CN101679141A - 使用锗-沸石催化剂的烷烃芳基化 - Google Patents

使用锗-沸石催化剂的烷烃芳基化 Download PDF

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Publication number
CN101679141A
CN101679141A CN200880015759A CN200880015759A CN101679141A CN 101679141 A CN101679141 A CN 101679141A CN 200880015759 A CN200880015759 A CN 200880015759A CN 200880015759 A CN200880015759 A CN 200880015759A CN 101679141 A CN101679141 A CN 101679141A
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catalyst
zeolite
hydrogen
germanium
sulfur
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Chinese (zh)
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S·A·施蒂文森
D·B·法默尔
S·F·米切尔
G·G·贾图
A·K·卡马梅多瓦
P·E·艾里斯
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/047—Germanosilicates; Aluminogermanosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
    • C10G45/70—Aromatisation of hydrocarbon oil fractions with catalysts containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200880015759A 2007-04-12 2008-03-20 使用锗-沸石催化剂的烷烃芳基化 Pending CN101679141A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/786,590 2007-04-12
US11/786,590 US7902413B2 (en) 2007-04-12 2007-04-12 Aromatization of alkanes using a germanium-zeolite catalyst
PCT/US2008/003710 WO2008127538A1 (en) 2007-04-12 2008-03-20 Aromatization of alkanes using a germanium-zeolite catalyst

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CN101679141A true CN101679141A (zh) 2010-03-24

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US (1) US7902413B2 (enExample)
EP (1) EP2155633B1 (enExample)
JP (1) JP5576266B2 (enExample)
KR (1) KR101539784B1 (enExample)
CN (1) CN101679141A (enExample)
WO (1) WO2008127538A1 (enExample)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102858723A (zh) * 2010-04-26 2013-01-02 沙特基础工业公司 由丁烯通过易位和芳构化制备丙烯和芳族化合物的方法
CN104321139A (zh) * 2012-06-29 2015-01-28 沙特基础工业公司 锗硅沸石催化剂及制备方法和用途
CN105636693A (zh) * 2013-11-22 2016-06-01 沙特基础工业公司 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂
CN105705235A (zh) * 2013-12-13 2016-06-22 沙特基础工业公司 Cs-Pt/Ge-ZSM-5烃芳构化催化剂组合物和形成方法
CN104271242B (zh) * 2012-05-02 2017-03-15 沙特基础工业公司 用于轻石脑油芳构化的催化剂
US9637692B2 (en) 2010-03-29 2017-05-02 Jx Nippon Oil & Energy Corporation Hydroisomerization catalyst, process for producing the same, method of dewaxing hydrocarbon oil, process for producing hydrocarbon, and process for producing lube base oil
CN106660896A (zh) * 2014-06-26 2017-05-10 Sabic环球技术有限责任公司 用于从混合的烃进料物流生产纯化的芳族烃的方法
CN105142786B (zh) * 2013-04-23 2017-06-27 沙特基础工业公司 制备烃芳构化催化剂的方法、该催化剂以及该催化剂的用途
CN107922857A (zh) * 2015-06-29 2018-04-17 沙特基础工业全球技术有限公司 用于从混合烃原料流生产枯烯和/或乙苯的方法
CN110550640A (zh) * 2018-06-04 2019-12-10 中国石油化工股份有限公司 一种含锗的l型分子筛及制备方法
US10654767B2 (en) 2014-06-26 2020-05-19 Sabic Global Technologies B.V. Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream
CN112517052A (zh) * 2020-12-07 2021-03-19 陕西天元智能再制造股份有限公司 一种ZnCl2-H改性分子筛复合催化剂及其制备方法与用途
CN116273144A (zh) * 2023-03-17 2023-06-23 湖北兴发化工集团股份有限公司 改性丝光沸石制备高比例一甲胺催化剂的制备方法及产品
CN117185892A (zh) * 2022-05-31 2023-12-08 中国石油化工股份有限公司 多产乙苯的烷烃转化方法

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US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1
US8969232B2 (en) 2007-05-24 2015-03-03 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2
WO2008153759A2 (en) 2007-05-24 2008-12-18 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition
US20110132804A1 (en) * 2009-12-04 2011-06-09 Saudi Basic Industries Corporation Increasing octane number of light naphtha using a germanium-zeolite catalyst
US9180441B2 (en) 2012-09-20 2015-11-10 Saudi Basic Industries Corporation Method of forming zeolite shaped body with silica binder
US10682634B2 (en) * 2014-04-01 2020-06-16 Reaction 35, Llc Method for preparation of modified catalysts with high catalytic performance and low coking rate
CN109382116B (zh) * 2017-08-02 2021-08-10 中国石油化工股份有限公司 耐硫变换催化剂及其制备方法
US20210162380A1 (en) 2018-08-30 2021-06-03 Sabic Global Technologies B.V. Aromatization catalyst with improved isomerization, process of making and using thereof
WO2021048693A1 (en) 2019-09-10 2021-03-18 Sabic Global Technologies B.V. Aromatization catalyst with improved isomerization, reactor configurations and use thereof
US11439991B2 (en) * 2019-12-19 2022-09-13 King Fahd University Of Petroleum & Minerals Catalyst compositions for aromatizing hydrocarbons and processes for producing aromatic compounds using the catalyst compositions
CN111604086B (zh) * 2020-06-19 2024-01-19 山东省科学院能源研究所 铂基正构链烷烃芳构化催化剂的制备方法与应用
KR20220064236A (ko) 2020-11-11 2022-05-18 전남대학교산학협력단 포화탄화수소제거용 귀금속 담지 제올라이트 촉매 제조방법 및 그 방법으로 제조된 포화탄화수소제거용 귀금속 담지 제올라이트 촉매
JP2022127708A (ja) * 2021-02-22 2022-09-01 東ソー株式会社 ベンゼンの製造方法
JP7712653B2 (ja) * 2021-04-19 2025-07-24 公立大学法人北九州市立大学 芳香族炭化水素の製造方法
US12264130B2 (en) 2023-05-26 2025-04-01 Saudi Arabian Oil Company Processes for aromatization of naphtha isoparaffins

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9637692B2 (en) 2010-03-29 2017-05-02 Jx Nippon Oil & Energy Corporation Hydroisomerization catalyst, process for producing the same, method of dewaxing hydrocarbon oil, process for producing hydrocarbon, and process for producing lube base oil
CN102858723B (zh) * 2010-04-26 2015-03-25 沙特基础工业公司 由丁烯通过易位和芳构化制备丙烯和芳族化合物的方法
CN102858723A (zh) * 2010-04-26 2013-01-02 沙特基础工业公司 由丁烯通过易位和芳构化制备丙烯和芳族化合物的方法
CN104271242B (zh) * 2012-05-02 2017-03-15 沙特基础工业公司 用于轻石脑油芳构化的催化剂
CN104321139A (zh) * 2012-06-29 2015-01-28 沙特基础工业公司 锗硅沸石催化剂及制备方法和用途
CN105142786B (zh) * 2013-04-23 2017-06-27 沙特基础工业公司 制备烃芳构化催化剂的方法、该催化剂以及该催化剂的用途
CN105636693A (zh) * 2013-11-22 2016-06-01 沙特基础工业公司 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂
CN105636693B (zh) * 2013-11-22 2019-12-13 沙特基础工业公司 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂
CN105705235A (zh) * 2013-12-13 2016-06-22 沙特基础工业公司 Cs-Pt/Ge-ZSM-5烃芳构化催化剂组合物和形成方法
CN106660896A (zh) * 2014-06-26 2017-05-10 Sabic环球技术有限责任公司 用于从混合的烃进料物流生产纯化的芳族烃的方法
US10654767B2 (en) 2014-06-26 2020-05-19 Sabic Global Technologies B.V. Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream
CN114644542A (zh) * 2014-06-26 2022-06-21 Sabic环球技术有限责任公司 用于从混合的烃进料物流生产纯化的芳族烃的方法
CN107922857A (zh) * 2015-06-29 2018-04-17 沙特基础工业全球技术有限公司 用于从混合烃原料流生产枯烯和/或乙苯的方法
CN107922857B (zh) * 2015-06-29 2021-05-25 沙特基础工业全球技术有限公司 用于从混合烃原料流生产枯烯和/或乙苯的方法
CN110550640A (zh) * 2018-06-04 2019-12-10 中国石油化工股份有限公司 一种含锗的l型分子筛及制备方法
CN112517052A (zh) * 2020-12-07 2021-03-19 陕西天元智能再制造股份有限公司 一种ZnCl2-H改性分子筛复合催化剂及其制备方法与用途
CN112517052B (zh) * 2020-12-07 2023-03-28 陕西天元智能再制造股份有限公司 一种ZnCl2-H改性分子筛复合催化剂及其制备方法与用途
CN117185892A (zh) * 2022-05-31 2023-12-08 中国石油化工股份有限公司 多产乙苯的烷烃转化方法
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