CN103725158A - Weather-proof wear-proof epoxy resin oil paint for copper sculptures - Google Patents
Weather-proof wear-proof epoxy resin oil paint for copper sculptures Download PDFInfo
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- CN103725158A CN103725158A CN201310671599.7A CN201310671599A CN103725158A CN 103725158 A CN103725158 A CN 103725158A CN 201310671599 A CN201310671599 A CN 201310671599A CN 103725158 A CN103725158 A CN 103725158A
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Abstract
The invention relates to an oil paint, in particular to a weather-proof wear-proof epoxy resin oil paint used for copper sculptures. The oil paint is prepared from the following raw materials in parts by weight: 30-34 parts of E-52 epoxy resin, 10-12 parts of amino resin, 10-12 parts of alkyd resin, 2-3 parts of dimethyl dodecyl dimethyl benzyl ammonium chloride, 10-12 parts of polyethylene glycol, 1-2 part(s) of isopropanol, 10-12 parts of ethoxylated trimethylolpropane triacrylate, 1-2 part(s) of fatty alcohol polyoxyethylen ether phosphate ester, 1-2 part(s) of morpholine, 1-2 part(s) of an accelerator DTDM, 1-2 part(s) of an antioxidant MB, 12-15 parts of argil, 3-4 parts of stearic acid, 3-4 parts of fungacetin, 1-2 part(s) of dicumyl peroxide, 2-3 parts of cobalt naphthenate, 5-6 parts of an auxiliary, 10-12 parts of dimethylbenzene and 10-12 parts of n-butyl acetate. The paint film of the oil paint has the advantages of strong adhesive force, high glossiness, flexibility and wear resistance ,weather resistance and ageing resistance, long service life, and relatively simple manufacturing technique, so that the oil paint is widely used for protecting various copper sculpture artworks.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to weather-proof antiwear epoxy resin paint and preparation technology thereof for a kind of copper sculpture.
Background technology
Copper sculpture is a class artwork common in daily life, there is higher artistic value and enjoying value, yet, copper sculpture artwork is due to itself material character and the feature of putting environment, easily there is the problems such as oxidation corrosion, affect attractive in appearance and work-ing life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and copper sculpture is had to certain requirement with paint, such as sticking power, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, make the paint that is applicable to different use occasions, increase its artistic value.
Summary of the invention
The object of the invention is to, provide a kind of copper sculpture to paint with weather-proof antiwear epoxy resin, to protect sculpture, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of copper sculpture paints with weather-proof antiwear epoxy resin, it is characterized in that, material of the present invention is made by the raw material of following weight part: E-52 epoxy resin 30-34, aminoresin 10-12, Synolac 10-12, dimethyl dodecylbenzyl ammonium chloride 2-3, polyoxyethylene glycol 10-12, Virahol 1-2, ethoxylated trimethylolpropane triacrylate 10-12, aliphatic alcohol polyoxyvinethene phosphate 1-2, morpholine 1-2, vulkacit D TDM1-2, antioxidant MB 1-2, potter's clay 12-15, stearic acid 3-4, Vanay 3-4, dicumyl peroxide 1-2, cobalt naphthenate 2-3, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.
Described auxiliary agent is made by the raw material of following weight part: clay 9-12, magnesium oxide 3-4, zinc oxide 1-2, bauxitic clay 5-6, vanadium carbide 1-2, TM monex TM2-3, jade 3-4, anilinomethyl triethoxysilane 2-3, dimethyl isophthalate 35-40, Tenox PG 1-2, coix seed oil 2-3, l-Epicatechol 1-2; Its preparation method is that clay, bauxitic clay, jade are sent in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, with clear water, clean, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
Described a kind of copper sculpture paints with weather-proof antiwear epoxy resin, and its preparation technology is:
(1) Virahol, ethoxylated trimethylolpropane triacrylate, potter's clay, stearic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds Vanay, dicumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Compared with prior art, copper sculpture provided by the invention is painted and is possessed following advantage: this paint paint film adhesion is strong, and glossiness is high, pliable and tough wear-resisting, weather-resistant, long service life, production technique is relatively simple, is widely used in all kinds of copper sculpture artworks of protection.
Embodiment
Embodiment
The present embodiment paint is made by following weight part raw material: E-52 epoxy resin 32, aminoresin 12, Synolac 12, dimethyl dodecylbenzyl ammonium chloride 3, polyoxyethylene glycol 12, Virahol 2, ethoxylated trimethylolpropane triacrylate 12, aliphatic alcohol polyoxyvinethene phosphate 2, morpholine 2, vulkacit D TDM2, antioxidant MB 2, potter's clay 15, stearic acid 4, Vanay 4, dicumyl peroxide 2, cobalt naphthenate 3, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.
Described auxiliary agent is made by the raw material of following weight part: clay 10, magnesium oxide 4, zinc oxide 2, bauxitic clay 6, vanadium carbide 2, TM monex TM3, jade 4, anilinomethyl triethoxysilane 3, dimethyl isophthalate 40, Tenox PG 2, coix seed oil 3, l-Epicatechol 2; Its preparation method is that clay, bauxitic clay, jade are sent in calcining furnace and at 720-740 ℃, calcined 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.
Described a kind of copper sculpture paints with weather-proof antiwear epoxy resin, and its preparation technology is:
(1) Virahol, ethoxylated trimethylolpropane triacrylate, potter's clay, stearic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;
(2) material of step (1) is cooled to 70-85 ℃, adds Vanay, dicumyl peroxide, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 60 μ m slurries, obtains.
The performance test results of the present invention's paint is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a copper sculpture paints with weather-proof antiwear epoxy resin, it is characterized in that, this paint is made by the raw material of following weight part: E-52 epoxy resin 30-34, aminoresin 10-12, Synolac 10-12, dimethyl dodecylbenzyl ammonium chloride 2-3, polyoxyethylene glycol 10-12, Virahol 1-2, ethoxylated trimethylolpropane triacrylate 10-12, aliphatic alcohol polyoxyvinethene phosphate 1-2, morpholine 1-2, vulkacit D TDM 1-2, antioxidant MB 1-2, potter's clay 12-15, stearic acid 3-4, Vanay 3-4, dicumyl peroxide 1-2, cobalt naphthenate 2-3, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,
Described auxiliary agent is made by the raw material of following weight part: clay 9-12, magnesium oxide 3-4, zinc oxide 1-2, bauxitic clay 5-6, vanadium carbide 1-2, TM monex TM 2-3, jade 3-4, anilinomethyl triethoxysilane 2-3, dimethyl isophthalate 35-40, Tenox PG 1-2, coix seed oil 2-3, l-Epicatechol 1-2; Its preparation method is that clay, bauxitic clay, jade are sent in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, with clear water, clean, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
2. a kind of copper sculpture as claimed in claim 1 paints with weather-proof antiwear epoxy resin, and its manufacture craft is:
(1) Virahol, ethoxylated trimethylolpropane triacrylate, potter's clay, stearic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds Vanay, dicumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Priority Applications (1)
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CN201310671599.7A CN103725158A (en) | 2013-12-07 | 2013-12-07 | Weather-proof wear-proof epoxy resin oil paint for copper sculptures |
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CN201310671599.7A CN103725158A (en) | 2013-12-07 | 2013-12-07 | Weather-proof wear-proof epoxy resin oil paint for copper sculptures |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105153898A (en) * | 2015-09-14 | 2015-12-16 | 安徽华润涂料有限公司 | Adhesive for domestic security door outer layer wear-resistant paint and preparation method thereof |
CN105153901A (en) * | 2015-09-14 | 2015-12-16 | 安徽华润涂料有限公司 | Wear-resistant paint on outer layers of household security windows and preparation method thereof |
CN105175999A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Plastic handle and projective jacket composition for baby bottle and preparation method of composition |
CN105602321A (en) * | 2016-02-23 | 2016-05-25 | 和县科嘉阀门铸造有限公司 | Outer-layer protection coating for membrane valve manufacture |
CN106752714A (en) * | 2016-12-23 | 2017-05-31 | 安徽国威电动车制造有限公司 | A kind of protection japanning outside electric three-wheel Wheel |
CN106928762A (en) * | 2017-03-20 | 2017-07-07 | 界首市欧思润体育用品有限公司 | A kind of coating outside emulation soft fishing bait |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101824209A (en) * | 2010-04-09 | 2010-09-08 | 湖南大学 | Preparation method of polyester acrylate hybrid aqueous dispersion |
CN102181192A (en) * | 2011-01-24 | 2011-09-14 | 上海宏盾防伪材料有限公司 | Dual-curing coating and preparation method thereof |
CN103173101A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Salt spray resistant anticorrosive paint |
-
2013
- 2013-12-07 CN CN201310671599.7A patent/CN103725158A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101824209A (en) * | 2010-04-09 | 2010-09-08 | 湖南大学 | Preparation method of polyester acrylate hybrid aqueous dispersion |
CN102181192A (en) * | 2011-01-24 | 2011-09-14 | 上海宏盾防伪材料有限公司 | Dual-curing coating and preparation method thereof |
CN103173101A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Salt spray resistant anticorrosive paint |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105153898A (en) * | 2015-09-14 | 2015-12-16 | 安徽华润涂料有限公司 | Adhesive for domestic security door outer layer wear-resistant paint and preparation method thereof |
CN105153901A (en) * | 2015-09-14 | 2015-12-16 | 安徽华润涂料有限公司 | Wear-resistant paint on outer layers of household security windows and preparation method thereof |
CN105175999A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Plastic handle and projective jacket composition for baby bottle and preparation method of composition |
CN105175999B (en) * | 2015-09-18 | 2018-01-23 | 汕头市德丰盛妇幼用品有限公司 | A kind of baby bottles plastic handles and jacket composition and preparation method thereof |
CN105602321A (en) * | 2016-02-23 | 2016-05-25 | 和县科嘉阀门铸造有限公司 | Outer-layer protection coating for membrane valve manufacture |
CN106752714A (en) * | 2016-12-23 | 2017-05-31 | 安徽国威电动车制造有限公司 | A kind of protection japanning outside electric three-wheel Wheel |
CN106928762A (en) * | 2017-03-20 | 2017-07-07 | 界首市欧思润体育用品有限公司 | A kind of coating outside emulation soft fishing bait |
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Application publication date: 20140416 |