CN102365267B - 作为香精和香料的硫代碳酸酯 - Google Patents
作为香精和香料的硫代碳酸酯 Download PDFInfo
- Publication number
- CN102365267B CN102365267B CN201080015291.1A CN201080015291A CN102365267B CN 102365267 B CN102365267 B CN 102365267B CN 201080015291 A CN201080015291 A CN 201080015291A CN 102365267 B CN102365267 B CN 102365267B
- Authority
- CN
- China
- Prior art keywords
- compound
- formula
- coffee
- ethyl
- essence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003205 fragrance Substances 0.000 title claims description 13
- 239000000796 flavoring agent Substances 0.000 title claims description 9
- 235000019634 flavors Nutrition 0.000 title claims description 9
- WRWHFVRDUAQRIQ-UHFFFAOYSA-N carbonothioic O,O-acid Chemical class OC(O)=S WRWHFVRDUAQRIQ-UHFFFAOYSA-N 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims description 38
- 150000002148 esters Chemical class 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- 235000013599 spices Nutrition 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 7
- -1 methyl Chemical group 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 3
- 235000013353 coffee beverage Nutrition 0.000 description 23
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000284 extract Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000000605 extraction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 210000000214 mouth Anatomy 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- 240000001890 Ribes hudsonianum Species 0.000 description 2
- 235000016954 Ribes hudsonianum Nutrition 0.000 description 2
- 235000001466 Ribes nigrum Nutrition 0.000 description 2
- 241000533293 Sesbania emerus Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 2
- 235000015123 black coffee Nutrition 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- PQLFROTZSIMBKR-UHFFFAOYSA-N ethenyl carbonochloridate Chemical compound ClC(=O)OC=C PQLFROTZSIMBKR-UHFFFAOYSA-N 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 235000021539 instant coffee Nutrition 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000001069 triethyl citrate Substances 0.000 description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 2
- 235000013769 triethyl citrate Nutrition 0.000 description 2
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 1
- XBTDLLKONSPIBM-UHFFFAOYSA-N 2-ethyl-3-(2-methoxyethyl)thiirane Chemical compound CCC1SC1CCOC XBTDLLKONSPIBM-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 241001284615 Frangula californica Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000014109 instant soup Nutrition 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 150000002678 macrocyclic compounds Chemical class 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- XMJHPCRAQCTCFT-UHFFFAOYSA-N methyl chloroformate Chemical compound COC(Cl)=O XMJHPCRAQCTCFT-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 210000001706 olfactory mucosa Anatomy 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 238000002953 preparative HPLC Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
- C07C329/02—Monothiocarbonic acids; Derivatives thereof
- C07C329/04—Esters of monothiocarbonic acids
- C07C329/06—Esters of monothiocarbonic acids having sulfur atoms of thiocarbonic groups bound to acyclic carbon atoms
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/202—Aliphatic compounds
- A23L27/2022—Aliphatic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0011—Aliphatic compounds containing S
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nutrition Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Fats And Perfumes (AREA)
- Seasonings (AREA)
- Tea And Coffee (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0906009.6A GB0906009D0 (en) | 2009-04-07 | 2009-04-07 | Organic compounds |
| GB0906009.6 | 2009-04-07 | ||
| PCT/EP2010/054582 WO2010115920A1 (en) | 2009-04-07 | 2010-04-07 | Carbonothioates as flavours and fragrances |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102365267A CN102365267A (zh) | 2012-02-29 |
| CN102365267B true CN102365267B (zh) | 2014-07-02 |
Family
ID=40750238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080015291.1A Active CN102365267B (zh) | 2009-04-07 | 2010-04-07 | 作为香精和香料的硫代碳酸酯 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8765204B2 (enExample) |
| EP (1) | EP2417105B1 (enExample) |
| JP (1) | JP5805070B2 (enExample) |
| CN (1) | CN102365267B (enExample) |
| BR (1) | BRPI1014384B1 (enExample) |
| GB (1) | GB0906009D0 (enExample) |
| SG (1) | SG174391A1 (enExample) |
| WO (1) | WO2010115920A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6805477B2 (ja) * | 2015-07-30 | 2020-12-23 | 味の素株式会社 | 油脂含有乳風味飲食品のコク味増強方法 |
| DE102015217864A1 (de) * | 2015-09-17 | 2017-03-23 | Henkel Ag & Co. Kgaa | Parfümzusammensetzung mit Geruchsmodulatorverbindungen zur Steigerung der Duftintensität |
| EP3558030A1 (de) * | 2016-12-20 | 2019-10-30 | Symrise AG | Aromamischung zur reduktion des geruchs oder geschmacks biogener amine |
| GB201707639D0 (en) * | 2017-05-12 | 2017-06-28 | Givaudan Sa | Improvements in or relating to organic compounds |
| JP6697429B2 (ja) * | 2017-11-06 | 2020-05-20 | 長谷川香料株式会社 | 新規アルカンチオ酸誘導体および該化合物を含有する香料組成物 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3885051A (en) * | 1972-10-30 | 1975-05-20 | Int Flavors & Fragrances Inc | Flavoring and aromatising with 3-acetyl-2,5-dialkyl furans or thiophenes |
| US3978240A (en) * | 1973-12-30 | 1976-08-31 | Lever Brothers Company | Foodstuff containing a diester of monothiocarbonic acid |
| US6129941A (en) * | 1998-08-21 | 2000-10-10 | Firmenich Sa | 1-methoxy-3-hexanethiol and its S-acetyl derivative as perfuming and flavoring ingredients |
| EP1264547A1 (en) * | 2001-06-06 | 2002-12-11 | Givaudan SA | Flavour and fragrance compositions |
| WO2007033508A2 (en) * | 2005-09-21 | 2007-03-29 | Givaudan Sa | Organic compounds |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1379019A (en) | 1970-12-07 | 1975-01-02 | Unilever Ltd | Flavouring food products |
| NZ328102A (en) * | 1996-06-24 | 1998-04-27 | Givaudan Roure Int | Fragrance precursors and deodorant compositions |
| DE60131930T2 (de) | 2000-07-07 | 2008-12-11 | Quest International Services B.V. | Thiocarbonate als Vorläufer von Aromavermittler |
| DE10323703A1 (de) * | 2003-05-22 | 2004-12-23 | Beiersdorf Ag | Mikrobizide Zubereitungen und ihre Verwendung |
-
2009
- 2009-04-07 GB GBGB0906009.6A patent/GB0906009D0/en not_active Ceased
-
2010
- 2010-04-07 BR BRPI1014384A patent/BRPI1014384B1/pt active IP Right Grant
- 2010-04-07 CN CN201080015291.1A patent/CN102365267B/zh active Active
- 2010-04-07 US US13/262,267 patent/US8765204B2/en active Active
- 2010-04-07 WO PCT/EP2010/054582 patent/WO2010115920A1/en not_active Ceased
- 2010-04-07 JP JP2012504006A patent/JP5805070B2/ja active Active
- 2010-04-07 EP EP10714876A patent/EP2417105B1/en active Active
- 2010-04-07 SG SG2011066370A patent/SG174391A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3885051A (en) * | 1972-10-30 | 1975-05-20 | Int Flavors & Fragrances Inc | Flavoring and aromatising with 3-acetyl-2,5-dialkyl furans or thiophenes |
| US3978240A (en) * | 1973-12-30 | 1976-08-31 | Lever Brothers Company | Foodstuff containing a diester of monothiocarbonic acid |
| US6129941A (en) * | 1998-08-21 | 2000-10-10 | Firmenich Sa | 1-methoxy-3-hexanethiol and its S-acetyl derivative as perfuming and flavoring ingredients |
| EP1264547A1 (en) * | 2001-06-06 | 2002-12-11 | Givaudan SA | Flavour and fragrance compositions |
| WO2007033508A2 (en) * | 2005-09-21 | 2007-03-29 | Givaudan Sa | Organic compounds |
Non-Patent Citations (4)
| Title |
|---|
| 《中国含硫香料的现状和发展趋势》;孙宝国等;《2006年中国香料香精学术研讨会论文集》;20061231;第99-102页 * |
| 《我国含硫香料研究进展》;郑福平等;《精细化工原料及中间体》;20060228(第2期);第5-6页 * |
| 孙宝国等.《中国含硫香料的现状和发展趋势》.《2006年中国香料香精学术研讨会论文集》.2006,第99-102页. |
| 郑福平等.《我国含硫香料研究进展》.《精细化工原料及中间体》.2006,(第2期),第5-6页. |
Also Published As
| Publication number | Publication date |
|---|---|
| US8765204B2 (en) | 2014-07-01 |
| BRPI1014384B1 (pt) | 2019-01-29 |
| GB0906009D0 (en) | 2009-05-20 |
| BRPI1014384A2 (pt) | 2016-05-24 |
| WO2010115920A1 (en) | 2010-10-14 |
| JP5805070B2 (ja) | 2015-11-04 |
| SG174391A1 (en) | 2011-11-28 |
| CN102365267A (zh) | 2012-02-29 |
| EP2417105A1 (en) | 2012-02-15 |
| US20120052178A1 (en) | 2012-03-01 |
| JP2012522826A (ja) | 2012-09-27 |
| EP2417105B1 (en) | 2013-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105419944B (zh) | 一种香草巧克力香精及其在卷烟中的应用 | |
| CN101522052B (zh) | 香料组合物 | |
| JP5153195B2 (ja) | コーヒーの淹れたて感賦与剤 | |
| CN102365267B (zh) | 作为香精和香料的硫代碳酸酯 | |
| CN107920572A (zh) | 抹茶香味改善剂 | |
| JP4360654B1 (ja) | 香酸柑橘様香味増強剤 | |
| CN109135925A (zh) | 水蜜桃味香精配方 | |
| JP6525492B2 (ja) | ウーロン茶飲料及びその製造方法 | |
| JP4088905B2 (ja) | エーテル化合物を含有するフレーバー組成物 | |
| CN116103086A (zh) | 茶类香味赋予组合物 | |
| JP6065206B2 (ja) | 香料組成物 | |
| JP6859419B1 (ja) | ３−メルカプト−３−メチルペンチル アセテートおよび香味付与剤 | |
| JP4783421B2 (ja) | ゴマ様香味増強剤 | |
| EP3621953B1 (en) | Alkenyl carbonothioates as flavour ingredients | |
| US20060251786A1 (en) | Cyclopropanated coumarin derivatives | |
| JP2021143150A (ja) | 含硫化合物および香味付与剤 | |
| JP7469281B2 (ja) | 抹茶香味付与組成物 | |
| JP3745725B2 (ja) | バニラ風味の補強、改善 | |
| JP2005046056A (ja) | 茶系フレーバー | |
| JPH06287591A (ja) | 香料組成物 | |
| JPH08109390A (ja) | 香料組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |