CN109020443B - Rusty stone effect imitating dry powder coating and preparation method thereof - Google Patents

Rusty stone effect imitating dry powder coating and preparation method thereof Download PDF

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Publication number
CN109020443B
CN109020443B CN201811048048.4A CN201811048048A CN109020443B CN 109020443 B CN109020443 B CN 109020443B CN 201811048048 A CN201811048048 A CN 201811048048A CN 109020443 B CN109020443 B CN 109020443B
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parts
quartz sand
agent
dry powder
water
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CN109020443A (en
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张立功
张宪
于春生
陈晨
郭显松
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Lanshe Diatom New Material Co ltd
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Lanshe Diatom New Material Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Paints Or Removers (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The rust stone effect imitating dry powder coating comprises a bottom material and a finish coat, wherein the bottom material comprises special white cement, 16-18 meshes of quartz sand, 20-40 meshes of quartz sand, 80-120 meshes of quartz sand, 90-130 meshes of quartz sand, iron sand, natural gypsum, sodium chloride, redispersible latex powder, hydroxypropyl methyl cellulose, cellulose ether, a water repellent, a retarder, a mildew preventive and an inorganic toner; the finish coat comprises water, water-based finish coat emulsion, a leveling agent, a film forming auxiliary agent, a defoaming agent, an anti-aging agent, a preservative, a bactericide and a thickening agent. According to the invention, through compounding of the materials, the metal sand is quickly rusted in the drying process of the coating, and a surface layer is coated after the coating is dried to fix the rusty color. Thereby achieving the surface effect of the rust stone. The paint is suitable for inner and outer wall decoration surface layers, stone carving surface decoration layers and the like, has good adhesive force with a base material, and has good weather resistance.

Description

Rusty stone effect imitating dry powder coating and preparation method thereof
Technical Field
The invention belongs to the technical field of building coatings, and particularly relates to a dry powder type rust stone imitating coating and a preparation method thereof.
Background
The rusty stone is a mineral stone in the nature, the unique appearance effect of the rusty stone is always the favorite of architectural designers, but the natural rusty stone is expensive, and the possible color difference of mass production is large; the development of the rust effect in the field of building design is limited by the defects of small yield of high-quality rust without black spots, multiple rusts and clear and visible rusty spots. The invention patent with application number of 201511003800.X provides a stone-like dry powder coating and a construction method thereof, a simple rust stone-like effect can be achieved by adding toner and colored sand, but the simulation degree is not high, the texture of natural rust stone is not achieved, and the actual rust stone-like effect is difficult to achieve by the conventional stone-like dry powder coating.
Therefore, there is a need in the art for a new solution to solve this problem.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the materials are added with sodium chloride, cement and other materials, so that a large amount of electrolytes are ionized in the water adding process of the dry powder coating, the reaction of a galvanic cell with iron oxidation and rusting is accelerated, the iron powder is quickly rusted in the drying process of the coating, a surface layer is painted after the drying, the rust color is fixed, and the surface effect of the rusty stone is achieved.
Meanwhile, the raw material can be industrial waste iron powder, so that waste resources are recycled, and the method is environment-friendly and sustainable.
The rust stone imitating effect dry powder coating is characterized in that: the primer comprises 80-120 parts of special white cement, 0-300 parts of 16-18-mesh quartz sand, 140-220 parts of 20-40-mesh quartz sand, 240 parts of 80-120-mesh quartz sand, 160 parts of 90-130-mesh quartz sand, 20-30 parts of iron powder, 20-30 parts of gypsum, 10-15 parts of sodium chloride, 50-60 parts of redispersible latex powder, 3-5 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 6-10 parts of a water repellent, 1-2 parts of a retarder, 3-5 parts of a mildew preventive and 0-15 parts of an inorganic toner;
the finishing coat comprises, by weight, 400-500 parts of water, 470-520 parts of water-based finishing emulsion, 2-4 parts of a leveling agent, 7-15 parts of a film-forming additive, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 0.5-2 parts of a preservative, 1-2 parts of a bactericide and 0.5-1.5 parts of a thickener.
The base material comprises, by weight, 100-120 parts of special white cement, 150-180 parts of 16-18-mesh quartz sand, 140-150 parts of 20-40-mesh quartz sand, 220-240 parts of 80-120-mesh quartz sand, 150-160 parts of 90-130-mesh quartz sand, 20 parts of iron powder, 20-25 parts of gypsum, 10-15 parts of sodium chloride, 50-55 parts of redispersible latex powder, 2-4 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 8-10 parts of a water repellent, 1-1.5 parts of a retarder and 3-5 parts of a mildew preventive;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
The base material comprises, by weight, 90-100 parts of special white cement, 270-300 parts of 20-40-mesh quartz sand, 220-250 parts of 80-120-mesh quartz sand, 150-160 parts of 90-130-mesh quartz sand, 30 parts of iron powder, 20-30 parts of gypsum, 10-15 parts of sodium chloride, 55-60 parts of redispersible latex powder, 3-5 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 8-10 parts of a water repellent, 1.5-2 parts of a retarder and 3-5 parts of a mildew preventive;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
The bottom material also comprises yellow quartz sand of 20 meshes to 40 meshes or red quartz sand of 20 meshes to 40 meshes.
The mildew preventive comprises a dry film mildew preventive TIO-20.
The bactericide comprises ROCIMA623 and LXZ bactericide.
The antifoaming agent comprises A203E antifoaming agent, A10 antifoaming agent and NXZ antifoaming agent.
The thickener comprises 3500 thickener.
The gypsum contains a sulfur trioxide strong oxidizer.
The preparation method of the rusty stone imitating effect dry powder coating is characterized by comprising the following steps: comprises a method for preparing a primer and a finish coat, and the following steps are carried out in sequence,
the method for preparing the bottom material comprises the following steps:
step one, putting the redispersible latex powder, hydroxypropyl methyl cellulose, cellulose ether, a water repellent and a retarder into a No. 1 stirring tank according to the proportion, and premixing for 10 minutes at the rotating speed of 300 revolutions per minute to obtain a premix;
step two, putting white cement, quartz sand, iron powder, gypsum, sodium chloride and the premix obtained in the step one into a No. 2 stirring tank according to the proportion, mixing for 5 minutes at the rotating speed of 200 revolutions per minute, adding a mildew preventive, and stirring for 15 minutes to obtain a finished product powder base material;
the manufacturing method of the finish paint comprises the following steps:
adjusting the rotating speed of the high-speed dispersion mixer to 200 revolutions per minute, sequentially adding water, a defoaming agent, a bactericide, a preservative, a film-forming assistant and a thickening agent according to the mixture ratio, stirring for 10-15 minutes, adjusting the rotating speed of the high-speed dispersion mixer to 400 revolutions per minute, adding the aqueous finish emulsion, and stirring for 15-20 minutes to obtain the finished finish paint.
Through the design scheme, the invention can bring the following beneficial effects: the rust stone imitating effect dry powder coating and the preparation method thereof use real rust to make the rust stone imitating effect, achieve the maximum simulation degree, are suitable for various base materials, have excellent adhesive force, greatly reduce the cost, are easy to construct, are environment-friendly, have light dead weight and no radiation, create various decorative effects by adjusting sand stone materials with different colors and adding different toners, and can be stably produced in large batch and meet the requirements of building design.
Detailed Description
The invention will be further described with reference to specific embodiments: the rust stone effect imitating dry powder coating comprises a backing material and a finish coat, wherein the backing material comprises 80-120 parts by weight of special white cement, 0-300 parts by weight of 16-18-mesh quartz sand, 140-220 parts by weight of 20-40-mesh quartz sand, 240 parts by weight of 80-120-mesh quartz sand, 160 parts by weight of 90-130-mesh quartz sand, 20-30 parts by weight of iron powder, 20-30 parts by weight of gypsum, 10-15 parts by weight of sodium chloride, 50-60 parts by weight of redispersible latex powder, 3-5 parts by weight of hydroxypropyl methyl cellulose, 7-9 parts by weight of cellulose ether, 6-10 parts by weight of a water repellent, 1-2 parts by weight of a retarder, 3-5 parts by weight of a mildew preventive and 0-15 parts by weight of an inorganic toner;
the finishing coat comprises, by weight, 400-500 parts of water, 470-520 parts of water-based finishing emulsion, 2-4 parts of a leveling agent, 7-15 parts of a film-forming additive, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 0.5-2 parts of a preservative, 1-2 parts of a bactericide and 0.5-1.5 parts of a thickener.
Wherein the viscosity of the hydroxypropyl methyl cellulose in the base material is 10 ten thousand; the brand of the re-dispersible latex powder is German Wake 821 rubber powder.
Example one, preferably, a coarse-grained rustic stone imitating effect dry powder coating,
the primer comprises 100 parts of special white cement, 160 parts of 16-18 mesh quartz sand, 140 parts of 20-40 mesh quartz sand, 240 parts of 80-120 mesh quartz sand, 160 parts of 90-130 mesh quartz sand, 20 parts of iron powder, 20 parts of gypsum, 15 parts of sodium chloride, 50 parts of redispersible emulsion powder, 3 parts of hydroxypropyl methyl cellulose, 7 parts of cellulose ether, 10 parts of a water repellent, 1.5 parts of a retarder and 3 parts of a mildew inhibitor according to the weight part ratio;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
Example two, preferably, a fine-grained rustic stone imitating effect dry powder coating,
the primer comprises 100 parts of special white cement, 300 parts of 20-40 mesh quartz sand, 240 parts of 80-120 mesh quartz sand, 160 parts of 90-130 mesh quartz sand, 30 parts of iron powder, 20 parts of gypsum, 15 parts of sodium chloride, 50 parts of redispersible latex powder, 3 parts of hydroxypropyl methyl cellulose, 7 parts of cellulose ether, 10 parts of a water repellent, 2 parts of a retarder and 3 parts of a mildew preventive according to the weight part ratio;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
Example three, preferably, a color sand rust imitating effect dry powder coating,
the white cement comprises a base material and a finish coat, wherein the base material comprises 100 parts of special white cement and 200 parts of 20-40-mesh quartz sand in parts by weight; 50 parts of yellow quartz sand of 20-40 meshes; 50 parts of 20-40-mesh red quartz sand; 240 parts of 80-120 mesh quartz sand; 160 parts of 90-130 mesh quartz sand; 30 parts of iron powder; 20 parts of gypsum; 15 parts of sodium chloride and 50g of redispersible latex powder; 4g of hydroxypropyl methyl cellulose; 7g of cellulose ether; 10 parts of a water repellent; 1.5 parts of retarder; 3 parts of a mildew preventive;
the formula of the finishing paint is as follows: 450-470 parts of water; 450 to 480 parts of water-based cover emulsion; 3-5 parts of a leveling agent; 10-15 parts of a film-forming assistant; and 4-6 parts of a defoaming agent. 1 to 3 parts of anti-aging agent, 1 to 2 parts of preservative, 1 part of bactericide and 0.5 to 1 part of thickening agent.
The preparation method of the rusty stone imitating effect dry powder coating is characterized by comprising the following steps: comprises the following steps which are sequentially carried out,
step one, putting the redispersible latex powder, hydroxypropyl methyl cellulose, cellulose ether, a water repellent and a retarder into a No. 1 stirring tank according to the proportion, and premixing for 15 minutes at the rotating speed of 300 revolutions per minute to obtain a premixed dry powder;
step two, putting white cement, quartz sand, iron powder, gypsum, sodium chloride and the premix obtained in the step one into a No. 2 stirring tank according to the proportion, mixing for 5 minutes at the rotating speed of 200 revolutions per minute, adding a mildew preventive, and stirring for 15 minutes to obtain a finished product base material;
and step three, adjusting the rotating speed of the high-speed dispersion mixer to 200 revolutions per minute, sequentially adding water, a defoaming agent, a bactericide, a preservative, a film-forming assistant and a thickening agent according to the mixture ratio, stirring for 10 to 15 minutes, adjusting the rotating speed of the high-speed dispersion mixer to 400 revolutions per minute, adding the water-based finish emulsion, and stirring for 15 to 20 minutes to obtain the finished finish paint.
The use method of the finished product comprises the following steps:
(1) the use method of the bottom layer dry powder comprises the following steps:
according to the water adding proportion (by weight): take 10kg as an example, according to the following ratio of 1: adding 0.2 +/-0.02 of water, and stirring for 3 minutes by using an electric hand drill with the power of 1200W and the rotating speed of 0-1000 rpm;
uniformly spraying the uniformly stirred paste on the surface of the object to be brushed by using a funnel spray gun with the caliber of 1.8mm,the spraying amount is about 2 kg/m2～2.5kg/m2(the paste is sprayed within 25 minutes, the construction is in a suitable environment with the temperature of 5-35 ℃ and the air humidity of 50-80%).
(2) After the primer layer is completely dried (approximately 5 h) the finish is sprayed: the spray amount of a suspended kettle spray gun with the model number of w-71 is about 100g/m2And naturally drying to obtain the finished product.
(3) If the surface is required to be smooth, the primer layer is dried and then polished by a 100-150-mesh abrasive cloth, and then the finish paint is sprayed.

Claims (10)

1. The rust stone imitating effect dry powder coating is characterized in that: the primer comprises 80-120 parts of special white cement, 0-300 parts of 16-18-mesh quartz sand, 140-220 parts of 20-40-mesh quartz sand, 220-250 parts of 80-120-mesh quartz sand, 140-160 parts of 90-130-mesh quartz sand, 20-30 parts of iron powder, 20-30 parts of gypsum, 10-15 parts of sodium chloride, 50-60 parts of redispersible latex powder, 3-5 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 6-10 parts of a water repellent, 1-2 parts of a retarder, 3-5 parts of a mildew preventive and 0-15 parts of an inorganic toner;
the finishing coat comprises, by weight, 400-500 parts of water, 470-520 parts of water-based finishing emulsion, 2-4 parts of a leveling agent, 7-15 parts of a film-forming additive, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 0.5-2 parts of a preservative, 1-2 parts of a bactericide and 0.5-1.5 parts of a thickener.
2. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the base material comprises, by weight, 100-120 parts of special white cement, 150-180 parts of 16-18-mesh quartz sand, 140-150 parts of 20-40-mesh quartz sand, 220-240 parts of 80-120-mesh quartz sand, 150-160 parts of 90-130-mesh quartz sand, 20 parts of iron powder, 20-25 parts of gypsum, 10-15 parts of sodium chloride, 50-55 parts of redispersible latex powder, 2-4 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 8-10 parts of a water repellent, 1-1.5 parts of a retarder and 3-5 parts of a mildew preventive;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
3. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the base material comprises, by weight, 90-100 parts of special white cement, 270-300 parts of 20-40-mesh quartz sand, 220-250 parts of 80-120-mesh quartz sand, 150-160 parts of 90-130-mesh quartz sand, 30 parts of iron powder, 20-30 parts of gypsum, 10-15 parts of sodium chloride, 55-60 parts of redispersible latex powder, 3-5 parts of hydroxypropyl methyl cellulose, 7-9 parts of cellulose ether, 8-10 parts of a water repellent, 1.5-2 parts of a retarder and 3-5 parts of a mildew preventive;
the finishing paint comprises, by weight, 450-470 parts of water, 450-480 parts of water-based finishing emulsion, 3-5 parts of a leveling agent, 10-15 parts of a film-forming aid, 4-6 parts of a defoaming agent, 1-3 parts of an anti-aging agent, 1-2 parts of a preservative, 1 part of a bactericide and 0.5-1 part of a thickener.
4. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the bottom material also comprises yellow quartz sand of 20 meshes to 40 meshes or red quartz sand of 20 meshes to 40 meshes.
5. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the mildew preventive comprises a dry film mildew preventive TIO-20.
6. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the bactericide comprises ROCIMA623 and LXZ bactericide.
7. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the antifoaming agent comprises A203E antifoaming agent, A10 antifoaming agent and NXZ antifoaming agent.
8. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the thickener comprises 3500 thickener.
9. The rust stone imitating effect dry powder coating as claimed in claim 1, wherein: the gypsum contains a sulfur trioxide strong oxidizer.
10. The method for preparing the rustic stone imitating effect dry powder coating according to claim 1, which is characterized in that: comprises a method for preparing a primer and a finish coat, and the following steps are carried out in sequence,
the method for preparing the bottom material comprises the following steps:
step one, putting the redispersible latex powder, hydroxypropyl methyl cellulose, cellulose ether, a water repellent and a retarder into a No. 1 stirring tank according to the proportion, and premixing for 10 minutes at the rotating speed of 300 revolutions per minute to obtain a premix;
step two, putting white cement, quartz sand, iron powder, gypsum, sodium chloride and the premix obtained in the step one into a No. 2 stirring tank according to the proportion, mixing for 5 minutes at the rotating speed of 200 revolutions per minute, adding a mildew preventive, and stirring for 15 minutes to obtain a finished product powder base material;
the manufacturing method of the finish paint comprises the following steps:
adjusting the rotating speed of the high-speed dispersion mixer to 200 revolutions per minute, sequentially adding water, a defoaming agent, a bactericide, a preservative, a film-forming assistant and a thickening agent according to the mixture ratio, stirring for 10-15 minutes, adjusting the rotating speed of the high-speed dispersion mixer to 400 revolutions per minute, adding the aqueous finish emulsion, and stirring for 15-20 minutes to obtain the finished finish paint.
CN201811048048.4A 2018-09-10 2018-09-10 Rusty stone effect imitating dry powder coating and preparation method thereof Active CN109020443B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971351B (en) * 2019-04-03 2021-05-25 东莞市尚兰科技有限公司 Imitation rust flowerpot, imitation rust paint and manufacturing process of imitation rust flowerpot
CN109988477A (en) * 2019-04-23 2019-07-09 广东金涂宝新材料股份有限公司 The aqueous imitative iron rust coating of one kind and its construction method
CN111187038B (en) * 2019-12-19 2022-05-13 深圳市点绿科技有限公司 Preparation method of rusty stone sand

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CN102261174A (en) * 2011-07-13 2011-11-30 罗笛峰 Complex metal rust paint plate as well as preparation method and application thereof
JP5175006B2 (en) * 2007-05-24 2013-04-03 和雄 吉澤 Artificial rust stone manufacturing method and bonsai rust stone thereby
CN205476181U (en) * 2016-01-04 2016-08-17 佛山市顺德区佳涂乐恒融建筑装饰有限公司 Imitative rust stone wall decorations layer structure
CN106630854A (en) * 2016-12-29 2017-05-10 中民筑友科技投资有限公司 Stone imitation concrete decoration plate and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5175006B2 (en) * 2007-05-24 2013-04-03 和雄 吉澤 Artificial rust stone manufacturing method and bonsai rust stone thereby
CN102261174A (en) * 2011-07-13 2011-11-30 罗笛峰 Complex metal rust paint plate as well as preparation method and application thereof
CN205476181U (en) * 2016-01-04 2016-08-17 佛山市顺德区佳涂乐恒融建筑装饰有限公司 Imitative rust stone wall decorations layer structure
CN106630854A (en) * 2016-12-29 2017-05-10 中民筑友科技投资有限公司 Stone imitation concrete decoration plate and preparation method thereof

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