CN106497185A - A kind of mould proof metope dry powder paint of conch meal - Google Patents
A kind of mould proof metope dry powder paint of conch meal Download PDFInfo
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- CN106497185A CN106497185A CN201611030991.3A CN201611030991A CN106497185A CN 106497185 A CN106497185 A CN 106497185A CN 201611030991 A CN201611030991 A CN 201611030991A CN 106497185 A CN106497185 A CN 106497185A
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- parts
- conch meal
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- dry powder
- powder paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of mould proof metope dry powder paint of conch meal, in parts by weight, including：100～150 parts of methylpropanoic acid ester methyl ester, 120～200 parts of acrylic resin, 20～50 parts of nano-material modified conch meal, 20～50 parts of Calcium Carbonate, 16～24 parts of montmorillonite powder, 13～22 parts of butyl acetate, 4～8 parts of ethylene glycol, 5～8 parts of defoamer；The nano-material modified conch meal is made up of the nano aluminium oxide of 5%～10% percentage by weight and the conch meal of surplus.Modification of the coating that the present invention is provided by various ingredients and material, with ultralow VOC content, minimum to environment and people and animals' harm；Hardness is excellent not to sink and with good anti-mildew function, with good application potential and extensive industrial production value.
Description
Technical field
A kind of the present invention relates to technical field of coatings, more particularly to the mould proof metope dry powder paint of conch meal.
Background technology
Wall paint is the final coating of application, is a layer finally smeared in construction wall finishing, is presented after finishing
Whole structure is embodied by this layer.Therefore there is higher requirement to material therefor, will not only have good colourity
And brightness, more require that there is good anti-pollution, ageing-resistant, moistureproof, fungicidal properties, and free from environmental pollution, safety non-toxic, nothing
The features such as fire hazard, easy construction, fast dried coating film, good guarantor's light guarantor's color, good permeability, while decoration and protection work(will be had
Energy, such as color, gloss, texture etc., also need the repellence in the face of adverse circumstances.
In each field, the application of coating is ubiquitous, such as external wall, industrial warehouse, food service industry class storage
Tank or pipeline inside, also commonly used such dry powder paint on Factory Building and modernization plant etc. building.But with when
Between elapse, add the changeable of weather, dry powder paint occurs the mouldy situation that comes off in use for some time, and traditional dry powder is applied
Material is organic solvent, and the most contaminative of such dry powder paint is serious, and subsequently everybody is widely used dry powder paint, but for dry powder
For coating, anti-mold effect is not strong, and the defect that composition occurs in constituting cannot tackle the changeable of weather, easily make when causing to use
Into going mouldy, cause damage to commercial production.
Accordingly it is desirable to metope dry powder paint further can be improved in application and performance, especially in hardness, wear-resisting
Property, the aspect that prevents from going mouldy improves to some extent.
Content of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of conch meal mould proof metope dry powder paint, tool
There is preferable fungicidal properties.
The invention provides a kind of mould proof metope dry powder paint of conch meal, in parts by weight, including：
100～150 parts of methylpropanoic acid ester methyl ester, 120～200 parts of acrylic resin, nano-material modified conch meal 20
～50 parts, 20～50 parts of Calcium Carbonate, 16～24 parts of montmorillonite powder, 13～22 parts of butyl acetate, 4～8 parts of ethylene glycol, froth breaking
5～8 parts of agent；
The shell of nano aluminium oxide and surplus of the nano-material modified conch meal by 5%～10% percentage by weight
Powder is constituted.
Preferably, the nano-material modified conch meal is prepared by the following method：
Shell is calcined, is crushed, grinding obtains conch meal, then being mixed with nano aluminium oxide, obtain nano-material modified
Conch meal.
Preferably, the temperature of the calcining is 750 DEG C～850 DEG C, and calcination time is 60～80 minutes.
Preferably, the shell is oyster shell.
Preferably, 200～300 mesh sieves crossed by the conch meal, then mix with nano aluminium oxide.
Preferably, the defoamer is polysiloxane-polyether copolymer.
Preferably, the hardness of the mould proof metope dry powder paint of the conch meal is more than or equal to 2H.
Preferably, nano aluminium oxide, 5%～10% weight percent of the conch meal by 5%～10% percentage by weight
The conch meal composition of the nano titanium oxide of ratio and surplus.
Compared with prior art, the invention provides a kind of mould proof metope dry powder paint of conch meal, in parts by weight, wraps
Include：100～150 parts of methylpropanoic acid ester methyl ester, 120～200 parts of acrylic resin, nano-material modified conch meal 20～50
Part, 20～50 parts of Calcium Carbonate, 16～24 parts of montmorillonite powder, 13～22 parts of butyl acetate, 4～8 parts of ethylene glycol, defoamer 5
～8 parts；The conch meal of nano aluminium oxide and surplus of the nano-material modified conch meal by 5%～10% percentage by weight
Composition.Modification of the coating that the present invention is provided by various ingredients and material, with ultralow VOC content, to environment and people and animals
Harm is minimum；Hardness is excellent not to sink and with good anti-mildew function, with good application potential and extensive work
Industry productive value.
Specific embodiment
The invention provides a kind of mould proof metope dry powder paint of conch meal, in parts by weight, including：
100～150 parts of methylpropanoic acid ester methyl ester, 120～200 parts of acrylic resin, nano-material modified conch meal 20
～50 parts, 20～50 parts of Calcium Carbonate, 16～24 parts of montmorillonite powder, 13～22 parts of butyl acetate, 4～8 parts of ethylene glycol, froth breaking
5～8 parts of agent；
The shell of nano aluminium oxide and surplus of the nano-material modified conch meal by 5%～10% percentage by weight
Powder is constituted.
Modification of the coating that the present invention is provided by various ingredients and material, with ultralow VOC content, to environment and people
Poultry harm is minimum；Hardness is excellent not to sink and with good anti-mildew function, with good application potential and widely
Industrial production value.
The mould proof metope dry powder paint of conch meal that the present invention is provided, component include：
100～150 parts of methylpropanoic acid ester methyl ester, its content are preferably 120～130 parts.
120～200 parts of acrylic resin, its content are preferably 140～180 parts.
20～50 parts of nano-material modified conch meal, its content are preferably 30～40 parts.
20～50 parts of Calcium Carbonate, its content are preferably 30～40 parts.
16～24 parts of montmorillonite powder, its content are preferably 18～22 parts.
13～22 parts of butyl acetate, its content are preferably 15～20 parts；
4～8 parts of ethylene glycol, its content are preferably 5～7 parts.
5～8 parts of defoamer, its content are preferably 6～7 parts.The present invention has no special limit to the concrete species of the defoamer
Fixed, can be defoamer well known to those skilled in the art, preferably polysiloxane-polyether copolymer.
The nano-material modified conch meal is preferably by nano aluminium oxide and the surplus of 5%～10% percentage by weight
Conch meal is constituted.
It is preferred that the nano-material modified conch meal is prepared by the following method：
Shell is calcined, is crushed, grinding obtains conch meal, then being mixed with nano aluminium oxide, obtain nano-material modified
Conch meal.
The temperature of the calcining is preferably 750 DEG C～850 DEG C, and calcination time is preferably 60～80 minutes.
The shell is preferably oyster shell.
Preferably, 200～300 mesh sieves crossed by the conch meal, then mix with nano aluminium oxide.
Specifically, the oyster shell that cleans is calcined 60～80 minutes at 750～850 DEG C, is then naturally cooling to room
Temperature, by calcining after shell crush, grinding, cross 200～300 mesh sieves, obtain conch meal, be then respectively adding nano aluminium oxide,
Mix homogeneously.
In addition, in preferred embodiment of the invention, the nano-material modified conch meal is preferably by 5%～10% weight
The conch meal composition of the nano aluminium oxide of percentage ratio, the nano titanium oxide of 5%～10% percentage by weight and surplus.
It is preferred that the nano-material modified conch meal is prepared by the following method：
Shell is calcined, is crushed, grinding obtains conch meal, then being mixed with nano aluminium oxide, nano titanium oxide, obtain
Nano-material modified conch meal.
The temperature of the calcining is preferably 750 DEG C～850 DEG C, and calcination time is preferably 60～80 minutes.
The shell is preferably oyster shell.
Preferably, 200～300 mesh sieves crossed by the conch meal, then mix with nano aluminium oxide and nano titanium oxide.
Specifically, the oyster shell that cleans is calcined 60～80 minutes at 750～850 DEG C, is then naturally cooling to room
Temperature, by calcining after shell crush, grinding, cross 200～300 mesh sieves, obtain conch meal, be then respectively adding nano aluminium oxide and
Nano titanium oxide, mix homogeneously.
The hardness of the mould proof metope dry powder paint of conch meal prepared by the present invention is more than or equal to 2H.And with ultralow
VOC content, and with good anti-mildew function, with good application potential and extensive industrial production value.
In order to further illustrate the present invention, the mould proof metope dry powder of the conch meal for providing of the invention is applied with reference to embodiment
Material is described in detail.
Embodiment 1
Water-based inner wall priming paint dry powder paint is prepared, wherein, percentage, including：
100 parts of methylpropanoic acid ester methyl ester, 120 parts of acrylic resin, 20 parts of nano modification conch meal, 20 parts of Calcium Carbonate, day
Right 16 parts of montmorillonite powder, 13 parts of butyl acetate, 4 parts of ethylene glycol, 6 parts of defoamer, defoamer are polysiloxane-polyether copolymerization
Thing.
Nano-material modified conch meal is made up of the nano aluminium oxide of 8% percentage by weight and the conch meal of surplus.
Sprayed in gypsum board surface with the above-mentioned dry powder paint for preparing, dry 10 minutes in 160 DEG C of baking ovens, obtain thickness
For 35 μm of film.
With reference to JC/T 2083-2011 standards, JC/T2177-2013 and GB 18582-2008《Indoor decorating and refurnishing materials
Limits of harmful substances in interior wall coating》, film performance is detected, 1 is the results are shown in Table, table 1 be the embodiment of the present invention 1～4 with
And 1 film performance test data of comparative example.
Embodiment 2
Water-based inner wall priming paint dry powder paint is prepared, wherein, percentage, including：
150 parts of methylpropanoic acid ester methyl ester, 200 parts of acrylic resin, 50 parts of nano modification conch meal, 50 parts of Calcium Carbonate, day
Right 24 parts of montmorillonite powder, 22 parts of butyl acetate, 8 parts of ethylene glycol, 8 parts of defoamer, defoamer are polysiloxane-polyether copolymerization
Thing.
Nano-material modified conch meal is made up of the nano aluminium oxide of 10% percentage by weight and the conch meal of surplus.
Sprayed in gypsum board surface with the above-mentioned dry powder paint for preparing, dry 10 minutes in 160 DEG C of baking ovens, obtain thickness
For 35 μm of film.
With reference to JC/T 2083-2011 standards, JC/T2177-2013 and GB 18582-2008《Indoor decorating and refurnishing materials
Limits of harmful substances in interior wall coating》, film performance is detected, 1 is the results are shown in Table, table 1 be the embodiment of the present invention 1～4 with
And 1 film performance test data of comparative example.
Embodiment 3
Water-based inner wall priming paint dry powder paint is prepared, wherein, percentage, including：
120 parts of methylpropanoic acid ester methyl ester, 180 parts of acrylic resin, 30 parts of nano modification conch meal, 30 parts of Calcium Carbonate, day
Right 18 parts of montmorillonite powder, 15 parts of butyl acetate, 7 parts of ethylene glycol, 6 parts of defoamer, defoamer are polysiloxane-polyether copolymerization
Thing.
Nano-material modified conch meal is made up of the nano aluminium oxide of 8% percentage by weight and the conch meal of surplus.
Sprayed in gypsum board surface with the above-mentioned dry powder paint for preparing, dry 10 minutes in 160 DEG C of baking ovens, obtain thickness
For 35 μm of film.
With reference to JC/T 2083-2011 standards, JC/T2177-2013 and GB 18582-2008《Indoor decorating and refurnishing materials
Limits of harmful substances in interior wall coating》, film performance is detected, 1 is the results are shown in Table, table 1 be the embodiment of the present invention 1～4 with
And 1 film performance test data of comparative example.
Embodiment 4
Water-based inner wall bottom paint latex is prepared, wherein, percentage, including：
100 parts of methylpropanoic acid ester methyl ester, 120 parts of acrylic resin, 20 parts of nano modification conch meal, 20 parts of Calcium Carbonate, day
Right 16 parts of montmorillonite powder, 13 parts of butyl acetate, 4 parts of ethylene glycol, 6 parts of defoamer, defoamer are polysiloxane-polyether copolymerization
Thing.
Nano-material modified conch meal by the nano aluminium oxide of 8% percentage by weight, 10% nano titanium oxide with
And the conch meal composition of surplus.
Sprayed in gypsum board surface with the above-mentioned dry powder paint for preparing, dry 10 minutes in 160 DEG C of baking ovens, obtain thickness
For 35 μm of film.
With reference to JC/T 2083-2011 standards, JC/T2177-2013 and GB 18582-2008《Indoor decorating and refurnishing materials
Limits of harmful substances in interior wall coating》, film performance is detected, 1 is the results are shown in Table, table 1 be the embodiment of the present invention 1～4 with
And 1 film performance test data of comparative example.
Comparative example 1
Water-based inner wall priming paint dry powder paint is prepared, wherein, percentage, including：
100 parts of methylpropanoic acid ester methyl ester, 120 parts of acrylic resin, 20 parts of Pulvis Talci, 20 parts of Calcium Carbonate, natural smectite
16 parts of powder, 13 parts of butyl acetate, 4 parts of ethylene glycol, 6 parts of defoamer, defoamer is polysiloxane-polyether copolymer.
Sprayed in gypsum board surface with the above-mentioned dry powder paint for preparing, dry 10 minutes in 160 DEG C of baking ovens, obtain thickness
For 35 μm of film.
With reference to JC/T 2083-2011 standards, JC/T2177-2013 and GB 18582-2008《Indoor decorating and refurnishing materials
Limits of harmful substances in interior wall coating》, film performance is detected, 1 is the results are shown in Table, table 1 be the embodiment of the present invention 1～4 with
And 1 film performance test data of comparative example.
1 film performance test data of 1 embodiment of the present invention 1～4 of table and comparative example
Fungicidal properties is detected：Film immersion obtained by embodiment 1～4 and comparative example 1 is contained colibacillary culture
In liquid, growing state of the observation escherichia coli in film coated surface, wherein after culture 36h, occurs on 1 surface of comparative example daily
, there are the escherichia coli of a small amount of attachment on 1 surface of embodiment after cultivating 48h in the escherichia coli of a large amount of attachments, culture 54h it
Occur the escherichia coli of a small amount of attachment afterwards on 2 surface of embodiment, after cultivating 48h, a small amount of attachment occur on 3 surface of embodiment
, there are the escherichia coli of a small amount of attachment on 4 surface of embodiment after cultivating 48h, illustrate prepared by embodiment 1～4 in escherichia coli
Film has the ability of higher micro-organism growth.
Coating of the present invention be can be seen that from testing result above while having higher hardness and relatively low
VOC content, and good water resistance and washability.The especially addition of Titanium Dioxide so that wash-resistant property is obtained
Significant raising.
The explanation of above example is only intended to help and understands the method for the present invention and its core concept.It should be pointed out that right
For those skilled in the art, under the premise without departing from the principles of the invention, the present invention can also be carried out
Some improvement and modification, these improvement and modification are also fallen in the protection domain of the claims in the present invention.
Claims (8)
1. the mould proof metope dry powder paint of a kind of conch meal, it is characterised in that in parts by weight, including：
100～150 parts of methylpropanoic acid ester methyl ester, 120～200 parts of acrylic resin, nano-material modified conch meal 20～50
Part, 20～50 parts of Calcium Carbonate, 16～24 parts of montmorillonite powder, 13～22 parts of butyl acetate, 4～8 parts of ethylene glycol, defoamer 5
～8 parts；
The conch meal group of nano aluminium oxide and surplus of the nano-material modified conch meal by 5%～10% percentage by weight
Into.
2. the mould proof metope dry powder paint of conch meal according to claim 1, it is characterised in that described nano-material modified
Conch meal is prepared by the following method：
Shell is calcined, is crushed, grinding obtains conch meal, then being mixed with nano aluminium oxide, obtain nano-material modified shellfish
Shell powder.
3. the mould proof metope dry powder paint of conch meal according to claim 2, it is characterised in that the temperature of the calcining is
750 DEG C～850 DEG C, calcination time is 60～80 minutes.
4. the mould proof metope dry powder paint of conch meal according to claim 2, it is characterised in that the shell is Concha Ostreae shellfish
Shell.
5. the mould proof metope dry powder paint of conch meal according to claim 2, it is characterised in that the conch meal crosses 200～
300 mesh sieves, are then mixed with nano aluminium oxide.
6. the mould proof metope dry powder paint of conch meal according to claim 1, it is characterised in that the defoamer is poly- silica
Alkane-copolyether.
7. the mould proof metope dry powder paint of conch meal according to claim 1, it is characterised in that the mould proof metope of the conch meal
The hardness of dry powder paint is more than or equal to 2H.
8. the mould proof metope dry powder paint of conch meal according to claim 1, it is characterised in that the conch meal by 5%～
The conch meal of the nano aluminium oxide of 10% percentage by weight, the nano titanium oxide of 5%～10% percentage by weight and surplus
Composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611030991.3A CN106497185A (en) | 2016-11-22 | 2016-11-22 | A kind of mould proof metope dry powder paint of conch meal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611030991.3A CN106497185A (en) | 2016-11-22 | 2016-11-22 | A kind of mould proof metope dry powder paint of conch meal |
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| CN106497185A true CN106497185A (en) | 2017-03-15 |
Family
ID=58328293
Family Applications (1)
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|---|---|---|---|
| CN201611030991.3A Pending CN106497185A (en) | 2016-11-22 | 2016-11-22 | A kind of mould proof metope dry powder paint of conch meal |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905806A (en) * | 2017-03-23 | 2017-06-30 | 焦英华 | Oyster shell whiting fungus-proof antisepsis decorative paint and preparation method thereof |
| CN109287656A (en) * | 2018-10-31 | 2019-02-01 | 浙江海洋大学 | A kind of high polymer finishing coat wall preparation method for removing mould mildew resistant spraying agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106905806A (en) * | 2017-03-23 | 2017-06-30 | 焦英华 | Oyster shell whiting fungus-proof antisepsis decorative paint and preparation method thereof |
| CN109287656A (en) * | 2018-10-31 | 2019-02-01 | 浙江海洋大学 | A kind of high polymer finishing coat wall preparation method for removing mould mildew resistant spraying agent |
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