CN107311563A - A kind of tile pointing agent and preparation method thereof - Google Patents
A kind of tile pointing agent and preparation method thereof Download PDFInfo
- Publication number
- CN107311563A CN107311563A CN201710498137.8A CN201710498137A CN107311563A CN 107311563 A CN107311563 A CN 107311563A CN 201710498137 A CN201710498137 A CN 201710498137A CN 107311563 A CN107311563 A CN 107311563A
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- epoxy resin
- weight
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
- C04B2111/00672—Pointing or jointing materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:40~60 parts of white cement, 5~12 parts of epoxy resin, 8~16 parts of polyethylene glycol, 3~6 parts of atoleine, 4~8 parts of OPE, 1~3 part of triethyltin chloride, 0.5~1.5 part of tributyltin chloride, 10~18 parts of super finely ground slag, 5~9 parts of land plaster, 3~8 parts of colouring agent, 0.5~1.2 part of light stabilizer, 10~16 parts of acetone, 20~32 parts of water;Preparation, the preparation of epoxy resin solution, mixture A preparation, the preparation of tile pointing agent semi-finished product, the filling, sealing that its preparation method includes mixed slurry are got product.Jointing agent proposed by the present invention, is formulated reasonable, uniform color, brightness is high, stickiness is strong, workability is good, wearability is strong, and is difficult bacterium of mildewing, and easy to use, cheap, preparation method is simple.
Description
Technical field
The present invention relates to building material technical field, more particularly to a kind of tile pointing agent and preparation method thereof.
Background technology
Ceramic tile is common ornament in our daily lifes, the left and right on existing attractive, decorative thing surface, while again can be with
Upholstered surface is played a protective role.After laying ceramic tile, we would generally be between ceramic tile and ceramic tile, or ceramic tile and wall
Jointing agent is filled in gap between body, to ensure between ceramic tile and ceramic tile or be combined closely between ceramic tile and metope.Usual our institutes
Its color of jointing agent is dark, and dehydration after or meet expand with heat and contract with cold after easily there is crackle, ceramic tile is seeped water, in addition its long-time
In wet environment or oil pollution environment easily long mildew and attachment spot, it is more difficult to clear up.And used in tile pointing agent
Friction, especially floor tile can be often run into journey, rubs more, easily causes the severe attrition of jointing agent, and then causes the phenomenon that seeps water.
In addition, existing jointing agent is divided into two kinds, and one kind is powdered, and another is gluey.Powdered jointing agent
It is difficult to store and transports, and need to blend with water in use, then used, the concentration blent every time is difficult the palm
Hold, certain difficulty is caused to construction.And glue jointing agent cost is higher, and less stable, remain static for a long time
When easily occur sedimentation phenomenon, using preceding needing to be well mixed.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of tile pointing agent for proposing and its
Preparation method.
A kind of tile pointing agent, includes the raw material of following parts by weight:40~60 parts of white cement, 5~12 parts of epoxy resin gathers
8~16 parts of ethylene glycol, 3~6 parts of atoleine, 4~8 parts of OPE, 1~3 part of triethyltin chloride, chlorination tributyl
0.5~1.5 part of tin, 10~18 parts of super finely ground slag, 5~9 parts of land plaster, 3~8 parts of colouring agent, 0.5~1.2 part of light stabilizer, third
10~16 parts of ketone, 20~32 parts of water.
It is preferred that, a kind of described tile pointing agent includes the raw material of following parts by weight:40~60 parts of white cement, epoxy
6~12 parts of resin, 10~16 parts of polyethylene glycol, 3~5 parts of atoleine, 6~8 parts of OPE, triethyltin chloride 1
~3 parts, 0.5~1.5 part of tributyltin chloride, 10~18 parts of super finely ground slag, 5~9 parts of land plaster, 3~8 parts of colouring agent, light is steady
Determine 0.6~1.2 part of agent, 12~15 parts of acetone, 24~30 parts of water.
It is preferred that, a kind of described tile pointing agent includes the raw material of following parts by weight:50 parts of white cement, epoxy resin
10 parts, 12 parts of polyethylene glycol, 4 parts of atoleine, 7 parts of OPE, 2 parts of triethyltin chloride, tributyltin chloride 1
Part, 15 parts of super finely ground slag, 7 parts of land plaster, 5 parts of colouring agent, 1 part of light stabilizer, 13 parts of acetone, 27 parts of water.
It is preferred that, the epoxy resin accounts for 10%~30% of white cement in raw material
It is preferred that, the weight part ratio of the triethyltin chloride and tributyltin chloride is 1~6:1.
It is preferred that, the light stabilizer is 2- dihydroxy benaophenonels and (1,2,2,6, the 6- pentamethyl -4- of phosphorous acid three
Hydroxy piperidine) ester complexing agent, wherein 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxyl piperazines
Pyridine) ester weight part ratio be 1:0.5~1.5.
It is preferred that, the weight part ratio of the acetone and water is 1:2~3
The invention also provides a kind of preparation method of tile pointing agent, comprise the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing 10~20min of stirring, must be mixed
Slurry;
S2:The epoxy resin of corresponding parts by weight is added into acetone, and in 40~60 DEG C of sealing 3~5h of stirring, produces asphalt mixtures modified by epoxy resin
Lipoprotein solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 30~60min with 300~500r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent and light stabilizer, and be transferred to 15~35min of ultrasonic disperse in Ultrasound Instrument, produce tile pointing agent semi-finished product, then through it is filling,
Sealing is got product.
It is preferred that, the epoxy resin in the S2 steps grinds to form granularity more than 20 mesh powders in grinder in advance.
A kind of tile pointing agent proposed by the present invention, formula rationally, uniform color, brightness is high, stickiness is strong, workability is good,
Wearability is strong, and is difficult bacterium of mildewing, easy to use, cheap;Using white cement cheap and easy to get as primary raw material, epoxy is added
Resin ensures the water resistance of jointing agent, while the acetone and water to dissolve each other both can guarantee that water-soluble substances as mixed solvent
Mixing, also can guarantee that epoxy resin is evenly distributed in jointing agent;The collaboration of polyethylene glycol and atoleine in jointing agent makes
With that can significantly improve the workability of jointing agent, while the brightness of jointing agent can be improved by increasing OPE, effectively
The problem of jointing agent color using white cement as raw material is dark is solved, and jointing agent prepared by formula proposed by the present invention also has
Have functions that to suppress mould generation, it is kept good glossiness and waterproof effect, extension in wet condition
Its service life;The addition of super finely ground slag and land plaster can significantly improve the anti-wear performance of jointing agent, what is rubbed repeatedly
In the case of will not also occur severe attrition, and the jointing agent prepared according to formula proposed by the present invention and preparation method is liquid
Shape, it is to avoid powdery jointing agent is watered operation, while each component is stable in the presence of in solvent in jointing agent, it is to avoid tradition is gluey to be hooked
That stitches agent rocks married operation, directly uses and can reach the consistent effect of uniform color, and preparation method is simple.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:60 parts of white cement, 7 parts of epoxy resin gathers
10 parts of ethylene glycol, 4 parts of atoleine, 6 parts of OPE, 2 parts of triethyltin chloride, 1 part of tributyltin chloride, ultra-fine ore deposit
18 parts of powder, 9 parts of land plaster, 5 parts of colouring agent, 0.5 part of 2- dihydroxy benaophenonels, phosphorous acid three (1,2,2,6,6- pentamethyl-
4- hydroxy piperidines) 0.7 part of ester, 12 parts of acetone, 26 parts of water.
Its preparation method, comprises the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing stirring 15min, mixed slurry is obtained;
S2:Epoxy resin is ground to form into granularity more than 20 mesh powders in grinder, in the acetone for adding corresponding parts by weight,
And in 50 DEG C of sealing stirring 3h, produce epoxy resin solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 50min with 400r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent, 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, and it is transferred to Ultrasound Instrument
Middle ultrasonic disperse 25min, produces tile pointing agent semi-finished product, then get product through filling, sealing.
Embodiment two
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:50 parts of white cement, 12 parts of epoxy resin,
16 parts of polyethylene glycol, 4 parts of atoleine, 4 parts of OPE, 3 parts of triethyltin chloride, 1.5 parts of tributyltin chloride surpasses
12 parts of mineral fine, 6 parts of land plaster, 7 parts of colouring agent, 0.4 part of 2- dihydroxy benaophenonels, (1,2,2,6,6- five first of phosphorous acid three
Base -4- hydroxy piperidines) 0.5 part of ester, 14 parts of acetone, 28 parts of water.
Its preparation method, comprises the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing 10~20min of stirring, must be mixed
Slurry;
S2:Epoxy resin is ground to form into granularity more than 20 mesh powders in grinder, in the acetone for adding corresponding parts by weight,
And in 40~60 DEG C of sealing 3~5h of stirring, produce epoxy resin solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 30~60min with 300~500r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent, 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, and it is transferred to Ultrasound Instrument
Middle 15~35min of ultrasonic disperse, produces tile pointing agent semi-finished product, then get product through filling, sealing.
Embodiment three
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:40 parts of white cement, 12 parts of epoxy resin,
8 parts of polyethylene glycol, 4 parts of atoleine, 6 parts of OPE, 2 parts of triethyltin chloride, 1.5 parts of tributyltin chloride surpasses
14 parts of mineral fine, 5 parts of land plaster, 8 parts of colouring agent, 0.6 part of 2- dihydroxy benaophenonels, (1,2,2,6,6- five first of phosphorous acid three
Base -4- hydroxy piperidines) 0.3 part of ester, 13 parts of acetone, 32 parts of water.
Its preparation method, comprises the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing stirring 20min, mixed slurry is obtained;
S2:Epoxy resin is ground to form into granularity more than 20 mesh powders in grinder, in the acetone for adding corresponding parts by weight,
And in 60 DEG C of sealing stirring 3h, produce epoxy resin solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 30min with 500r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent, 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, and it is transferred to Ultrasound Instrument
Middle ultrasonic disperse 35min, produces tile pointing agent semi-finished product, then get product through filling, sealing.
Example IV
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:40 parts of white cement, 5 parts of epoxy resin gathers
14 parts of ethylene glycol, 3 parts of atoleine, 8 parts of OPE, 3 parts of triethyltin chloride, 1.5 parts of tributyltin chloride is ultra-fine
18 parts of miberal powder, 5 parts of land plaster, 8 parts of colouring agent, 0.5 part of 2- dihydroxy benaophenonels, (1,2,2,6,6- five first of phosphorous acid three
Base -4- hydroxy piperidines) 0.5 part of ester, 16 parts of acetone, 30 parts of water.
Its preparation method, comprises the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing stirring 10min, mixed slurry is obtained;
S2:Epoxy resin is ground to form into granularity more than 20 mesh powders in grinder, in the acetone for adding corresponding parts by weight,
And in 50 DEG C of sealing stirring 4h, produce epoxy resin solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 30min with 500r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent, 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, and it is transferred to Ultrasound Instrument
Middle ultrasonic disperse 20min, produces tile pointing agent semi-finished product, then get product through filling, sealing.
Embodiment five
A kind of tile pointing agent proposed by the present invention, includes the raw material of following parts by weight:50 parts of white cement, 10 parts of epoxy resin,
16 parts of polyethylene glycol, 6 parts of atoleine, 5 parts of OPE, 2 parts of triethyltin chloride, 1 part of tributyltin chloride is ultra-fine
10 parts of miberal powder, 9 parts of land plaster, 3 parts of colouring agent, 0.3 part of 2- dihydroxy benaophenonels, (1,2,2,6,6- five first of phosphorous acid three
Base -4- hydroxy piperidines) 0.4 part of ester, 10 parts of acetone, 30 parts of water.
Its preparation method, comprises the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing stirring 20min, mixed slurry is obtained;
S2:Epoxy resin is ground to form into granularity more than 20 mesh powders in grinder, in the acetone for adding corresponding parts by weight,
And in 40 DEG C of sealing stirring 5h, produce epoxy resin solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 60min with 300r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent, 2- dihydroxy benaophenonels and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, and it is transferred to Ultrasound Instrument
Middle 15~35min of ultrasonic disperse, produces tile pointing agent semi-finished product, then get product through filling, sealing.
The jointing agent and commercially available gluey jointing agent prepared to above-described embodiment one~five carries out performance detection respectively, detects
As a result it is as follows:
Embodiment | One | Two | Three | Four | Five | It is commercially available |
Outward appearance | Uniformly | Uniformly | Uniformly | Uniformly | Uniformly | Uniformly |
Brightness | It is bright | It is bright | It is bright | It is bright | It is bright | Secretly |
Water penetration (24h)/ml | 1.3 | 1.1 | 1.2 | 1.3 | 1.1 | 2.0 |
Tensile bond strength/MPa | 0.96 | 0.95 | 0.96 | 0.94 | 0.93 | 0.75 |
Setting time/h | 4.5 | 4.6 | 4.8 | 4.6 | 4.7 | 6.6 |
Testing result shows, jointing agent appearance uniform prepared by embodiment one~five, and brightness is better than commercially available jointing agent, is carrying out
During permeable experiment in 24 hours, jointing agent prepared by embodiment one~five it is permeable it is maximum only have 1.3ml, and commercially available jointing agent is permeable reaches
To 2.0ml, show that the jointing agent percolation-proof effect prepared according to the formula and preparation method of jointing agent proposed by the present invention is good, draw
Stretch detected intensities to show, jointing agent tensile bond strength prepared by embodiment one~five can reach 0.9MPa, and commercially available
Jointing agent only has 0.73, shows that jointing agent cohesive force proposed by the present invention is strong, service life is long;And prepared by embodiment one~five
Jointing agent setting time it is short, it is not easy to crack.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (9)
1. a kind of tile pointing agent, it is characterised in that include the raw material of following parts by weight:40~60 parts of white cement, epoxy resin 5
~12 parts, 8~16 parts of polyethylene glycol, 3~6 parts of atoleine, 4~8 parts of OPE, 1~3 part of triethyltin chloride,
0.5~1.5 part of tributyltin chloride, 10~18 parts of super finely ground slag, 5~9 parts of land plaster, 3~8 parts of colouring agent, light stabilizer 0.5
~1.2 parts, 10~16 parts of acetone, 20~32 parts of water.
2. a kind of tile pointing agent according to claim 1, it is characterised in that include the raw material of following parts by weight:Plain boiled water
40~60 parts of mud, 6~12 parts of epoxy resin, 10~16 parts of polyethylene glycol, 3~5 parts of atoleine, OPE 6~8
Part, 1~3 part of triethyltin chloride, 0.5~1.5 part of tributyltin chloride, 10~18 parts of super finely ground slag, 5~9 parts of land plaster
3~8 parts of toner, 0.6~1.2 part of light stabilizer, 12~15 parts of acetone, 24~30 parts of water.
3. a kind of tile pointing agent according to claim 1, it is characterised in that include the raw material of following parts by weight:Plain boiled water
50 parts of mud, 10 parts of epoxy resin, 12 parts of polyethylene glycol, 4 parts of atoleine, 7 parts of OPE, 2 parts of triethyltin chloride,
1 part of tributyltin chloride, 15 parts of super finely ground slag, 7 parts of land plaster, 5 parts of colouring agent, 1 part of light stabilizer, 13 parts of acetone, 27 parts of water.
4. a kind of tile pointing agent according to claim 1, it is characterised in that the epoxy resin accounts for white cement in raw material
10%~30%.
5. a kind of tile pointing agent according to claim 1, it is characterised in that the triethyltin chloride and the fourth of chlorination three
The weight part ratio of base tin is 1~6:1.
6. a kind of tile pointing agent according to claim 1, it is characterised in that the light stabilizer is 2- hydroxy benzophenones
The complexing agent of ketone and phosphorous acid three (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester, wherein 2- dihydroxy benaophenonels and Asia
The weight part ratio of tricresyl phosphate (1,2,2,6,6- pentamethyl -4- hydroxy piperidines) ester is 1:0.5~1.5.
7. a kind of tile pointing agent according to claim 1, it is characterised in that the weight part ratio of the acetone and water is 1:
2~3.
8. a kind of preparation method of tile pointing agent, it is characterised in that comprise the following steps:
S1:The white cement and land plaster of corresponding parts by weight are added to the water, and carry out sealing 10~20min of stirring, must be mixed
Slurry;
S2:The epoxy resin of corresponding parts by weight is added into acetone, and in 40~60 DEG C of sealing 3~5h of stirring, produces asphalt mixtures modified by epoxy resin
Lipoprotein solution;
S3:Above-mentioned mixed slurry and epoxy resin solution are mixed, while adding polyethylene glycol, atoleine and aoxidizing poly- second
Alkene wax, stirs 30~60min with 300~500r/min speed, produces mixture A;
S4:The triethyltin chlorides of corresponding parts by weight, tributyltin chloride, super finely ground slag, coloring are added into said mixture A
Agent and light stabilizer, and be transferred to 15~35min of ultrasonic disperse in Ultrasound Instrument, produce tile pointing agent semi-finished product, then through it is filling,
Sealing is got product.
9. a kind of preparation method of tile pointing agent according to claim 8, it is characterised in that the ring in the S2 steps
Oxygen tree fat grinds to form granularity more than 20 mesh powders in grinder in advance.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102992715A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Stain-resistant scrubbing-resistant colorful ceramic tile joint mixture as well as preparation method and application of mixture |
CN103420658A (en) * | 2013-08-13 | 2013-12-04 | 潘保华 | Tile seam filling agent |
CN104649610A (en) * | 2014-12-31 | 2015-05-27 | 北京天维宝辰化学产品有限公司 | Tile binder and application thereof |
CN105084934A (en) * | 2015-09-09 | 2015-11-25 | 广东龙湖科技股份有限公司 | Powder brightener for improving surface gloss of mortar |
CN105392754A (en) * | 2013-07-16 | 2016-03-09 | Sika技术股份公司 | Combination of ternary binders with aqueous epoxy resin system |
-
2017
- 2017-06-27 CN CN201710498137.8A patent/CN107311563A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102992715A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Stain-resistant scrubbing-resistant colorful ceramic tile joint mixture as well as preparation method and application of mixture |
CN105392754A (en) * | 2013-07-16 | 2016-03-09 | Sika技术股份公司 | Combination of ternary binders with aqueous epoxy resin system |
CN103420658A (en) * | 2013-08-13 | 2013-12-04 | 潘保华 | Tile seam filling agent |
CN104649610A (en) * | 2014-12-31 | 2015-05-27 | 北京天维宝辰化学产品有限公司 | Tile binder and application thereof |
CN105084934A (en) * | 2015-09-09 | 2015-11-25 | 广东龙湖科技股份有限公司 | Powder brightener for improving surface gloss of mortar |
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Application publication date: 20171103 |