CN101534941B - 使用由金簇配合物制备的催化剂的氢化-氧化方法 - Google Patents

使用由金簇配合物制备的催化剂的氢化-氧化方法 Download PDF

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CN101534941B
CN101534941B CN200780042532XA CN200780042532A CN101534941B CN 101534941 B CN101534941 B CN 101534941B CN 200780042532X A CN200780042532X A CN 200780042532XA CN 200780042532 A CN200780042532 A CN 200780042532A CN 101534941 B CN101534941 B CN 101534941B
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catalyst
gold
pph
aupph
hydrogenation
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CN101534941A (zh
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桑迪普·德林拉
里克·施罗德恩
基思·沃森
戴维·巴顿
罗伯特·波曼
拉里·伊托
戴维·特伦特
海科·韦纳
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Dow Global Technologies LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/325—Cyclopropanations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
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  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
CN200780042532XA 2006-11-17 2007-11-07 使用由金簇配合物制备的催化剂的氢化-氧化方法 Expired - Fee Related CN101534941B (zh)

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US85973806P 2006-11-17 2006-11-17
US60/859,738 2006-11-17
PCT/US2007/083859 WO2008063880A1 (en) 2006-11-17 2007-11-07 Hydro-oxidation process using a catalyst prepared from a gold cluster complex

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102962029A (zh) * 2012-12-11 2013-03-13 常州大学 一种造纸废水的处理剂

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090250353A1 (en) * 2006-05-26 2009-10-08 Aicheng Chen Nanoporous Material
JP2010222333A (ja) * 2009-03-25 2010-10-07 Hokkaido Univ Ａｕ１３クラスタ及び金クラスタの製造方法
US9441072B2 (en) * 2009-11-06 2016-09-13 The Regents Of The University Of California Metal colloids with accessible metal surfaces
KR101268280B1 (ko) 2010-12-28 2013-05-28 연세대학교 산학협력단 광촉매 활성을 갖는 금 클러스터 이산화티타늄 나노 복합체, 그 제조방법 및 이를 이용한 유기염료 분해방법
US8617502B2 (en) 2011-02-07 2013-12-31 Cristal Usa Inc. Ce containing, V-free mobile denox catalyst
EP2682206A4 (en) * 2011-03-04 2014-09-17 Toyota Motor Co Ltd METAL PARTS, CATALYST FOR THE PURIFICATION OF PURIFICATION AND MANUFACTURING METHOD THEREFOR
ES2396896B1 (es) * 2011-05-19 2014-01-16 Sumitomo Chemical Company, Limited Proceso para producir óxido de olefina.
HK1198960A1 (en) * 2011-06-10 2015-06-19 因温斯特技术公司 Improvement in metal-ligand catalyst formation
GB201111819D0 (en) * 2011-07-11 2011-08-24 Johnson Matthey Plc Catalyst and method for its preparation
CN103781548B (zh) 2011-08-23 2016-05-04 丰田自动车株式会社 排气用净化催化剂及其制造方法
EP2794089A4 (en) * 2011-12-22 2015-09-09 3M Innovative Properties Co ETHYLENE DISTANCE MEDIUM
JP5943280B2 (ja) * 2012-06-12 2016-07-05 公立大学法人首都大学東京 金クラスター触媒及びその製造方法
US20140081040A1 (en) * 2012-09-20 2014-03-20 Lyondell Chemical Technology, L.P. Process for pre-treatment of a catalyst support and catalyst prepared therefrom
US9931623B2 (en) * 2012-11-30 2018-04-03 Hiroshima University Method for producing metal nanoparticle complex, and metal nanoparticle complex produced by said method
US20170014805A1 (en) * 2014-04-22 2017-01-19 Sabic Global Technologies B.V. Method for the synthesis of supported gold (au) nanoparticles for epoxidation reactions
NL2013836B1 (en) * 2014-11-20 2016-10-10 Univ Delft Tech Production of nanostructured materials.
JP6461663B2 (ja) * 2015-03-20 2019-01-30 高知県公立大学法人 酸化チタン触媒およびその製造方法
CN113603658A (zh) * 2015-08-28 2021-11-05 利安德化学技术有限公司 环氧化工艺及其使用的催化剂
US9849445B2 (en) * 2015-09-28 2017-12-26 Uchicago Argonne, Llc Subnanometer to nanometer transition metal CO oxidation catalysts
AU2016363675A1 (en) * 2015-11-30 2018-07-19 Adelaide Research And Innovation Photocatalytic conversion of carbon dioxide and water into substituted or unsubstituted hydrocarbon(s)
CN105344383B (zh) * 2015-12-11 2018-07-20 中国科学院上海高等研究院 一种载体TiO2及其制备方法与应用
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US10753247B2 (en) * 2018-02-22 2020-08-25 GM Global Technology Operations LLC Bi-metallic oxidation catalyst materials and appurtenant devices and systems
KR102134767B1 (ko) * 2018-06-01 2020-08-26 한국과학기술연구원 Au-Pt 합금을 포함하는 촉매, 이의 제조방법 및 이를 이용한 과산화수소 합성 방법
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EP3862080B1 (en) 2019-09-30 2025-02-12 LG Chem, Ltd. Catalyst for ammoxidation of propylene, method for preparing same, and method for ammoxidation of propylene by using same
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19609301A1 (de) * 1996-03-09 1997-09-11 Veba Oel Ag Clusterbeladene Träger

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4425672A1 (de) * 1994-07-20 1996-01-25 Basf Ag Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
JP2615432B2 (ja) 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
DE19600708A1 (de) 1996-01-11 1997-07-17 Basf Ag Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
DE19623609A1 (de) 1996-06-13 1997-12-18 Basf Ag Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators
DE69708880T2 (de) 1996-07-01 2002-04-11 The Dow Chemical Co., Midland Verfahren zur direkten oxidation von olefinen zu olefinoxiden
US6323351B1 (en) 1997-06-30 2001-11-27 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
US6562986B2 (en) 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
JP4016121B2 (ja) * 1997-09-05 2007-12-05 独立行政法人産業技術総合研究所 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
AU3387099A (en) * 1998-04-15 1999-11-01 Dow Chemical Company, The Process for the direct oxidation of olefins to olefin oxides
ES2190280T3 (es) 1998-12-16 2003-07-16 Dow Global Technologies Inc Procedimiento para la oxidacion directa de olefinas a oxidos de olefina.
JP4646409B2 (ja) * 1999-04-08 2011-03-09 ダウ グローバル テクノロジーズ インコーポレイティド 酸化された金触媒を使用してオレフィンをオレフィンオキシドにハイドロ酸化するための方法
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
JP2001026422A (ja) * 1999-05-10 2001-01-30 Nippon Shokubai Co Ltd 金含有複合体の製造方法
BR0108536A (pt) * 2000-02-22 2003-04-22 Arco Chemical Techinology L P Processo de epoxidação direta empregando composição de catalisador melhorado
BR0211796A (pt) * 2001-08-01 2004-08-03 Dow Global Technologies Inc Método para aumentar a vida útil de um catalisador de hidro-oxidação
AU2003209327A1 (en) 2002-01-23 2003-09-02 Huntsman International Llc Gas-phase process and catalyst for the preparation of propylene oxide
US7081433B2 (en) * 2003-03-12 2006-07-25 The United States Of America As Represented By The Secretary Of The Navy Catalytic three dimensional aerogels having mesoporous nanoarchitecture
RU2359754C2 (ru) 2003-09-26 2009-06-27 Зм Инновейтив Пропертиз Компани Наномерные золотые катализаторы, активаторы, твердые носители и соответствующие методики, применяемые для изготовления таких каталитических систем, особенно при осаждении золота на твердый носитель с использованием конденсации из паровой фазы
EP1776187A1 (en) 2004-07-06 2007-04-25 University College Cardiff Consultants, Ltd. Supported gold catalysts
US7432384B2 (en) * 2005-10-25 2008-10-07 Lyondell Chemical Technology, L.P. Direct epoxidation process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19609301A1 (de) * 1996-03-09 1997-09-11 Veba Oel Ag Clusterbeladene Träger

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102962029A (zh) * 2012-12-11 2013-03-13 常州大学 一种造纸废水的处理剂

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WO2008063880A1 (en) 2008-05-29
CN102309987A (zh) 2012-01-11
JP2010510048A (ja) 2010-04-02
RU2009122732A (ru) 2010-12-27
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ATE527057T1 (de) 2011-10-15
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