CN103372653B - 制造高长径比银纳米线的方法 - Google Patents
制造高长径比银纳米线的方法 Download PDFInfo
- Publication number
- CN103372653B CN103372653B CN201310148815.XA CN201310148815A CN103372653B CN 103372653 B CN103372653 B CN 103372653B CN 201310148815 A CN201310148815 A CN 201310148815A CN 103372653 B CN103372653 B CN 103372653B
- Authority
- CN
- China
- Prior art keywords
- silver
- component
- copper
- container
- described container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 136
- 238000000034 method Methods 0.000 title claims abstract description 48
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000002042 Silver nanowire Substances 0.000 title abstract description 12
- 229910052709 silver Inorganic materials 0.000 claims description 92
- 239000004332 silver Substances 0.000 claims description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 90
- -1 Halogen ion Chemical class 0.000 claims description 37
- 239000010949 copper Substances 0.000 claims description 33
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 31
- 229910052802 copper Inorganic materials 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 31
- 150000004820 halides Chemical class 0.000 claims description 30
- 229910052736 halogen Inorganic materials 0.000 claims description 23
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 14
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 11
- 239000000470 constituent Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 150000002009 diols Chemical class 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 6
- 239000008103 glucose Substances 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical group Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 5
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 4
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 4
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 4
- 229930091371 Fructose Natural products 0.000 claims description 4
- 239000005715 Fructose Substances 0.000 claims description 4
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 12
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 6
- 238000013019 agitation Methods 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 25
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000008367 deionised water Substances 0.000 description 26
- 229910021641 deionized water Inorganic materials 0.000 description 26
- 238000002360 preparation method Methods 0.000 description 22
- 239000012153 distilled water Substances 0.000 description 17
- 238000003756 stirring Methods 0.000 description 12
- 239000012265 solid product Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000005119 centrifugation Methods 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000004917 polyol method Methods 0.000 description 3
- 101710134784 Agnoprotein Proteins 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- 125000002353 D-glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0547—Nanofibres or nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/25—Noble metals, i.e. Ag Au, Ir, Os, Pd, Pt, Rh, Ru
- B22F2301/255—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2304/00—Physical aspects of the powder
- B22F2304/05—Submicron size particles
- B22F2304/054—Particle size between 1 and 100 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261640323P | 2012-04-30 | 2012-04-30 | |
| US61/640,323 | 2012-04-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103372653A CN103372653A (zh) | 2013-10-30 |
| CN103372653B true CN103372653B (zh) | 2015-07-08 |
Family
ID=49323346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310148815.XA Expired - Fee Related CN103372653B (zh) | 2012-04-30 | 2013-04-25 | 制造高长径比银纳米线的方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9034075B2 (enExample) |
| JP (1) | JP6104681B2 (enExample) |
| KR (1) | KR102074702B1 (enExample) |
| CN (1) | CN103372653B (enExample) |
| DE (1) | DE102013007194A1 (enExample) |
| FR (1) | FR2989908A1 (enExample) |
| TW (1) | TWI481566B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104583114B (zh) * | 2012-06-18 | 2017-04-05 | 苏州诺菲纳米科技有限公司 | 储存于容器中的纳米线悬浮液的聚结物减少 |
| US10081058B2 (en) | 2014-04-11 | 2018-09-25 | Cam Holding Corporation | Methods of controlling nanowire morphology |
| CN104043838B (zh) * | 2014-05-14 | 2017-03-29 | 中国科学院合肥物质科学研究院 | 利用不同分子量的pvp及反应温度调控银纳米线长度的方法 |
| DE102015013219A1 (de) * | 2014-10-28 | 2016-04-28 | Dow Global Technologies Llc | Verfahren zur Herstellung von Silber-Nanodrähten |
| DE102015013238A1 (de) * | 2014-10-28 | 2016-04-28 | Dow Global Technologies Llc | Verfahren mit niedriger Sauerstoffkonzentration zur Herstellung von Silber-Nanodrähten |
| DE102015013239A1 (de) | 2014-10-28 | 2016-04-28 | Dow Global Technologies Llc | Hydrothermalverfahren zur Herstellung von Silber-Nanodrähten |
| DE102015013220A1 (de) * | 2014-10-28 | 2016-04-28 | Dow Global Technologies Llc | Verfahren zur Herstellung von Silber-Nanodrähten |
| US10376898B2 (en) * | 2015-06-12 | 2019-08-13 | Dow Global Technologies Llc | Method for manufacturing high aspect ratio silver nanowires |
| US10081020B2 (en) | 2015-06-12 | 2018-09-25 | Dow Global Technologies Llc | Hydrothermal method for manufacturing filtered silver nanowires |
| CN105304210A (zh) * | 2015-10-09 | 2016-02-03 | 重庆文理学院 | 一种银纳米线的制备方法 |
| CN105478795B (zh) * | 2015-12-14 | 2017-11-28 | 上海理工大学 | 一种利用甘蔗提取液制备银纳米颗粒的方法 |
| CN108602119B (zh) * | 2016-03-14 | 2020-09-01 | 尤尼吉可株式会社 | 纳米线及其制造方法、纳米线分散液以及透明导电膜 |
| JP6526739B2 (ja) * | 2016-06-02 | 2019-06-05 | Ｄｏｗａエレクトロニクス株式会社 | 銀ナノワイヤおよびその製造法並びに銀ナノワイヤインクおよび透明導電膜 |
| CN106345997A (zh) * | 2016-09-30 | 2017-01-25 | 天津宝兴威科技有限公司 | 一种形貌均一的超细银纳米线及其制备方法 |
| CN106226376B (zh) * | 2016-10-09 | 2019-07-05 | 南京膜材料产业技术研究院有限公司 | 一种可供电极印刷的纳米浆料的制备方法 |
| CN107639236B (zh) * | 2017-09-08 | 2020-08-18 | 中国乐凯集团有限公司 | 一种银纳米线的制备方法及制品 |
| CN109604630B (zh) * | 2018-12-07 | 2022-04-01 | 陕西煤业化工技术研究院有限责任公司 | 一种高长径比银纳米线及其制备方法 |
| CN114029499B (zh) * | 2021-11-08 | 2022-08-19 | 西北有色金属研究院 | 一种超长纳米银线材料的制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101111334A (zh) * | 2005-02-02 | 2008-01-23 | 同和电子科技有限公司 | 银粒子粉末及其制造方法 |
| TW201024002A (en) * | 2008-12-23 | 2010-07-01 | Ind Tech Res Inst | Preparing composition of silver nanowire and method for forming silver nanowire |
| CN102161102A (zh) * | 2011-02-12 | 2011-08-24 | 明基材料有限公司 | 纳米银线及其制造方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003032084A2 (en) | 2001-10-05 | 2003-04-17 | Superior Micropowders Llc | Low viscosity precursor compositions and methods for the deposition of conductive electronic features |
| US7585349B2 (en) | 2002-12-09 | 2009-09-08 | The University Of Washington | Methods of nanostructure formation and shape selection |
| JP4284283B2 (ja) * | 2005-02-02 | 2009-06-24 | Ｄｏｗａエレクトロニクス株式会社 | 銀の粒子粉末の製造法 |
| US7291292B2 (en) | 2005-08-26 | 2007-11-06 | E.I. Du Pont De Nemours And Company | Preparation of silver particles using thermomorphic polymers |
| US7968008B2 (en) | 2006-08-03 | 2011-06-28 | Fry's Metals, Inc. | Particles and inks and films using them |
| JP4846495B2 (ja) * | 2006-09-12 | 2011-12-28 | 住友大阪セメント株式会社 | 平板状軟磁性金属粒子の製造方法 |
| US7922787B2 (en) | 2008-02-02 | 2011-04-12 | Seashell Technology, Llc | Methods for the production of silver nanowires |
| JP5203769B2 (ja) * | 2008-03-31 | 2013-06-05 | 富士フイルム株式会社 | 銀ナノワイヤー及びその製造方法、並びに水性分散物及び透明導電体 |
| JP5306760B2 (ja) * | 2008-09-30 | 2013-10-02 | 富士フイルム株式会社 | 透明導電体、タッチパネル、及び太陽電池パネル |
| US20100242679A1 (en) * | 2009-03-29 | 2010-09-30 | Yi-Hsiuan Yu | Method for continuously fabricating silver nanowire |
| JP2012003900A (ja) * | 2010-06-15 | 2012-01-05 | Fujifilm Corp | 導電膜及びその製造方法、並びにタッチパネル及び集積型太陽電池 |
| EP2632850B1 (en) * | 2010-12-14 | 2015-12-09 | LG Innotek Co., Ltd. | Nano wire and method for manufacturing the same |
| KR101966031B1 (ko) * | 2010-12-17 | 2019-04-04 | 세이코 피엠씨 가부시키가이샤 | 은 나노와이어의 제조방법 및 은 나노와이어 성장 제어제 |
| WO2014138749A1 (en) * | 2013-03-08 | 2014-09-12 | Innova Dynamics, Inc. | Production of nanostructures |
-
2013
- 2013-04-05 US US13/857,407 patent/US9034075B2/en not_active Expired - Fee Related
- 2013-04-08 JP JP2013080124A patent/JP6104681B2/ja not_active Expired - Fee Related
- 2013-04-12 TW TW102113018A patent/TWI481566B/zh not_active IP Right Cessation
- 2013-04-25 DE DE102013007194A patent/DE102013007194A1/de not_active Withdrawn
- 2013-04-25 CN CN201310148815.XA patent/CN103372653B/zh not_active Expired - Fee Related
- 2013-04-29 KR KR1020130047355A patent/KR102074702B1/ko not_active Expired - Fee Related
- 2013-04-30 FR FR1353963A patent/FR2989908A1/fr not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101111334A (zh) * | 2005-02-02 | 2008-01-23 | 同和电子科技有限公司 | 银粒子粉末及其制造方法 |
| TW201024002A (en) * | 2008-12-23 | 2010-07-01 | Ind Tech Res Inst | Preparing composition of silver nanowire and method for forming silver nanowire |
| CN102161102A (zh) * | 2011-02-12 | 2011-08-24 | 明基材料有限公司 | 纳米银线及其制造方法 |
Non-Patent Citations (1)
| Title |
|---|
| Rapid synthesis of silver nanowires through a CuCl- or CuCl2-mediated polyol process;Kylee E. Korte 等;《Journal of Materials Chemistry》;20081231;第18卷(第4期);437-441 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US9034075B2 (en) | 2015-05-19 |
| KR102074702B1 (ko) | 2020-02-07 |
| FR2989908A1 (fr) | 2013-11-01 |
| JP2013231231A (ja) | 2013-11-14 |
| JP6104681B2 (ja) | 2017-03-29 |
| US20130283974A1 (en) | 2013-10-31 |
| CN103372653A (zh) | 2013-10-30 |
| TWI481566B (zh) | 2015-04-21 |
| KR20130122568A (ko) | 2013-11-07 |
| DE102013007194A1 (de) | 2013-10-31 |
| TW201350436A (zh) | 2013-12-16 |
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