CN104649610A - Tile binder and application thereof - Google Patents

Tile binder and application thereof Download PDF

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Publication number
CN104649610A
CN104649610A CN201410850942.9A CN201410850942A CN104649610A CN 104649610 A CN104649610 A CN 104649610A CN 201410850942 A CN201410850942 A CN 201410850942A CN 104649610 A CN104649610 A CN 104649610A
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China
Prior art keywords
agent
ceramic tile
emulsion
tile bond
binder
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CN201410850942.9A
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Chinese (zh)
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CN104649610B (en
Inventor
王�义
王辉
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北京天维宝辰化学产品有限公司
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Publication of CN104649610A publication Critical patent/CN104649610A/en
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Abstract

The invention discloses a tile binder. The binder comprises the following components in percentage by mass: 15%-30% of aqueous polymer resin, 65%-85% of filler, 10%-20% of photocatalysis catalyzer, 0.2%-0.4% of thickener, 0.2%-0.3% of water repellent, 0.2%-0.3% of defoamer, 0.4%-0.6% of corrosion remover, 0.1%-0.3% of wetting dispersant, 0.2-0.5% of thixotropic agent, 0.5%-1.0% of storage stabilizer, 1.0%-1.5% of brightener, 0-5% of mill base and the balance of water. According to the binder, the saltpetering problem caused by overhigh alkalinity is solved, and corrosion to mosaic and other glass materials caused by alkaline components in the binder is avoided; meanwhile, the compactness and brightness of the binder are improved, and the binder has stain resistance; the selected raw materials are non-toxic and harmless, is an environment-friendly product, and has great promotion value.

Description

A kind of ceramic tile bond and application thereof
Technical field
The invention belongs to building chemical field of material technology, specifically relate to a kind of ceramic tile bond, this material binding agent possesses neutrality, water-fast easy wiping, environment friendly and pollution-free feature.
Background technology
Along with the development of ceramics, ceramic tile is more and more subject to human consumer parent as building and ornament materials and looks at.Meanwhile, use also more and more extensive as ornamental splendid high-grade mosaic.When ceramic tile or mosaic are used for interior decoration, all need to use the surface of binding agent and architecture noumenon to realize fitting tightly.For this reason, binding agent, except requiring to have except good cohesive strength, also requires that binding agent and ceramic tile or mosaic have good matching, and namely the composition of binding agent forms and can not have an impact to tile material; In addition, owing to usually needing to complete after ceramic tile pastes and will repair the gap between adjacent tiles, belong to outside surface exposed layer at the spackling of filling the use of ceramic tile gap, be easily subject to pollution and the erosion of external environment, thus cause the reduction of combination with decorative surfaces effect.Therefore, spackling requires possess excellent contamination resistance, mildew resistance and be easy to scrubbing character usually.Traditional ceramic tile or the binding agent of mosaic and spackling are formed primarily of cement base products or epoxy resin component.The binding agent of cement based material and the basicity of spackling higher, easily there is accumulation of salt in the surface soil phenomenon in long-time use, color deposition is produced at ceramic tile surface or its gap, the aesthetic property of extreme influence decoration, the more important thing is when combination with decorative surfaces is the category of glass materials such as mosaic, highly basic composition in cement based adhesive produces serious corrosive nature by mosaic surface, the generation making it lose decorative effect even to cause surperficial break-off; And although epoxy resin binding agent can not cause accumulation of salt in the surface soil phenomenon or category of glass is ostentatious comes off, but it uses and the processing step that makes is comparatively loaded down with trivial details and material cost is higher, more seriously epoxy resin binding agent does not meet the requirement of environment-friendly materials containing toxic ingredient, thus limits its application in the market.For the spackling being exposed to building surface, must need the cleaning carrying out pollutent after using for a long time, the spackling of above-mentioned two kinds of materials is all difficult to realize cleaning function; According to inorganic gel class material, as the overbased material such as silicate cement, aluminate cement binding agent, although be conducive to cleaning, the reduction of ceramic tile cementation performance can be caused.And according to neutral gelling material, if the gypsoide of different crystal forms is as binding agent or spackling, because its water tolerance is very poor, be easy to cause dissolving in wet environment, destroy bond effect.So developing good, the easy to clean scouring of a kind of water tolerance, neutral binding agent and spackling will play a role in promoting to building material technology progress in building decoration field.
Summary of the invention
For solving the defect of conventional cement base or epoxy resin ceramic tile bond and spackling, the present invention have developed that one belongs to neutral, water tolerance is good, anti-pollution ability is strong, be easy to clean, anti-mildew and construction technology is easy, surface effect is bright, non-dusting environmental protection binding agent composition.Concrete technical scheme is: a kind of ceramic tile bond, consisting of of this binding agent: aqueous polymer resin 15%-30%, filler 65%-85%, photochemical catalysis activator 10%-20%, thickening material 0.2%-0.4%, hydrophober 0.2%-0.3%, defoamer 0.2%-0.3%, sanitas 0.4%-0.6%, wetting dispersing agent 0.1%-0.3%, thixotropic agent 0.2%-0.5%, storage-stable agent 0.5%-1.0%, brightening agent 1.0%-1.5%, mill base 0-5%, all the other are water; Above-mentioned per-cent is mass percent.From the pectisation of binding agent, environmental protection and practical application effect are considered, aqueous polymer resin is a kind of in emulsion resin or solution resin, when selecting emulsion resin, select a kind of in ACRYLIC EMULSION, styrene-butadiene emulsion, VAE emulsion, benzene emulsion, tertiary acrylic emulsion, tertiary vinegar milk liquid, organosilicon crylic acid latex or two kinds and above emulsion mixture, this material has higher performance in burst size of methanal, water tolerance and stability in storage etc.
The photochemical catalysis activator used in above-mentioned formula is nano titanium oxide, its reason is that nano titanium oxide not only possesses photocatalyst effect, and there is the effect of fungus and mildew resistance, the binding agent of technical scheme is mainly used in kitichen and toilet, easy breed bacteria and mouldy, therefore selects the suitable realization of photochemical catalysis activator to final effect to have vital effect.
In the selection of filler, be improve the compactness of surface effect, filler is one or both and above mixture in water-ground limestone, light calcium carbonate, silica powder, talcum powder, zinc sulfide white, and its particle size range is at 0-45 micron.
Described thickening material is one or both and above mixture in hydroxyethyl ether cellulose, alkali swelling type thickening material, Acrylates thickening material, polyurethanes thickening material; Described hydrophober is the one in organosilicon moisture repellent, mineral oils hydrophober; Described thixotropic agent is the one in magnesium aluminum silicates, wilkinite; Described storage stabilizing agent is pH adjusting agent, as sodium bicarbonate, sodium-acetate or sodium phosphate have pH adjustment functional agent, or antioxidant, as aromatic amine, Hinered phenols, phosphite antioxidant; Described brightening agent is sulfonated melamine compound resin class brightening agent.
The ceramic tile bond of filling a prescription described in technical solution of the present invention also can be applied as spackling.
In the binder formula that technical solution of the present invention proposes, by selecting neutral enhanced water resistance resin to solve the accumulation of salt in the surface soil problem brought because basicity is too high, realize the neutralisation of binding agent, the alkaline components avoided in binding agent corrodes glass material ceramic tiles such as mosaics; Increased the compactness of binding agent by Fillers selection and Gradation Optimization, improve the glossiness of adhesive surface, make it possess higher stain resistant ability, be very easy to cleaning, particularly overcome traditional spackling and stain the shortcoming of rear difficulty cleaning; Water-base resin water tolerance and easy scrubbing character is improved by other auxiliary agents and formulation optimization.Utilize aqueous polymer resin flexibility higher, possess the characteristic of superelevation unit elongation, achieve and do not shrink the advantage strong with glass Mosaic class ceramic tile consistency that do not ftracture; By adding sanitas and antioxidant, arriving fungus-proof antisepsis effect, ensureing decoration permanence; By selecting dispersed splendid mill base and wetting dispersing agent, making binding agent evenly bright-colored, no color differnece, ensureing the aesthetic property of decoration; Selected material cost is cheap, nontoxic, packing of product easy construction, without the need to again stirring during use, reducing dust and noise pollution, belonging to environmentally friendly machine, possess great promotional value.
 
Embodiment
For convenience of the understanding of technical solution of the present invention, now illustrate that the concrete composition of this ceramic tile bond is formed and quality proportion relation.
Embodiment 1, select styrene-butadiene emulsion 10 parts, benzene emulsion 5 parts mixing composition aqueous polymer resin, nano titanium oxide 10 parts as photochemical catalysis activator, nanometer grade calcium carbonate 30 parts, light calcium carbonate 30 parts, ultrafine quartz powder 10 parts mixing composition particle diameter is 15 microns of fillers; Acrylic thickener 0.3 part, organosilicon moisture repellent 0.2 part, mineral oil antifoam agent 0.3 part, sanitas 0.5 part, Acrylates wetting dispersing agent 0.2 part, neusilin thixotropic agent 0.4 part, storage-stable agent 1.0 parts, brightening agent 1.4 parts mixing is added mill base 0.7 part again and is carried out mix and blend and make ceramic tile bond after dropping in stirring tank and stirring.Above-mentioned number is mass fraction.
Embodiment 2, select pure-acrylic emulsion 20 parts, nano titanium oxide 10 parts, utilize light calcium carbonate 25 parts, 20 parts, heavy carbonic acid, calcium talcum powder 20 parts mixing composition particle diameter is 35 microns of fillers, HEC0.3 part, organosilicon moisture repellent 0.3 part, silicone antifoam agent 0.2 part, fungicidal preservative 0.5 part, Acrylates wetting dispersing agent 0.2 part, organobentonite 0.3 part, storage-stable agent 0.8 part, brightening agent 1.2 parts, the material mixing of above-mentioned mass fraction is added mill base 1.2 parts of stirrings again after dropping into and stirring in stirring tank and is made ceramic tile bond.
Each composition in embodiment 1,2 can be replaced according to describing above.According to " ceramic wall and floor bricks tackiness agent " (JG/T 547-2005), " ceramic wall and floor tile gap filler " JC/T1004-2007, " exterior wall coating material of synthetic resin emulsion " GB/T9755-2001 and " wall facing mortar " JC/T 1024-2007, product performance are checked to the tackiness agent that embodiment 1,2 is formed.Effect and parameter are as following table:
Can find out according to test-results, contrast with traditional ceramic tile bond or spackling, this binding agent can not only reach good cohesive strength, higher water tolerance, lower water-intake rate, and has and stop the accumulation of salt in the surface soil, surface gloss high; Also there is superelevation unit elongation, do not shrink, do not ftracture and can keep excellent compatibility with ceramic tile; And this binding agent possesses high-wearing feature, splendid abrasion resistance, ensures the permanence of bonding and joint filling decoration.
The description of technique scheme only embodies the preferred technical solution of the present invention; based on embodiments of the invention; anyone the other forms of technical scheme obtained under the prerequisite not making creative work; no matter it, in structure or formal which kind of done change, all belongs within protection scope of the present invention.

Claims (7)

1. a ceramic tile bond, is characterized in that, consisting of of this binding agent: aqueous polymer resin 15%-30%, filler 65%-75%, photochemical catalysis activator 10%-20%, thickening material 0.2%-0.4%, hydrophober 0.2%-0.3%, defoamer 0.2%-0.3%, sanitas 0.4%-0.6%, wetting dispersing agent 0.1%-0.3%, thixotropic agent 0.2%-0.5%, storage-stable agent 0.5%-1.0%, brightening agent 1.0%-1.5% mill base 0-5%, all the other are water; Above-mentioned per-cent is mass percent.
2. ceramic tile bond according to claim 1, it is characterized in that, aqueous polymer resin is the one in emulsion resin or solution resin, when selecting emulsion resin, select a kind of in ACRYLIC EMULSION, styrene-butadiene emulsion, VAE emulsion, benzene emulsion, tertiary acrylic emulsion, tertiary vinegar milk liquid, organosilicon crylic acid latex or two kinds and above emulsion mixture.
3. the ceramic tile bond according to right 1, is characterized in that, photochemical catalysis activator is nano titanium oxide.
4. according to the ceramic tile bond that right 1 requires, it is characterized in that, filler is one or both and above mixture in water-ground limestone, light calcium carbonate, silica powder, talcum powder, zinc sulfide white, and its particle size range is at 0-45 micron.
5. according to the ceramic tile bond that right 1 requires, it is characterized in that, thickening material is one or both and above mixture in hydroxyethyl ether cellulose, alkali swelling type thickening material, Acrylates thickening material, polyurethanes thickening material; Described hydrophober is the one in organosilicon moisture repellent, mineral oils hydrophober; Described thixotropic agent is the one in magnesium aluminum silicates, wilkinite; Described storage stabilizing agent is pH adjusting agent or antioxidant; Described brightening agent is sulfonated melamine compound resin class brightening agent.
6., according to the ceramic tile bond that right 5 requires, it is characterized in that, the pH adjusting agent as storage stabilizing agent is sodium bicarbonate, sodium-acetate or sodium phosphate etc. have pH and adjust the auxiliary agent of function; Antioxidant is aromatic amine, Hinered phenols or phosphite antioxidant.
7. the ceramic tile bond according to the arbitrary claim of 1-6, is characterized in that, this ceramic tile bond is as the application of spackling.
CN201410850942.9A 2014-12-31 2014-12-31 A kind of ceramic tile bond and application thereof CN104649610B (en)

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CN104649610B CN104649610B (en) 2016-08-31

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Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105174804A (en) * 2015-09-19 2015-12-23 孙军 Joint mixture air-purifying promoter and preparation method
CN105174813A (en) * 2015-09-19 2015-12-23 孙军 Cold-resistant and environment-friendly joint mixture, preparing method and using method
CN105174806A (en) * 2015-09-19 2015-12-23 孙军 Joint mixture stabilizer for glaze polished bricks and preparing method
CN105174805A (en) * 2015-09-19 2015-12-23 孙军 Waterproof accelerant of toilet ground gap filling agent and preparation method
CN105174812A (en) * 2015-09-19 2015-12-23 孙军 Environment-friendly wall surface joint mixture and preparing method and using method thereof
CN105174807A (en) * 2015-09-19 2015-12-23 孙军 Weather resistance stabilizing agent of crack filler and preparation method
CN105198285A (en) * 2015-09-19 2015-12-30 孙军 Joint mixture used for acoustics room and preparing method and using method thereof
CN105254215A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for video walls, and preparation method and use method thereof
CN105254219A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for polished tiles, and preparation method and use method thereof
CN105254218A (en) * 2015-09-19 2016-01-20 孙军 Green, environmentally-friendly and discoloration and fading-free gap filler, and preparation method and use method thereof
CN105254217A (en) * 2015-09-19 2016-01-20 孙军 Sound insulation and shock resistance gap filler, and preparation method and use method thereof
CN105254270A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for heat insulation walls, and preparation method and use method thereof
CN105254214A (en) * 2015-09-19 2016-01-20 孙军 Gap filler with air purifying effect, and preparation method and use method thereof
CN105255299A (en) * 2015-11-10 2016-01-20 广东龙湖科技股份有限公司 High-solid content single-component seam beautifying agent and preparation method
CN105272025A (en) * 2015-09-19 2016-01-27 孙军 Mildew-proof formaldehyde-removing caulking agent and preparation method and application method thereof
CN105271976A (en) * 2015-09-25 2016-01-27 沈阳饰壁涂料科技有限公司 Gap filler specially used for simulated stone heat insulation and decoration integrated boards, and preparation method and use method thereof
CN105503039A (en) * 2015-12-24 2016-04-20 北京宝辰联合科技有限公司 Pasty joint mixture comprising two components
CN105753373A (en) * 2015-11-09 2016-07-13 派丽(上海)管理有限公司 Iridescent joint filling plaster
CN106010388A (en) * 2016-08-03 2016-10-12 无锡市虎皇漆业有限公司 Tile adhesive and preparation method thereof
CN106244055A (en) * 2016-08-18 2016-12-21 广州阁美仕建材有限公司 A kind of ceramic tile back of the body gluing and preparation method thereof, patch block method
CN106947413A (en) * 2017-03-31 2017-07-14 高安市联航建材有限公司 A kind of special filleting glue squeegeeed for house ornamentation seam and preparation method
CN106947422A (en) * 2017-04-28 2017-07-14 广东鹏美森木业科技有限公司 A kind of timber floor glue and preparation method thereof
CN107011749A (en) * 2017-04-27 2017-08-04 无锡市福享天下科技有限公司 Luxury wall binding agent
CN107311563A (en) * 2017-06-27 2017-11-03 六安三创建筑材料有限公司 A kind of tile pointing agent and preparation method thereof
CN109437679A (en) * 2018-11-09 2019-03-08 广西里尔新材料有限公司 A kind of porcelain tendre adhesive special
CN110157359A (en) * 2019-06-21 2019-08-23 江苏国胶新材料有限公司 A kind of environment protection tile gum and preparation method thereof
CN110205059A (en) * 2019-07-15 2019-09-06 湖北碱克新材料有限公司 A kind of ceramic tile stone material gum of high-weatherability and preparation method thereof

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CN103214212A (en) * 2013-04-17 2013-07-24 北京东方雨虹防水技术股份有限公司 Paste tile adhesive and use thereof
CN104211357A (en) * 2014-08-26 2014-12-17 德清扬泰建筑材料有限公司 Improved low-alkaline ceramic tile adhesive

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GB2141726A (en) * 1981-02-28 1985-01-03 Building Adhesives Ltd Adhesive compositions
CN102603249A (en) * 2011-12-23 2012-07-25 上海中技桩业股份有限公司 Economical anti-efflorescence and anti-cracking joint mixture for ceramic tile
CN103214212A (en) * 2013-04-17 2013-07-24 北京东方雨虹防水技术股份有限公司 Paste tile adhesive and use thereof
CN104211357A (en) * 2014-08-26 2014-12-17 德清扬泰建筑材料有限公司 Improved low-alkaline ceramic tile adhesive

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272025A (en) * 2015-09-19 2016-01-27 孙军 Mildew-proof formaldehyde-removing caulking agent and preparation method and application method thereof
CN105174813A (en) * 2015-09-19 2015-12-23 孙军 Cold-resistant and environment-friendly joint mixture, preparing method and using method
CN105174806A (en) * 2015-09-19 2015-12-23 孙军 Joint mixture stabilizer for glaze polished bricks and preparing method
CN105174805A (en) * 2015-09-19 2015-12-23 孙军 Waterproof accelerant of toilet ground gap filling agent and preparation method
CN105174812A (en) * 2015-09-19 2015-12-23 孙军 Environment-friendly wall surface joint mixture and preparing method and using method thereof
CN105174807A (en) * 2015-09-19 2015-12-23 孙军 Weather resistance stabilizing agent of crack filler and preparation method
CN105198285A (en) * 2015-09-19 2015-12-30 孙军 Joint mixture used for acoustics room and preparing method and using method thereof
CN105254215A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for video walls, and preparation method and use method thereof
CN105254219A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for polished tiles, and preparation method and use method thereof
CN105254218A (en) * 2015-09-19 2016-01-20 孙军 Green, environmentally-friendly and discoloration and fading-free gap filler, and preparation method and use method thereof
CN105254217A (en) * 2015-09-19 2016-01-20 孙军 Sound insulation and shock resistance gap filler, and preparation method and use method thereof
CN105254270A (en) * 2015-09-19 2016-01-20 孙军 Gap filler for heat insulation walls, and preparation method and use method thereof
CN105254214A (en) * 2015-09-19 2016-01-20 孙军 Gap filler with air purifying effect, and preparation method and use method thereof
CN105174804A (en) * 2015-09-19 2015-12-23 孙军 Joint mixture air-purifying promoter and preparation method
CN105271976A (en) * 2015-09-25 2016-01-27 沈阳饰壁涂料科技有限公司 Gap filler specially used for simulated stone heat insulation and decoration integrated boards, and preparation method and use method thereof
CN105753373A (en) * 2015-11-09 2016-07-13 派丽(上海)管理有限公司 Iridescent joint filling plaster
CN105255299A (en) * 2015-11-10 2016-01-20 广东龙湖科技股份有限公司 High-solid content single-component seam beautifying agent and preparation method
CN105503039A (en) * 2015-12-24 2016-04-20 北京宝辰联合科技有限公司 Pasty joint mixture comprising two components
CN105503039B (en) * 2015-12-24 2017-10-10 北京宝辰联合科技有限公司 A kind of bi-component paste gap filler
CN106010388B (en) * 2016-08-03 2018-02-13 无锡市虎皇漆业有限公司 A kind of ceramic tile bond and preparation method thereof
CN106010388A (en) * 2016-08-03 2016-10-12 无锡市虎皇漆业有限公司 Tile adhesive and preparation method thereof
CN106244055A (en) * 2016-08-18 2016-12-21 广州阁美仕建材有限公司 A kind of ceramic tile back of the body gluing and preparation method thereof, patch block method
CN106947413A (en) * 2017-03-31 2017-07-14 高安市联航建材有限公司 A kind of special filleting glue squeegeeed for house ornamentation seam and preparation method
CN107011749A (en) * 2017-04-27 2017-08-04 无锡市福享天下科技有限公司 Luxury wall binding agent
CN106947422A (en) * 2017-04-28 2017-07-14 广东鹏美森木业科技有限公司 A kind of timber floor glue and preparation method thereof
CN107311563A (en) * 2017-06-27 2017-11-03 六安三创建筑材料有限公司 A kind of tile pointing agent and preparation method thereof
CN109437679A (en) * 2018-11-09 2019-03-08 广西里尔新材料有限公司 A kind of porcelain tendre adhesive special
CN110157359A (en) * 2019-06-21 2019-08-23 江苏国胶新材料有限公司 A kind of environment protection tile gum and preparation method thereof
CN110205059A (en) * 2019-07-15 2019-09-06 湖北碱克新材料有限公司 A kind of ceramic tile stone material gum of high-weatherability and preparation method thereof

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Denomination of invention: Tile binder and application thereof

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