CN108314939A - A kind of anticorrosive nano paint and preparation method thereof - Google Patents
A kind of anticorrosive nano paint and preparation method thereof Download PDFInfo
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- CN108314939A CN108314939A CN201810169696.9A CN201810169696A CN108314939A CN 108314939 A CN108314939 A CN 108314939A CN 201810169696 A CN201810169696 A CN 201810169696A CN 108314939 A CN108314939 A CN 108314939A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2286—Oxides; Hydroxides of metals of silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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Abstract
The invention discloses a kind of anticorrosive nano paints, prepare raw material and consist of the following compositions in parts by weight：Acrylic resin, nano phase ag_2 o, Nano silica sol, nano silicon dioxide, p-methyl benzenesulfonic acid, 3 pyridine carboxylic acid magnesium, three zinc of citric acid, titanate coupling agent, crosslinking alcohol amine cellulose, silane modifier, aluminium hydroxide, 35 parts of dimethyltin laurate, toughener, pigment and ethyl alcohol.The anticorrosive nano paint preparation process includes：Dispensing, grinding, paint, inspection, filtering and canned.The anticorrosive paint of the present invention is made of high anticorrosive nano material, has the various superior functions of high anticorrosive nano material, has the characteristics that high corrosion prevention percentage, high abrasion and high rigidity.
Description
Technical field
The present invention relates to anticorrosive paint technology fields, and in particular to a kind of anticorrosive nano paint and preparation method thereof.
Background technology
Corrosion refers to that metal or nonmetallic generated under surrounding medium (water, air, acid, alkali, salt, solvent etc.) effect are damaged
Consumption and the process destroyed, it is a kind of process of spontaneous progress, and the economic loss and social danger brought to the mankind are very big.Metal
Corrosion, spread national economy every field, nearly all industry, including：The energy (petroleum gas, nuclear power, water power, wind
Electricity etc.), communications and transportation (aerospace, highway, railway, ship sea-freight etc.), mechanical metallurgy (electrometallurgy, chemical industry metallurgical etc.), change
Industrial and commercial bank's industry (petrochemical industry, coal chemical industry, fine chemistry industry etc.), light industry, town and country construction, information, agricultural, the marine utilization exploitation etc.,
Further include some frontier science and technology and national defense facility.Therefore anticorrosion also becomes one of the problem of the world today.
China has succeeded in developing many anticorrosive paint kinds, such as chlorinated rubber coating, epoxy micaceous iron coating, bituminous epoxy
Coating, chlorosulfonated polythylene coatings etc. play an important role to China's metal structure anticorrosion, but the development of anticorrosive paint is still not
The needs of China's construction project are adapted to, a large amount of marine and bank engineering, petrochemical industry project and metallurgical construction engineering long-effective corrosion
Erosion problem also fails to solve at all.Presently, there are main problem be：Lack the anticorrosive coating with property.
Invention content
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, a kind of anticorrosive nano paint and its preparation are provided
Method, the coating are made of high anticorrosive nano material, have the various superior functions of high anticorrosive nano material, have high anti-corrosion
The characteristics of rate, high abrasion and high rigidity.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme that：
A kind of anticorrosive nano paint, prepares raw material and consists of the following compositions in parts by weight：44-48 parts of acrylic resin,
12-16 parts of nano phase ag_2 o, 9-13 parts of Nano silica sol, 3-5 parts of nano silicon dioxide, 4-8 parts of p-methyl benzenesulfonic acid, 3- pyridine first
Sour magnesium 2-4 parts, 1-4 parts of three zinc of citric acid, 0.4-0.8 parts of titanate coupling agent, crosslinking 4-6 parts of alcohol amine cellulose, silane-modified
14-18 parts of 2-5 parts of agent, 4-8 parts of aluminium hydroxide, 3-5 parts of dimethyltin laurate, 1-3 parts of toughener, 4-8 parts of pigment and ethyl alcohol.
It is consisted of the following compositions in parts by weight preferably, it prepares raw material：46 parts of acrylic resin, nanometer titanium dioxide
24 parts, 14 parts of nano phase ag_2 o, 11 parts of Nano silica sol, 4 parts of nano silicon dioxide, 6 parts of p-methyl benzenesulfonic acid, acidum nicotinicum magnesium
3 parts, 3 parts of three zinc of citric acid, 0.6 part of titanate coupling agent, 5 parts of crosslinking alcohol amine cellulose, 3.5 parts of silane modifier, hydroxide
16 parts of 6 parts of aluminium, 4 parts of dimethyltin laurate, 2 parts of toughener, 6 parts of pigment and ethyl alcohol.
Preferably, the toughener is organoclay.
Preferably, the pigment is grouped as by the group of following parts by weight：12-14 parts of body pigment, 2-4 parts of barium sulfate, silicon
1-3 parts of micro mist.
Preferably, the body pigment is titanium dioxide or brown iron oxide.
A kind of preparation method of anticorrosive nano paint, includes the following steps：
（1）Dispensing：The above-mentioned raw material for preparing is mixed, dispersion is then stirred；
（2）Grinding：Mixed material obtained by step (1) is ground, the fineness of the particulate matter in polished mixed material
It is 80-100 μm；
（3）Paint：Mixed material to completing grinding carries out the debugging of viscosity and color, according to requiring to be added in debugging process
Ethyl alcohol so that viscosity≤100s of the material after the completion of debugging, material color meet the manufacture requirement of design；
（4）It examines：It tests to the material after completion paint；
（5）It filters, is canned：It examines qualified material to be filtered step (4), obtains the anticorrosive nano paint of finished product, then
It carries out filling.
Preferably, in step（1）In first by acrylic resin, nanometer titanium dioxide, nano phase ag_2 o, nano silicasol
Glue, nano silicon dioxide, p-methyl benzenesulfonic acid, acidum nicotinicum magnesium, three zinc of citric acid, titanate coupling agent, crosslinking hydramine fiber
Element, silane modifier, aluminium hydroxide, dimethyltin laurate, toughener, ethyl alcohol are mixed, then carry out middling speed dispersion, dispersion
The speed of machine disperses 12-16min in 400-500r/min；Body pigment, sulfuric acid is added after the completion of dispersion into above-mentioned material again
Barium, silicon powder, then carry out high speed dispersion again, and the speed control of dispersion machine disperses 25-28min in 700-800r/min.
Preferably, when titanium dioxide is as body pigment, the fineness of polished particulate matter is 80 μm；Work as brown iron oxide
When as body pigment, the fineness of polished particulate matter is 100 μm.
Preferably, being filtered using the strainer of 140-180 mesh in step (5).
Compared with prior art, the present invention has following advantageous effect：The anticorrosive paint of the present invention is received using high anti-corrosion
Rice material is made, and has the various superior functions of high anticorrosive nano material, the spy with high corrosion prevention percentage, high abrasion and high rigidity
Point, concrete condition are as follows：
（1）The preparation method of anticorrosive nano paint of the present invention, in original dispensing, by the way that nanometer titanium dioxide is added, receives
Rice silver oxide, Nano silica sol, nano silicon dioxide not only can be with the rotproofness of coating, while also improving the wear-resisting of the coating
Property；It is crosslinked alcohol amine cellulose, dimethyltin laurate by addition, improves the Corrosion Protection of the coating；Pass through the choosing of substance
With with the selection that matches to each other so that interference is not will produce between their performances, but collaboration collectively promotes the promotion of performance,
Prepare anticorrosive nano paint；
（2）Anticorrosive nano paint raw material of the invention is cheap, preparation process is simple, is suitable for industrialized production, highly practical；
（3）Volatile organic content in the anticorrosive nano-coating of the present invention is very low and has no irritating odor, and reduces to ring
The pollution in border reduces the harm to human body.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
A kind of anticorrosive nano paint, prepares raw material and consists of the following compositions in parts by weight：Acrylic resin 46 part, nanometer
24 parts of titanium dioxide, 14 parts of nano phase ag_2 o, 11 parts of Nano silica sol, 4 parts of nano silicon dioxide, 6 parts of p-methyl benzenesulfonic acid, 3- pyridines
3 parts of magnesium formate, 3 parts of three zinc of citric acid, 0.6 part of titanate coupling agent, 5 parts of crosslinking alcohol amine cellulose, 3.5 parts of silane modifier,
16 parts of 6 parts of aluminium hydroxide, 4 parts of dimethyltin laurate, 2 parts of toughener, 6 parts of pigment and ethyl alcohol.
Wherein, the toughener is organoclay.
Wherein, the pigment is grouped as by the group of following parts by weight：13 parts of body pigment, 3 parts of barium sulfate, 2 parts of silicon powder.
Wherein, the body pigment is titanium dioxide or brown iron oxide.
A kind of preparation method of anticorrosive nano paint, includes the following steps：
（1）Dispensing：The above-mentioned raw material for preparing is mixed, dispersion is then stirred；
（2）Grinding：Mixed material obtained by step (1) is ground, the fineness of the particulate matter in polished mixed material
It is 900 μm；
（3）Paint：Mixed material to completing grinding carries out the debugging of viscosity and color, according to requiring to be added in debugging process
Ethyl alcohol so that viscosity≤100s of the material after the completion of debugging, material color meet the manufacture requirement of design；
（4）It examines：It tests to the material after completion paint；
（5）It filters, is canned：It examines qualified material to be filtered step (4), obtains the anticorrosive nano paint of finished product, then
It carries out filling.
Wherein, in step（1）In first by acrylic resin, nanometer titanium dioxide, nano phase ag_2 o, Nano silica sol, receive
Rice silica, p-methyl benzenesulfonic acid, acidum nicotinicum magnesium, three zinc of citric acid, titanate coupling agent, crosslinking alcohol amine cellulose, silicon
Alkane modifying agent, aluminium hydroxide, dimethyltin laurate, toughener, ethyl alcohol are mixed, then carry out middling speed dispersion, dispersion machine
Speed disperses 14min in 450r/min；Body pigment, barium sulfate, silicon powder is added after the completion of dispersion into above-mentioned material again, so
Carry out high speed dispersion again afterwards, the speed control of dispersion machine disperses 26.5min in 750r/min.
Wherein, when titanium dioxide is as body pigment, the fineness of polished particulate matter is 80 μm；When brown iron oxide conduct
When body pigment, the fineness of polished particulate matter is 100 μm.
Wherein, it is filtered using the strainer of 160 mesh in step (5).
Embodiment 2
A kind of anticorrosive nano paint, prepares raw material and consists of the following compositions in parts by weight：Acrylic resin 44 part, nanometer
12 parts of silver oxide, 9 parts of Nano silica sol, 3 parts of nano silicon dioxide, 4 parts of p-methyl benzenesulfonic acid, 2 parts of acidum nicotinicum magnesium, citric acid
Three 1 part of zinc, 0.4 part of titanate coupling agent, 4 parts of crosslinking alcohol amine cellulose, 2 parts of silane modifier, 4 parts of aluminium hydroxide, lauric acid
14 parts of 3 parts of stannous methide, 1 part of toughener, 4 parts of pigment and ethyl alcohol.
Wherein, the toughener is organoclay.
Wherein, the pigment is grouped as by the group of following parts by weight：12 parts of body pigment, 2 parts of barium sulfate, 1 part of silicon powder.
Wherein, the body pigment is titanium dioxide or brown iron oxide.
A kind of preparation method of anticorrosive nano paint, includes the following steps：
（1）Dispensing：The above-mentioned raw material for preparing is mixed, dispersion is then stirred；
（2）Grinding：Mixed material obtained by step (1) is ground, the fineness of the particulate matter in polished mixed material
It is 80 μm；
（3）Paint：Mixed material to completing grinding carries out the debugging of viscosity and color, according to requiring to be added in debugging process
Ethyl alcohol so that viscosity≤100s of the material after the completion of debugging, material color meet the manufacture requirement of design；
（4）It examines：It tests to the material after completion paint；
（5）It filters, is canned：It examines qualified material to be filtered step (4), obtains the anticorrosive nano paint of finished product, then
It carries out filling.
Wherein, in step（1）In first by acrylic resin, nanometer titanium dioxide, nano phase ag_2 o, Nano silica sol, receive
Rice silica, p-methyl benzenesulfonic acid, acidum nicotinicum magnesium, three zinc of citric acid, titanate coupling agent, crosslinking alcohol amine cellulose, silicon
Alkane modifying agent, aluminium hydroxide, dimethyltin laurate, toughener, ethyl alcohol are mixed, then carry out middling speed dispersion, dispersion machine
Speed disperses 12min in 400r/min；Body pigment, barium sulfate, silicon powder is added after the completion of dispersion into above-mentioned material again, so
Carry out high speed dispersion again afterwards, the speed control of dispersion machine disperses 25min in 700r/min.
Wherein, when titanium dioxide is as body pigment, the fineness of polished particulate matter is 80 μm；When brown iron oxide conduct
When body pigment, the fineness of polished particulate matter is 100 μm.
Wherein, it is filtered using the strainer of 140 mesh in step (5).
Embodiment 3
A kind of anticorrosive nano paint, prepares raw material and consists of the following compositions in parts by weight：Acrylic resin 48 part, nanometer
16 parts of silver oxide, 13 parts of Nano silica sol, 5 parts of nano silicon dioxide, 8 parts of p-methyl benzenesulfonic acid, 4 parts of acidum nicotinicum magnesium, lemon
Sour 4 parts of three zinc, 0.8 part of titanate coupling agent, 6 parts of crosslinking alcohol amine cellulose, 5 parts of silane modifier, 8 parts of aluminium hydroxide, bay
18 parts of 5 parts of sour stannous methide, 3 parts of toughener, 8 parts of pigment and ethyl alcohol.
Wherein, the toughener is organoclay.
Wherein, the pigment is grouped as by the group of following parts by weight：14 parts of body pigment, 4 parts of barium sulfate, 3 parts of silicon powder.
Wherein, the body pigment is titanium dioxide or brown iron oxide.
A kind of preparation method of anticorrosive nano paint, includes the following steps：
（1）Dispensing：The above-mentioned raw material for preparing is mixed, dispersion is then stirred；
（2）Grinding：Mixed material obtained by step (1) is ground, the fineness of the particulate matter in polished mixed material
It is 100 μm；
（3）Paint：Mixed material to completing grinding carries out the debugging of viscosity and color, according to requiring to be added in debugging process
Ethyl alcohol so that viscosity≤100s of the material after the completion of debugging, material color meet the manufacture requirement of design；
（4）It examines：It tests to the material after completion paint；
（5）It filters, is canned：It examines qualified material to be filtered step (4), obtains the anticorrosive nano paint of finished product, then
It carries out filling.
Wherein, in step（1）In first by acrylic resin, nanometer titanium dioxide, nano phase ag_2 o, Nano silica sol, receive
Rice silica, p-methyl benzenesulfonic acid, acidum nicotinicum magnesium, three zinc of citric acid, titanate coupling agent, crosslinking alcohol amine cellulose, silicon
Alkane modifying agent, aluminium hydroxide, dimethyltin laurate, toughener, ethyl alcohol are mixed, then carry out middling speed dispersion, dispersion machine
Speed disperses 16min in 500r/min；Body pigment, barium sulfate, silicon powder is added after the completion of dispersion into above-mentioned material again, so
Carry out high speed dispersion again afterwards, the speed control of dispersion machine disperses 28min in 800r/min.
Wherein, when titanium dioxide is as body pigment, the fineness of polished particulate matter is 80 μm；When brown iron oxide conduct
When body pigment, the fineness of polished particulate matter is 100 μm.
Wherein, it is filtered using the strainer of 180 mesh in step (5).
To sum up, anticorrosive paint of the invention is made of high anticorrosive nano material, has the various of high anticorrosive nano material
Superior function has the characteristics that high corrosion prevention percentage, high abrasion and high rigidity
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment,
All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (9)
1. a kind of anticorrosive nano paint, it is characterised in that：It prepares raw material and consists of the following compositions in parts by weight：Acrylic acid
44-48 parts of resin, 12-16 parts of nano phase ag_2 o, 9-13 parts of Nano silica sol, 3-5 parts of nano silicon dioxide, p-methyl benzenesulfonic acid 4-
8 parts, 2-4 parts of acidum nicotinicum magnesium, 1-4 parts of three zinc of citric acid, 0.4-0.8 parts of titanate coupling agent, crosslinking alcohol amine cellulose 4-6
Part, 2-5 parts of silane modifier, 4-8 parts of aluminium hydroxide, 3-5 parts of dimethyltin laurate, 1-3 parts of toughener, 4-8 parts of pigment and
14-18 parts of ethyl alcohol.
2. anticorrosive nano paint according to claim 1, it is characterised in that：It prepares raw material in parts by weight by following
At being grouped as：46 parts of acrylic resin, 24 parts of nanometer titanium dioxide, 14 parts of nano phase ag_2 o, 11 parts of Nano silica sol, nano-silica
4 parts of SiClx, 6 parts of p-methyl benzenesulfonic acid, 3 parts of acidum nicotinicum magnesium, 3 parts of three zinc of citric acid, 0.6 part of titanate coupling agent, crosslinking alcohol
5 parts of amine cellulose, 3.5 parts of silane modifier, 6 parts of aluminium hydroxide, 4 parts of dimethyltin laurate, 2 parts of toughener, 6 parts of pigment and
16 parts of ethyl alcohol.
3. anticorrosive nano paint according to claim 1, it is characterised in that：The toughener is organoclay.
4. anticorrosive nano paint according to claim 1, it is characterised in that：The pigment by following parts by weight component
Composition：12-14 parts of body pigment, 2-4 parts of barium sulfate, 1-3 parts of silicon powder.
5. anticorrosive nano paint according to claim 4, it is characterised in that：The body pigment is titanium dioxide or iron oxide
Powder.
6. a kind of preparation method of anticorrosive nano paint according to claim 1, it is characterised in that：Including following step
Suddenly：
（1）Dispensing：The above-mentioned raw material for preparing is mixed, dispersion is then stirred；
（2）Grinding：Mixed material obtained by step (1) is ground, the fineness of the particulate matter in polished mixed material
It is 80-100 μm；
（3）Paint：Mixed material to completing grinding carries out the debugging of viscosity and color, according to requiring to be added in debugging process
Ethyl alcohol so that viscosity≤100s of the material after the completion of debugging, material color meet the manufacture requirement of design；
（4）It examines：It tests to the material after completion paint；
（5）It filters, is canned：It examines qualified material to be filtered step (4), obtains the anticorrosive nano paint of finished product, then
It carries out filling.
7. the preparation method of anticorrosive nano paint according to claim 6, it is characterised in that：In step（1）In first
By acrylic resin, nanometer titanium dioxide, nano phase ag_2 o, Nano silica sol, nano silicon dioxide, p-methyl benzenesulfonic acid, 3- pyridines
Magnesium formate, three zinc of citric acid, titanate coupling agent, crosslinking alcohol amine cellulose, silane modifier, aluminium hydroxide, lauric acid diformazan
Ji Xi, toughener, ethyl alcohol are mixed, then carry out middling speed dispersion, and the speed of dispersion machine disperses 12- in 400-500r/min
16min；Body pigment, barium sulfate, silicon powder is added after the completion of dispersion into above-mentioned material again, then carries out high speed dispersion again, point
The speed control of machine is dissipated in 700-800r/min, disperses 25-28min.
8. the preparation method of anticorrosive nano paint according to claim 6, it is characterised in that：When titanium dioxide is as main face
When material, the fineness of polished particulate matter is 80 μm；When brown iron oxide is as body pigment, polished particulate matter
Fineness is 100 μm.
9. the preparation method of anticorrosive nano paint according to claim 6, it is characterised in that：It is used in step (5)
The strainer of 140-180 mesh is filtered.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810169696.9A CN108314939A (en) | 2018-03-01 | 2018-03-01 | A kind of anticorrosive nano paint and preparation method thereof |
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| CN201810169696.9A CN108314939A (en) | 2018-03-01 | 2018-03-01 | A kind of anticorrosive nano paint and preparation method thereof |
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| CN201810169696.9A Withdrawn CN108314939A (en) | 2018-03-01 | 2018-03-01 | A kind of anticorrosive nano paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114716911A (en) * | 2021-03-22 | 2022-07-08 | 武汉开门见山科技有限公司 | Coating material of security equipment and application thereof |
| CN115363049A (en) * | 2022-06-17 | 2022-11-22 | 苏州京程材料有限公司 | Preparation method of nano composite material and product thereof |
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| CN101629040A (en) * | 2009-07-13 | 2010-01-20 | 黎源 | Transparent heat insulation coating with nanoparticles and preparation method thereof |
| CN102533028A (en) * | 2011-12-29 | 2012-07-04 | 陕西宝塔山油漆股份有限公司 | Water-based, primer-free and high-performance exterior water coating |
| CN105295623A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Outdoor waterproof coating material and preparation method thereof |
| CN106674983A (en) * | 2016-12-12 | 2017-05-17 | 成都育芽科技有限公司 | Anti-corrosive and antibacterial nano material and preparation method thereof |
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2018
- 2018-03-01 CN CN201810169696.9A patent/CN108314939A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629040A (en) * | 2009-07-13 | 2010-01-20 | 黎源 | Transparent heat insulation coating with nanoparticles and preparation method thereof |
| CN102533028A (en) * | 2011-12-29 | 2012-07-04 | 陕西宝塔山油漆股份有限公司 | Water-based, primer-free and high-performance exterior water coating |
| CN105295623A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Outdoor waterproof coating material and preparation method thereof |
| CN106674983A (en) * | 2016-12-12 | 2017-05-17 | 成都育芽科技有限公司 | Anti-corrosive and antibacterial nano material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114716911A (en) * | 2021-03-22 | 2022-07-08 | 武汉开门见山科技有限公司 | Coating material of security equipment and application thereof |
| CN115363049A (en) * | 2022-06-17 | 2022-11-22 | 苏州京程材料有限公司 | Preparation method of nano composite material and product thereof |
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