CN103380156B - 作为用于熔融沉积成型(fdm)印刷机的可溶性支撑材料的马来酸酐共聚物 - Google Patents
作为用于熔融沉积成型(fdm)印刷机的可溶性支撑材料的马来酸酐共聚物 Download PDFInfo
- Publication number
- CN103380156B CN103380156B CN201280009711.4A CN201280009711A CN103380156B CN 103380156 B CN103380156 B CN 103380156B CN 201280009711 A CN201280009711 A CN 201280009711A CN 103380156 B CN103380156 B CN 103380156B
- Authority
- CN
- China
- Prior art keywords
- weight
- support material
- maleic anhydride
- copolymer
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
- C08F222/08—Maleic anhydride with vinyl aromatic monomers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/40—Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11163199.0 | 2011-04-20 | ||
| EP11163199A EP2514775A1 (en) | 2011-04-20 | 2011-04-20 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer |
| EP111631990 | 2011-04-20 | ||
| PCT/EP2012/054306 WO2012143182A1 (en) | 2011-04-20 | 2012-03-13 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (fdm) printer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103380156A CN103380156A (zh) | 2013-10-30 |
| CN103380156B true CN103380156B (zh) | 2016-01-20 |
Family
ID=44560045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280009711.4A Expired - Fee Related CN103380156B (zh) | 2011-04-20 | 2012-03-13 | 作为用于熔融沉积成型(fdm)印刷机的可溶性支撑材料的马来酸酐共聚物 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8822590B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP2514775A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5893128B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20140009442A (cg-RX-API-DMAC7.html) |
| CN (1) | CN103380156B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2012244499B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013023429B8 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2833752C (cg-RX-API-DMAC7.html) |
| IL (1) | IL227363A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2013151313A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012143182A1 (cg-RX-API-DMAC7.html) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US9498593B2 (en) | 2013-06-17 | 2016-11-22 | MetaMason, Inc. | Customized medical devices and apparel |
| US9029058B2 (en) * | 2013-07-17 | 2015-05-12 | Stratasys, Inc. | Soluble support material for electrophotography-based additive manufacturing |
| US9745458B2 (en) | 2013-07-26 | 2017-08-29 | Hewlett-Packard Development Company, L.P. | Composite support material for three-dimensional printing |
| US10843401B2 (en) * | 2013-11-01 | 2020-11-24 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
| WO2015091814A1 (de) * | 2013-12-18 | 2015-06-25 | Styrolution Group Gmbh | Verwendung von formmassen basierend auf vinylaromat-dien-blockcopolymeren für den 3d druck |
| CN106029774A (zh) * | 2013-12-18 | 2016-10-12 | 英力士苯领集团股份公司 | 用于3-d打印的基于乙烯基芳族聚合物的成型材料 |
| ES2650265T3 (es) * | 2013-12-18 | 2018-01-17 | Ineos Styrolution Group Gmbh | Masas moldeables que se basan en copolímeros de compuesto aromático de vinilo para la impresión 3D |
| JP6546179B2 (ja) * | 2014-01-16 | 2019-07-17 | ダウ グローバル テクノロジーズ エルエルシー | 3d印刷用支持材料 |
| WO2015108770A1 (en) | 2014-01-16 | 2015-07-23 | Dow Global Technologies Llc | Recovery of additive manufacturing support materials |
| US9102099B1 (en) | 2014-02-05 | 2015-08-11 | MetaMason, Inc. | Methods for additive manufacturing processes incorporating active deposition |
| MX2016010793A (es) * | 2014-02-19 | 2016-12-15 | Basf Se | Polimeros como material de soporte para su uso en la fabricacion de filamentos fusionados. |
| US9676159B2 (en) | 2014-05-09 | 2017-06-13 | Nike, Inc. | Method for forming three-dimensional structures with different material portions |
| JP2017525588A (ja) * | 2014-06-16 | 2017-09-07 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 付加製造プロセス |
| CN104263150B (zh) * | 2014-09-10 | 2018-03-06 | 珠海天威飞马打印耗材有限公司 | 一种3d打印机及其工作台膜层的制备方法、涂覆在3d打印机工作台的涂料及其制备方法 |
| JP6491467B2 (ja) | 2014-10-14 | 2019-03-27 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2016059987A1 (ja) * | 2014-10-14 | 2016-04-21 | 花王株式会社 | 三次元造形用可溶性材料 |
| JP5972335B2 (ja) * | 2014-10-14 | 2016-08-17 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2016106062A1 (en) | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes |
| FR3030529B1 (fr) * | 2014-12-23 | 2017-01-27 | Arkema France | Copolymere a blocs hydrosoluble et son utilisation comme materiau support pour impression 3d |
| KR102064816B1 (ko) | 2015-06-19 | 2020-01-10 | 스트래터시스,인코포레이티드 | 적층 제조에 사용되는 수계 분산형 중합체 |
| EP3328930B1 (en) | 2015-07-27 | 2019-05-29 | Dow Global Technologies LLC | Method to additive manufacture biocompatible material and articles made by the method |
| EP3328613A4 (en) * | 2015-07-30 | 2019-03-20 | Wildcat DP LLC | MATERIAL AND METHOD FOR 3D MANUFACTURING |
| US10800094B2 (en) | 2015-09-14 | 2020-10-13 | Carbon, Inc. | Light-curable article of manufacture with portions of differing solubility |
| US10647873B2 (en) | 2015-10-30 | 2020-05-12 | Carbon, Inc. | Dual cure article of manufacture with portions of differing solubility |
| KR102053481B1 (ko) * | 2015-11-03 | 2019-12-06 | 주식회사 엘지화학 | 3차원 조형물의 형성 방법 |
| EP3384481A1 (en) | 2015-12-03 | 2018-10-10 | Stephen L. Buchanan | Anatomic apparatus and training system for remote and interactive hands-on surgical training for dentists |
| EP3390006B1 (en) | 2015-12-17 | 2021-01-27 | Bridgestone Americas Tire Operations, LLC | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
| JP6885611B2 (ja) | 2015-12-18 | 2021-06-16 | ユニバーシティ オブ カンタベリー | 分離媒体 |
| US10953595B2 (en) | 2015-12-24 | 2021-03-23 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| US11045997B2 (en) * | 2015-12-24 | 2021-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| JP6806088B2 (ja) * | 2016-01-05 | 2021-01-06 | コニカミノルタ株式会社 | 粉末材料、立体造形物の製造方法および立体造形装置 |
| US10449713B2 (en) | 2016-01-25 | 2019-10-22 | Te Connectivity Corporation | Article and method of forming an article |
| JP6953434B2 (ja) | 2016-05-04 | 2021-10-27 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 3d印刷における支持材料としてのコポリカーボネート |
| EP3509817B1 (en) | 2016-09-12 | 2020-03-18 | SABIC Global Technologies B.V. | Sacrificial high heat support materials for additive manufacturing processes |
| WO2018081053A1 (en) | 2016-10-27 | 2018-05-03 | Bridgestone Americas Tire Operations, Llc | Processes for producing cured polymeric products by additive manufacturing |
| JP6990594B2 (ja) * | 2017-02-07 | 2022-01-12 | 株式会社日本触媒 | 水性樹脂組成物 |
| KR102626745B1 (ko) | 2017-05-26 | 2024-01-17 | 인피니트 머티리얼 솔루션즈, 엘엘씨 | 수용성 중합체 조성물 |
| WO2018227094A1 (en) | 2017-06-08 | 2018-12-13 | Buchanan Stephen L | Tooth or tooth replica holding sleeve for use with an paex locator |
| EP3689585B1 (en) * | 2017-09-28 | 2022-02-09 | Kao Corporation | Soluble material for three-dimensional modeling |
| JP2019064258A (ja) * | 2017-09-28 | 2019-04-25 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2019075107A1 (en) | 2017-10-10 | 2019-04-18 | Stratasys, Inc. | WATER-DISPERSIBLE THERMOPLASTIC MATERIAL COMPRISING A SULFINATED COPOLYMER FOR USE IN ADDITIVE MANUFACTURE |
| FR3074181B1 (fr) | 2017-11-28 | 2020-11-06 | Arkema France | Composition copolymerique hydrosoluble a ph neutre |
| JP7136131B2 (ja) * | 2018-02-02 | 2022-09-13 | 三菱ケミカル株式会社 | 3次元造形用材料、3次元造形用フィラメント、該フィラメントの巻回体および3次元プリンター用カートリッジ |
| CN111630144B (zh) | 2018-02-22 | 2021-12-31 | 宝洁公司 | 用于制备单位剂量制品的方法 |
| EP3864093A1 (en) * | 2018-10-10 | 2021-08-18 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| FR3088327B1 (fr) | 2018-11-08 | 2021-11-05 | Arkema France | Composition copolymerique hydrosoluble |
| JP2023507990A (ja) * | 2019-12-17 | 2023-02-28 | ティコナ・エルエルシー | 強化ポリアリーレンスルフィド組成物を用いる三次元印刷システム |
| EP3865302B1 (en) | 2020-02-14 | 2024-08-14 | iSQUARED AG | Copolymer for use in a digital manufacturing process |
| US12371581B2 (en) | 2020-03-25 | 2025-07-29 | Infinite Material Solutions, Llc | High performance water soluble polymer compositions |
| CN116034008A (zh) * | 2020-08-06 | 2023-04-28 | 昕诺飞控股有限公司 | 使用fdm的连续中空管打印 |
| US12157800B2 (en) | 2021-04-12 | 2024-12-03 | Stratasys, Inc. | Method for underwater processing of water-dispersible materials |
| WO2022225815A1 (en) | 2021-04-19 | 2022-10-27 | Jabil Inc. | Improved additive manufacturing break away support material |
| FR3124420B1 (fr) * | 2021-06-23 | 2024-09-27 | Arkema France | Utilisation de copolymères multi blocs en tant que matériau sacrificiel dans un procédé d’impression 3D |
| WO2024076464A1 (en) | 2022-10-03 | 2024-04-11 | Jabil Inc. | Additive manufactured article comprising a grafted aliphatic polyketone, filament and powder |
| NL2036419B1 (en) | 2023-12-04 | 2025-06-13 | Tectonic 3D Swip B V | Fused deposition modeling method and method to dissolve a high temperature polycarbonate support used in this method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0047889A2 (de) * | 1980-09-11 | 1982-03-24 | BASF Aktiengesellschaft | Alkalilösliche Harze auf Basis von Copolymerisaten aus monoolefinisch ungesättigten Carbonsäuren und durch Aromaten substituierten alpha-Olefinen und ihre Verwendung als Harzkomponente in Polymerdispersionen |
| US6790403B1 (en) * | 1999-04-20 | 2004-09-14 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| CN1799821A (zh) * | 2006-01-16 | 2006-07-12 | 南京师范大学 | 采用逐层喷涂方式制作三维物体的方法 |
| CN1814431A (zh) * | 2006-03-03 | 2006-08-09 | 南京师范大学 | 制作三维物体和支撑的打印成型方法 |
| WO2010045147A2 (en) * | 2008-10-17 | 2010-04-22 | Stratasys, Inc. | Support material for digital manufacturing systems |
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| FR2154030A5 (cg-RX-API-DMAC7.html) | 1971-09-22 | 1973-05-04 | Dow Chemical Co | |
| JPH0260909A (ja) * | 1988-08-26 | 1990-03-01 | Nippon Oil & Fats Co Ltd | 熱硬化型水溶性樹脂及びその硬化物 |
| US5121329A (en) | 1989-10-30 | 1992-06-09 | Stratasys, Inc. | Apparatus and method for creating three-dimensional objects |
| JPH075302A (ja) * | 1993-06-15 | 1995-01-10 | Tosoh Corp | マイクロ集光レンズ形成用感光性組成物 |
| US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
| US6228923B1 (en) * | 1997-04-02 | 2001-05-08 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
| US6070107A (en) * | 1997-04-02 | 2000-05-30 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
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| JP4148733B2 (ja) * | 2002-09-02 | 2008-09-10 | リコープリンティングシステムズ株式会社 | 三次元積層造形法とその装置 |
| KR20060069428A (ko) | 2003-07-24 | 2006-06-21 | 노바 케미칼즈 인코포레이팃드 | 스티렌계 수지 조성물 및 이것으로 제조된 물품 |
| JP2006111710A (ja) * | 2004-10-14 | 2006-04-27 | Nof Corp | 無水マレイン酸(共)重合体の製造方法、無水マレイン酸(共)重合体、及びその加水分解物 |
-
2011
- 2011-04-20 EP EP11163199A patent/EP2514775A1/en not_active Withdrawn
-
2012
- 2012-03-13 RU RU2013151313/04A patent/RU2013151313A/ru not_active Application Discontinuation
- 2012-03-13 KR KR1020137026041A patent/KR20140009442A/ko not_active Withdrawn
- 2012-03-13 WO PCT/EP2012/054306 patent/WO2012143182A1/en not_active Ceased
- 2012-03-13 AU AU2012244499A patent/AU2012244499B2/en not_active Ceased
- 2012-03-13 JP JP2014505552A patent/JP5893128B2/ja not_active Expired - Fee Related
- 2012-03-13 CA CA2833752A patent/CA2833752C/en active Active
- 2012-03-13 BR BR112013023429A patent/BR112013023429B8/pt not_active IP Right Cessation
- 2012-03-13 US US13/982,431 patent/US8822590B2/en active Active
- 2012-03-13 CN CN201280009711.4A patent/CN103380156B/zh not_active Expired - Fee Related
- 2012-03-13 EP EP12708835.9A patent/EP2699611B1/en active Active
-
2013
- 2013-07-07 IL IL227363A patent/IL227363A/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0047889A2 (de) * | 1980-09-11 | 1982-03-24 | BASF Aktiengesellschaft | Alkalilösliche Harze auf Basis von Copolymerisaten aus monoolefinisch ungesättigten Carbonsäuren und durch Aromaten substituierten alpha-Olefinen und ihre Verwendung als Harzkomponente in Polymerdispersionen |
| US6790403B1 (en) * | 1999-04-20 | 2004-09-14 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| CN1799821A (zh) * | 2006-01-16 | 2006-07-12 | 南京师范大学 | 采用逐层喷涂方式制作三维物体的方法 |
| CN1814431A (zh) * | 2006-03-03 | 2006-08-09 | 南京师范大学 | 制作三维物体和支撑的打印成型方法 |
| WO2010045147A2 (en) * | 2008-10-17 | 2010-04-22 | Stratasys, Inc. | Support material for digital manufacturing systems |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2833752A1 (en) | 2012-10-26 |
| US20130317164A1 (en) | 2013-11-28 |
| AU2012244499B2 (en) | 2015-05-21 |
| JP5893128B2 (ja) | 2016-03-23 |
| BR112013023429B1 (pt) | 2020-11-17 |
| AU2012244499A1 (en) | 2013-07-25 |
| BR112013023429A2 (pt) | 2016-12-13 |
| EP2514775A1 (en) | 2012-10-24 |
| KR20140009442A (ko) | 2014-01-22 |
| JP2014511933A (ja) | 2014-05-19 |
| BR112013023429B8 (pt) | 2022-07-05 |
| RU2013151313A (ru) | 2015-05-27 |
| WO2012143182A1 (en) | 2012-10-26 |
| EP2699611A1 (en) | 2014-02-26 |
| CN103380156A (zh) | 2013-10-30 |
| IL227363A (en) | 2016-09-29 |
| CA2833752C (en) | 2019-05-14 |
| IL227363A0 (en) | 2013-09-30 |
| US8822590B2 (en) | 2014-09-02 |
| EP2699611B1 (en) | 2015-05-06 |
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