CN102764590B - 含铁铝硅酸盐沸石及其制备和使用方法 - Google Patents

含铁铝硅酸盐沸石及其制备和使用方法 Download PDF

Info

Publication number
CN102764590B
CN102764590B CN201210123893.XA CN201210123893A CN102764590B CN 102764590 B CN102764590 B CN 102764590B CN 201210123893 A CN201210123893 A CN 201210123893A CN 102764590 B CN102764590 B CN 102764590B
Authority
CN
China
Prior art keywords
iron
zeolite
waste gas
zeolites
scr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201210123893.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN102764590A (zh
Inventor
黎鸿昕
B·莫登
W·E·科米尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PQ Corp
Original Assignee
PQ Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PQ Corp filed Critical PQ Corp
Publication of CN102764590A publication Critical patent/CN102764590A/zh
Application granted granted Critical
Publication of CN102764590B publication Critical patent/CN102764590B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
    • B01J29/68—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/69—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7815—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
CN201210123893.XA 2007-08-13 2008-08-13 含铁铝硅酸盐沸石及其制备和使用方法 Expired - Fee Related CN102764590B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US93543607P 2007-08-13 2007-08-13
US60/935,436 2007-08-13

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN2008801030115A Division CN101827654B (zh) 2007-08-13 2008-08-13 含铁铝硅酸盐沸石及其制备和使用方法

Publications (2)

Publication Number Publication Date
CN102764590A CN102764590A (zh) 2012-11-07
CN102764590B true CN102764590B (zh) 2015-05-13

Family

ID=40262119

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201210123893.XA Expired - Fee Related CN102764590B (zh) 2007-08-13 2008-08-13 含铁铝硅酸盐沸石及其制备和使用方法
CN2008801030115A Active CN101827654B (zh) 2007-08-13 2008-08-13 含铁铝硅酸盐沸石及其制备和使用方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2008801030115A Active CN101827654B (zh) 2007-08-13 2008-08-13 含铁铝硅酸盐沸石及其制备和使用方法

Country Status (5)

Country Link
US (2) US8541331B2 (enExample)
EP (2) EP2689846A1 (enExample)
JP (2) JP6176891B2 (enExample)
CN (2) CN102764590B (enExample)
WO (1) WO2009023202A2 (enExample)

Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7998423B2 (en) 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
BRPI0808091A2 (pt) * 2007-02-27 2014-07-15 Basf Catalysts Llc Catalisador, sistema de tratamento de gás de exaustão, processo para a redução de óxidos de nitrogênio, e, artigo de catalisador.
US10384162B2 (en) * 2007-03-26 2019-08-20 Pq Corporation High silica chabazite for selective catalytic reduction, methods of making and using same
US20100290963A1 (en) 2007-04-26 2010-11-18 Johnson Matthey Public Limited Company Transition metal / zeolite scr catalysts
US20090196812A1 (en) 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
WO2009146955A1 (en) * 2008-06-06 2009-12-10 Total Petrochemicals Research Feluy Process for making crystalline metallosilicates
EP2161242A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
KR101251499B1 (ko) * 2008-12-05 2013-04-05 오덱(주) 질소 산화물 제거용 제올라이트 촉매, 이의 제조 방법 및 이를 이용한 질소 산화물 제거 방법
EP2462059B1 (en) 2009-06-18 2016-04-20 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
US8865121B2 (en) 2009-06-18 2014-10-21 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
GB2475740B (en) * 2009-11-30 2017-06-07 Johnson Matthey Plc Catalysts for treating transient NOx emissions
US8293198B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
US8293199B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods
EP2518017B1 (en) * 2009-12-22 2019-07-24 Tosoh Corporation Novel metallosilicate and production method thereof
JP5594121B2 (ja) * 2009-12-22 2014-09-24 東ソー株式会社 新規メタロシリケート及び窒素酸化物浄化触媒
JP5609620B2 (ja) * 2009-12-25 2014-10-22 東ソー株式会社 新規メタロシリケート
US8440586B2 (en) * 2010-02-26 2013-05-14 Corning Incorporated Low pressure drop extruded catalyst filter
JP5882238B2 (ja) * 2010-03-11 2016-03-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ ＮＯｘの選択触媒還元のための無秩序なモレキュラーシーブ担体
US9352307B2 (en) * 2010-04-08 2016-05-31 Basf Corporation Cu-CHA/Fe-MFI mixed zeolite catalyst and process for the treatment of NOx in gas streams
MX360154B (es) * 2010-04-08 2018-10-24 Basf Se Catalizador de zeolita mixta de cu-cha/fe-mfi y proceso para tratar nox en corriente de gas usando el mismo.
RU2641771C1 (ru) * 2010-05-21 2018-01-22 ПиКью КОРПОРЕЙШН СПОСОБ СИНТЕЗА НОВОГО СОДЕРЖАЩЕГО ЖЕЛЕЗО ЦЕОЛИТА БЕТА ДЛЯ ВОССТАНОВЛЕНИЯ NOx
FR2962923B1 (fr) * 2010-07-22 2015-01-02 Peugeot Citroen Automobiles Sa Composition catalytique et dispositif de traitement des gaz comprenant une telle composition
US8987162B2 (en) 2010-08-13 2015-03-24 Ut-Battelle, Llc Hydrothermally stable, low-temperature NOx reduction NH3-SCR catalyst
US8987161B2 (en) 2010-08-13 2015-03-24 Ut-Battelle, Llc Zeolite-based SCR catalysts and their use in diesel engine emission treatment
EP2441513B1 (en) * 2010-10-13 2013-08-07 Ibiden Co., Ltd. Honeycomb catalyst body and method for manufacturing honeycomb catalyst body
JP5625735B2 (ja) * 2010-10-22 2014-11-19 東ソー株式会社 高耐熱水性ｓｃｒ触媒及びその製造方法
CN102464326B (zh) * 2010-11-04 2013-10-09 中国石油化工股份有限公司 合成高硅丝光沸石的方法
RU2614411C2 (ru) * 2010-12-02 2017-03-28 Джонсон Мэтти Паблик Лимитед Компани Цеолитный катализатор, содержащий металл
JP6104882B2 (ja) * 2011-04-04 2017-03-29 ピーキュー コーポレイション Ｆｅ−ＳＡＰＯ−３４触媒及びその製造方法
KR101830326B1 (ko) * 2011-04-18 2018-02-20 피큐 코포레이션 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법
CN103534210B (zh) * 2011-05-17 2015-12-09 东曹株式会社 β型硅酸铁组合物和氮氧化物还原方法
EP2753578B1 (en) * 2011-09-09 2020-07-29 Basf Se Process for the organotemplate-free synthetic production of a zeolitic material using recycled mother liquor
JP5821540B2 (ja) * 2011-11-07 2015-11-24 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5817522B2 (ja) * 2011-12-28 2015-11-18 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5970927B2 (ja) * 2012-04-05 2016-08-17 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5988743B2 (ja) * 2012-07-18 2016-09-07 ユニゼオ株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
JP6028195B2 (ja) * 2012-07-19 2016-11-16 株式会社ゼオライト・アーティフィシャル ゼオライト金属塩複合体及びその製造方法
JP6127232B2 (ja) * 2012-07-19 2017-05-17 株式会社 Ａｃｒ 抗シンタリング触媒
CN107335425B (zh) 2012-08-17 2020-12-01 庄信万丰股份有限公司 沸石助催化的V/Ti/W催化剂
CA2888517C (en) 2012-10-19 2020-10-06 Basf Corporation 8-ring small pore molecular sieve as high temperature scr catalyst
RU2015118441A (ru) 2012-10-19 2016-12-10 Басф Корпорейшн Мелкопористые молекулярные сита с 8-членными кольцами и с промотором для улучшения низкотемпературных характеристик
JP6058433B2 (ja) 2013-03-12 2017-01-11 ユニゼオ株式会社 ハイドロカーボンリフォーマトラップ材及びハイドロカーボンの除去方法
JP6153196B2 (ja) 2013-06-14 2017-06-28 ユニゼオ株式会社 Ｍｎ＋置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素の除去方法
WO2015077484A1 (en) 2013-11-25 2015-05-28 University Of Idaho Biochar water treatment
KR102299703B1 (ko) * 2013-12-02 2021-09-09 존슨 맛쎄이 퍼블릭 리미티드 컴파니 고실리카 Cu-CHA의 혼합 주형 합성
US20150231620A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc IRON-ZEOLITE CHABAZITE CATALYST FOR USE IN NOx REDUCTION AND METHOD OF MAKING
US20150231617A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc Fe-SAPO-34 CATALYST FOR USE IN NOX REDUCTION AND METHOD OF MAKING
GB2543166A (en) * 2014-02-28 2017-04-12 Johnson Matthey Plc SCR Catalysts having improved low temperature performance and methods of making and using the same
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
JP6126141B2 (ja) * 2014-05-30 2017-05-10 トヨタ自動車株式会社 排ガス浄化用触媒の製造方法
EP3189020B1 (en) 2014-09-03 2020-12-23 Corning Incorporated Exhaust filter with active plugs
DE102015119596A1 (de) * 2014-11-14 2016-05-19 Johnson Matthey Public Limited Company Afx-zeolith
GB2537206A (en) 2015-01-29 2016-10-12 Johnson Matthey Plc Direct incorporation of iron complexes into SAPO-34 (CHA) type materials
CN105032163A (zh) * 2015-07-02 2015-11-11 黄立维 一种从气流中去除氮氧化物和二氧化硫的方法及其装置
WO2017109705A1 (en) * 2015-12-22 2017-06-29 Basf Corporation Process for preparing iron(iii)-exchanged zeolite composition
WO2017134006A1 (en) * 2016-02-01 2017-08-10 Haldor Topsøe A/S Method for the direct synthesis of iron-containing aei-zeolite catalyst
CN105921170A (zh) * 2016-05-03 2016-09-07 新疆大学 用于烟气脱硝的新型纳米级FeZSM-5催化剂的技术方法
KR101679793B1 (ko) * 2016-06-08 2016-11-25 한국건설기술연구원 철성분 함유 다공성 제올라이트의 제조방법 및 이에 의해 제조된 다공성 제올라이트
CN106187595A (zh) * 2016-07-12 2016-12-07 山东胜伟园林科技有限公司 一种基于脱硫石膏的盐碱地改良肥的配方
KR102443392B1 (ko) * 2016-08-05 2022-09-15 바스프 코포레이션 선택적 접촉 환원 물품 및 시스템
AU2018301347B2 (en) * 2017-07-11 2021-07-15 Shell Internationale Research Maatschappij B.V. Catalyst and method of use thereof in the conversion of NOX and N2O
EP3651900A1 (en) * 2017-07-11 2020-05-20 Shell Internationale Research Maatschappij B.V. A catalyst and method of use thereof
CN107899608B (zh) * 2017-11-24 2020-07-28 中国科学院长春应用化学研究所 一种自支撑金属改性Beta分子筛的制备方法及其在合成异戊二烯中的应用
CN108217681B (zh) * 2018-01-19 2021-07-06 山东齐鲁华信高科有限公司 一种高铁含量的Fe-ZSM-5分子筛的制备方法
US11267717B2 (en) * 2018-03-21 2022-03-08 Basf Corporation CHA zeolite material and related method of synthesis
US20190321761A1 (en) * 2018-04-18 2019-10-24 Kohler Co. Filter member and method of making same
JP7176717B2 (ja) * 2018-05-02 2022-11-22 公立大学法人北九州市立大学 ゼオライト構造体・ゼオライト担持白金構造体とゼオライト構造体の製造方法、１，３－ブタジエンの製造方法
CN108751335A (zh) * 2018-05-04 2018-11-06 中山大学 一种光-芬顿体系协同催化氧化降解水环境中抗生素的方法
US11278874B2 (en) * 2018-11-30 2022-03-22 Johnson Matthey Public Limited Company Enhanced introduction of extra-framework metal into aluminosilicate zeolites
GB201900484D0 (en) * 2019-01-14 2019-02-27 Johnson Matthey Catalysts Germany Gmbh Iron-loaded small pore aluminosilicate zeolites and method of making metal loaded small pore aluminosilicate zeolites
DE112020000444T5 (de) * 2019-01-18 2021-09-30 Cummins Emission Solutions Inc. Behandelte SCR-Katalysatoren mit verbesserter Schwefelbeständigkeit
WO2020222105A2 (en) * 2019-04-27 2020-11-05 Sud Chemie India Pvt. Ltd. Methods of preparation of metal exchanged zeolites
JP2022545638A (ja) 2019-08-29 2022-10-28 ビーエーエスエフ コーポレーション 鉄促進化ゼオライトおよびそれから作製された触媒
CN114728802B (zh) 2019-11-19 2024-12-17 巴斯夫公司 沸石合成
US20240174524A1 (en) * 2022-11-29 2024-05-30 Saudi Arabian Oil Company Method for synthesizing nano-sized zeolite beta
CN118047392A (zh) * 2024-01-08 2024-05-17 黄冈师范学院 一种Fe-Beta分子筛、制备及作为脱硝催化剂的应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2659840B2 (ja) * 1990-02-05 1997-09-30 三菱重工業株式会社 窒素酸化物含有排ガスの浄化方法
CN1320475A (zh) * 2000-04-22 2001-11-07 dmc2德古萨金属催化剂塞尔德克股份公司 还原氮氧化物的方法及催化剂

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185136A (en) * 1985-08-08 1993-02-09 Exxon Research And Engineering Co. Trivalent transition-metal-aluminosilicate hydrocarbon conversion catalysts having mazzite-like structures, ECR-23-T (C-2491)
US4952385A (en) 1987-03-02 1990-08-28 Georgia Tech Research Corp. Ferrisilicate molecular sieve and use as a catalyst
DD281172A5 (de) * 1988-03-28 1990-08-01 Akad Wissenschaften Ddr Zeolithischer katalysator und verfahren zu seiner herstellung
US4961917A (en) 1989-04-20 1990-10-09 Engelhard Corporation Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts
JPH05305240A (ja) * 1992-04-27 1993-11-19 N E Chemcat Corp 排気ガス浄化用触媒
US5451387A (en) 1994-07-07 1995-09-19 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
JP3839565B2 (ja) * 1997-01-20 2006-11-01 日本碍子株式会社 高シリカ珪酸塩系分子篩の合成方法
FR2789911B1 (fr) 1999-02-18 2001-05-04 Grande Paroisse Sa Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent
US6689709B1 (en) 2000-11-15 2004-02-10 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
US6914026B2 (en) * 2001-09-07 2005-07-05 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
AU2002347682A1 (en) 2002-11-25 2004-06-18 Yara International Asa Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement
FR2869894B1 (fr) * 2004-05-10 2007-02-23 Inst Francais Du Petrole Methode de synthese de metalloaluminosilicate cristallise par synthese directe
JP4957176B2 (ja) * 2006-10-24 2012-06-20 東ソー株式会社 窒素酸化物浄化触媒及び窒素酸化物浄化方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2659840B2 (ja) * 1990-02-05 1997-09-30 三菱重工業株式会社 窒素酸化物含有排ガスの浄化方法
CN1320475A (zh) * 2000-04-22 2001-11-07 dmc2德古萨金属催化剂塞尔德克股份公司 还原氮氧化物的方法及催化剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Evolution of isomorphously substituted iron zeolites during activation: comparison of Fe-beta and Fe-ZSM-5;J.Perez-Ramirez et al;《Journal of Catalysis》;20050305;第232卷;318-334 *

Also Published As

Publication number Publication date
CN101827654A (zh) 2010-09-08
US8541331B2 (en) 2013-09-24
WO2009023202A3 (en) 2009-04-23
EP2192982A2 (en) 2010-06-09
JP2015205270A (ja) 2015-11-19
WO2009023202A2 (en) 2009-02-19
EP2689846A1 (en) 2014-01-29
US8512659B2 (en) 2013-08-20
JP2010536692A (ja) 2010-12-02
JP6176891B2 (ja) 2017-08-09
US20100143224A1 (en) 2010-06-10
US20090048095A1 (en) 2009-02-19
CN101827654B (zh) 2013-11-06
CN102764590A (zh) 2012-11-07

Similar Documents

Publication Publication Date Title
CN102764590B (zh) 含铁铝硅酸盐沸石及其制备和使用方法
US11786864B2 (en) Metal-containing zeolite beta for NOx reduction and methods of making the same
EP2150328B1 (en) SCR METHOD AND SYSTEM USING Cu/SAPO-34 ZEOLITE CATALYST
CN110546108B (zh) 具有低碱金属含量的含铜小孔沸石、其制备方法以及它们作为scr催化剂的用途
JP2009519817A (ja) Ｎｏｘ選択的触媒還元効率の改善されたゼオライト触媒
JP6509877B2 (ja) 有機テンプレートを使用しない合成による二金属交換ゼオライトベータ、およびＮＯｘの選択触媒還元においてそれを使用する方法
US20150290632A1 (en) IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
US20170050179A1 (en) Copper-containing kfi-type zeolite and use in scr catalysis
CN113710360B (zh) 快速合成含有具有afx结构的沸石和用于选择性nox还原的至少一种过渡金属的催化剂
CN110961144A (zh) 一种具有cha/lev拓扑结构共生复合分子筛及其制备方法和scr应用
US20240075466A1 (en) One-Pot Synthesis of Transition Metal-Promoted Chabazites
CN107362824A (zh) 获自无有机模板合成法的含铁和铜的沸石β
RU2575727C2 (ru) НОВЫЙ МЕТАЛЛОСОДЕРЖАЩИЙ ЦЕОЛИТ БЕТА ДЛЯ ВОССТАНОВЛЕНИЯ NOx И СПОСОБ ЕГО ИСПОЛЬЗОВАНИЯ
JP2024520348A (ja) Ｎｏｘ吸着用パラジウム含有ａｆｘゼオライト触媒の合成
JPH06170169A (ja) 窒素酸化物の除去方法
JPH0760064A (ja) 窒素酸化物除去方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150513

Termination date: 20210813