CN108485427A - A kind of high texture imitates sandstone coating and preparation method thereof - Google Patents

A kind of high texture imitates sandstone coating and preparation method thereof Download PDF

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Publication number
CN108485427A
CN108485427A CN201810229112.2A CN201810229112A CN108485427A CN 108485427 A CN108485427 A CN 108485427A CN 201810229112 A CN201810229112 A CN 201810229112A CN 108485427 A CN108485427 A CN 108485427A
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Prior art keywords
parts
coating
imitates
high texture
sandstone
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CN201810229112.2A
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Chinese (zh)
Inventor
侯进全
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Habitat (shanghai) Polytron Technologies Inc
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Habitat (shanghai) Polytron Technologies Inc
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Priority to CN201810229112.2A priority Critical patent/CN108485427A/en
Publication of CN108485427A publication Critical patent/CN108485427A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to a kind of high texture to imitate sandstone coating, including following components and parts by weight content：10 20 parts of silicone acrylic emulsion, 10 15 parts of natural colour sand, 24 parts of pigment of reflection, 35 parts of ceramic microsphere, 46 parts of reflective insulation powder, 12 parts of calcium formate, 1 1.5 parts of bentonite, 0.5 1 parts of lignocellulosic, 23 parts of rubber powder, 45 parts of coalescents, 57 parts of dispersant, 45 parts of antifoaming agent, 23 parts of thickener, 20 30 parts of deionized water.Compared with prior art, coating of the present invention mixes natural colour sand with ceramic microsphere progress grading, is dispersed in coating, enhances sandstone texture, the reflection pigment and reflective insulation powder of addition enhance the reflecting feel of coating.The addition of calcium formate, bentonite, lignocellulosic and rubber powder, improve the compatibility of the organic components such as silicone acrylic emulsion and inorganic component, the adhesion strength for improving coating ensures, in the case where adding a large amount of inorganic component, still to keep preferable impact resistance.

Description

A kind of high texture imitates sandstone coating and preparation method thereof
Technical field
The present invention relates to a kind of stone-like coatings, and sandstone coating and preparation method thereof is imitated more particularly, to a kind of high texture.
Background technology
Stone-like coating is widely popularized on building materials industry exterior wall interior wall, and stone-like coating is also known as lacquer, is It is equipped with the decorating inner and external walls coating that lithotome pulverized particles are main raw material(s) with synthetic resin emulsion.Lacquer China most It early appears in the 1980s, the annual project for selecting lacquer can be more and more at present, although stone-like coating is with imitative natural Based on stone material, its color is imitated, is also only limited to carry out construction usage at project scene, due to site environment (scaffold Build, weather, basal plane) etc. reasons, live stone-like coating using when will appear floating phenomena such as.Present stone-like coating in toning and True stone material color can only be imitated in work progress, but the smoothness of the natural texture and surface for some stone materials It can not be imitated, some high-grade stone markets cannot be promoted due to this.
Chinese patent CN104974621A discloses a kind of environment-friendly water-soluble and imitates sandstone decorative paint and its application, by setting Fat synthetic emulsion is mixed to form with natural colour sand；Imitative sandstone decorative paint is for manufacturing imitative sandstone decorative paint production board, method It is as follows：Stone base paint special is imitated in roller coating first on cladding production board, forms prime coat；Trowelling or spraying are imitated sandstone decoration and are applied Material forms first layer and imitates sandstone decorative coveringn；It carries out spraying again or trowelling imitates sandstone decorative paint, form making for setting Type forms the second layer and imitates sandstone decorative coveringn；Sandstone decorative coveringn surface roller coating profession protective topcoat is imitated in the second layer, is formed and is protected Sheath.But sandstone is laborious on building occupancy, and technique is cumbersome, and costly, the quality for imitating sandstone coating is not fully up to expectations for price.
Invention content
The purpose of the present invention is exactly to solve the above-mentioned problems and provides a kind of high texture and imitate sandstone coating and its preparation side Method.
The purpose of the present invention is achieved through the following technical solutions：
A kind of imitative sandstone coating of high texture, including following components and parts by weight content：10-20 parts of silicone acrylic emulsion, natural color 10-15 parts of sand, 2-4 parts of pigment of reflection, 3-5 parts of ceramic microsphere, 4-6 parts of reflective insulation powder, 1-2 parts of calcium formate, bentonite 1-1.5 Part, 0.5-1 parts of lignocellulosic, 2-3 parts of rubber powder, 4-5 parts of coalescents, 5-7 parts of dispersant, 4-5 parts of antifoaming agent, thickener 2- 3 parts, 20-30 parts of deionized water.
The natural colour sand granularity is selected from 50-70 mesh.
The reflection pigment is titanium dioxide.
The reflective insulation powder is any one or more in aluminium oxide, iron oxide or copper oxide.
The grain size of the ceramic microsphere is 20-40 mesh.
The rubber powder is cinnamic acrylic ester or VAE rubber powders.
The coalescents be propandiol butyl ether, propylene glycol methyl ether acetate, butyl glycol ether or propylene glycol phenylate one Kind is a variety of.
The dispersant is polycarboxylate sodium's anionic dispersing agents.
The thickener is polyurethanes thickener, and the antifoaming agent is metal soap antifoaming agent.
A kind of high texture imitates the preparation method of sandstone coating, includes the following steps：
(1) natural colour sand, reflection pigment, ceramic microsphere and reflective insulation powder are uniformly mixed；
(2) silicone acrylic emulsion, lignocellulosic and rubber powder are uniformly mixed；
(3) mixture that step (1) and step (2) obtain is mixed, and sequentially add calcium formate, bentonite, at Film auxiliary agent, dispersant, antifoaming agent, thickener and deionized water are dispersed with stirring uniformly, obtain product.
Compared with prior art, it is 20- by natural colour sand and grain size that granularity is 50-70 mesh in formulation for coating material of the present invention The ceramic microsphere of 40 mesh carries out grading mixing, and the ceramic microsphere of small particle contributes to natural colour sand point with after natural colour sand doping It is dispersed in coating, enhances sandstone texture.The reflection pigment and reflective insulation powder of this formula addition, enhance the gloss of coating Sense, reflection pigment titanium white main component are the white pigment of titanium dioxide, are a kind of polycrystalline compounds, and particle is arranged in rule Row have grid system, are added into this coating together with reflective insulation powder, significantly improve the quality gloss of coating.And it is Inorganic matter can be mixed well with ceramic microsphere and natural colour sand.Calcium formate, bentonite, lignocellulosic and rubber powder add Add, improve the compatibility of the organic components such as silicone acrylic emulsion and inorganic component, improve the adhesion strength of coating, ensures adding In the case of a large amount of inorganic component, coating still keeps preferable impact resistance, improves product quality.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail, but should be in no way restrictive.
Embodiment 1
A kind of imitative sandstone coating of high texture, including following components and content：It is silicone acrylic emulsion 10kg, natural colour sand 10kg, anti- Penetrate pigment 2kg, ceramic microsphere 3kg, reflective insulation powder 4kg, calcium formate 1kg, bentonite 1kg, lignocellulosic 0.5kg, rubber powder 2kg, coalescents 4kg, dispersant 5kg, antifoaming agent 4kg, thickener 2kg, deionized water 20kg.
Wherein, natural colour sand granularity is in 50-70 mesh, and for the grain size of ceramic microsphere in 20-40 mesh, reflection pigment is titanium dioxide, Reflective insulation powder is aluminium oxide, and rubber powder is cinnamic acrylic ester, and coalescents are propandiol butyl ether, and dispersant is polycarboxylic acids Sodium salt anionic dispersing agents, thickener are polyurethanes thickener, and antifoaming agent is metal soap antifoaming agent.
When specific preparation, steps are as follows：
(1) natural colour sand, reflection pigment, ceramic microsphere and reflective insulation powder are uniformly mixed；
(2) silicone acrylic emulsion, lignocellulosic and rubber powder are uniformly mixed；
(3) mixture that step (1) and step (2) obtain is mixed, and sequentially add calcium formate, bentonite, at Film auxiliary agent, dispersant, antifoaming agent, thickener and deionized water are dispersed with stirring uniformly, obtain product.
Embodiment 2
A kind of imitative sandstone coating of high texture, including following components and content：It is silicone acrylic emulsion 15kg, natural colour sand 15kg, anti- Penetrate pigment 4kg, ceramic microsphere 5kg, reflective insulation powder 6kg, calcium formate 2kg, bentonite 1.5kg, lignocellulosic 1kg, rubber powder 3kg, coalescents 5kg, dispersant 7kg, antifoaming agent 5kg, thickener 3kg, deionized water 30kg.Wherein, natural colour sand granularity In 50-70 mesh, for the grain size of ceramic microsphere in 20-40 mesh, reflection pigment is titanium dioxide, and reflective insulation powder is iron oxide, and rubber powder is VAE rubber powders, coalescents are propandiol butyl ether, and dispersant is polycarboxylate sodium's anionic dispersing agents, and thickener is polyurethanes Thickener, antifoaming agent are metal soap antifoaming agent.
The preparation method is the same as that of Example 1.
Embodiment 3
A kind of imitative sandstone coating of high texture, including following components and content：It is silicone acrylic emulsion 17kg, natural colour sand 13kg, anti- Penetrate pigment 3kg, ceramic microsphere 4.2kg, reflective insulation powder 4.8kg, calcium formate 1.7kg, bentonite 1.3kg, lignocellulosic 0.9kg, rubber powder 2.5kg, coalescents 4.5kg, dispersant 6.3kg, antifoaming agent 4.7kg, thickener 2.5kg, deionized water 28kg.Wherein, natural colour sand granularity is in 50-70 mesh, and for the grain size of ceramic microsphere in 20-40 mesh, reflection pigment is titanium dioxide, reflection Heat-insulating powder is iron oxide, and rubber powder is cinnamic acrylic ester, and coalescents are propandiol butyl ether, and dispersant is polycarboxylate sodium Anionic dispersing agents, thickener are polyurethanes thickener, and antifoaming agent is metal soap antifoaming agent.
The preparation method is the same as that of Example 1.
Comparative example 1
Ceramic microsphere is not added, remaining is same as Example 1.
Comparative example 2
Reflection pigment and reflective insulation powder are not added, remaining is same as Example 1.
The product obtained by embodiment 1-3 and comparative example 1-3 is detected respectively by standard JG/T24-2000, part The results are shown in Table 1.As shown in Table 1, this coating can be significantly improved using ceramic microsphere, reflection pigment and reflective insulation powder Energy.
1 embodiment 1-3 of table and comparative example 1-3 testing results
☆ number indicates product fine at degree.

Claims (10)

1. a kind of high texture imitates sandstone coating, which is characterized in that including following components and parts by weight content：Silicone acrylic emulsion 10-20 It is part, 10-15 parts of natural colour sand, 2-4 parts of pigment of reflection, 3-5 parts of ceramic microsphere, 4-6 parts of reflective insulation powder, 1-2 parts of calcium formate, swollen Moisten 1-1.5 parts of soil, 0.5-1 parts of lignocellulosic, 2-3 parts of rubber powder, 4-5 parts of coalescents, 5-7 parts of dispersant, antifoaming agent 4-5 Part, 2-3 parts of thickener, 20-30 parts of deionized water.
2. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the natural colour sand granularity is selected from 50-70 mesh.
3. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the reflection pigment is titanium white Powder.
4. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the reflective insulation powder is oxidation Any one or more in aluminium, iron oxide or copper oxide.
5. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the grain size of the ceramic microsphere is 20-40 mesh.
6. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the rubber powder is styrene-the third Olefin(e) acid ester or VAE rubber powders.
7. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the coalescents are propylene glycol Butyl ether, propylene glycol methyl ether acetate, butyl glycol ether or propylene glycol phenylate it is one or more.
8. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the dispersant is sodium polycarboxylate Salt anionic dispersant.
9. a kind of high texture according to claim 1 imitates sandstone coating, which is characterized in that the thickener is polyurethanes Thickener, the antifoaming agent are metal soap antifoaming agent.
10. a kind of a kind of high texture as described in claim 1 imitates the preparation method of sandstone coating, which is characterized in that including with Lower step：
(1) natural colour sand, reflection pigment, ceramic microsphere and reflective insulation powder are uniformly mixed；
(2) silicone acrylic emulsion, lignocellulosic and rubber powder are uniformly mixed；
(3) mixture that step (1) and step (2) obtain is mixed, and sequentially adds calcium formate, bentonite, film forming and helps Agent, dispersant, antifoaming agent, thickener and deionized water are dispersed with stirring uniformly, obtain product.
CN201810229112.2A 2018-03-20 2018-03-20 A kind of high texture imitates sandstone coating and preparation method thereof Pending CN108485427A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112795215A (en) * 2020-12-30 2021-05-14 广东嘉宝莉科技材料有限公司 Sand-containing glaze coating and preparation method and application thereof
CN114315198A (en) * 2021-11-30 2022-04-12 固克节能科技股份有限公司 Water-based double-component polyurethane, light reflective heat-insulating colored sand and preparation method thereof
CN114369398A (en) * 2022-03-17 2022-04-19 广东嘉宝莉科技材料有限公司 Strong-stereoscopic-sense easily-molded micro-sand textured coating and preparation method and application thereof
CN116814124A (en) * 2023-06-29 2023-09-29 太原龙投富思特新材料科技有限公司 Stone-like paint and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112795215A (en) * 2020-12-30 2021-05-14 广东嘉宝莉科技材料有限公司 Sand-containing glaze coating and preparation method and application thereof
CN112795215B (en) * 2020-12-30 2022-05-31 广东嘉宝莉科技材料有限公司 Sand-containing glaze coating and preparation method and application thereof
CN114315198A (en) * 2021-11-30 2022-04-12 固克节能科技股份有限公司 Water-based double-component polyurethane, light reflective heat-insulating colored sand and preparation method thereof
CN114369398A (en) * 2022-03-17 2022-04-19 广东嘉宝莉科技材料有限公司 Strong-stereoscopic-sense easily-molded micro-sand textured coating and preparation method and application thereof
CN116814124A (en) * 2023-06-29 2023-09-29 太原龙投富思特新材料科技有限公司 Stone-like paint and preparation method thereof

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Application publication date: 20180904