CN102143932A - 使用负载金属催化剂由乙酸直接选择性制备乙醛 - Google Patents

使用负载金属催化剂由乙酸直接选择性制备乙醛 Download PDF

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Publication number
CN102143932A
CN102143932A CN2009801340830A CN200980134083A CN102143932A CN 102143932 A CN102143932 A CN 102143932A CN 2009801340830 A CN2009801340830 A CN 2009801340830A CN 200980134083 A CN200980134083 A CN 200980134083A CN 102143932 A CN102143932 A CN 102143932A
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China
Prior art keywords
catalyst
iron
support
dioxide
silicon
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Pending
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CN2009801340830A
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English (en)
Chinese (zh)
Inventor
V·J·约翰斯顿
J·H·津克
L·陈
B·F·金米奇
J·T·查普曼
J·C·范德瓦尔
V·祖赞纽克
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Celanese International Corp
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Celanese International Corp
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Publication of CN102143932A publication Critical patent/CN102143932A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/06—Acetaldehyde

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2009801340830A 2008-07-31 2009-07-20 使用负载金属催化剂由乙酸直接选择性制备乙醛 Pending CN102143932A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/221,135 2008-07-31
US12/221,135 US7816565B2 (en) 2008-07-31 2008-07-31 Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst
PCT/US2009/004187 WO2010014146A2 (en) 2008-07-31 2009-07-20 Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst

Publications (1)

Publication Number Publication Date
CN102143932A true CN102143932A (zh) 2011-08-03

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CN2009801340830A Pending CN102143932A (zh) 2008-07-31 2009-07-20 使用负载金属催化剂由乙酸直接选择性制备乙醛

Country Status (14)

Country Link
US (4) US7816565B2 (enExample)
EP (1) EP2318348A2 (enExample)
JP (2) JP5053458B2 (enExample)
KR (1) KR20110047209A (enExample)
CN (1) CN102143932A (enExample)
AR (1) AR074714A1 (enExample)
AU (1) AU2009277184B2 (enExample)
CA (1) CA2732364A1 (enExample)
CO (1) CO6541516A2 (enExample)
IL (1) IL210947A0 (enExample)
RU (1) RU2011107273A (enExample)
TW (1) TW201012785A (enExample)
WO (1) WO2010014146A2 (enExample)
ZA (1) ZA201100790B (enExample)

Cited By (2)

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CN104162446A (zh) * 2014-08-11 2014-11-26 华东理工大学 用于乙酸加氢制备乙醛的催化剂的制备方法
CN113198521A (zh) * 2021-04-30 2021-08-03 江苏常青树新材料科技股份有限公司 一种usy分子筛催化剂的制备方法、及该催化剂在制备二乙烯苯中的应用

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US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8680317B2 (en) * 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8304586B2 (en) * 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US7816565B2 (en) 2008-07-31 2010-10-19 Celanese International Corporation Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst
GB0817109D0 (en) * 2008-09-18 2008-10-29 Johnson Matthey Plc Catalyst and process
US8178715B2 (en) * 2008-12-31 2012-05-15 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde
US8680321B2 (en) * 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
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US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
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US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
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US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
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US8704008B2 (en) 2010-07-09 2014-04-22 Celanese International Corporation Process for producing ethanol using a stacked bed reactor
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
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US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
TW201302684A (zh) 2011-04-26 2013-01-16 Celanese Int Corp 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8853466B2 (en) 2011-08-19 2014-10-07 Celanese International Corporation Integrated process for producing ethanol from methanol
US8829253B2 (en) 2011-08-19 2014-09-09 Celanese International Corporation Integrated process for producing ethanol from methanol
US8853467B2 (en) 2011-08-19 2014-10-07 Celanese International Corporation Integrated process for producing ethanol
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US9353034B2 (en) 2012-02-07 2016-05-31 Celanese International Corporation Hydrogenation process with reduced residence time for vapor phase reactants
US8729311B2 (en) * 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof
US8802903B2 (en) 2012-03-13 2014-08-12 Celanese International Corporation Stacked bed reactor with diluents for producing ethanol
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
CN102658165B (zh) * 2012-04-06 2014-11-05 华东理工大学 乙酸气相加氢制备乙醇的催化剂及其制备方法
US8853469B2 (en) 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
WO2014119185A1 (ja) * 2013-01-30 2014-08-07 株式会社ダイセル アセトアルデヒドの製造方法
DE102013106790A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von 1,3-Butandiol
DE102013106787A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von n-Butanderivaten
WO2015156061A1 (ja) * 2014-04-10 2015-10-15 株式会社ダイセル アセトアルデヒドの製造方法
WO2015163020A1 (ja) * 2014-04-22 2015-10-29 株式会社ダイセル アルデヒド類製造用固体触媒、及びアルデヒド類の製造方法
JP6723151B2 (ja) * 2014-04-28 2020-07-15 株式会社ダイセル 酢酸とアセトアルデヒドと酢酸エチルの製造方法
JP6360801B2 (ja) * 2015-02-19 2018-07-18 株式会社ダイセル 触媒、アルデヒド類及び／又はアルコール類の製造方法
JP6480835B2 (ja) * 2015-09-02 2019-03-13 株式会社ダイセル 固体触媒、固体触媒の製造方法、及びアセトアルデヒドの製造方法
CN105478120B (zh) * 2015-11-18 2017-12-15 河南理工大学 一种赤泥基铁系催化剂的制备方法及其在甲烷裂解制氢中的应用
JP6650351B2 (ja) * 2016-06-21 2020-02-19 株式会社ダイセル 触媒、触媒の製造方法、及びアルデヒド類の製造方法
JP6758113B2 (ja) * 2016-07-12 2020-09-23 株式会社ダイセル 固体触媒、及びアルデヒド類の製造方法
JP2018149507A (ja) * 2017-03-14 2018-09-27 株式会社ダイセル 触媒及びアルデヒド類の製造方法
JP2019107590A (ja) * 2017-12-15 2019-07-04 株式会社ダイセル 触媒、アルデヒド類および／またはアルコール類の製造方法
JP7098434B2 (ja) * 2017-12-20 2022-07-11 株式会社ダイセル 固体触媒、及びアルデヒド類の製造方法
JP7098435B2 (ja) * 2018-06-22 2022-07-11 株式会社ダイセル 固体触媒、及びアルデヒド類の製造方法

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN104162446A (zh) * 2014-08-11 2014-11-26 华东理工大学 用于乙酸加氢制备乙醛的催化剂的制备方法
CN113198521A (zh) * 2021-04-30 2021-08-03 江苏常青树新材料科技股份有限公司 一种usy分子筛催化剂的制备方法、及该催化剂在制备二乙烯苯中的应用
CN113198521B (zh) * 2021-04-30 2023-04-07 江苏常青树新材料科技股份有限公司 一种usy分子筛催化剂的制备方法、及该催化剂在制备二乙烯苯中的应用

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US8227644B2 (en) 2012-07-24
US20100029993A1 (en) 2010-02-04
AR074714A1 (es) 2011-02-09
AU2009277184A2 (en) 2011-02-24
JP5053458B2 (ja) 2012-10-17
WO2010014146A3 (en) 2010-05-06
US7994368B2 (en) 2011-08-09
KR20110047209A (ko) 2011-05-06
US20120283480A1 (en) 2012-11-08
EP2318348A2 (en) 2011-05-11
CA2732364A1 (en) 2010-02-04
JP5108980B2 (ja) 2012-12-26
AU2009277184A1 (en) 2010-02-04
TW201012785A (en) 2010-04-01
ZA201100790B (en) 2012-04-25
US8461395B2 (en) 2013-06-11
JP2011529494A (ja) 2011-12-08
US7816565B2 (en) 2010-10-19
JP2012153698A (ja) 2012-08-16
AU2009277184B2 (en) 2012-12-06
CO6541516A2 (es) 2012-10-16
WO2010014146A2 (en) 2010-02-04
US20110251435A1 (en) 2011-10-13
RU2011107273A (ru) 2012-09-10
IL210947A0 (en) 2011-04-28
US20110004026A1 (en) 2011-01-06

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