CN104073047B - A kind of exterior wall putty - Google Patents
A kind of exterior wall putty Download PDFInfo
- Publication number
- CN104073047B CN104073047B CN201410346935.5A CN201410346935A CN104073047B CN 104073047 B CN104073047 B CN 104073047B CN 201410346935 A CN201410346935 A CN 201410346935A CN 104073047 B CN104073047 B CN 104073047B
- Authority
- CN
- China
- Prior art keywords
- parts
- exterior wall
- wall putty
- powder
- mullite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 claims abstract description 37
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 36
- -1 polyethylene Polymers 0.000 claims abstract description 32
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011449 brick Substances 0.000 claims abstract description 21
- 239000004568 cement Substances 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 21
- 239000004927 clay Substances 0.000 claims abstract description 20
- 229910052570 clay Inorganic materials 0.000 claims abstract description 20
- 239000010451 perlite Substances 0.000 claims abstract description 20
- 235000019362 perlite Nutrition 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000004743 Polypropylene Substances 0.000 claims abstract description 13
- 229920001155 polypropylene Polymers 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000591 gum Polymers 0.000 claims abstract description 9
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 9
- 239000001923 methylcellulose Substances 0.000 claims abstract description 9
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N Bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 8
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 claims abstract description 8
- 229920001353 Dextrin Polymers 0.000 claims abstract description 8
- 239000004698 Polyethylene (PE) Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000004815 dispersion polymerization Substances 0.000 claims abstract description 7
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 230000004048 modification Effects 0.000 claims abstract description 7
- 238000006011 modification reaction Methods 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 239000011863 silicon-based powder Substances 0.000 claims abstract description 7
- 239000000725 suspension Substances 0.000 claims abstract description 7
- 239000004699 Ultra-high molecular weight polyethylene (UHMWPE) Substances 0.000 claims abstract description 6
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 claims abstract description 6
- 239000004567 concrete Substances 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 6
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- 229920001897 terpolymer Polymers 0.000 claims abstract description 6
- FYGDTMLNYKFZSV-CSHPIKHBSA-N β-cellotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-CSHPIKHBSA-N 0.000 claims abstract description 6
- 239000003063 flame retardant Substances 0.000 claims description 18
- 238000004513 sizing Methods 0.000 claims description 17
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 239000004254 Ammonium phosphate Substances 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- JFCQEDHGNNZCLN-UHFFFAOYSA-N Glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 5
- MGIYRDNGCNKGJU-UHFFFAOYSA-N Isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 5
- 229920000388 Polyphosphate Polymers 0.000 claims description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N Triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 5
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 5
- GTTSNKDQDACYLV-UHFFFAOYSA-N butane-1,1,1-triol Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 claims description 5
- OSGAYBCDTDRGGQ-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca+2].OS(O)(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-N 0.000 claims description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 239000001205 polyphosphate Substances 0.000 claims description 5
- 235000011176 polyphosphates Nutrition 0.000 claims description 5
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 235000014692 zinc oxide Nutrition 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000002390 adhesive tape Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229920000126 Latex Polymers 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229910001760 lithium mineral Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- KREXGRSOTUKPLX-UHFFFAOYSA-N octadecanoic acid;zinc Chemical compound [Zn].CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O KREXGRSOTUKPLX-UHFFFAOYSA-N 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Abstract
The invention belongs to building material field, relate to a kind of exterior wall putty.The alumina sol that it comprises polymer powder 10-15 part by weight, lightweight clay brick 30-50 part, perlite 10-15 part, high-alumina cement 6-9 part, mullite 12-18 part, wilkinite 10-15 part, szaibelyite 2-4 part, dextrine powder 1-3 part, methylcellulose gum 3-5 part, silicon powder 5-8 part, flaxen fiber or viscose fiber 5-10 part, water glass 8-18 part, polymer dispersion powder 4-6 part, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 10-15 part; Polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 15-25 part molecular weight toward 30-60 part molecular weight is by weight add aluminium dihydrogen phosphate 4-9 part, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na? 0.5-4 part, terpolymer EP rubber EPDM? 3-4 part, aluminate coupling agent 6-8 part and phosphorous acid ester 2-3 part, mediate 40-50min in Banbury mixer at 110-120 DEG C.The present invention has excellent tack and fillibility, can prevent body of wall variable color from coming off.
Description
Technical field
The invention belongs to building material field, relate to a kind of exterior wall putty.
Background technology
Current exterior wall putty has varied, is mainly used in cement wall surface, mixed earth metope, and intensity is not etc.When exterior wall putty carries out renewal and reform to some ceramic tile metopes, mosaic wall surface, there is the defects such as sticking power is not strong, water tolerance is poor in putty; Also there is fire-protection rating low simultaneously, for external wall structure dependency, large and aesthetics is restricted, and realizing fp while, cannot focus on other important indicators such as insulation, waterproof, intensity, rate of moisture absorption, more cannot take into account that working life is long, resource consumption is few, environmental pollution is light, the problems such as lightweight.
CN101544856B(2012-9-26) disclose a kind of exterior wall putty, but its tack, fillibility, waterproof, intensity, rate of moisture absorption, prevent the performances such as body of wall variable color comes off from still having much room for improvement.
Summary of the invention
The object of this invention is to provide a kind of exterior wall putty, there is excellent tack, fillibility, waterproof, intensity, rate of moisture absorption, prevent body of wall variable color to come off performance.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of exterior wall putty, the alumina sol that it comprises polymer powder 10-15 part by weight, lightweight clay brick 30-50 part, perlite 10-15 part, high-alumina cement 6-9 part, mullite 12-18 part, wilkinite 10-15 part, szaibelyite 2-4 part, dextrine powder 1-3 part, methylcellulose gum 3-5 part, silicon powder 5-8 part, flaxen fiber or viscose fiber 5-10 part, water glass 8-18 part, polymer dispersion powder 4-6 part, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 10-15 part;
Described polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 15-25 part molecular weight toward 30-60 part molecular weight is by weight add aluminium dihydrogen phosphate 4-9 part, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na0.5-4 part, terpolymer EP rubber EPDM3-4 part, aluminate coupling agent 6-8 part and phosphorous acid ester 2-3 part, mediate 40-50min in Banbury mixer at 110-120 DEG C.
The polymer powder that the present invention combines by specific proportioning and lightweight clay brick, perlite, high-alumina cement and composite suspension liquid do filmogen, adopt water glass, wilkinite, szaibelyite and dextrine powder make dispersion agent and properties-correcting agent, filmogen and dispersion agent and properties-correcting agent is made to form hydrophobic systems and slight crosslinking reaction occurs, mullite, methylcellulose gum, flaxen fiber or viscose fiber further increase again sticking power function and the intensity of putty, especially the polyethylene of particular modification and polypropylene miser can increase the fillibility of putty, waterproof and intensity, prevent body of wall variable color from coming off.
As preferably, described exterior wall putty also comprises isothiazolinone 3-6 part, wax emulsion 0.5-2 part, Zinic stearas 2-4 part.
The isothiazolinone of proportioning of the present invention, wax emulsion and Zinic stearas can increase tack and the fillibility of putty further.
As preferably, described exterior wall putty also comprises J-5 terra alba 1-3 part, poly carboxylic acid amine salt 5-8 part.
Terra alba of the present invention and poly carboxylic acid amine salt can increase the water-repellancy of putty, intensity and rate of moisture absorption further.
As preferably, described exterior wall putty also comprises sizing material 4-7 part, and described sizing material is made up of the raw material of following parts by weight:
Phthalic anhydride 25-35 part, triethylene glycol 10-12 part, pentanedioic acid 15-18 part, trihydroxybutane 8-10 part, zinc white 5-7 part, magnesium oxide 3-5 part, chloroprene rubber 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, methylcarbonate 15-20 part, ethylbenzene 20-30 part, fire retardant 1-3 part.
Sizing material of the present invention, while the imparting larger sticking power of putty and intensity, can prevent body of wall variable color from coming off, and increases body of wall fire-protection rating.
As preferably, described fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 ~ 50 parts, 10 ~ 25 parts, ammonium phosphate, ammonium pyrophosphate 6 ~ 12 parts, 5 ~ 20 parts, ammonium sulfate, boric acid 5 ~ 10 parts, 10 ~ 25 parts, water.
The flame retardant properties of fire retardant of the present invention is good, and fire-protection rating is high, Environmental Safety.
As preferably, the alumina content in described lightweight clay brick is 35%-45%.
As preferably, the dioxide-containing silica in described perlite is 55-65%.
As preferably, the alumina content in described high-alumina cement is 40-50%.
As preferably, described mullite is M45 mullite.
As preferably, the granularity of described lightweight clay brick, perlite, high-alumina cement and/or M45 mullite is 0.4-0.8mm.
The lightweight clay brick of granularity of the present invention, perlite, high-alumina cement and/or M45 mullite can ensure sticking power and the intensity of putty, if granularity is too little, then intensity is difficult to meet the demands; If granularity is too large, then sticking power is inadequate; Adopt the lightweight clay brick of 0.4-0.8mm, perlite, high-alumina cement and/or M45 mullite that the sticking power of putty and intensity can be made to reach best of breed.
In sum, the present invention has following beneficial effect:
1. exterior wall putty of the present invention has excellent tack, fillibility, waterproof, intensity, rate of moisture absorption, prevents body of wall variable color to come off performance;
2. exterior wall putty of the present invention is suitable for mosaic, ceramic tile, marble, grouan, the surface of wall of brick, energy filling cracks aperture, product has strong adhesion after doing something in disregard of obstacles, water tolerance and resistance to abrasion good, top layer is smooth, anticracking, good crashworthiness feature, putty of the present invention after testing, in cohesive strength, standard state is issued to 1.0MPa, after freeze-thaw cycle 5 times, the cohesive strength of putty reaches 1.23MPa, cohesive strength under the state that is above standard, embody the performance that there is good weathering resistance Yu overcome external stress, external wall reconstruction renovation can be widely used in, use for coating provides soft and smooth bottom surface base material.
Embodiment
Exterior wall putty formula one: comprise polymer powder 10 by weight, alumina sol that part, lightweight clay brick 30, part, perlite 10, part, high-alumina cement 6, part, mullite 12, part, wilkinite 10, part, szaibelyite 2, part, dextrine powder 1, part, methylcellulose gum 3, part, silicon powder 5 parts, viscose fiber 5 parts, water glass 8 parts, polymer dispersion powder 4 parts, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 15 parts; Isothiazolinone 6 parts, wax emulsion 2 parts, Zinic stearas 4 parts; Sizing material 7 parts.
Wherein, the alumina content in lightweight clay brick is 35%;
Dioxide-containing silica in perlite is 55%;
Alumina content in high-alumina cement is 40%;
Mullite is M45 mullite;
The granularity of lightweight clay brick, perlite, high-alumina cement and/or M45 mullite is 0.4mm.
Exterior wall putty formula two: comprise polymer powder 15 parts by weight, alumina sol that lightweight clay brick 50 parts, perlite 15 parts, high-alumina cement 9 parts, mullite 18 parts, wilkinite 15 parts, szaibelyite 4 parts, dextrine powder 3 parts, methylcellulose gum 5 parts, silicon powder 8 parts, 10 parts, flaxen fiber, water glass 18 parts, polymer dispersion powder 6 parts, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 10 parts; J-5 terra alba 1 part, 5 parts, poly carboxylic acid amine salt; Sizing material 4 parts.
Wherein, the alumina content in lightweight clay brick is 45%;
Dioxide-containing silica in perlite is 65%;
Alumina content in high-alumina cement is 50%;
Mullite is M45 mullite;
The granularity of lightweight clay brick, perlite, high-alumina cement and/or M45 mullite is 0.8mm.
Exterior wall putty formula three: comprise polymer powder 12 parts by weight, alumina sol that lightweight clay brick 38 parts, perlite 12 parts, high-alumina cement 7 parts, mullite 15 parts, wilkinite 13 parts, szaibelyite 3 parts, dextrine powder 2 parts, methylcellulose gum 4 parts, silicon powder 7 parts, 8 parts, flaxen fiber, water glass 12 parts, polymer dispersion powder 5 parts, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 12 parts; Isothiazolinone 5 parts, wax emulsion 1.5 parts, Zinic stearas 3 parts; J-5 terra alba 2 parts, 7 parts, poly carboxylic acid amine salt; Sizing material 6 parts.
Wherein, the alumina content in lightweight clay brick is 40%;
Dioxide-containing silica in perlite is 60%;
Alumina content in high-alumina cement is 45%;
Mullite is M45 mullite;
The granularity of lightweight clay brick, perlite, high-alumina cement and/or M45 mullite is 0.5mm.
Embodiment one
Exterior wall putty is filled a prescription by formula one, and wherein polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 15 parts of molecular weight toward 30 parts of molecular weight is by weight add aluminium dihydrogen phosphate 4 parts, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na0.5 part, terpolymer EP rubber EPDM3 part, aluminate coupling agent 6 parts and phosphorous acid ester 3 parts, mediate 40min in Banbury mixer at 110 DEG C.
Sizing compound formula is:
Phthalic anhydride 25 parts, triethylene glycol 10 parts, pentanedioic acid 15 parts, trihydroxybutane 8 parts, zinc white 5 parts, 3 parts, magnesium oxide, chloroprene rubber 15 parts, elastic plastic 70 parts, softening oil 2 parts, methylcarbonate 15 parts, 30 parts, ethylbenzene, fire retardant 3 parts.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 50 parts, 25 parts, ammonium phosphate, ammonium pyrophosphate 12 parts, 20 parts, ammonium sulfate, boric acid 10 parts, 10 parts, water.
Embodiment two
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment one, are filled a prescription by formula two unlike exterior wall putty.
Embodiment three
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment one, are filled a prescription by formula three unlike exterior wall putty.
Embodiment four
Fill a prescription by formula one according to exterior wall putty, wherein polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 25 parts of molecular weight toward 60 parts of molecular weight is by weight add aluminium dihydrogen phosphate 9 parts, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na4 part, terpolymer EP rubber EPDM4 part, aluminate coupling agent 8 parts and phosphorous acid ester 2 parts, mediate 50min in Banbury mixer at 120 DEG C.
Sizing compound formula is:
Phthalic anhydride 35 parts, triethylene glycol 12 parts, pentanedioic acid 18 parts, trihydroxybutane 10 parts, zinc white 7 parts, 5 parts, magnesium oxide, chloroprene rubber 25 parts, elastic plastic 95 parts, softening oil 3 parts, methylcarbonate 20 parts, 20 parts, ethylbenzene, fire retardant 1 part.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 parts, 10 parts, ammonium phosphate, ammonium pyrophosphate 6 parts, 5 parts, ammonium sulfate, boric acid 5 parts, 25 parts, water.
Embodiment five
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment four, are filled a prescription by formula two unlike exterior wall putty.
Embodiment six
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment four, are filled a prescription by formula three unlike exterior wall putty.
Embodiment seven
Fill a prescription by formula one according to exterior wall putty, wherein polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 20 parts of molecular weight toward 50 parts of molecular weight is by weight add aluminium dihydrogen phosphate 5 parts, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na3 part, terpolymer EP rubber EPDM3.5 part, aluminate coupling agent 7 parts and phosphorous acid ester 2.5 parts, mediate 45min in Banbury mixer at 115 DEG C.
Sizing compound formula is:
Phthalic anhydride 28 parts, triethylene glycol 11 parts, pentanedioic acid 16 parts, trihydroxybutane 9 parts, zinc white 6 parts, 4 parts, magnesium oxide, chloroprene rubber 19 parts, elastic plastic 85 parts, softening oil 2.5 parts, methylcarbonate 18 parts, 25 parts, ethylbenzene, fire retardant 2 parts.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 30 parts, 15 parts, ammonium phosphate, ammonium pyrophosphate 9 parts, 15 parts, ammonium sulfate, boric acid 8 parts, 18 parts, water.
Embodiment eight
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment seven, are filled a prescription by formula two unlike exterior wall putty.
Embodiment nine
Polymer powder proportioning composition, sizing compound formula and flame retardant formulations, with embodiment seven, are filled a prescription by formula three unlike exterior wall putty.
Comparative example one
With embodiment one, unlike wherein not including polymer powder and water glass.
Comparative example two
With embodiment four, comprise polymer powder 15 parts, lightweight clay brick 20 parts, perlite 5 parts, high-alumina cement 15 parts, mullite 8 parts, wilkinite 8 parts, szaibelyite 1 part, dextrine powder 4 parts, methylcellulose gum 2 parts, silicon powder 9 parts, flaxen fiber or viscose fiber 2 parts, water glass 6 parts, polymer dispersion powder 8 parts by weight unlike exterior wall putty.
Comparative example three
0.3 kilogram, mixture, 40 kilograms, coarse whiting 200 order, 35 kilograms, talcum powder 400 order of soft water 13 kilograms, dry gram of methylcellulose gum 0.3, lithium minerals thickening material 0.2 kilogram, 0.5 kilogram, poly carboxylic acid amine salt, silicon third latex 15 kilograms, wax emulsion 0.5 kilogram, 2-amido-2-methyl isophthalic acid-propyl alcohol 0.2 kilogram, ethylene glycol 1 kilogram, 12 carbon ester alcohol 0.7 kilogram, Zinc Stearate 5 kilograms, organosilicon and mineral oil.
Putty sticking power is tested, and first uses sharp cutter (knife edge angle is 15 °-30 °) to draw 10 × 10 1mm × 1mm small grid in exterior wall sample surface, and each line should deeply and the bottom of putty; Clean down with the fragment of hairbrush by test zone; Use adhesive power 350g/cm
2-400g/m
2adhesive tape (3M600 gummed paper or equivalent) firmly withered live tested small grid; and to exert oneself wiping adhesive tape with eraser; to strengthen contact area and the dynamics in adhesive tape and tested region; adhesive tape one end is caught with hand; (90 °) shut down gummed paper rapidly in the vertical direction, and same position carries out 2 identical test;
Sticking power test grade classification:
5B-comes off without exterior wall,
The 4B-exterior wall total area that comes off is less than 5%;
3B-exterior wall comes off the total area between 5%-15%;
2B-exterior wall comes off the total area between 15%-35%;
1B-exterior wall comes off the total area between 35%-65%,
The 0B-exterior wall total area that comes off is greater than 65%.
Be qualified during requirement sticking power >=4B.
The product performance of table 1 embodiment and comparative example compare
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this specification sheets, as long as but be all subject to the protection of patent law in right of the present invention.
Claims (8)
1. an exterior wall putty, is characterized in that: comprise polymer powder 10-15 part by weight, alumina sol that lightweight clay brick 30-50 part, perlite 10-15 part, high-alumina cement 6-9 part, mullite 12-18 part, wilkinite 10-15 part, szaibelyite 2-4 part, dextrine powder 1-3 part, methylcellulose gum 3-5 part, silicon powder 5-8 part, flaxen fiber or viscose fiber 5-10 part, water glass 8-18 part, polymer dispersion powder 4-6 part, in mass ratio 1:1 are combined into and silicon dioxide gel composite suspension liquid 10-15 part;
Described polymer powder is modified polyethylene and polypropylene miser; Concrete modification is be the ultrahigh molecular weight polyethylene(UHMWPE) of 400-700 ten thousand and 15-25 part molecular weight toward 30-60 part molecular weight is by weight add aluminium dihydrogen phosphate 4-9 part, C in the base-material of the high density poly propylene composition of 100-140 ten thousand
12h
25sO
3na0.5-4 part, terpolymer EP rubber EPDM3-4 part, aluminate coupling agent 6-8 part and phosphorous acid ester 2-3 part, mediate 40-50min in Banbury mixer at 110-120 DEG C;
Described mullite is M45 mullite;
The granularity of described lightweight clay brick, perlite, high-alumina cement and M45 mullite is 0.4-0.8mm.
2. a kind of exterior wall putty according to claim 1, is characterized in that: described exterior wall putty also comprises isothiazolinone 3-6 part, wax emulsion 0.5-2 part, Zinic stearas 2-4 part.
3. a kind of exterior wall putty according to claim 1, is characterized in that: described exterior wall putty also comprises J-5 terra alba 1-3 part, poly carboxylic acid amine salt 5-8 part.
4. a kind of exterior wall putty according to claim 1, is characterized in that: described exterior wall putty also comprises sizing material 4-7 part, and described sizing material is made up of the raw material of following parts by weight:
Phthalic anhydride 25-35 part, triethylene glycol 10-12 part, pentanedioic acid 15-18 part, trihydroxybutane 8-10 part, zinc white 5-7 part, magnesium oxide 3-5 part, chloroprene rubber 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, methylcarbonate 15-20 part, ethylbenzene 20-30 part, fire retardant 1-3 part.
5. a kind of exterior wall putty according to claim 4, is characterized in that: described fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 ~ 50 parts, 10 ~ 25 parts, ammonium phosphate, ammonium pyrophosphate 6 ~ 12 parts, 5 ~ 20 parts, ammonium sulfate, boric acid 5 ~ 10 parts, 10 ~ 25 parts, water.
6. a kind of exterior wall putty according to any one of claim 1-5, is characterized in that: the alumina content in described lightweight clay brick is 35%-45%.
7. a kind of exterior wall putty according to any one of claim 1-5, is characterized in that: the dioxide-containing silica in described perlite is 55-65%.
8. a kind of exterior wall putty according to any one of claim 1-5, is characterized in that: the alumina content in described high-alumina cement is 40-50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410346935.5A CN104073047B (en) | 2014-07-21 | 2014-07-21 | A kind of exterior wall putty |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410346935.5A CN104073047B (en) | 2014-07-21 | 2014-07-21 | A kind of exterior wall putty |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104073047A CN104073047A (en) | 2014-10-01 |
| CN104073047B true CN104073047B (en) | 2016-04-27 |
Family
ID=51594666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410346935.5A Active CN104073047B (en) | 2014-07-21 | 2014-07-21 | A kind of exterior wall putty |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104073047B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293278B (en) * | 2014-10-16 | 2016-05-04 | 安徽省阜阳沪千人造板制造有限公司 | A kind of sheet material is produced with being easy to curing adhesive |
| CN104312247A (en) * | 2014-11-05 | 2015-01-28 | 湖州三利漆业有限公司 | Putty combination |
| CN104860630A (en) * | 2015-04-29 | 2015-08-26 | 肖先波 | Environmental protection paint for building exterior wall |
| CN105731982A (en) * | 2016-03-10 | 2016-07-06 | 吕凤荣 | Non-toxic anti-crack putty and method for preparing same |
| CN105566985A (en) * | 2016-03-10 | 2016-05-11 | 吕凤荣 | Environment-friendly waterproof putty and preparation method |
| CN105731955A (en) * | 2016-03-10 | 2016-07-06 | 吕凤荣 | Building putty and preparation method thereof |
| CN105778588A (en) * | 2016-05-16 | 2016-07-20 | 李军 | External-wall waterproof coating material for building and preparation method thereof |
| CN106188727A (en) * | 2016-07-12 | 2016-12-07 | 张海棠 | A kind of environmental protection waterproof material and preparation method thereof |
| CN107778951A (en) * | 2017-11-16 | 2018-03-09 | 桂林市晟博科技服务有限公司 | A kind of putty powder for exterior wall and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0461901A2 (en) * | 1990-06-15 | 1991-12-18 | Amcol International Corporation | Bentonite composition structurally supported with flexible material and method |
| CN103497559A (en) * | 2013-08-29 | 2014-01-08 | 王传福 | Weather resistant exterior wall putty powder |
| CN103497562A (en) * | 2013-08-29 | 2014-01-08 | 王传福 | Putty powder for exterior wall true stone paint |
| CN103642294A (en) * | 2013-11-15 | 2014-03-19 | 张春贵 | Putty paint |
| CN103740156A (en) * | 2014-01-26 | 2014-04-23 | 中建四局第五建筑工程有限公司云南分公司 | Novel low-cost easily constructed putty as well as preparation method and construction process thereof |
-
2014
- 2014-07-21 CN CN201410346935.5A patent/CN104073047B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0461901A2 (en) * | 1990-06-15 | 1991-12-18 | Amcol International Corporation | Bentonite composition structurally supported with flexible material and method |
| CN103497559A (en) * | 2013-08-29 | 2014-01-08 | 王传福 | Weather resistant exterior wall putty powder |
| CN103497562A (en) * | 2013-08-29 | 2014-01-08 | 王传福 | Putty powder for exterior wall true stone paint |
| CN103642294A (en) * | 2013-11-15 | 2014-03-19 | 张春贵 | Putty paint |
| CN103740156A (en) * | 2014-01-26 | 2014-04-23 | 中建四局第五建筑工程有限公司云南分公司 | Novel low-cost easily constructed putty as well as preparation method and construction process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104073047A (en) | 2014-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104073047B (en) | A kind of exterior wall putty | |
| CN104073107B (en) | A kind of texture paint | |
| CN104649610B (en) | A kind of ceramic tile bond and application thereof | |
| CN104327658A (en) | Textured coating | |
| CN105152603A (en) | Polymer cement water-resistant paint suitable for different molding surfaces | |
| CN103482934B (en) | A kind of cement-base waterproof coating | |
| CN104446271A (en) | Efforescence resistant colored wall finishing mortar | |
| CN102807345A (en) | Nano modified Portland cement base facing mortar and preparation method thereof | |
| CN104108917A (en) | Low-alkalinity tile glue | |
| CN104478288A (en) | Adhesive reinforcing agent for building inorganic coating material and preparation method of adhesive reinforcing agent | |
| CN104762007A (en) | Energy-saving texture thermal insulation coating used for building external wall | |
| CN103232778A (en) | Anti-crack building paint and preparation method thereof | |
| CN103601453B (en) | Multifunctional concentrated material used for preparing kitchen and bath cement-based waterproof material | |
| CN105315728B (en) | A kind of inorganic water-proof aging resistant coating and preparation method thereof | |
| JP4304201B2 (en) | Interior thin finish coating material having humidity control, manufacturing method thereof, interior thin finish wall material having humidity control and construction method thereof | |
| CN101974261A (en) | Neutral water-resistance putty paste and preparation method thereof | |
| CN103242014A (en) | Polyphenylene granular thermal-insulation mortar | |
| CN103803844A (en) | Cracking resistance reinforcing agent of inorganic coating material for building and a preparation method of cracking resistance reinforcing agent | |
| AU2014246682A1 (en) | Adhesive Compound | |
| CN103833415A (en) | Impervious reinforcing agent for constructional inorganic coating material and preparation method thereof | |
| CN106190003A (en) | A kind of jointing agent | |
| CN110204932A (en) | A kind of aqueous silicate compound heat-insulation anti-flaming dope and preparation method thereof | |
| CN104446235A (en) | Colorful environment-friendly alkali-efforescence-resistant wall facing mortar | |
| CN104072086A (en) | Dry powder decoration mortar free of cement | |
| CN105174802A (en) | Building top layer joint mixture additive and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180824 Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 313000 Zhejiang Huzhou Wuxing District Huan Zhu street shaaojia Dun village ONKYO Huzhou Sanli paint industry Co., Ltd. Patentee before: HUZHOU SANLI PAINT INDUSTRY CO., LTD. |
|
| TR01 | Transfer of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20160427 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20160427 |
|
| PD01 | Discharge of preservation of patent |