach this requirement.
The exterior coating accumulation of salt in the surface soil, cracking major part are relevant with the cement and lime of plaster layer with wall body structure, because the intensity of cement and lime is high, alkalescence is very large, after exposing to the sun and rain, there is expanding with heat and contract with cold phenomenon in body of wall, makes surface of wall chap, result also in exterior coating be full of cracks, thus the saline and alkaline part in cement is along with having oozed out surface in crack, destroys the surface effect of paint film, have impact on paint film property.At present, there is alkali resistant, anticracking both at home and abroad and have the functional materials of certain degree of hardness to be all single-material or simple function, be difficult to meet and require alkali resistant, anticracking and have the performance requriements of certain degree of hardness simultaneously.Therefore, selecting a kind of special filmogen emulsion and defend and split fibre, is the key solving prior art deficiency.
Summary of the invention
The object of this invention is to provide a kind of alkali resistant anticracking exterior wall paint, add modification flax fiber and modification composite emulsion, make paint film have anticracking and alkali resistant effect simultaneously.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of alkali resistant anticracking exterior wall paint, mixed by the raw material stirring of following parts by weight and make, wherein each component is: modification composite emulsion 30-36 part, modification flax fiber 0.2-0.5 part, Natvosol 0.5-0.7 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate 1.5-2 part, propylene glycol 1.5-2 part, 2-amino-2-methyl-1-propanol 0.15-0.25 part, color stuffing 40-60 part, defoamer 0.4-0.6 part, mould inhibitor 0.3-0.8 part, sanitas 0.2-0.3 part, water 10-12 part.
Preferably, mixed by the raw material of following parts by weight: modification composite emulsion 32 parts, modification flax fiber 0.25 part, Natvosol 0.65 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate 2 parts, propylene glycol 2 parts, 2-amino-2-methyl-1-propanol 0.15 part, color stuffing 50 parts, defoamer 0.5 part, mould inhibitor 0.3 part, sanitas 0.25 part, 11.9 parts, water.
Preferably, described modification flax fiber is made through following steps: in mixing machine, add water and flax, bleach, then add siccative, obtains after stirring, oven dry, pulverizing, classification.
Preferably, described modification composite emulsion is made up of the raw material of following parts by weight: pure-acrylic emulsion 55-60 part, organosilicon crylic acid latex 28-33 part, hydrophober 1-4 part, emulsifying agent 1-3 part, water 2-6 part, other auxiliary agents 1-2 part.
Preferably, described modification composite emulsion is made up of the raw material of following parts by weight: pure-acrylic emulsion 58 parts, organosilicon crylic acid latex 31 parts, hydrophober 3 parts, emulsifying agent 2 parts, 5 parts, water, other auxiliary agents 1 part.
Preferably, described modification composite emulsion is made through following steps: in interlayer stirring tank, add water and pure-acrylic emulsion successively, then adds hydrophober while stirring successively, organosilicon crylic acid latex, emulsifying agent, other auxiliary agents form.Other auxiliary agents described can be one or more in defoamer, mould inhibitor, sanitas.
Preferably, solid content >=52% of described modification composite emulsion.
Therefore, inventive point of the present invention is in exterior wall paint, add modification flax fiber and modification composite emulsion, to realize making paint film have anticracking and alkali resistant effect simultaneously; Improve the proportioning of color stuffing in exterior wall paint simultaneously, add weather resisteant and the sticking power of obtained exterior wall paint.
Defend and split fibre in alkali resistant anticracking water-based exterior wall paint is the various key propertys being related to paint film, and also has vital effect to water-fast.External wall paint, must ensure the performances such as paint film has high weather resisteant, the not accumulation of salt in the surface soil, do not ftracture, water-tolerant, product just can be made to have good cost performance.According to high weather resisteant, the not accumulation of salt in the surface soil, do not ftracture and the requirement of water-tolerant, test hydroxy ethyl fiber, Methyl cellulose, wood fibre, glass fibre, result is as shown in table 1 below.
The performance test of the several frequently seen fiber of table 1
As can be seen from the above table, all there is package stability difference in above several defend and split fibre, and paint film is the defect such as cracking resistance not, larger on the impact of alkali resistant, anticracking water-based exterior wall paint function and product over-all properties.For this reason, according to the producing principle of wood fibre, glass fibre, the present invention proposes the method being improved fibre property by modification flax fiber.Described modification flax fiber is made through following steps: in mixing machine, add water and flax, bleach, then add siccative, obtains after stirring, oven dry, pulverizing, classification.The flax fiber color and luster obtained thus is partially white, not yellowing, and fiber is shorter, is conducive to the resistance to cleavage improving paint film.
According to the testing method of fiber, test described modification flax fiber, result is as follows.
The performance test of table 2 modification flax fiber
This shows, modification flax fiber of the present invention has high-strength anti crack performance, for solution alkali resistant, anticracking water-based exterior wall paint have had feasibility in the selection of defend and split fibre.
Filmogen emulsion is related to the various key propertys of paint film, plays an important role equally to alkali resistant, anticracking, water resistance.According to weather resisteant, the not accumulation of salt in the surface soil, do not ftracture and the requirement of water-tolerant, test common phenylpropyl alcohol, pure third, silicon third, nanoemulsions, result is as shown in table 3.
The performance test of the several frequently seen emulsion of table 3
As can be seen from upper table 3, the defects such as above several emulsion all exists package stability difference, and film performance is not good, affect larger on alkali resistant, anticracking water-miscible paint product over-all properties.For this reason, according to the polymerization principle of emulsion, modification compound is carried out to pure-acrylic emulsion in the basis of current commercially available emulsion, improve the performance of emulsion.By adding self-crossing emulsion in pure-acrylic emulsion, improve sticking power and the hardness of paint film, hydrophober plays the effect of anti-soil, thus realizes the effect of alkali resistant.
Below the performance index of modification composite emulsion of the present invention:
Outward appearance: white band blue light emulsion;
600C gloss: 95%;
Solid content: >=52%;
PH value: 8 ~ 9;
Film-forming properties: excellent;
Freeze-thaw stability: 3 circulations are never degenerated;
Thermostability: never degenerate.
According to the testing method of emulsion, test described modification composite emulsion, result is as follows.
The performance test of table 4 modification composite emulsion
This shows, the modification success of composite emulsion of the present invention, solves the problem of stability of emulsion difference.
The proportioning of color stuffing is exterior wall paint weathering, the key point that paint film is solid.The external wall paint weather resisteant of ratio of color stuffing plays an important role, and the ratio of color stuffing is appropriate, and weather resisteant, the sticking power of exterior wall paint are better.According to above formula, color stuffing not etc. is not carried out testing (seeing the following form 5) with 40%-60% respectively, and brush and contrast on test board, conclusion is: color stuffing dosage is few, affects opacifying power and workability; Color stuffing is added, and paint film weather resisteant, sticking power, water tolerance and application property can be caused poor.
The performance test of table 5 color stuffing
Therefore, it is the most desirable when color stuffing dosage is 50%.
In sum, the invention has the beneficial effects as follows: alkali resistant anticracking exterior wall paint of the present invention, adds modification flax fiber as defend and split fibre, makes paint film have high strength anti crack performance; Also add modification composite emulsion, the technical indicator of paint film is reached: scrubbing resistance number of times >=10000 time, alkali resistance 7 days is without exception, and water tolerance 7 days is without exception, folding strength >=4MPa, cohesive strength >=1.2MPa, anti-permeability strength >=1.5MPa; By selecting the ratio of best color stuffing, guarantee the weather resisteant of exterior wall paint, sticking power, therefore paint film is solid, hardness good, do not ftracture, and makes saline and alkaline part of the cement sand-lime of buildings main body can not ooze out surface by pore crack, thus reaches alkali resistant and effect of anti-cracking.
Embodiment
Below in conjunction with specific embodiment, set forth the present invention further.
Embodiment 1
A kind of alkali resistant anticracking exterior wall paint, be made up of the raw material mixing and stirring of following parts by weight, each component is respectively: modification composite emulsion 32 parts, modification flax fiber 0.25 part, Natvosol 0.65 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrates (Texanol) 2 parts, propylene glycol 2 parts, 2-amino-2-methyl-1-propanol (AMP-95) 0.15 part, color stuffing 50 parts, defoamer (BYK-033) 0.5 part, mould inhibitor 0.3 part, sanitas 0.25 part, 11.9 parts, water.
Wherein, described modification composite emulsion is made through following steps: in interlayer stirring tank, add 5 parts, water and pure-acrylic emulsion 58 parts successively, then add hydrophober 3 parts, organosilicon crylic acid latex 31 parts, emulsifying agent 2 parts, defoamer 1 part while stirring successively, stir.
Embodiment 2
A kind of alkali resistant anticracking exterior wall paint, is mixed by the raw material of following parts by weight: modification composite emulsion 30 parts, modification flax fiber 0.2 part, Natvosol 0.5 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate (Texanol) 1.5 parts, propylene glycol 1.5 parts, 2-amino-2-methyl-1-propanol (AMP-95) 0.15 part, color stuffing 40 parts, defoamer (BYK-033) 0.4 part, mould inhibitor 0.3 part, sanitas 0.2 part, 10 parts, water.
Wherein, described modification composite emulsion is made through following steps: in interlayer stirring tank, add 2 parts, water and pure-acrylic emulsion 55 parts successively, then add hydrophober 1 part, organosilicon crylic acid latex 28 parts, emulsifying agent 1 part, sanitas 1 part while stirring successively, stir.
Embodiment 3
A kind of alkali resistant anticracking exterior wall paint, is mixed by the raw material of following parts by weight: modification composite emulsion 36 parts, modification flax fiber 0.5 part, Natvosol 0.7 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate (Texanol) 2 parts, propylene glycol 2 parts, 2-amino-2-methyl-1-propanol (AMP-95) 0.25 part, color stuffing 60 parts, defoamer (BYK-033) 0.6 part, mould inhibitor 0.8 part, sanitas 0.3 part, 12 parts, water.
Wherein, described modification composite emulsion is made through following steps: in interlayer stirring tank, add 6 parts, water and pure-acrylic emulsion 60 parts successively, then add hydrophober 4 parts, organosilicon crylic acid latex 33 parts, emulsifying agent 3 parts, mould inhibitor 2 parts while stirring successively, stir.
Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.After the content of having read the present invention's instruction, those skilled in the art can do various conversion or amendment with any same or similar means to the present invention, and these equivalent form of values fall within protection scope of the present invention equally.

Claims (8)

1. an alkali resistant anticracking exterior wall paint, is characterized in that being mixed by the raw material of following parts by weight: modification composite emulsion 30-36 part, modification flax fiber 0.2-0.5 part, Natvosol 0.5-0.7 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate 1.5-2 part, propylene glycol 1.5-2 part, 2-amino-2-methyl-1-propanol 0.15-0.25 part, color stuffing 40-60 part, defoamer 0.4-0.6 part, mould inhibitor 0.3-0.8 part, sanitas 0.2-0.3 part, water 10-12 part.
2. alkali resistant anticracking exterior wall paint according to claim 1, is characterized in that being mixed by the raw material of following parts by weight: modification composite emulsion 32 parts, modification flax fiber 0.25 part, Natvosol 0.65 part, 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate 2 parts, propylene glycol 2 parts, 2-amino-2-methyl-1-propanol 0.15 part, color stuffing 50 parts, defoamer 0.5 part, mould inhibitor 0.3 part, sanitas 0.25 part, 11.9 parts, water.
3. alkali resistant anticracking exterior wall paint according to claim 1 and 2, is characterized in that described modification flax fiber is made through following steps: in mixing machine, add water and flax, bleach, then add siccative, obtains after stirring, oven dry, pulverizing, classification.
4. alkali resistant anticracking exterior wall paint according to claim 1 and 2, is characterized in that described modification composite emulsion is made up of the raw material of following parts by weight: pure-acrylic emulsion 55-60 part, organosilicon crylic acid latex 28-33 part, hydrophober 1-4 part, emulsifying agent 1-3 part, water 2-6 part, other auxiliary agents 1-2 part.
5. alkali resistant anticracking exterior wall paint according to claim 4, is characterized in that described modification composite emulsion is made up of the raw material of following parts by weight: pure-acrylic emulsion 58 parts, organosilicon crylic acid latex 31 parts, hydrophober 3 parts, emulsifying agent 2 parts, 5 parts, water, other auxiliary agents 1 part.
6. alkali resistant anticracking exterior wall paint according to claim 4, it is characterized in that described modification composite emulsion is made through following steps: in interlayer stirring tank, add water and pure-acrylic emulsion successively, then add hydrophober while stirring successively, organosilicon crylic acid latex, emulsifying agent, other auxiliary agents form.
7. alkali resistant anticracking exterior wall paint according to claim 6, is characterized in that solid content >=52% of described modification composite emulsion.
8. alkali resistant anticracking exterior wall paint according to claim 4, other auxiliary agents described in it is characterized in that are one or more in defoamer, mould inhibitor, sanitas.
CN201410714473.8A 2014-11-28 2014-11-28 Alkaline-resistant anti-cracking paint for exterior wall Active CN104449167B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295680A (en) * 2015-11-20 2016-02-03 天津美士邦涂料化工有限公司 Water-based alkali resistant paint
CN107987642A (en) * 2017-12-29 2018-05-04 重庆蓝兔塑胶制品有限公司 A kind of wall paint
CN108059907A (en) * 2017-12-26 2018-05-22 天长市金陵电子有限责任公司 A kind of LED lamp radiator surface coating
CN108485433A (en) * 2018-03-28 2018-09-04 中山市泰莱涂料化工有限公司 The exterior wall paint of construction and the mould proof alkali resistant cracking resistance of waterproof directly on cement basal plane

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CN1978555A (en) * 2005-12-09 2007-06-13 杨生凤 Exposed wall elastic anti-crack putty
CN103232778A (en) * 2013-04-22 2013-08-07 广西启利新材料科技股份有限公司 Anti-crack building paint and preparation method thereof
CN103351695A (en) * 2013-06-25 2013-10-16 天长市开林化工有限公司 Anti-cracking exterior wall putty

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JPS55118977A (en) * 1979-03-05 1980-09-12 Shikoku Chem Corp Wall surface finishing material with waterproof property
US5840806A (en) * 1995-05-09 1998-11-24 Dainippon Ink And Chemicals, Inc. Curable resin compositions
CN1978555A (en) * 2005-12-09 2007-06-13 杨生凤 Exposed wall elastic anti-crack putty
CN103232778A (en) * 2013-04-22 2013-08-07 广西启利新材料科技股份有限公司 Anti-crack building paint and preparation method thereof
CN103351695A (en) * 2013-06-25 2013-10-16 天长市开林化工有限公司 Anti-cracking exterior wall putty

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Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105295680A (en) * 2015-11-20 2016-02-03 天津美士邦涂料化工有限公司 Water-based alkali resistant paint
CN108059907A (en) * 2017-12-26 2018-05-22 天长市金陵电子有限责任公司 A kind of LED lamp radiator surface coating
CN107987642A (en) * 2017-12-29 2018-05-04 重庆蓝兔塑胶制品有限公司 A kind of wall paint
CN108485433A (en) * 2018-03-28 2018-09-04 中山市泰莱涂料化工有限公司 The exterior wall paint of construction and the mould proof alkali resistant cracking resistance of waterproof directly on cement basal plane

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Address after: 529095, Jiangmen District, Guangdong City, Pengjiang Province town of Lotus Village Industrial Zone

Patentee after: Guangdong Qiaoben new material development Co., Ltd

Address before: 529095, Jiangmen District, Guangdong City, Pengjiang Province town of Lotus Village Industrial Zone

Patentee before: QBON CHEMICAL INDUSTRY Co.,Ltd.