CN109988477A - The aqueous imitative iron rust coating of one kind and its construction method - Google Patents
The aqueous imitative iron rust coating of one kind and its construction method Download PDFInfo
- Publication number
- CN109988477A CN109988477A CN201910330721.1A CN201910330721A CN109988477A CN 109988477 A CN109988477 A CN 109988477A CN 201910330721 A CN201910330721 A CN 201910330721A CN 109988477 A CN109988477 A CN 109988477A
- Authority
- CN
- China
- Prior art keywords
- iron rust
- agent
- solution
- rust coating
- construction method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 68
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 34
- 238000000576 coating method Methods 0.000 title claims abstract description 29
- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 238000010276 construction Methods 0.000 title claims abstract description 21
- 239000003973 paint Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 6
- 239000000417 fungicide Substances 0.000 claims abstract description 6
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 230000001680 brushing effect Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000007761 roller coating Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 23
- 238000005260 corrosion Methods 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 10
- 230000036632 reaction speed Effects 0.000 abstract description 4
- 239000000758 substrate Substances 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 24
- 239000000945 filler Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000002421 finishing Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000012173 sealing wax Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Abstract
The present invention discloses a kind of aqueous imitative iron rust coating, including mian paint and solution, the mian paint, including following each component and its mass percent: water 15%-25%, fungicide 0.1%-0.2%, inorganic thickening agent 0.1%-0.4%, pH adjusting agent 0.1%-0.2%, defoaming agent 0.1%-0.2%, dispersing agent 0.1%-0.3%, wetting agent 0.1%-0.2%, functional stuffing 40%-50%, coarse whiting 10%-20%, acrylic emulsion 10%-15%, coalescing agent 0.2%-0.4%, anti-flash rusting auxiliary agent 0.1%-0.3%, thickener 0.1%-0.3%；The solution, including following each component and its mass percent: water 94.5%-97.5%, metal salt 2%-5%；The aqueous imitative iron rust coating of the present invention has the advantages that quick, imitative iron rust effect is good；The invention also discloses a kind of construction methods of aqueous imitative iron rust coating, and class corrosion effect can be made in wide variety of substrates, and compared to traditional construction method, easy to operate, easy, reaction speed is fast, and producing efficiency is high.
Description
Technical field:
The present invention relates to technical field of coatings, especially a kind of aqueous imitative iron rust coating and its construction method.
Background technique:
Currently, the finishings such as household and hotel eatery are more and more applied using personalized art with the prevalence of artistic coating
Dress, including various art coatings effects, such as: it is texture, stamp, pearly-lustre, modelled after an antique.Wherein corrosion belongs to antique effect
One kind, corrosion effect can found out a kind of sense of age, antiquated sense, there is its unique wind in bar, shop, theme dining room finishing
Lattice.Currently, corrosion effect production method is usually irony device to be accelerated to generate rust staining with brine corrosion, or directly use coating
Adjust advancing colour construction.Both methods, the former speed is slower, generally requires a few houres or even a couple of days is differed, and salt water is rotten
After erosion, corrosion is easy to be continued for, and destroys irony ground；The latter's coating effect similarity is not high, and effect is undesirable.
Summary of the invention:
The purpose of the present invention is to provide a kind of aqueous imitative iron rust coating that quick, imitative iron rust effect is good.
Another object of the present invention also reside in provide it is a kind of implement be easy, quickly aqueous imitative iron rust coating application method.
Following technical scheme has can be used in the purpose of the present invention:
A kind of aqueous imitative iron rust coating, characterized in that including mian paint and solution；
The mian paint, including following each component and its mass percent: water 15%-25%, fungicide 0.1%-0.2%, inorganic increasing
Thick dose of 0.1%-0.4%, pH adjusting agent 0.1%-0.2%, defoaming agent 0.1%-0.2%, dispersing agent 0.1%-0.3%, wetting agent
0.1%-0.2%, functional stuffing 40%-50%, coarse whiting 10%-20%, acrylic emulsion 10%-15%, coalescing agent 0.2%-0.4% prevent
Flash rusting auxiliary agent 0.1%-0.3%, thickener 0.1%-0.3%；
The solution, including following each component and its mass percent: water 94.5%-97.5%, metal salt 2%-5%.
Wherein, water is mentioned as in-can preservative, inorganic thickening agent as formula system as sealing wax decentralized medium, fungicide
For rheological characteristic, pH adjusting agent is alkalinity for regulation system pH, and alkaline environment is conducive to the stabilization of in-can preservation and pigments and fillers,
Defoaming agent can eliminate the bubble generated in work progress, and dispersing agent is used for stably dispersing pigments and fillers, and wetting agent is wetting pigments and fillers,
For functional stuffing for filling and iron rust effect, coarse whiting is filling effect, and acrylic emulsion is film forming matter, cementation, film forming
Auxiliary agent can reduce the film-forming temperature of film forming matter, and for preventing flash rusting in construction flash rusting and tank, thickener is to provide anti-flash rusting auxiliary agent
Certain rheological properties, convenient for construction and storage.
Here several important components, the respectively functional stuffing and acrylic emulsion of mian paint, the gold in solution are mainly introduced
Belong to salt and weak acid, effect and adding proportion, functional stuffing is specific function filler, its effect is that mian paint surface is solid
After film forming layer, functional stuffing can react with solution, generate class iron rust effect, the adding proportion of functional stuffing 40-50% can
To ensure to have in dry film enough such fillers to react with solution, it is ensured that can finally obtain apparent class iron rust effect；
Acrylic emulsion is copolymer resin, plays bonding film forming, this relatively relatively low adding proportion of 10-15% can be with
In the case where ensuring that the filler in film dry film obtains bonding enough, and it can avoid filler surface and all coated and dropped by resin
Low-function filler particular fillers and solution reaction generate the efficiency of iron rust.
Metal salt in solution reacts on the surface of functional stuffing, generates class iron rust effect, and weak acid can help
The oxidation film on functional stuffing surface, promotion functions filler and reacting metal salt are eliminated, the formation speed of iron rust effect is greatly speeded up.
It is another object of the present invention to what is be achieved:
A kind of construction method of aqueous imitative iron rust coating, characterized in that first mian paint obtained is arranged on ground, it is dry to mian paint
Gu after film forming layer, then solution arranged in the film layer of ground.
Further, the mian paint by roller coating, drape over one's shoulders and scrape, be arranged on ground in a manner of brushing.
Further, the mian paint is arranged needs environment temperature control at 20-30 DEG C in ground, and 50%-70% humidity environment
Under, waiting 30-50 minutes can solid film forming layer.
Further, the solution is arranged in the film layer of ground in a manner of smearing or being added dropwise, in 2-8 minutes, in film layer
Apparent color reaction can occur for the place for speckling with solution, generate reddish brown chromatograph.
Further, after the solution evaporation is retreated, the reddish brown chromatograph becomes dark reddish brown layer.
The construction method of the aqueous imitative iron rust coating, it is easy to operate, and can quickly obtain corrosion effect;Concrete scheme
Construction process it is as follows: contain a kind of functional stuffing in mian paint component, after mian paint drying and forming-film, this functional stuffing is distributed in film
Layer surface.Solution can be chemically reacted with this functional stuffing in mian paint component, generated bronzing in filler surface and produced
Object；The shade of bronzing product and the thickness of mian paint, the length in solution each component reaction time and solution have a relationship, and one
As for, in 5 minutes, the time is longer, and color is deeper, and after five minutes, color is no longer deepened, when solution is more (as: thickness apply) produce
Raw bronzing product is deeper, and bronzing is shallower when (scumbling) when less；The present invention can make class corrosion effect in wide variety of substrates,
Simple to operate compared to traditional production method, reaction speed is fast, and producing efficiency is high.
Beneficial effects of the present invention are as follows:
(1) aqueous imitative iron rust coating of the invention has the advantages that quick, imitative iron rust effect is good.
(2) construction method of the aqueous imitative iron rust coating of the present invention, can make class corrosion effect in wide variety of substrates, compared to
Traditional construction method, easy to operate, easy, reaction speed is fast, and producing efficiency is high.
Specific embodiment:
The present invention is further described combined with specific embodiments below.
A kind of aqueous imitative iron rust coating, characterized in that including mian paint and solution；
The mian paint, including following each component and its mass percent: water 15%-25%, fungicide 0.1%-0.2%, inorganic increasing
Thick dose of 0.1%-0.4%, pH adjusting agent 0.1%-0.2%, defoaming agent 0.1%-0.2%, dispersing agent 0.1%-0.3%, wetting agent
0.1%-0.2%, functional stuffing 40%-50%, coarse whiting 10%-20%, acrylic emulsion 10%-15%, coalescing agent 0.2%-0.4% prevent
Flash rusting auxiliary agent 0.1%-0.3%, thickener 0.1%-0.3%；
The solution, including following each component and its mass percent: water 94.5%-97.5%, metal salt 2%-5%.
Example 1: aqueous imitative iron rust coating, including mian paint and solution；
The mian paint, including following each component and its mass percent: water 20%, fungicide 0.15%, inorganic thickening agent
0.15%, pH adjusting agent 0.2%, defoaming agent 0.2%, dispersing agent 0.2%, wetting agent 0.15%, functional stuffing 50%, coarse whiting
18.25%, acrylic emulsion 10%, coalescing agent 0.3%, anti-flash rusting auxiliary agent 0.2%, thickener 0.2%；
The solution, including following each component and its mass percent: water 96%, metal salt 4%.
Mian paint obtained above and solution, mass ratio can be determined by user oneself according to actual needs.
A kind of construction method of aqueous imitative iron rust coating, characterized in that first arrange mian paint obtained on ground, wait lead
After Qi Gangu film forming layer, then solution arranged in the film layer of ground.
As more specific scheme, the mian paint by roller coating, drape over one's shoulders and scrape, be arranged on ground in a manner of brushing.The mian paint is applied
Being located at ground needs environment temperature control at 20-30 DEG C, and under 50%-70% humidity environment, waits solid can form a film within 30-50 minutes
Layer.The solution is arranged in the film layer of ground in a manner of smearing or being added dropwise, and the place of solution is speckled in 2-8 minutes, in film layer
Apparent color reaction can occur, generate reddish brown chromatograph.After the solution evaporation is retreated, the reddish brown chromatograph becomes dark reddish brown
Layer.
Aqueous imitative iron rust coating of the invention has the advantages that quick, imitative iron rust effect is good.
The construction method of the aqueous imitative iron rust coating of the present invention, can make class corrosion effect, compared to biography in wide variety of substrates
The construction method of system, easy to operate, easy, reaction speed is fast, and producing efficiency is high.
Certainly, the above description is only a specific example of the present invention, be not to limit practical range of the invention, it is all according to
The equivalent change or modification that structure, feature and principle described in scope of the present invention patent is done should be included in Shen of the present invention
It please be in the scope of the patents.
Claims (6)
1. a kind of aqueous imitative iron rust coating, characterized in that including mian paint and solution；
The mian paint, including following each component and its mass percent: water 15%-25%, fungicide 0.1%-0.2%, inorganic increasing
Thick dose of 0.1%-0.4%, pH adjusting agent 0.1%-0.2%, defoaming agent 0.1%-0.2%, dispersing agent 0.1%-0.3%, wetting agent
0.1%-0.2%, functional stuffing 40%-50%, coarse whiting 10%-20%, acrylic emulsion 10%-15%, coalescing agent 0.2%-0.4% prevent
Flash rusting auxiliary agent 0.1%-0.3%, thickener 0.1%-0.3%；
The solution, including following each component and its mass percent: water 94.5%-97.5%, metal salt 2%-5%.
2. a kind of construction method of aqueous imitative iron rust coating as described in claim 1, characterized in that first arrange mian paint obtained
On ground, arranged in the film layer of ground after the solid film forming layer of mian paint, then by solution.
3. the construction method of aqueous imitative iron rust coating according to claim 2, characterized in that the mian paint with roller coating, drape over one's shoulders scrape,
Brushing mode is arranged on ground.
4. the construction method of aqueous imitative iron rust coating according to claim 2, characterized in that the mian paint is arranged to be needed in ground
Environment temperature is controlled at 20-30 DEG C, and under 50%-70% humidity environment, and waiting 30-50 minutes can solid film forming layer.
5. the construction method of aqueous imitative iron rust coating according to claim 2, characterized in that the solution is to smear or be added dropwise
Mode is arranged in the film layer of ground, and apparent color reaction can occur for the place that solution is speckled in 2-8 minutes, in film layer, raw
At reddish brown chromatograph.
6. the construction method of aqueous imitative iron rust coating according to claim 5, characterized in that after the solution evaporation is retreated,
The reddish brown chromatograph becomes dark reddish brown layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910330721.1A CN109988477A (en) | 2019-04-23 | 2019-04-23 | The aqueous imitative iron rust coating of one kind and its construction method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910330721.1A CN109988477A (en) | 2019-04-23 | 2019-04-23 | The aqueous imitative iron rust coating of one kind and its construction method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109988477A true CN109988477A (en) | 2019-07-09 |
Family
ID=67135227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910330721.1A Pending CN109988477A (en) | 2019-04-23 | 2019-04-23 | The aqueous imitative iron rust coating of one kind and its construction method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109988477A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804346A (en) * | 2019-11-11 | 2020-02-18 | 河南大向展陈文化发展有限公司 | Rust-imitating paint, preparation method thereof and rust-imitating method |
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|---|---|---|---|---|
| WO1995029207A1 (en) * | 1994-04-26 | 1995-11-02 | Copper Refineries Pty. Ltd. | Artificial patina |
| CN1643182A (en) * | 2002-04-09 | 2005-07-20 | 奥托库姆普联合股份公司 | Method for preparing patination materials and patination material |
| CN201700533U (en) * | 2010-04-16 | 2011-01-12 | 南昌市汉霖工贸有限公司 | Rusty metal zipper head |
| CN102261174A (en) * | 2011-07-13 | 2011-11-30 | 罗笛峰 | Complex metal rust paint plate as well as preparation method and application thereof |
| CN106824719A (en) * | 2017-01-11 | 2017-06-13 | 上海衡峰氟碳材料有限公司 | A kind of steel fluorine carbon rust skill paint coating process |
| CN109020443A (en) * | 2018-09-10 | 2018-12-18 | 兰舍硅藻新材料有限公司 | Imitative rust stone effect dry powder paint and preparation method thereof |
-
2019
- 2019-04-23 CN CN201910330721.1A patent/CN109988477A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995029207A1 (en) * | 1994-04-26 | 1995-11-02 | Copper Refineries Pty. Ltd. | Artificial patina |
| CN1643182A (en) * | 2002-04-09 | 2005-07-20 | 奥托库姆普联合股份公司 | Method for preparing patination materials and patination material |
| CN201700533U (en) * | 2010-04-16 | 2011-01-12 | 南昌市汉霖工贸有限公司 | Rusty metal zipper head |
| CN102261174A (en) * | 2011-07-13 | 2011-11-30 | 罗笛峰 | Complex metal rust paint plate as well as preparation method and application thereof |
| CN106824719A (en) * | 2017-01-11 | 2017-06-13 | 上海衡峰氟碳材料有限公司 | A kind of steel fluorine carbon rust skill paint coating process |
| CN109020443A (en) * | 2018-09-10 | 2018-12-18 | 兰舍硅藻新材料有限公司 | Imitative rust stone effect dry powder paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴15338719978: "仿铁锈漆", 《百度知道》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804346A (en) * | 2019-11-11 | 2020-02-18 | 河南大向展陈文化发展有限公司 | Rust-imitating paint, preparation method thereof and rust-imitating method |
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Application publication date: 20190709 |