KR20140009442A - 용융 침착 모델링 (fdm) 인쇄기용 가용성 지지체 물질로서의 말레산 무수물 공중합체 - Google Patents
용융 침착 모델링 (fdm) 인쇄기용 가용성 지지체 물질로서의 말레산 무수물 공중합체 Download PDFInfo
- Publication number
- KR20140009442A KR20140009442A KR1020137026041A KR20137026041A KR20140009442A KR 20140009442 A KR20140009442 A KR 20140009442A KR 1020137026041 A KR1020137026041 A KR 1020137026041A KR 20137026041 A KR20137026041 A KR 20137026041A KR 20140009442 A KR20140009442 A KR 20140009442A
- Authority
- KR
- South Korea
- Prior art keywords
- support material
- weight
- maleic anhydride
- styrene
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title claims abstract description 77
- 229920001577 copolymer Polymers 0.000 title claims description 36
- 230000008021 deposition Effects 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 40
- 238000010146 3D printing Methods 0.000 claims abstract description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 66
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 38
- 239000000178 monomer Substances 0.000 claims description 16
- 239000004609 Impact Modifier Substances 0.000 claims description 14
- 230000009477 glass transition Effects 0.000 claims description 13
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 239000004014 plasticizer Substances 0.000 claims description 7
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 3
- 239000006254 rheological additive Substances 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 abstract description 6
- 229920000147 Styrene maleic anhydride Polymers 0.000 abstract description 6
- 239000000155 melt Substances 0.000 abstract description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 19
- 238000007639 printing Methods 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 10
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- 239000012299 nitrogen atmosphere Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000011258 core-shell material Substances 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- -1 aromatic phthalates Chemical class 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011162 core material Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000000110 selective laser sintering Methods 0.000 description 3
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 102100021202 Desmocollin-1 Human genes 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101000968043 Homo sapiens Desmocollin-1 Proteins 0.000 description 1
- 101000880960 Homo sapiens Desmocollin-3 Proteins 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229920006187 aquazol Polymers 0.000 description 1
- 239000012861 aquazol Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
- C08F222/08—Maleic anhydride with vinyl aromatic monomers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/40—Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11163199.0 | 2011-04-20 | ||
| EP11163199A EP2514775A1 (en) | 2011-04-20 | 2011-04-20 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer |
| PCT/EP2012/054306 WO2012143182A1 (en) | 2011-04-20 | 2012-03-13 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (fdm) printer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140009442A true KR20140009442A (ko) | 2014-01-22 |
Family
ID=44560045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137026041A Withdrawn KR20140009442A (ko) | 2011-04-20 | 2012-03-13 | 용융 침착 모델링 (fdm) 인쇄기용 가용성 지지체 물질로서의 말레산 무수물 공중합체 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8822590B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP2514775A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5893128B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20140009442A (cg-RX-API-DMAC7.html) |
| CN (1) | CN103380156B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2012244499B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013023429B8 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2833752C (cg-RX-API-DMAC7.html) |
| IL (1) | IL227363A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2013151313A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012143182A1 (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017078332A1 (ko) * | 2015-11-03 | 2017-05-11 | 주식회사 엘지화학 | 3차원 조형물의 형성 방법 |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9498593B2 (en) | 2013-06-17 | 2016-11-22 | MetaMason, Inc. | Customized medical devices and apparel |
| US9029058B2 (en) * | 2013-07-17 | 2015-05-12 | Stratasys, Inc. | Soluble support material for electrophotography-based additive manufacturing |
| US9745458B2 (en) | 2013-07-26 | 2017-08-29 | Hewlett-Packard Development Company, L.P. | Composite support material for three-dimensional printing |
| US10843401B2 (en) * | 2013-11-01 | 2020-11-24 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
| WO2015091814A1 (de) * | 2013-12-18 | 2015-06-25 | Styrolution Group Gmbh | Verwendung von formmassen basierend auf vinylaromat-dien-blockcopolymeren für den 3d druck |
| CN106029774A (zh) * | 2013-12-18 | 2016-10-12 | 英力士苯领集团股份公司 | 用于3-d打印的基于乙烯基芳族聚合物的成型材料 |
| ES2650265T3 (es) * | 2013-12-18 | 2018-01-17 | Ineos Styrolution Group Gmbh | Masas moldeables que se basan en copolímeros de compuesto aromático de vinilo para la impresión 3D |
| JP6546179B2 (ja) * | 2014-01-16 | 2019-07-17 | ダウ グローバル テクノロジーズ エルエルシー | ３ｄ印刷用支持材料 |
| WO2015108770A1 (en) | 2014-01-16 | 2015-07-23 | Dow Global Technologies Llc | Recovery of additive manufacturing support materials |
| US9102099B1 (en) | 2014-02-05 | 2015-08-11 | MetaMason, Inc. | Methods for additive manufacturing processes incorporating active deposition |
| MX2016010793A (es) * | 2014-02-19 | 2016-12-15 | Basf Se | Polimeros como material de soporte para su uso en la fabricacion de filamentos fusionados. |
| US9676159B2 (en) | 2014-05-09 | 2017-06-13 | Nike, Inc. | Method for forming three-dimensional structures with different material portions |
| JP2017525588A (ja) * | 2014-06-16 | 2017-09-07 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 付加製造プロセス |
| CN104263150B (zh) * | 2014-09-10 | 2018-03-06 | 珠海天威飞马打印耗材有限公司 | 一种3d打印机及其工作台膜层的制备方法、涂覆在3d打印机工作台的涂料及其制备方法 |
| JP6491467B2 (ja) | 2014-10-14 | 2019-03-27 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2016059987A1 (ja) * | 2014-10-14 | 2016-04-21 | 花王株式会社 | 三次元造形用可溶性材料 |
| JP5972335B2 (ja) * | 2014-10-14 | 2016-08-17 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2016106062A1 (en) | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes |
| FR3030529B1 (fr) * | 2014-12-23 | 2017-01-27 | Arkema France | Copolymere a blocs hydrosoluble et son utilisation comme materiau support pour impression 3d |
| KR102064816B1 (ko) | 2015-06-19 | 2020-01-10 | 스트래터시스,인코포레이티드 | 적층 제조에 사용되는 수계 분산형 중합체 |
| EP3328930B1 (en) | 2015-07-27 | 2019-05-29 | Dow Global Technologies LLC | Method to additive manufacture biocompatible material and articles made by the method |
| EP3328613A4 (en) * | 2015-07-30 | 2019-03-20 | Wildcat DP LLC | MATERIAL AND METHOD FOR 3D MANUFACTURING |
| US10800094B2 (en) | 2015-09-14 | 2020-10-13 | Carbon, Inc. | Light-curable article of manufacture with portions of differing solubility |
| US10647873B2 (en) | 2015-10-30 | 2020-05-12 | Carbon, Inc. | Dual cure article of manufacture with portions of differing solubility |
| EP3384481A1 (en) | 2015-12-03 | 2018-10-10 | Stephen L. Buchanan | Anatomic apparatus and training system for remote and interactive hands-on surgical training for dentists |
| EP3390006B1 (en) | 2015-12-17 | 2021-01-27 | Bridgestone Americas Tire Operations, LLC | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
| JP6885611B2 (ja) | 2015-12-18 | 2021-06-16 | ユニバーシティ オブ カンタベリー | 分離媒体 |
| US10953595B2 (en) | 2015-12-24 | 2021-03-23 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| US11045997B2 (en) * | 2015-12-24 | 2021-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| JP6806088B2 (ja) * | 2016-01-05 | 2021-01-06 | コニカミノルタ株式会社 | 粉末材料、立体造形物の製造方法および立体造形装置 |
| US10449713B2 (en) | 2016-01-25 | 2019-10-22 | Te Connectivity Corporation | Article and method of forming an article |
| JP6953434B2 (ja) | 2016-05-04 | 2021-10-27 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ | ３ｄ印刷における支持材料としてのコポリカーボネート |
| EP3509817B1 (en) | 2016-09-12 | 2020-03-18 | SABIC Global Technologies B.V. | Sacrificial high heat support materials for additive manufacturing processes |
| WO2018081053A1 (en) | 2016-10-27 | 2018-05-03 | Bridgestone Americas Tire Operations, Llc | Processes for producing cured polymeric products by additive manufacturing |
| JP6990594B2 (ja) * | 2017-02-07 | 2022-01-12 | 株式会社日本触媒 | 水性樹脂組成物 |
| KR102626745B1 (ko) | 2017-05-26 | 2024-01-17 | 인피니트 머티리얼 솔루션즈, 엘엘씨 | 수용성 중합체 조성물 |
| WO2018227094A1 (en) | 2017-06-08 | 2018-12-13 | Buchanan Stephen L | Tooth or tooth replica holding sleeve for use with an paex locator |
| EP3689585B1 (en) * | 2017-09-28 | 2022-02-09 | Kao Corporation | Soluble material for three-dimensional modeling |
| JP2019064258A (ja) * | 2017-09-28 | 2019-04-25 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2019075107A1 (en) | 2017-10-10 | 2019-04-18 | Stratasys, Inc. | WATER-DISPERSIBLE THERMOPLASTIC MATERIAL COMPRISING A SULFINATED COPOLYMER FOR USE IN ADDITIVE MANUFACTURE |
| FR3074181B1 (fr) | 2017-11-28 | 2020-11-06 | Arkema France | Composition copolymerique hydrosoluble a ph neutre |
| JP7136131B2 (ja) * | 2018-02-02 | 2022-09-13 | 三菱ケミカル株式会社 | ３次元造形用材料、３次元造形用フィラメント、該フィラメントの巻回体および３次元プリンター用カートリッジ |
| CN111630144B (zh) | 2018-02-22 | 2021-12-31 | 宝洁公司 | 用于制备单位剂量制品的方法 |
| EP3864093A1 (en) * | 2018-10-10 | 2021-08-18 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| FR3088327B1 (fr) | 2018-11-08 | 2021-11-05 | Arkema France | Composition copolymerique hydrosoluble |
| JP2023507990A (ja) * | 2019-12-17 | 2023-02-28 | ティコナ・エルエルシー | 強化ポリアリーレンスルフィド組成物を用いる三次元印刷システム |
| EP3865302B1 (en) | 2020-02-14 | 2024-08-14 | iSQUARED AG | Copolymer for use in a digital manufacturing process |
| US12371581B2 (en) | 2020-03-25 | 2025-07-29 | Infinite Material Solutions, Llc | High performance water soluble polymer compositions |
| CN116034008A (zh) * | 2020-08-06 | 2023-04-28 | 昕诺飞控股有限公司 | 使用fdm的连续中空管打印 |
| US12157800B2 (en) | 2021-04-12 | 2024-12-03 | Stratasys, Inc. | Method for underwater processing of water-dispersible materials |
| WO2022225815A1 (en) | 2021-04-19 | 2022-10-27 | Jabil Inc. | Improved additive manufacturing break away support material |
| FR3124420B1 (fr) * | 2021-06-23 | 2024-09-27 | Arkema France | Utilisation de copolymères multi blocs en tant que matériau sacrificiel dans un procédé d’impression 3D |
| WO2024076464A1 (en) | 2022-10-03 | 2024-04-11 | Jabil Inc. | Additive manufactured article comprising a grafted aliphatic polyketone, filament and powder |
| NL2036419B1 (en) | 2023-12-04 | 2025-06-13 | Tectonic 3D Swip B V | Fused deposition modeling method and method to dissolve a high temperature polycarbonate support used in this method |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2154030A5 (cg-RX-API-DMAC7.html) | 1971-09-22 | 1973-05-04 | Dow Chemical Co | |
| DE3034171A1 (de) * | 1980-09-11 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Alkaliloesliche harze auf basis von copolymerisaten aus monoolefinisch ungesaettigten carbonsaeuren und durch aromaten substituierten (alpha) -olefinen und ihre verwendung als harzkomponente in polymerdispersionen |
| JPH0260909A (ja) * | 1988-08-26 | 1990-03-01 | Nippon Oil & Fats Co Ltd | 熱硬化型水溶性樹脂及びその硬化物 |
| US5121329A (en) | 1989-10-30 | 1992-06-09 | Stratasys, Inc. | Apparatus and method for creating three-dimensional objects |
| JPH075302A (ja) * | 1993-06-15 | 1995-01-10 | Tosoh Corp | マイクロ集光レンズ形成用感光性組成物 |
| US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
| US6228923B1 (en) * | 1997-04-02 | 2001-05-08 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
| US6070107A (en) * | 1997-04-02 | 2000-05-30 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
| US7754807B2 (en) | 1999-04-20 | 2010-07-13 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| US6790403B1 (en) * | 1999-04-20 | 2004-09-14 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| JP4148733B2 (ja) * | 2002-09-02 | 2008-09-10 | リコープリンティングシステムズ株式会社 | 三次元積層造形法とその装置 |
| KR20060069428A (ko) | 2003-07-24 | 2006-06-21 | 노바 케미칼즈 인코포레이팃드 | 스티렌계 수지 조성물 및 이것으로 제조된 물품 |
| JP2006111710A (ja) * | 2004-10-14 | 2006-04-27 | Nof Corp | 無水マレイン酸（共）重合体の製造方法、無水マレイン酸（共）重合体、及びその加水分解物 |
| CN100387419C (zh) * | 2006-01-16 | 2008-05-14 | 南京师范大学 | 采用逐层喷涂方式制作三维物体的方法 |
| CN100340388C (zh) * | 2006-03-03 | 2007-10-03 | 南京师范大学 | 制作三维物体和支撑的打印成型方法 |
| US8246888B2 (en) * | 2008-10-17 | 2012-08-21 | Stratasys, Inc. | Support material for digital manufacturing systems |
-
2011
- 2011-04-20 EP EP11163199A patent/EP2514775A1/en not_active Withdrawn
-
2012
- 2012-03-13 RU RU2013151313/04A patent/RU2013151313A/ru not_active Application Discontinuation
- 2012-03-13 KR KR1020137026041A patent/KR20140009442A/ko not_active Withdrawn
- 2012-03-13 WO PCT/EP2012/054306 patent/WO2012143182A1/en not_active Ceased
- 2012-03-13 AU AU2012244499A patent/AU2012244499B2/en not_active Ceased
- 2012-03-13 JP JP2014505552A patent/JP5893128B2/ja not_active Expired - Fee Related
- 2012-03-13 CA CA2833752A patent/CA2833752C/en active Active
- 2012-03-13 BR BR112013023429A patent/BR112013023429B8/pt not_active IP Right Cessation
- 2012-03-13 US US13/982,431 patent/US8822590B2/en active Active
- 2012-03-13 CN CN201280009711.4A patent/CN103380156B/zh not_active Expired - Fee Related
- 2012-03-13 EP EP12708835.9A patent/EP2699611B1/en active Active
-
2013
- 2013-07-07 IL IL227363A patent/IL227363A/en active IP Right Grant
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017078332A1 (ko) * | 2015-11-03 | 2017-05-11 | 주식회사 엘지화학 | 3차원 조형물의 형성 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2833752A1 (en) | 2012-10-26 |
| CN103380156B (zh) | 2016-01-20 |
| US20130317164A1 (en) | 2013-11-28 |
| AU2012244499B2 (en) | 2015-05-21 |
| JP5893128B2 (ja) | 2016-03-23 |
| BR112013023429B1 (pt) | 2020-11-17 |
| AU2012244499A1 (en) | 2013-07-25 |
| BR112013023429A2 (pt) | 2016-12-13 |
| EP2514775A1 (en) | 2012-10-24 |
| JP2014511933A (ja) | 2014-05-19 |
| BR112013023429B8 (pt) | 2022-07-05 |
| RU2013151313A (ru) | 2015-05-27 |
| WO2012143182A1 (en) | 2012-10-26 |
| EP2699611A1 (en) | 2014-02-26 |
| CN103380156A (zh) | 2013-10-30 |
| IL227363A (en) | 2016-09-29 |
| CA2833752C (en) | 2019-05-14 |
| IL227363A0 (en) | 2013-09-30 |
| US8822590B2 (en) | 2014-09-02 |
| EP2699611B1 (en) | 2015-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR20140009442A (ko) | 용융 침착 모델링 (fdm) 인쇄기용 가용성 지지체 물질로서의 말레산 무수물 공중합체 | |
| EP3320047B1 (en) | Curable compositions comprising mono-functional acrylates | |
| JP7619392B2 (ja) | 共重合体の製造方法 | |
| TWI853994B (zh) | 具有改良的機械性質之基於ｐｍｍａ之鑄塑聚合物 | |
| JP6939002B2 (ja) | 樹脂組成物および成形材料 | |
| KR101963523B1 (ko) | 알콕시아민의 저온 라디칼 중합 | |
| CN110105736A (zh) | 热固化性树脂组合物、团状模塑料及其成形品 | |
| CA2608029C (en) | An embedment casting composition | |
| US20250075066A1 (en) | (meth)acrylic composition, composite material obtained from such a composition, method for producing said composition and uses thereof | |
| US12134213B2 (en) | Process for forming a rotational molded article | |
| KR20240071939A (ko) | 3d 프린팅용 광경화성 조성물 및 이의 제조 방법 | |
| JP2025144178A (ja) | 粒子、成形材料、成形体、およびそれらの製造方法 | |
| JP2024139722A (ja) | 樹脂組成物 | |
| KR20140136561A (ko) | 폴리메틸메타크릴레이트 필름용 조성물 | |
| JPH03199252A (ja) | スチレン系樹脂組成物 | |
| JP2004521179A (ja) | ポリビニルアセテート−プラスチック用の可塑剤としてのアルコキシル化されたアルコール |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20131002 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |