CN102482383B - 通过自由基引发聚合制备羟芳基-官能化共聚体的方法 - Google Patents

通过自由基引发聚合制备羟芳基-官能化共聚体的方法 Download PDF

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Publication number
CN102482383B
CN102482383B CN201080038976.8A CN201080038976A CN102482383B CN 102482383 B CN102482383 B CN 102482383B CN 201080038976 A CN201080038976 A CN 201080038976A CN 102482383 B CN102482383 B CN 102482383B
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polymkeric substance
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approximately
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compound
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Chinese (zh)
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CN102482383A (zh
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燕远勇
秦增全
潘晓东
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Bridgestone Corp
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Bridgestone Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
  • Materials Engineering (AREA)
CN201080038976.8A 2009-07-01 2010-07-01 通过自由基引发聚合制备羟芳基-官能化共聚体的方法 Expired - Fee Related CN102482383B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US22247709P 2009-07-01 2009-07-01
US22231009P 2009-07-01 2009-07-01
US61/222,477 2009-07-01
US61/222,310 2009-07-01
PCT/US2010/040784 WO2011002994A2 (en) 2009-07-01 2010-07-01 Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization

Publications (2)

Publication Number Publication Date
CN102482383A CN102482383A (zh) 2012-05-30
CN102482383B true CN102482383B (zh) 2014-07-30

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CN201080038976.8A Expired - Fee Related CN102482383B (zh) 2009-07-01 2010-07-01 通过自由基引发聚合制备羟芳基-官能化共聚体的方法

Country Status (8)

Country Link
US (2) US9926400B2 (https=)
EP (1) EP2448985B1 (https=)
JP (1) JP5889787B2 (https=)
KR (1) KR101728184B1 (https=)
CN (1) CN102482383B (https=)
BR (1) BRPI1015573B1 (https=)
ES (1) ES2533713T3 (https=)
WO (1) WO2011002994A2 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160110557A (ko) 2007-12-28 2016-09-21 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
US9365660B2 (en) 2009-06-30 2016-06-14 Bridgestone Corporation Anionic polymerization initiators and processes
WO2011002830A2 (en) 2009-06-30 2011-01-06 Bridgestone Corporation Polymers functionalized with hydroxyl group-containing diphenylethylene
EP2448985B1 (en) 2009-07-01 2015-01-14 Bridgestone Corporation Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization
EP2576490B1 (en) 2010-05-31 2016-08-31 Bridgestone Corporation Hydroxyl group-containing methylstyrene and polymers incorporating same
US8637600B2 (en) 2010-08-11 2014-01-28 Bridgestone Corporation Processing of rubber compositions including siliceous fillers
FR3027602B1 (fr) 2014-10-27 2017-12-29 Michelin & Cie Procede de synthese d'un polymere porteur de groupement hydroxyaryle, produit issu de ce procede et composition le contenant
FR3027904B1 (fr) * 2014-11-04 2016-12-30 Michelin & Cie Procede de synthese d'un polymere porteur de groupement hydroxyaryle, produit issu de ce procede et composition le contenant
WO2016152310A1 (ja) * 2015-03-25 2016-09-29 日本ゼオン株式会社 重合体、成形材料及び樹脂成形体
FR3040058B1 (fr) 2015-08-13 2019-07-19 Compagnie Generale Des Etablissements Michelin Procede de synthese d'un polymere porteur d'un groupement fonctionnel, produit issu de ce procede et composition le contenant.
FR3043591A1 (fr) 2015-11-13 2017-05-19 Michelin & Cie Composite a base de composant metallique et d'une matrice polymere fonctionnelle

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324804A (en) * 1992-04-29 1994-06-28 Ciba-Geigy Corporation Photoresist material based on polystyrenes

Family Cites Families (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2356128A (en) * 1939-10-20 1944-08-22 Jasco Inc Mixed olefinic polymerization process and product
JPS4941116B1 (https=) 1970-06-29 1974-11-07
JPS4941116A (https=) 1972-09-06 1974-04-17
JPS5853001B2 (ja) * 1974-03-22 1983-11-26 住友化学工業株式会社 シンキエラストマ− ノ セイゾウホウホウ
US4182803A (en) * 1973-06-07 1980-01-08 Sumitomo Chemical Company, Limited Elastomer
US3931107A (en) 1973-06-21 1976-01-06 Phillips Petroleum Company Polyalkoxy monovinylaromatic compound in copolymerization of a conjugated diene with a monovinyl-substituted aromatic compound
US4181545A (en) * 1977-04-28 1980-01-01 United Technologies Corporation Hydroxylic aromatic compounds as additives for rubber-based, composite solid propellants
US4321343A (en) * 1980-10-17 1982-03-23 W. R. Grace & Co. Polyisobutylene/phenol polymers treated with diisocyanates and poly(oxyalkylene)polyols
JPS58189203A (ja) * 1982-04-30 1983-11-04 Nippon Zeon Co Ltd ゴム組成物
US4499243A (en) * 1983-11-07 1985-02-12 Monsanto Company Method of treating diene rubber with amino- and hydroxy aryl compounds
US4678843A (en) 1986-09-29 1987-07-07 Celanese Corporation Process for the ammonium hydroxide hydrolysis of polymers of acetoxystyrene to polymers of vinylphenol
JPS6475527A (en) * 1987-09-18 1989-03-22 Sumitomo Chemical Co Production of thermoplastic resin composition
US5153291A (en) * 1988-06-28 1992-10-06 Bayer Aktiengesellschaft Trialkylsilyloxy-1,1-diphenyl ethylenes and polymers produced therewith
CA2000710A1 (en) * 1988-10-21 1990-04-21 Richard Vicari Copolymers of 4-hydroxystyrene and alkyl substituted-4-hydroxystyrene
US4975491A (en) * 1989-01-18 1990-12-04 The Dow Chemical Company Functionalized polymers prepared by anionic polymerization
US5081191A (en) * 1989-01-18 1992-01-14 The Dow Chemical Company Functionalized polymers prepared by anionic polymerization
JPH03200811A (ja) * 1989-12-28 1991-09-02 Hitachi Chem Co Ltd 水酸基含有重合体の製造方法
DE4003079A1 (de) 1990-02-02 1991-08-08 Bayer Ag Benzophenonderivate und polymere mit phenolischen hydroxylgruppen
CA2040457A1 (en) 1990-04-30 1991-10-31 Timothy E. Long Block copolymers containing poly(1,3-conjugated dienes) and poly (vinylphenols), silyl protected poly (vinylphenols) or poly (metal phenolates)
JP3057508B2 (ja) * 1990-06-21 2000-06-26 日本曹達株式会社 ｐ―アルケニルフェノール系重合体の製造方法
JP2987949B2 (ja) * 1991-01-25 1999-12-06 三菱化学株式会社 多孔性樹脂及びその製造方法
FR2677544B1 (fr) * 1991-06-14 1993-09-24 Oreal Composition cosmetique contenant un melange de nanopigments d'oxydes metalliques et de pigments melaniques.
US5872167A (en) * 1991-10-16 1999-02-16 The Goodyear Tire & Rubber Company Rubber stocks containing a metal salt of hydroxy aryl substituted maleamic acid
US5362819A (en) * 1992-01-30 1994-11-08 Gencorp Inc. Polyester-flexible polymer block copolymers and mixtures thereof
JPH05230126A (ja) 1992-02-25 1993-09-07 Nippon Steel Chem Co Ltd 芳香族ヒドロキシル基を有するスチレン系ポリマーとその製造法
US5455307A (en) * 1992-04-03 1995-10-03 Exxon Chemical Patents Inc. Polymeric stabilizers for polyolefins
US5674798A (en) * 1992-10-16 1997-10-07 Bridgestone Corporation Hydrocarbon soluble anionic polymerization initiators
US5302662A (en) * 1993-02-19 1994-04-12 Eastman Kodak Company Compatible polyamide blends
US5336726A (en) * 1993-03-11 1994-08-09 Shell Oil Company Butadiene polymers having terminal silyl groups
US5310811A (en) * 1993-09-22 1994-05-10 The Goodyear Tire & Rubber Company Free radical cured rubber employing acrylate or methacrylate esters of hydroxybenzene and hydroxynaphthalene compounds as co-curing agents
JP3246172B2 (ja) 1994-03-18 2002-01-15 住友化学工業株式会社 ゴム組成物およびそれを用いるスチールコードとの加硫接着方法
EP0745655A3 (en) 1995-06-02 1998-04-29 National Starch and Chemical Investment Holding Corporation Dissipative laminating adhesive
US5780551A (en) * 1995-11-02 1998-07-14 Fmc Corporation Telechelic polymers from mixed initiator
FR2746803B1 (fr) * 1996-03-29 1998-04-24 Ceca Sa Resines novolaques phenol/diene, procede de preparation et compositions a base de caoutchouc renfermant lesdites resines
US6242522B1 (en) * 1998-03-24 2001-06-05 Bridgestone Corporation Rubber composition for tire tread and pneumatic tire using same
JPH11286524A (ja) 1998-03-31 1999-10-19 Nippon Zeon Co Ltd ジエン系ゴム、その製造方法、およびゴム組成物
US6291723B1 (en) * 1999-09-02 2001-09-18 Borden Chemical, Inc. Diolefin/hydroxyaryl condensates and catalyst therefor
WO2001034658A1 (en) * 1999-11-12 2001-05-17 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
US6699935B2 (en) * 2000-06-29 2004-03-02 Jsr Corporation Rubber composition
EP1184415A3 (en) * 2000-08-30 2003-08-06 JSR Corporation Conjugated diene-based rubber, oil extended rubber and rubber composition containing the same
US20030087338A1 (en) * 2001-07-20 2003-05-08 Messersmith Phillip B. Adhesive DOPA-containing polymers and related methods of use
US7858679B2 (en) * 2001-07-20 2010-12-28 Northwestern University Polymeric compositions and related methods of use
US8815793B2 (en) * 2001-07-20 2014-08-26 Northwestern University Polymeric compositions and related methods of use
US7618937B2 (en) * 2001-07-20 2009-11-17 Northwestern University Peptidomimetic polymers for antifouling surfaces
CN100347208C (zh) 2001-09-27 2007-11-07 Jsr株式会社 共轭二烯均聚或共聚橡胶、均聚或共聚橡胶的制造方法、橡胶组合物、复合体以及轮胎
US6838539B2 (en) * 2002-02-12 2005-01-04 Bridgestone Corporation Cureable silane functionalized sealant composition and manufacture of same
JP3797262B2 (ja) * 2002-04-05 2006-07-12 住友化学株式会社 変性ジエン系重合体ゴム、その製造方法及びゴム組成物
WO2004003027A1 (ja) * 2002-06-27 2004-01-08 Asahi Kasei Chemicals Corporation 水添共重合体及びその組成物
WO2004007563A2 (en) * 2002-07-11 2004-01-22 Bridgestone Corporation Preparation of functionalized anionic polymerization initiators
US20080171012A1 (en) * 2007-01-11 2008-07-17 Phillip Messersmith Fouling Resistant Coatings and Methods of Making Same
US8911831B2 (en) * 2002-07-19 2014-12-16 Northwestern University Surface independent, surface-modifying, multifunctional coatings and applications thereof
JP4744144B2 (ja) * 2002-08-30 2011-08-10 株式会社ブリヂストン 官能性ポリマー、及びそれにより改良された加硫物
WO2004042068A2 (en) 2002-10-31 2004-05-21 Northwestern University Injectable and bioadhesive polymeric hydrogels as well as related methods of enzymatic preparation
US7056985B2 (en) 2004-02-11 2006-06-06 University Of Massachusetts Lowell End-capped polymer chains and products thereof
US7226979B2 (en) 2004-02-11 2007-06-05 University Of Massachusetts Lowell Copolymers comprising olefin and protected or unprotected hydroxystyrene units
EP1732529A4 (en) * 2004-03-25 2009-02-25 Univ Michigan GOSSYPOL KOKRISTALLE AND ITS USE
CN100577692C (zh) * 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
KR100644878B1 (ko) * 2005-01-14 2006-11-14 금호폴리켐 주식회사 라디칼 중합법을 이용한 이피디엠의 극성 향상 방법
JP2006225476A (ja) * 2005-02-16 2006-08-31 Shin Etsu Chem Co Ltd ポジ型レジスト材料及びパターン形成方法
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
US7868110B2 (en) * 2005-05-20 2011-01-11 Bridgestone Corporation Anionic polymerization initiators and polymers therefrom
US7816483B2 (en) * 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP4934323B2 (ja) 2006-02-07 2012-05-16 株式会社ブリヂストン 変性天然ゴム及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ
WO2008049108A1 (en) * 2006-10-19 2008-04-24 Northwestern University Surface-independent, surface-modifying, multifunctional coatings and applications thereof
JP4941116B2 (ja) 2007-06-08 2012-05-30 株式会社カネカ 野菜加工品の製造方法および野菜加工品並びにそれを用いた食品
KR20160110557A (ko) * 2007-12-28 2016-09-21 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
JP5256953B2 (ja) * 2008-03-26 2013-08-07 Ｊｓｒ株式会社 感放射線性組成物及びパターン形成方法
EP2141029B1 (en) * 2008-06-30 2011-08-31 The Yokohama Rubber Co., Ltd. Tire rubber composition
WO2011002930A2 (en) 2009-06-30 2011-01-06 Bridgestone Corporation Hydroxyaryl functionalized polymers
US9365660B2 (en) * 2009-06-30 2016-06-14 Bridgestone Corporation Anionic polymerization initiators and processes
WO2011002830A2 (en) 2009-06-30 2011-01-06 Bridgestone Corporation Polymers functionalized with hydroxyl group-containing diphenylethylene
EP2448985B1 (en) * 2009-07-01 2015-01-14 Bridgestone Corporation Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization
JP5288278B2 (ja) * 2009-09-17 2013-09-11 住友ゴム工業株式会社 共重合体ならびにそれを用いたゴム組成物および空気入りタイヤ
WO2011106765A2 (en) 2010-02-28 2011-09-01 Bridgestone Corporation Rubber compositions including siliceous fillers
EP2576490B1 (en) 2010-05-31 2016-08-31 Bridgestone Corporation Hydroxyl group-containing methylstyrene and polymers incorporating same
US8637600B2 (en) * 2010-08-11 2014-01-28 Bridgestone Corporation Processing of rubber compositions including siliceous fillers

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324804A (en) * 1992-04-29 1994-06-28 Ciba-Geigy Corporation Photoresist material based on polystyrenes

Also Published As

Publication number Publication date
WO2011002994A2 (en) 2011-01-06
US8440755B2 (en) 2013-05-14
BRPI1015573B1 (pt) 2019-11-12
WO2011002994A4 (en) 2011-06-03
KR101728184B1 (ko) 2017-04-18
US20110028632A1 (en) 2011-02-03
ES2533713T3 (es) 2015-04-14
KR20120102582A (ko) 2012-09-18
JP5889787B2 (ja) 2016-03-22
US9926400B2 (en) 2018-03-27
JP2013527250A (ja) 2013-06-27
EP2448985A4 (en) 2013-01-16
CN102482383A (zh) 2012-05-30
US20120136091A1 (en) 2012-05-31
BRPI1015573A2 (pt) 2019-04-09
WO2011002994A3 (en) 2011-04-07
EP2448985A2 (en) 2012-05-09
EP2448985B1 (en) 2015-01-14

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